CN105968814A - Fire-resistant rubber - Google Patents
Fire-resistant rubber Download PDFInfo
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- CN105968814A CN105968814A CN201610462389.0A CN201610462389A CN105968814A CN 105968814 A CN105968814 A CN 105968814A CN 201610462389 A CN201610462389 A CN 201610462389A CN 105968814 A CN105968814 A CN 105968814A
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- resistant rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to the field of rubber products, and in particular to fire-resistant rubber which is prepared from the following raw materials in parts by weight: 70-80 parts of silicon rubber, 60-70 parts of isoprene rubber, 50-70 parts of fluororubber, 1-5 parts of expanded vermiculite, 15-20 parts of tread rubber powder, 10-20 parts of bentonite, 1-10 parts of asphalt, 1-3 parts of 2-thiol imidazoline, 5-15 parts of coumarone resin, 1-5 parts of methyl methacrylate, 5-10 parts of insoluble sulfur, 1-3 parts of an accelerant, 1-5 parts of a dispersing agent, 1-3 parts of a defoaming agent, 5-10 parts of a wetting agent, 1-5 parts of a penetrant, 5-10 parts of a flame retardant and 5-10 parts of a fire-resistant agent. The fire-resistant rubber prepared according to the formula is good in fire resistance and flame retardancy, has a certain protection function in big fire, and has the advantages of high elasticity, chemical resistance, weather resistance and the like, loss caused by fire can be reduced for people, and the rubber is simple in production process, high in material availability and low in cost.
Description
Technical field
The present invention relates to rubber product field, being specifically related to one can fire-resistant rubber.
Background technology
Elastomeric material belongs to strategic materials, occupies critical role in national defense industry, and various Model engineerings are not nearly all from
Opening rubber product, the especially application on modern opportunity of combat, naval vessels, rocket etc. is too numerous to enumerate；Rubber is also a kind of conventional life
Producing the material of apparatus, the use in daily production is extremely wide, and in use, the most essentially occurs bright
Fire etc., so that elastomeric material burns in use, and then bring certain potential safety hazard to productive life, therefore,
There is provided a kind of can problem that effectively fireproof elastomeric material stone needs solution badly.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of fire-resistant rubber, the present invention is real by following proposal
Existing:
A kind of fire-resistant rubber, including the raw material of following portions by weight, silicone rubber 70-80 part, isoprene rubber 60-70 part, fluorubber
50-70 part, expanded vermiculite 1-5 part, tyre surface rubber powder 15-20 part, bentonite 10-20 part, Colophonium 1-10 part, 2-mercapto imidazoline
1-3 part, coumarone indene resin 5-15 part, methyl methacrylate 1-5 part, insoluble sulfur 5-10 part, accelerator 1-3 part, dispersion
Agent 1-5 part, defoamer 1-3 part, wetting agent 5-10 part, penetrating agent 1-5 part, fire retardant 5-10 part, fireproof agent 5-10 part.
Preferably, a kind of fire-resistant rubber, including the raw material of following portions by weight, silicone rubber 73-77 part, isoprene rubber 63-
67 parts, fluorubber 55-65 part, expanded vermiculite 2-4 part, tyre surface rubber powder 17-19 part, bentonite 13-17 part, Colophonium 3-7 part, 2-sulfur
Alcohol radical imidazoline 2 parts, coumarone indene resin 9-11 part, methyl methacrylate 2-4 part, insoluble sulfur 6-9 part, accelerator 2 parts,
Dispersant 2-4 part, defoamer 2 parts, wetting agent 6-9 part, penetrating agent 2-4 part, fire retardant 6-9 part, fireproof agent 6-9 part.
Preferably, a kind of fire-resistant rubber, including the raw material of following portions by weight, 75 parts of silicone rubber, isoprene rubber 65 parts, fluorine
Rubber 60 parts, expanded vermiculite 3 parts, tyre surface rubber powder 18 parts, bentonite 15 parts, Colophonium 5 parts, 2-mercapto imidazoline 2 parts, coumarone
Resin 10 parts, methyl methacrylate 3 parts, insoluble sulfur 7 parts, accelerator 2 parts, dispersant 3 parts, defoamer 2 parts, wetting agent
8 parts, penetrating agent 3 parts, fire retardant 8 parts, fireproof agent 8 parts.
It is more highly preferred to, above-mentioned accelerator triethylamine, TMTD, tetramethyl thiourea, one or more in BZ.
Being more highly preferred to, above-mentioned dispersant is aliphatic amide type dispersant, and described aliphatic amide type dispersant is for oneself
Thiazolinyl bis-stearamides.
Being more highly preferred to, above-mentioned defoamer is phenethanol oleate, polydimethylsiloxane and hydrophobic silica, described
Defoamer be the mass ratio of phenethanol oleate, polydimethylsiloxane and hydrophobic silica be 1:2:1.
Particularly, above-mentioned wetting agent is nonionic surfactant, and above-mentioned nonionic surfactant is polyoxy second
Allylic alkylation 2, 2-Oxydiphenol, polyoxyethylene aliphatic alcohol ether, any one or more in polyoxyethylene polyoxypropylene block copolymer.
Particularly, during above-mentioned penetrating agent is sulfamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene
Plant or multiple.
More particularly, above-mentioned fire retardant is encapsulated red phosphorus, HBCD, APP, any two kinds in Firebrake ZB.
Wherein, above-mentioned fireproof agent is sodium molybdate, antimony oxide, hexacholorocyclopentadiene, HBCD any one
Plant or multiple.
The invention has the beneficial effects as follows: use the fire-resistant rubber obtained by above-mentioned formula, fire resistance is good, has again good
Good anti-flammability, it is possible to play certain protective effect in big fire, it is possible to reduce the loss brought due to big fire, and
There is the advantages such as high resiliency, chemical resistance, weatherability；This rubber production technology is simple, and material is easy to get, with low cost.
Detailed description of the invention
Embodiment 1
A kind of fire-resistant rubber, including the raw material of following portions by weight, 70 parts of silicone rubber, isoprene rubber 60 parts, fluorubber 50 parts, swollen
Swollen Vermiculitum 1 part, tyre surface rubber powder 15 parts, bentonite 10 parts, Colophonium 1 part, 2-mercapto imidazoline 1 part, coumarone indene resin 5 parts, first
Base acrylic acid methyl ester. 1 part, insoluble sulfur 5 parts, accelerator 1 part, dispersant 1 part, defoamer 1 part, wetting agent 5 parts, penetrating agent 1
Part, fire retardant 5 parts, fireproof agent 5 parts；Accelerator is triethylamine, TMTD, tetramethyl thiourea and BZ, triethylamine, TMTD, tetramethyl
The mass ratio of thiourea and BZ is 1:4:2:1；Dispersant is hexenyl bis-stearamides；Defoamer is phenethanol oleate, poly-two
Methylsiloxane and hydrophobic silica, phenethanol oleate, the mass ratio of polydimethylsiloxane and hydrophobic silica is
1:2:1；Wetting agent is polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer,
The mass ratio of polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer is 2:3:3；
Penetrating agent is sulfamic acid sodium and fatty alcohol-polyoxyethylene ether, and the mass ratio of sulfamic acid sodium and fatty alcohol-polyoxyethylene ether is 1:
1；Fire retardant be the mass ratio of encapsulated red phosphorus and APP, encapsulated red phosphorus and APP be 3:1；Fireproof agent is sodium molybdate,
Antimony oxide, hexacholorocyclopentadiene and HBCD, sodium molybdate, antimony oxide, hexacholorocyclopentadiene and hexabromo ring
The mass ratio of dodecane is 1:2:5:2.
Embodiment 2
A kind of fire-resistant rubber, including the raw material of following portions by weight, 80 parts of silicone rubber, isoprene rubber 70 parts, fluorubber 70 parts, swollen
Swollen Vermiculitum 5 parts, tyre surface rubber powder 20 parts, bentonite 20 parts, Colophonium 10 parts, 2-mercapto imidazoline 3 parts, coumarone indene resin 15 parts,
Methyl methacrylate 5 parts, insoluble sulfur 10 parts, accelerator 3 parts, dispersant 5 parts, defoamer 3 parts, wetting agent 10 parts, oozes
Agent 5 parts thoroughly, fire retardant 10 parts, fireproof agent 10 parts；Accelerator is triethylamine；Dispersant is hexenyl bis-stearamides；Defoamer
For phenethanol oleate, polydimethylsiloxane and hydrophobic silica, phenethanol oleate, polydimethylsiloxane and hydrophobic
The mass ratio of silicon dioxide is 1:2:1；Wetting agent is polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer,
The mass ratio of polyoxyethylene aliphatic alcohol ether and polyoxyethylene polyoxypropylene block copolymer is 2:1；Penetrating agent is sulfamic acid sodium
And alkylphenol polyoxyethylene, the mass ratio of sulfamic acid sodium and alkylphenol polyoxyethylene is 5:7；Fire retardant is red for cladding
The mass ratio of phosphorus, APP and Firebrake ZB, encapsulated red phosphorus, APP and Firebrake ZB is 3:1:6；Fireproof agent be sodium molybdate and
The mass ratio of HBCD, sodium molybdate and HBCD is 7:1.
Embodiment 3
A kind of fire-resistant rubber, including the raw material of following portions by weight, 73 parts of silicone rubber, isoprene rubber 63 parts, fluorubber 55 parts, swollen
Swollen Vermiculitum 2 parts, tyre surface rubber powder 17 parts, bentonite 13 parts, Colophonium 3 parts, 2-mercapto imidazoline 2 parts, coumarone indene resin 9 parts, first
Base acrylic acid methyl ester. 2 parts, insoluble sulfur 6 parts, accelerator 2 parts, dispersant 2 parts, defoamer 2 parts, wetting agent 6 parts, penetrating agent 2
Part, fire retardant 6 parts, fireproof agent 6 parts；Accelerator is TMTD and tetramethyl thiourea, and the mass ratio of the two is 7:5；Dispersant is for oneself
Thiazolinyl bis-stearamides；Defoamer is phenethanol oleate, polydimethylsiloxane and hydrophobic silica, phenethanol oleic acid
The mass ratio of ester, polydimethylsiloxane and hydrophobic silica is 1:2:1；Wetting agent is polyoxyethylene aliphatic alcohol ether and polyoxy
Ethylene polyoxypropylene block copolymers, the mass ratio of the two is 3:4；Penetrating agent is sulfamic acid sodium and alkylphenol-polyethenoxy
Ether, the mass ratio of the two is 1:3；Fire retardant is encapsulated red phosphorus and APP, and the mass ratio of the two is 1:1；Fireproof agent is molybdenum
Acid sodium and hexacholorocyclopentadiene, the mass ratio of the two is 5:9.
Embodiment 4
A kind of fire-resistant rubber, including the raw material of following portions by weight, 77 parts of silicone rubber, isoprene rubber 67 parts, fluorubber 65 parts, swollen
Swollen Vermiculitum 4 parts, tyre surface rubber powder 19 parts, bentonite 17 parts, Colophonium 7 parts, 2-mercapto imidazoline 2 parts, coumarone indene resin 11 parts, first
Base acrylic acid methyl ester. 4 parts, insoluble sulfur 9 parts, accelerator 2 parts, dispersant 4 parts, defoamer 2 parts, wetting agent 9 parts, penetrating agent 4
Part, fire retardant 9 parts, fireproof agent 9 parts；Accelerator is tetramethyl thiourea；Dispersant is hexenyl bis-stearamides；Defoamer is benzene
Ethanol oleate, polydimethylsiloxane and hydrophobic silica, phenethanol oleate, polydimethylsiloxane and hydrophobic dioxy
The mass ratio of SiClx is 1:2:1；Wetting agent is polyoxyethylated alkyl phenol and polyoxyethylene aliphatic alcohol ether, and the mass ratio of the two is
5:6；Penetrating agent is sulfamic acid sodium, fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene, sulfamic acid sodium, poly alkyl alcohol
The mass ratio of oxygen vinyl Ether and alkylphenol polyoxyethylene is 5:1:2；Fire retardant is encapsulated red phosphorus, APP and Firebrake ZB,
The mass ratio of encapsulated red phosphorus, APP and Firebrake ZB is 3:2:3；Fireproof agent is sodium molybdate, antimony oxide and hexabromo ring ten
The mass ratio of dioxane, sodium molybdate, antimony oxide and HBCD is 6:1:5.
Embodiment 5
A kind of fire-resistant rubber, including the raw material of following portions by weight, 75 parts of silicone rubber, isoprene rubber 65 parts, fluorubber 60 parts, swollen
Swollen Vermiculitum 3 parts, tyre surface rubber powder 18 parts, bentonite 15 parts, Colophonium 5 parts, 2-mercapto imidazoline 2 parts, coumarone indene resin 10 parts, first
Base acrylic acid methyl ester. 3 parts, insoluble sulfur 7 parts, accelerator 2 parts, dispersant 3 parts, defoamer 2 parts, wetting agent 8 parts, penetrating agent 3
Part, fire retardant 8 parts, fireproof agent 8 parts；Accelerator is triethylamine, TMTD, tetramethyl thiourea and BZ, triethylamine, TMTD, tetramethyl
The mass ratio of thiourea and BZ is 1:2:1:5；Dispersant is hexenyl bis-stearamides；Defoamer is phenethanol oleate, poly-two
Methylsiloxane and hydrophobic silica, phenethanol oleate, the mass ratio of polydimethylsiloxane and hydrophobic silica is
1:2:1；Wetting agent is polyoxyethylated alkyl phenol and polyoxyethylene aliphatic alcohol ether, and the mass ratio of the two is 2:3；Penetrating agent is ammonia
Base sodium sulfonate, fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene, penetrating agent is sulfamic acid sodium, aliphatic alcohol polyethenoxy
The mass ratio of ether and alkylphenol polyoxyethylene is 3:1:1；Fire retardant is encapsulated red phosphorus, APP and Firebrake ZB, covers red phosphorus,
The mass ratio of APP and Firebrake ZB is 1:1:2；Fireproof agent is sodium molybdate, antimony oxide and hexacholorocyclopentadiene, molybdic acid
The mass ratio of sodium, antimony oxide and hexacholorocyclopentadiene is 4:1:3.
Comparative example
A kind of fire-resistant rubber, including the raw material of following portions by weight, 65 parts of silicone rubber, isoprene rubber 75 parts, fluorubber 75 parts, swollen
Swollen Vermiculitum 0.5 part, tyre surface rubber powder 15 parts, bentonite 10 parts, Colophonium 10 parts, 2-mercapto imidazoline 4 parts, coumarone indene resin 14
Part, methyl methacrylate 6 parts, insoluble sulfur 3 parts, accelerator 0.5 part, dispersant 0.5 part, defoamer 0.5 part, wetting agent
10 parts, penetrating agent 1 part, fire retardant 4 parts, fireproof agent 11 parts；Accelerator is triethylamine, TMTD, tetramethyl thiourea and BZ, three second
The mass ratio of amine, TMTD, tetramethyl thiourea and BZ is 1:2:1:5；Dispersant is hexenyl bis-stearamides；Defoamer is benzene second
Alcohol oleate, polydimethylsiloxane and hydrophobic silica, phenethanol oleate, polydimethylsiloxane and hydrophobic titanium dioxide
The mass ratio of silicon is 3:2:4；Wetting agent is polyoxyethylated alkyl phenol and polyoxyethylene aliphatic alcohol ether, and the mass ratio of the two is 2:
3；Penetrating agent is sulfamic acid sodium, fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene, and penetrating agent is sulfamic acid sodium, fat
The mass ratio of fat polyoxyethylenated alcohol and alkylphenol polyoxyethylene is 3:1:1；Fire retardant is encapsulated red phosphorus, APP and boron
Acid zinc, the mass ratio covering red phosphorus, APP and Firebrake ZB is 1:1:2；Fireproof agent is sodium molybdate, antimony oxide and chlordene ring
The mass ratio of pentadiene, sodium molybdate, antimony oxide and hexacholorocyclopentadiene is 4:1:3.
Upper embodiment 1-5 and comparative example are carried out following test, test result following table:
Thermal expansion multiplying power: determine the expansion multiplying power after being placed in remaining the atmosphere of 330 DEG C 0.5 hour by test film；
Processability: when test film being shaped with calendaring molding machine, by can be no problem the test film that shapes be evaluated as " good
Good ", bad order will be there is or the test film of stable shaping cannot be realized be evaluated as " the best "；
Shape stability: utilize and visually contact the shape that have rated the test film after thermal expansion multiplying power measures with finger, will not send out
Raw avalanche and the test film with finger contact also not avalanche are evaluated as " well ", will because finger contacts avalanche immediately or metrorrhagia
The test film collapsed is evaluated as " the best ".
As seen from table, the content of component, each degradation of rubber are changed.
Claims (10)
1. a fire-resistant rubber, it is characterised in that include the raw material of following portions by weight, silicone rubber 70-80 part, isoprene rubber
60-70 part, fluorubber 50-70 part, expanded vermiculite 1-5 part, tyre surface rubber powder 15-20 part, bentonite 10-20 part, Colophonium 1-10 part,
2-mercapto imidazoline 1-3 part, coumarone indene resin 5-15 part, methyl methacrylate 1-5 part, insoluble sulfur 5-10 part, promote
Enter agent 1-3 part, dispersant 1-5 part, defoamer 1-3 part, wetting agent 5-10 part, penetrating agent 1-5 part, fire retardant 5-10 part, fire prevention
Agent 5-10 part.
2. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that include the raw material of following portions by weight, silicone rubber
73-77 part, isoprene rubber 63-67 part, fluorubber 55-65 part, expanded vermiculite 2-4 part, tyre surface rubber powder 17-19 part, bentonite 13-
17 parts, Colophonium 3-7 part, 2-mercapto imidazoline 2 parts, coumarone indene resin 9-11 part, methyl methacrylate 2-4 part is insoluble
Sulfur 6-9 part, accelerator 2 parts, dispersant 2-4 part, defoamer 2 parts, wetting agent 6-9 part, penetrating agent 2-4 part, fire retardant 6-9
Part, fireproof agent 6-9 part.
3. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that include the raw material of following portions by weight, silicone rubber
75 parts, isoprene rubber 65 parts, fluorubber 60 parts, expanded vermiculite 3 parts, tyre surface rubber powder 18 parts, bentonite 15 parts, Colophonium 5 parts, 2-sulfur
Alcohol radical imidazoline 2 parts, coumarone indene resin 10 parts, methyl methacrylate 3 parts, insoluble sulfur 7 parts, accelerator 2 parts, dispersant
3 parts, defoamer 2 parts, wetting agent 8 parts, penetrating agent 3 parts, fire retardant 8 parts, fireproof agent 8 parts.
4. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described accelerator triethylamine, TMTD, tetramethyl sulfur
Urea, one or more in BZ.
5. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described dispersant is aliphatic amide type dispersion
Agent, described aliphatic amide type dispersant is hexenyl bis-stearamides.
6. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described defoamer is phenethanol oleate, poly-two
Methylsiloxane and hydrophobic silica, described defoamer is phenethanol oleate, polydimethylsiloxane and hydrophobic titanium dioxide
The mass ratio of silicon is 1:2:1.
7. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described wetting agent is non-ionic surfactant
Agent, described nonionic surfactant is polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene
Any one or more in block copolymer.
8. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described penetrating agent is sulfamic acid sodium, fatty alcohol
One or more in polyoxyethylene ether, alkylphenol polyoxyethylene.
9. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described fire retardant is encapsulated red phosphorus, HBCD, poly-phosphorus
Acid ammonium, any two kinds in Firebrake ZB.
10. a kind of fire-resistant rubber as claimed in claim 1, it is characterised in that described fireproof agent is sodium molybdate, three oxidations two
Antimony, hexacholorocyclopentadiene, any one or more of HBCD.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610462389.0A CN105968814A (en) | 2016-06-23 | 2016-06-23 | Fire-resistant rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610462389.0A CN105968814A (en) | 2016-06-23 | 2016-06-23 | Fire-resistant rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105968814A true CN105968814A (en) | 2016-09-28 |
Family
ID=57022746
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610462389.0A Pending CN105968814A (en) | 2016-06-23 | 2016-06-23 | Fire-resistant rubber |
Country Status (1)
| Country | Link |
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| CN (1) | CN105968814A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107353459A (en) * | 2017-06-30 | 2017-11-17 | 南通鸿图橡塑有限公司 | A kind of fire-resistant rubber |
| CN107623305A (en) * | 2017-09-21 | 2018-01-23 | 科耐特输变电科技股份有限公司 | A kind of fire-retardant cold shrinking power cable adjuncts of 10KV |
| CN114456464A (en) * | 2022-01-07 | 2022-05-10 | 上海膜益信息科技有限公司 | Low-temperature permeation modified mildew-proof thermoplastic resin and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649090A (en) * | 2008-08-15 | 2010-02-17 | 陈志海 | Method for preparing anti-freezing flame-retardant sheath |
| CN103665496A (en) * | 2013-11-27 | 2014-03-26 | 东营中一橡胶有限公司 | Fire-resistant rubber |
| CN104059264A (en) * | 2014-06-26 | 2014-09-24 | 青岛博洋生物技术有限公司 | Rubber material with fire resistance |
| CN104292560A (en) * | 2014-09-25 | 2015-01-21 | 青岛高远光电测控技术有限公司 | Stable fire-resistant rubber |
| CN104327336A (en) * | 2014-09-30 | 2015-02-04 | 青岛东泰诚恩新材料科技发展有限公司 | Novel flame-retardant and fire-resistant rubber |
| CN104804439A (en) * | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | Cable rubber |
-
2016
- 2016-06-23 CN CN201610462389.0A patent/CN105968814A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649090A (en) * | 2008-08-15 | 2010-02-17 | 陈志海 | Method for preparing anti-freezing flame-retardant sheath |
| CN103665496A (en) * | 2013-11-27 | 2014-03-26 | 东营中一橡胶有限公司 | Fire-resistant rubber |
| CN104059264A (en) * | 2014-06-26 | 2014-09-24 | 青岛博洋生物技术有限公司 | Rubber material with fire resistance |
| CN104292560A (en) * | 2014-09-25 | 2015-01-21 | 青岛高远光电测控技术有限公司 | Stable fire-resistant rubber |
| CN104327336A (en) * | 2014-09-30 | 2015-02-04 | 青岛东泰诚恩新材料科技发展有限公司 | Novel flame-retardant and fire-resistant rubber |
| CN104804439A (en) * | 2015-04-21 | 2015-07-29 | 青岛承天伟业机械制造有限公司 | Cable rubber |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107353459A (en) * | 2017-06-30 | 2017-11-17 | 南通鸿图橡塑有限公司 | A kind of fire-resistant rubber |
| CN107623305A (en) * | 2017-09-21 | 2018-01-23 | 科耐特输变电科技股份有限公司 | A kind of fire-retardant cold shrinking power cable adjuncts of 10KV |
| CN114456464A (en) * | 2022-01-07 | 2022-05-10 | 上海膜益信息科技有限公司 | Low-temperature permeation modified mildew-proof thermoplastic resin and preparation method thereof |
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Application publication date: 20160928 |