CN105967734A - Wear-resistant insulation building gypsum powder and preparation method thereof - Google Patents
Wear-resistant insulation building gypsum powder and preparation method thereof Download PDFInfo
- Publication number
- CN105967734A CN105967734A CN201610184256.1A CN201610184256A CN105967734A CN 105967734 A CN105967734 A CN 105967734A CN 201610184256 A CN201610184256 A CN 201610184256A CN 105967734 A CN105967734 A CN 105967734A
- Authority
- CN
- China
- Prior art keywords
- ardealite
- hour
- powder
- gypsum
- building gypsum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/143—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being phosphogypsum
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00008—Obtaining or using nanotechnology related materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The invention discloses a wear-resistant insulation building gypsum powder. Aluminum nano-powder is added into raw materials, and water is added into the materials and all the materials are blended to generate hydrogen, and the hydrogen is released to form a porous structure. In addition, phosphogypsum is creatively roasted, crushed and air-blasted to boiling state, and a vaporous hydrochloric acid solution is sprayed. After improved acid pickling technology for modification, contents of other impurities are reduced, content of CaSO4.2H2O is increased, and cost of traditional acid pickling is reduced. The economical benefit is remarkable. By adding the product into natural gypsum, with compatibility of other effective compound additives and through grinding, lap joint between crystals of a gypsum hardened specimen is denser, and gap between crystals is correspondingly reduced. The prepared insulation building gypsum powder has wear resistance, high strength, large porosity and remarkable insulation effect. The invention is aimed at comprehensive treatment and recycling of carbide slag and phosphogypsum so as to achieve the purposes of changing waste into valuable things, reducing production cost and enhancing enterprises' cleanliness level.
Description
Technical field
The present invention relates to building material technical field, be specifically related to a kind of wear resistant heat preserving building gypsum plaster and preparation method thereof.
Background technology
In recent years, organic insulation material exterior wall heat-preserving system fire incident happens occasionally, and brings the biggest loss to the lives and properties of people, and exploitation low-carbon (LC) is extremely urgent with fire-retardant type insulation material.Plaster of Paris has light weight, the good characteristic prevented fires, be incubated, and currently used most common Gypsum Fibrosum is the natural gypsum, but the consumption of chemical gypsum the most quickly increases, and studying more in chemical gypsum is ardealite.Owing to containing a certain amount of impurity in ardealite, having a great impact its comprehensive utilization, in recent years, China's ardealite discharge capacity rapidly increases, and up to the present annual emissions is more than 20,000,000 t.Process to ardealite, currently used " stacking " mode, both take substantial amounts of soil, polluted underground water, bring the biggest financial burden to enterprise again.How by phosphogypsum modification and replace the natural gypsum, it it is our difficult problem of needing to solve.On the other hand owing to the water absorption rate of building gypsum products is high, intensity is low, condensation is fast and poor water resistance so that it is range of application is restricted.
The experimentation of plaster of Paris " ardealite prepare " improves the mechanical property of phosphorus building gypsum plaster by adding water reducer, by ardealite with after hydrochloric acid solution soak acid-cleaning, gesso is prepared by roasting, again by ageing modification, change gesso quality, thus reach efficiently, low cost, low energy consumption utilize the purpose of ardealite.But pickling high cost in this literary composition, having process needs heat consumption high, the shortcomings such as process time length, the building gypsum plaster combination property prepared is low, the most do not possess the functions such as insulation noise reduction, it is necessary existing production technology and dispensing are improved, to prepare efficiently, low cost, the building gypsum plaster that waterproof, intensity height heat insulation effect is excellent.
Summary of the invention
It is an object of the invention to provide a kind of wear resistant heat preserving building gypsum plaster and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of wear resistant heat preserving building gypsum plaster, it is characterized in that, be prepared by the raw materials in: natural gypsum 40-42, ardealite 49-51, paper pulp 10-12, carbide slag 14-16, carbon fibre 11-13, polyvinyl alcohol 3-5, phenolic resin 8-10, petroleum sodium sulfonate 6.5-6.7, sodium silicate 0.5-0.7, white carbon 7-9, sawdust 17-19, nanometer aluminium powder 0.01-0.03, nano-cerium oxide 3.1-3.5, suitable quantity of water.
The preparation method of described a kind of wear resistant heat preserving building gypsum plaster, it is characterised in that comprise the following steps:
(1) ardealite is removed through natural air drying the free water of 15-18%, it is crushed to 60-80 mesh, bakee 1-2 hour in 100-105 DEG C, be ground to 100-120 mesh, be cooled to 70-80 DEG C, air blast is to fluidized state, spray the hydrochloric acid solution of vaporific 1mol/L, keep temperature to continue to spray 10-15 minute, stand 10-12 hour, it is washed till neutrality with clear water, obtains pickling ardealite；
(2) sawdust is dried the addition phenolic resin of molten condition, polyvinyl alcohol, sodium silicate stirring and evenly mixing, be dried and prepare modified sawdust powder；
(3) being pulverized by carbon fibre, addition nanometer aluminium powder, nano-cerium oxide, white carbon, paper pulp, petroleum sodium sulfonate grind 20-40 minute, dry to obtain modified Nano aluminium powder；
(4) natural gypsum, the mixing of pickling ardealite being ground 1-2 hour, add water ageing 12 hours, filtering drying, roasting 2-3 hour at 170-180 DEG C, it is cooled to 90-100 DEG C, adds step (2), (3) reaction mass and the mixing of other residual components homogenizing, discharging and get final product.
The present invention has following beneficial effect: the present invention adds nanometer aluminium powder in raw material, meet water after water mixing mix and generate hydrogen releasing, form loose structure, additionally the invention by ardealite bakee after pulverize air blast to fluidized state, spray vaporific hydrochloric acid solution, after acid cleaning process modification after improved, reduce other impurity contents, improve CaSO4·2H2O content, and reduce the cost of traditional method pickling, remarkable in economical benefits, join in the natural gypsum and other ground process of effective composite assistant of compatibility, overlap more densely cross-linked between the crystal of gypsum hardenite, diminishing the most accordingly between crystal, the wear-resisting intensity of heat-preserving building Gypsum Fibrosum powder prepared is high, porosity is big, heat insulation effect is notable, it is contemplated that carbide slag, ardealite are carried out integrated treatment recycling, reach the purpose turned waste into wealth, reducing production cost, improve enterprise cleans level.
Detailed description of the invention
Described a kind of wear resistant heat preserving building gypsum plaster, it is characterized in that, be prepared by the raw materials in: the natural gypsum 40, ardealite 49, paper pulp 10, carbide slag 14, carbon fibre 11, polyvinyl alcohol 3, phenolic resin 8, petroleum sodium sulfonate 6.5, sodium silicate 0.5, white carbon 7, sawdust 17, nanometer aluminium powder 0.01, nano-cerium oxide 3.1, suitable quantity of water.
Manufacture method comprises the following steps:
(1) ardealite is removed through natural air drying the free water of 15-18%, it is crushed to 60-80 mesh, bakee 1-2 hour in 100-105 DEG C, be ground to 100-120 mesh, be cooled to 70-80 DEG C, air blast is to fluidized state, spray the hydrochloric acid solution of vaporific 1mol/L, keep temperature to continue to spray 10-15 minute, stand 10-12 hour, it is washed till neutrality with clear water, obtains pickling ardealite；
(2) sawdust is dried the addition phenolic resin of molten condition, polyvinyl alcohol, sodium silicate stirring and evenly mixing, be dried and prepare modified sawdust powder；
(3) being pulverized by carbon fibre, addition nanometer aluminium powder, nano-cerium oxide, white carbon, paper pulp, petroleum sodium sulfonate grind 20-40 minute, dry to obtain modified Nano aluminium powder；
(4) natural gypsum, the mixing of pickling ardealite being ground 1-2 hour, add water ageing 12 hours, filtering drying, roasting 2-3 hour at 170-180 DEG C, it is cooled to 90-100 DEG C, adds step (2), (3) reaction mass and the mixing of other residual components homogenizing, discharging and get final product.
The heat conductivity of this heat-preserving building Gypsum Fibrosum powder is 0.074W/ (K m) after measured；Rupture strength reaches 16.4 MPa；Apparent density is distributed in 801-862kg/m3Between；Porosity has been up to 60.4%.
Claims (2)
1. a wear resistant heat preserving building gypsum plaster, it is characterized in that, be prepared by the raw materials in: natural gypsum 40-42, ardealite 49-51, paper pulp 10-12, carbide slag 14-16, carbon fibre 11-13, polyvinyl alcohol 3-5, phenolic resin 8-10, petroleum sodium sulfonate 6.5-6.7, sodium silicate 0.5-0.7, white carbon 7-9, sawdust 17-19, nanometer aluminium powder 0.01-0.03, nano-cerium oxide 3.1-3.5, suitable quantity of water.
The manufacture method of a kind of wear resistant heat preserving building gypsum plaster the most according to claim 1, it is characterised in that comprise the following steps:
(1) ardealite is removed through natural air drying the free water of 15-18%, it is crushed to 60-80 mesh, bakee 1-2 hour in 100-105 DEG C, be ground to 100-120 mesh, be cooled to 70-80 DEG C, air blast is to fluidized state, spray the hydrochloric acid solution of vaporific 1mol/L, keep temperature to continue to spray 10-15 minute, stand 10-12 hour, it is washed till neutrality with clear water, obtains pickling ardealite；
(2) sawdust is dried the addition phenolic resin of molten condition, polyvinyl alcohol, sodium silicate stirring and evenly mixing, be dried and prepare modified sawdust powder；
(3) being pulverized by carbon fibre, addition nanometer aluminium powder, nano-cerium oxide, white carbon, paper pulp, petroleum sodium sulfonate grind 20-40 minute, dry to obtain modified Nano aluminium powder；
(4) natural gypsum, the mixing of pickling ardealite being ground 1-2 hour, add water ageing 12 hours, filtering drying, roasting 2-3 hour at 170-180 DEG C, it is cooled to 90-100 DEG C, adds step (2), (3) reaction mass and the mixing of other residual components homogenizing, discharging and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610184256.1A CN105967734A (en) | 2016-03-29 | 2016-03-29 | Wear-resistant insulation building gypsum powder and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610184256.1A CN105967734A (en) | 2016-03-29 | 2016-03-29 | Wear-resistant insulation building gypsum powder and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN105967734A true CN105967734A (en) | 2016-09-28 |
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| CN201610184256.1A Pending CN105967734A (en) | 2016-03-29 | 2016-03-29 | Wear-resistant insulation building gypsum powder and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129252A (en) * | 2017-05-22 | 2017-09-05 | 宁夏洁华石膏建材有限责任公司 | A kind of land plaster preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134345A (en) * | 2007-09-14 | 2008-03-05 | 洪光 | Method for continuously producing environment-protection light gypsum wall material by using industrial residue |
| CN103626462A (en) * | 2013-11-01 | 2014-03-12 | 贵州开磷（集团）有限责任公司 | Autoclaved yellow phosphorus slag pavement brick and making method thereof |
| CN104987117A (en) * | 2015-06-17 | 2015-10-21 | 江苏龙海建工集团有限公司 | Environment-friendly building thermal insulation materials |
| CN105084930A (en) * | 2015-08-11 | 2015-11-25 | 安徽锦洋氟化学有限公司 | Preparing method for modified fluorgypsum powder for plastering anhydrite |
-
2016
- 2016-03-29 CN CN201610184256.1A patent/CN105967734A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101134345A (en) * | 2007-09-14 | 2008-03-05 | 洪光 | Method for continuously producing environment-protection light gypsum wall material by using industrial residue |
| CN103626462A (en) * | 2013-11-01 | 2014-03-12 | 贵州开磷（集团）有限责任公司 | Autoclaved yellow phosphorus slag pavement brick and making method thereof |
| CN104987117A (en) * | 2015-06-17 | 2015-10-21 | 江苏龙海建工集团有限公司 | Environment-friendly building thermal insulation materials |
| CN105084930A (en) * | 2015-08-11 | 2015-11-25 | 安徽锦洋氟化学有限公司 | Preparing method for modified fluorgypsum powder for plastering anhydrite |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129252A (en) * | 2017-05-22 | 2017-09-05 | 宁夏洁华石膏建材有限责任公司 | A kind of land plaster preparation method |
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Application publication date: 20160928 |
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| RJ01 | Rejection of invention patent application after publication |