CN105966021A - Multilayer suede composite decorative film, and materials and parameters thereof - Google Patents

Multilayer suede composite decorative film, and materials and parameters thereof Download PDF

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Publication number
CN105966021A
CN105966021A CN201610275946.8A CN201610275946A CN105966021A CN 105966021 A CN105966021 A CN 105966021A CN 201610275946 A CN201610275946 A CN 201610275946A CN 105966021 A CN105966021 A CN 105966021A
Authority
CN
China
Prior art keywords
film
layer
ink
printing
polypropylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610275946.8A
Other languages
Chinese (zh)
Inventor
盛英明
吕妙玲
李洪丽
周杨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Shenglong Decoration Material Co Ltd
Original Assignee
Zhejiang Shenglong Decoration Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Shenglong Decoration Material Co Ltd filed Critical Zhejiang Shenglong Decoration Material Co Ltd
Priority to CN201610275946.8A priority Critical patent/CN105966021A/en
Publication of CN105966021A publication Critical patent/CN105966021A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/022 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00Furniture

Abstract

A multilayer suede composite decorative film is a laminated product and is provided with a co-adhesive coating layer (1), a printing bottom film layer (2), an ink printing layer (3), an adhesive layer (4), a surface film layer (5) and a suede effect layer (6) from bottom to top successively. A coating of the co-adhesive coating layer adopts polyurea acid resin, namely PU resin; a bottom film of the printing bottom film layer adopts a polypropylene two-way stretch film, namely a PP two-way stretch film; an ink of the ink printing layer adopts an oil printing ink; an adhesive of the adhesive layer adopts ethylene hot melt adhesive particles; a film of the surface film layer adopts a polypropylene calendering film, namely a PP calendering film; a coating adopted by the suede effect layer is acrylic resin containing a small amount of polyurethane and polyethylene wax. The printing bottom film of the decorative film adopts the PP film instead of a PVC film and can be automatically degraded, and the decorative film has no concern about a plasticizer harmful to human health, and has the advantages of high mechanical strength and strong hiding power; and suede and matte effects are more in line with welcome of the majority of consumption crowds.

Description

Multi-layered type matte composite decoration film and material thereof and parameter
Technical field
The present invention relates to a kind of surface villous feel is printed with picture and text the composite decoration film in laminated construction, for artificial board and the incrustation of furniture.
Background technology
Artificial board or furniture are carried out incrustation, start with single layer decorative paper, due to single layer decorative paper poor water resistance, stain removal undesirable, insufficient strength, non-scrubbing resistance, service life are short, market prospect is the best, and the facing paper being gradually combined by paper membrane and single layer decorative film or composite decoration film substitute.Owing to the material of the monofilm selected or composite membrane is different, film kind collocation mode is different, application would also vary from.Composite membrane is widely used in the multiple fields such as industrial component, the articles for daily use, cultural goods, in addition to the decorating film for wood-based plate or furniture surfacing, also have for making early morning tea food box, disposal cup or solaode, be respectively arranged with material and the performance requirement of correspondence.Panel overlay decorating film of the prior art, its printing film uses polrvinyl chloride (PVC) film, the plasticizer added when producing this film and phthalate, also harmful health such as o-phthalic acid dibutyl ester, PVC film is difficult to again degraded, adversely affects environment.In existing more than ten years or more than the 30 year history of the facing paper of China's panel overlay and the production of film and application, in application process, the perceptual effect of light and bright finish is had the effect gradually experienced by dumb light and matte to substitute by consumer groups, seem there is the psychological need expecting this type of new product release, but so far there are no, and product appears on the market.Through retrieval, CN20110058727.1 discloses " a kind of suede structure BZO/HGZO laminated film ", is one diethyl zinc and water is primary raw material, be added with the Zinc oxide doped thin film having borine, thickness is 800-2500 μm, is used for making solar power silicon hull cell;CN201310057774.3 discloses " a kind of double matte glass with antireflective coating ", is a kind of for reducing reflection, covers with paint, lacquer, colour wash, etc. the technology of matte at glass surface, there are no the report of vellum finish film.The application is by the enlightenment of other matte film (glass, paper), it is proposed that multi-layered type matte composite decoration film and material thereof and the new design of relevant parameter, makes known publicly.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of multi-layered type matte composite decoration film and material thereof and parameter.
Solve this technical problem and adopt the following technical scheme that this multi-layered type matte composite decoration film, for laminates, have the most successively: totally six layers of adhesion promoter coating, printing basal membrane layer, ink printed layer, bond layer, face mask layer and pile effects layer.
The coating of described adhesion promoter coating uses polyureas acid resin i.e. PU resin, the counterdie of printing basal membrane layer uses polypropylene bidirection drawing film i.e. PP biaxial stretching film, the ink of ink printed layer uses oiliness printing-ink, the bonding agent of bond layer uses ethylene hot-melt adhesive granules, the film of face mask layer uses calendering polypropylene i.e. PP calendered film, and the coating that pile effects layer uses contains the acrylic resin of a small amount of polyurethane and Tissuemat E.
Described PU resin is the production of glue princes and dukes department of Germany, single spreading amount 1-2g/;Polypropylene (PP) biaxial stretching film is produced by DNP Co., Ltd. of Japan, and grammes per square metre 35-60g/, water absorption coefficient≤0.005%, environmental protection reaches European Union's 6P requirement;The GTK series ink that oiliness printing-ink is produced by the Chinese redbud ink company limited of Tongxiang, Zhejiang, is coated with 4 glasss of 25 DEG C of viscosity 20-30S, colour saturation 100 ± 10%, fineness≤10 μm, temperature tolerance >=150 DEG C;The entitled ethylene-vinyl acetate copolymer of ethylene hot-melt adhesive granules, its softening temperature 110 ± 10 DEG C, model T3190;Grammes per square metre 20-30g/ of polypropylene (PP) calendered film, water absorption coefficient≤0.005%, environmental protection reach EU criteria 6P requirement;The paint special of pile effects layer is produced by Hangzhou Jin Xiu ornament materials company limited.
The invention has the beneficial effects as follows that printing film is used instead as polypropylene screen (PP film) by PVC film, can degrade and not contain plasticizer and the phthalate etc. poisoning human body, for environmental friendliness shaped material, in the case of light weight, equal thickness, mechanical strength is high and hiding rare is high.The mechanical strength of multi-layered type structure is more than the decorating film that the number of plies is few, and the hands of matte is touched the visual experience of impression and dumb light and met the popular consumption preference that people are recent, and market prospect is good.
Accompanying drawing explanation
Accompanying drawing is multi-layered type matte composite decoration film laminated construction schematic diagram.
Detailed description of the invention
The present invention below in conjunction with embodiment and is described in detail referring to the drawings: see accompanying drawing, this multi-layered type matte composite decoration film, for laminates, have the most successively: totally six layers of adhesion promoter coating 1, printing basal membrane layer 2, ink printed layer 3, bond layer 4, face mask layer 5 and pile effects layer 6.The coating of described adhesion promoter coating uses polyureas acid resin i.e. PU resin, the counterdie of printing basal membrane layer uses polypropylene bidirection drawing film i.e. PP biaxial stretching film, the ink of ink printed layer uses oiliness printing-ink, the bonding agent of bond layer uses ethylene hot-melt adhesive granules, the film of face mask layer uses calendering polypropylene i.e. PP calendered film, and the coating that pile effects layer uses contains the acrylic resin of a small amount of polyurethane and Tissuemat E.
Described multi-layered type matte composite decoration film, is characterized in that described PU resin is for the production of glue princes and dukes department of Germany, single spreading amount 1-2g/;Polypropylene (PP) biaxial stretching film is produced by DNP Co., Ltd. of Japan, and grammes per square metre 35-60g/, water absorption coefficient≤0.005%, environmental protection reaches European Union's 6P requirement;The GTK series ink that oiliness printing-ink is produced by the Chinese redbud ink company limited of Tongxiang, Zhejiang, is coated with 4 glasss of 25 DEG C of viscosity 20-30S, colour saturation 100 ± 10%, fineness≤10 μm, temperature tolerance >=150 DEG C;The entitled ethylene-vinyl acetate copolymer of ethylene hot-melt adhesive granules, its softening temperature 110 ± 10 DEG C, model T3190;Grammes per square metre 20-30g/ of polypropylene (PP) calendered film, water absorption coefficient≤0.005%, environmental protection reach EU criteria 6P requirement;The paint special of pile effects layer, is produced by Hangzhou Jin Xiu ornament materials company limited.
The layers of material that this decorating film uses is in terms of title, PU resin, PP calendered film, oiliness printing-ink, ethylene-vinyl acetate copolymer and pile effects paint special etc., by commercial or net purchase, many can have been bought in chemical industry, raw material enterprise, but because the use of homogeneous raw material of the same name is different, desired impact is different, just can confirm that after only being tested by checking one by one, for this, my department announces associated production producer, ProductName, model or relevant parameter one by one, can implement in the hope of colleague professional and technical personnel.The gluing of this decorating film, being combined, print, use printer and the compounding machine of roll-type, intaglio printing, the streamline of four gradient temperatures is dried, is all belonged to routine operation, the most carefully state.

Claims (3)

1. a multi-layered type matte composite decoration film, for laminates, it is characterized in that having the most successively: adhesion promoter coating (1), printing basal membrane layer (2), ink printed layer (3), bond layer (4), face mask layer (5) and totally six layers of pile effects layer (6).
2. multi-layered type matte composite decoration film as claimed in claim 1, it is characterized in that the coating of described adhesion promoter coating uses polyureas acid resin i.e. PU resin, the counterdie of printing basal membrane layer uses polypropylene bidirection drawing film i.e. PP biaxial stretching film, the ink of ink printed layer uses oiliness printing-ink, the bonding agent of bond layer uses ethylene hot-melt adhesive granules, the film of face mask layer uses calendering polypropylene i.e. PP calendered film, and the coating that pile effects layer uses contains the acrylic resin of a small amount of polyurethane and Tissuemat E.
3. multi-layered type matte composite decoration film as claimed in claim 2, is characterized in that described PU resin is for the production of glue princes and dukes department of Germany, single spreading amount 1-2g/;Polypropylene (PP) biaxial stretching film is produced by DNP Co., Ltd. of Japan, and grammes per square metre 35-60g/, water absorption coefficient≤0.005%, environmental protection reaches European Union's 6P requirement;The GTK series ink that oiliness printing-ink is produced by the Chinese redbud ink company limited of Tongxiang, Zhejiang, is coated with 4 glasss of 25 DEG C of viscosity 20-30S, colour saturation 100 ± 10%, fineness≤10 μm, temperature tolerance >=150 DEG C;The entitled ethylene-vinyl acetate copolymer of ethylene hot-melt adhesive granules, its softening temperature 110 ± 10 DEG C, model T3190;Grammes per square metre 20-30g/ of polypropylene (PP) calendered film, water absorption coefficient≤0.005%, environmental protection reach EU criteria 6P requirement.
CN201610275946.8A 2016-04-29 2016-04-29 Multilayer suede composite decorative film, and materials and parameters thereof Pending CN105966021A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610275946.8A CN105966021A (en) 2016-04-29 2016-04-29 Multilayer suede composite decorative film, and materials and parameters thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610275946.8A CN105966021A (en) 2016-04-29 2016-04-29 Multilayer suede composite decorative film, and materials and parameters thereof

Publications (1)

Publication Number Publication Date
CN105966021A true CN105966021A (en) 2016-09-28

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107718831A (en) * 2017-11-08 2018-02-23 佛山市顺德区宝丽马彩膜板业科技有限公司 A kind of decorating film easy to use
CN108016204A (en) * 2017-12-01 2018-05-11 南亚共和塑胶(南通)有限公司 A kind of preparation process of PP building materials and ornaments film

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2756441Y (en) * 2004-11-08 2006-02-08 江阴华东装饰材料有限公司 Non-toxic, flame-retardant, degradable positive printing PP decoration film
CN2832517Y (en) * 2005-07-13 2006-11-01 田瑞军 Low pollution low consumption composite material coiled material
CN201833809U (en) * 2010-06-07 2011-05-18 欧志明 Hot melt adhesive-type decorative patch structure
CN103571323A (en) * 2012-08-06 2014-02-12 上海麟多祈化工科技有限公司 Water-based suede coating
CN204605103U (en) * 2015-05-13 2015-09-02 杭州谦欣塑胶科技有限公司 Matte environmental-protection decorative film
CN205149101U (en) * 2015-11-03 2016-04-13 浙江汇锋薄膜科技有限公司 Cupboard decorating film is felt to imitative fine hair

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2756441Y (en) * 2004-11-08 2006-02-08 江阴华东装饰材料有限公司 Non-toxic, flame-retardant, degradable positive printing PP decoration film
CN2832517Y (en) * 2005-07-13 2006-11-01 田瑞军 Low pollution low consumption composite material coiled material
CN201833809U (en) * 2010-06-07 2011-05-18 欧志明 Hot melt adhesive-type decorative patch structure
CN103571323A (en) * 2012-08-06 2014-02-12 上海麟多祈化工科技有限公司 Water-based suede coating
CN204605103U (en) * 2015-05-13 2015-09-02 杭州谦欣塑胶科技有限公司 Matte environmental-protection decorative film
CN205149101U (en) * 2015-11-03 2016-04-13 浙江汇锋薄膜科技有限公司 Cupboard decorating film is felt to imitative fine hair

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107718831A (en) * 2017-11-08 2018-02-23 佛山市顺德区宝丽马彩膜板业科技有限公司 A kind of decorating film easy to use
CN108016204A (en) * 2017-12-01 2018-05-11 南亚共和塑胶(南通)有限公司 A kind of preparation process of PP building materials and ornaments film

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Application publication date: 20160928