CN105957598A - Chloroprene rubber filled waterproof cable and preparation method thereof - Google Patents

Chloroprene rubber filled waterproof cable and preparation method thereof Download PDF

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Publication number
CN105957598A
CN105957598A CN201610522845.6A CN201610522845A CN105957598A CN 105957598 A CN105957598 A CN 105957598A CN 201610522845 A CN201610522845 A CN 201610522845A CN 105957598 A CN105957598 A CN 105957598A
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CN
China
Prior art keywords
silver
aramid fiber
fiber yarn
insulating barrier
plated aramid
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CN201610522845.6A
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Chinese (zh)
Inventor
程奇
李平
朱文玲
王徐惠
李善才
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Wuhu Spaceflight Special Cable Factory Co Ltd
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Wuhu Spaceflight Special Cable Factory Co Ltd
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Priority to CN201610522845.6A priority Critical patent/CN105957598A/en
Publication of CN105957598A publication Critical patent/CN105957598A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0208Cables with several layers of insulating material
    • H01B7/0216Two layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/02Stranding-up
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/14Insulating conductors or cables by extrusion
    • H01B13/141Insulating conductors or cables by extrusion of two or more insulating layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/14Insulating conductors or cables by extrusion
    • H01B13/148Selection of the insulating material therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • H01B13/221Sheathing; Armouring; Screening; Applying other protective layers filling-up interstices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0275Disposition of insulation comprising one or more extruded layers of insulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/1895Internal space filling-up means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/282Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/14Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables

Abstract

The invention discloses a chloroprene rubber filled waterproof cable and a preparation method thereof. The waterproof cable comprises multiple strands of cable core units which are twisted mutually; a silver-plated aramid yarn weaved sleeve is sleeved outside the multiple strands of the cable core units; chloroprene rubber is filled in the silver-plated aramid yarn weaved sleeve; a first insulating layer, a critical layer and a second insulating layer are successively arranged outside the silver-plated aramid yarn weaved sleeve along a direction from inside to outside; the first insulating layer is an acrylonitrile-methyl methacrylate copolymer layer; the critical layer is filled with nano zirconium carbide; and the second insulating layer is an ethylene-tetrafluoroethylene copolymer layer. The cable prepared with the method has excellent waterproof performance.

Description

Water-proof cable that neoprene is filled and preparation method thereof
Technical field
The present invention relates to insulated cable, in particular it relates to a kind of neoprene fill water-proof cable and Preparation method.
Background technology
Cable is typically by the cable of similar rope of several or several groups wire strandings, often group wire it Between mutually insulated, and be often twisted into round a center, whole outside is surrounded by the cover layer of high-insulation. It is erected at aerial more or is contained in underground, the bottom, for telecommunication or power transmission.Cable is mainly by following 4 Part composition, 1. conducting wire center: make with high conductivity material (copper or aluminum).According to laying use bar The part requirement to cable softness, the every line heart may be formed by solid conductor or multiple conducting wires are stranded. 2. insulating barrier: the insulant as cable should have high insulation resistance, high breakdown field strength , low dielectric loss and low dielectric constant.Insulant conventional in cable has oil-paper, polychlorostyrene second Alkene, polyethylene, crosslinked polyethylene, rubber etc..Cable is often classified with insulant, and such as oil-paper is exhausted Edge cable, polyvinyl chloride cable, twisted polyethylene cable etc..3. sealing sheath: the protection covered wire heart is exempted from Damage by machinery, moisture, moisture, chemical substance, light etc..For the insulation of moisture-sensitive, typically adopt With lead or aluminium extrusion sealing sheath.4. cover layer is protected: in order to protect sealing sheath from mechanical damage. Sheath is outer (claims armouring electricity typically to use galvanized steel strip, steel wire or copper strips, copper wire etc. to surround as armor Cable), armor plays electric field shielding simultaneously and prevents the effect of external electromagnetic wave interference.
Although existing cable can disclosure satisfy that in most of occasion and produce and the demand of life, but It is in deep water, due to by the corroding of microorganism in the extruding of hydraulic pressure and water, respectively leading in cable Line interferes with each other before being easily compacted and then causing each line heart, and meanwhile, service life is also by pole Earth effect.
Summary of the invention
It is an object of the invention to provide water-proof cable of a kind of neoprene filling and preparation method thereof, pass through The cable that the method prepares has water resistance and the mechanical property of excellence.
To achieve these goals, the invention provides the water-proof cable that a kind of neoprene is filled, this is prevented Water power cable includes the most stranded multi cord core unit, and the outer cover of multi cord core unit is provided with silver-plated aramid fiber Silk wired tube, is filled with neoprene in silver-plated aramid fiber yarn wired tube;The outside of silver-plated aramid fiber yarn wired tube The first insulating barrier, critical layer and the second insulating barrier it is disposed with along direction from inside to outside;First is exhausted Edge layer is acrylonitrile methyl meth acrylat copolymer layer, and critical layer is filled with nano-zirconium carbide, second Insulating barrier is ethylene-tetrafluoroethylene copolymer layer.
Preferably, a diameter of 0.85-0.90mm of silver-plated aramid fiber yarn wired tube, the thickness of the first insulating barrier For 0.15-0.20mm, the thickness of critical layer is 0.05-0.12mm, and the thickness of the second insulating barrier is 0.20-0.25mm。
Preferably, the thickness of the silver coating on the outer surface of the silver-plated aramid fiber yarn in silver-plated aramid fiber yarn establishment set For 1-2 μm.
Preferably, on the basis of the area of the cross section of silver-plated aramid fiber yarn wired tube, silver-plated aramid fiber yarn weaves The area that in the cross section of set, neoprene occupies is 35-45%.
Preferably, core unit includes the most stranded multiply silver-gilt copper wire, the outside of multiply silver-gilt copper wire Being provided with protective layer, protective layer is filled by polystyrene and is formed.
Preferably, a diameter of 0.05-0.08mm of silver-gilt copper wire, a diameter of 0.20-0.30mm of protective layer.
Preferably, the thickness of the silver coating of the outer surface of multiply silver-gilt copper wire is 0.5-0.9 μm.
Present invention also offers the preparation method of the water-proof cable that a kind of above-mentioned neoprene is filled, this system Preparation Method includes:
1) by the most stranded for multi cord core unit, then silver-plated aramid fiber yarn wired tube is sheathed on multi cord The outside of core unit, then fills neoprene with the inside to silver-plated aramid fiber yarn wired tube;
2) acrylonitrile methyl meth acrylat copolymer is extruded in the outside of silver-plated aramid fiber yarn wired tube with Forming the first insulating barrier, the surface that nano-zirconium carbide is then embedded at the first insulating barrier forms critical layer, Then ethylene-tetrafluoroethylene copolymer is extruded and form the second insulating barrier with system in the outside of the first insulating barrier Obtain the water-proof cable that neoprene is filled.
Preferably, in step 1) before, method also includes: be soaked in acid solution by aramid fiber yarn, then Take out and plate on the outer surface of aramid fiber yarn silver layer with prepare silver-plated aramid fiber yarn, then by silver-plated aramid fiber yarn It is woven into silver-plated aramid fiber yarn wired tube.
Preferably, one or more in hydrochloric acid solution, salpeter solution and sulfuric acid solution of acid solution;And And, the concentration of acid solution is 50-70 weight %.
According to technique scheme, the present invention is by setting gradually neoprene rubber in the outside of multi cord core unit Glue, silver-plated aramid fiber yarn wired tube, the first insulating barrier, critical layer and the second insulating barrier, by each parts Synergism makes this cable have water resistance and the mechanical property of excellence;Especially, in critical layer Nano-zirconium carbide can spread in the first insulating barrier and the second insulating barrier and then make the first insulating barrier with Second insulating barrier forms one and then improves both single insulating properties and mechanical property.Due to this electricity The excellent insulating properties of cable and mechanical property, so that this cable stably can be carried out in deep water Work, and then ensure its service life.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Accompanying drawing explanation
Accompanying drawing is used to provide a further understanding of the present invention, and constitutes the part of description, with Detailed description below is used for explaining the present invention together, but is not intended that limitation of the present invention.? In accompanying drawing:
Fig. 1 is the structural representation of the water-proof cable that the neoprene that the present invention provides is filled.
Description of reference numerals
1, core unit 2, silver-gilt copper wire
3, silver coating 4, protective layer
5, neoprene 6, silver-plated aramid fiber yarn wired tube
7, the first insulating barrier 8, critical layer
9, the second insulating barrier
Detailed description of the invention
Below in conjunction with accompanying drawing, the detailed description of the invention of the present invention is described in detail.It should be appreciated that Detailed description of the invention described herein is merely to illustrate and explains the present invention, is not limited to this Bright.
In the present invention, in the case of illustrating on the contrary, " inside and outside " etc. is included in term The noun of locality only represents this term orientation under normal service condition, or is skilled artisan understands that It is commonly called as, and is not construed as the restriction to this term.
The invention provides the water-proof cable that a kind of neoprene is filled, as it is shown in figure 1, this water-proof cable Including the most stranded multi cord core unit 1, the outer cover of multi cord core unit 1 is provided with silver-plated aramid fiber yarn Wired tube 6, is filled with neoprene 5 in silver-plated aramid fiber yarn wired tube 6;Silver-plated aramid fiber yarn wired tube 6 Outside be disposed with the first insulating barrier 7, critical layer 8 and the second insulation along direction from inside to outside Layer 9;First insulating barrier 7 is acrylonitrile methyl meth acrylat copolymer layer, and critical layer 8 is filled with to be received Rice zirconium carbide, the second insulating barrier 9 is ethylene-tetrafluoroethylene copolymer layer.
The outside of above-mentioned multi cord core unit 1 sets gradually neoprene 5, silver-plated aramid fiber yarn wired tube 6, the first insulating barrier 7, critical layer 8 and the second insulating barrier 9, make this by the synergism of each parts Cable has the insulating properties of excellence, and meanwhile, this cable can keep the steady of excellence in rugged environment Qualitative;Wherein, the nano-zirconium carbide in critical layer 8 can be to the first insulating barrier 7 and the second insulating barrier 9 Middle diffusion and then make the first insulating barrier 7 and the second insulating barrier 9 forms one and then to improve both independent Insulating properties.Meanwhile, this cable has the stability of excellence, it is possible to keep steady in rugged environment Fixed performance, and then ensure that it can steady operation.
In the present invention, silver-plated aramid fiber yarn wired tube the 6, first insulating barrier 7, critical layer 8 and second are exhausted The size of edge layer 9 can select in wide scope, but in order to improve the water resistance of cable further, Preferably, a diameter of 0.85-0.90mm of silver-plated aramid fiber yarn wired tube 6, the thickness of the first insulating barrier 7 For 0.15-0.20mm, the thickness of critical layer 8 is 0.05-0.12mm, and the thickness of the second insulating barrier 9 is 0.20-0.25mm。
Meanwhile, the thickness of the silver coating of the silver-plated aramid fiber yarn in silver-plated aramid fiber yarn establishment set can be at wide model Enclose interior adjustment, but in order to improve capability of electromagnetic shielding and the stability of cable further, it is preferable that The thickness of the silver coating on the outer surface of the silver-plated aramid fiber yarn in silver-plated aramid fiber yarn establishment set is 1-2 μm.
Additionally, in this cable, the content of neoprene 5 can change in wide scope, but is Neoprene 5 can be fully filled between multi cord core unit 1 and core unit 1 with Between silver-plated aramid fiber yarn wired tube 6, it is preferable that with the area of the cross section of silver-plated aramid fiber yarn wired tube 6 On the basis of, the area that in the cross section of silver-plated aramid fiber yarn wired tube 6, neoprene 5 occupies is 35-45%.
On the basis of the above, the concrete knot of core unit 1 can select in wide scope, but It is to improve the stability of the signal during wired signal transmission and the transmission quality of signal, preferably Ground, core unit 1 includes the most stranded multiply silver-gilt copper wire 2, and the outside of multiply silver-gilt copper wire 2 sets Being equipped with protective layer 4, protective layer 4 is filled by polystyrene and is formed.So, can be filled by polystyrene Divide ground to come insulating between each core unit 1, and then ensure that each single core unit 1 can Transmit and do not result in interference, preferably between different signals, and the signal of each core unit 1 transmission Ground, a diameter of 0.05-0.08mm of silver-gilt copper wire 2, a diameter of 0.20-0.30mm of protective layer 4.
Additionally, the thickness of the silver coating 3 of multiply silver-gilt copper wire 2 can select in wide scope, but In order to improve the signal transmission performance of multiply silver-gilt copper wire 2, it is preferable that the appearance of multiply silver-gilt copper wire 2 The thickness of the silver coating 3 in face is 0.5-0.9 μm.
Present invention also offers the preparation method of the water-proof cable that a kind of above-mentioned neoprene is filled, this system Preparation Method includes:
1) by the most stranded for multi cord core unit 1, then silver-plated aramid fiber yarn wired tube 6 is sheathed on many The outside of strand core unit 1, then fills by neoprene 5 with the inside to silver-plated aramid fiber yarn wired tube 6;
2) acrylonitrile methyl meth acrylat copolymer is extruded in the outside of silver-plated aramid fiber yarn wired tube 6 To form the first insulating barrier 7, the surface formation that nano-zirconium carbide is then embedded at the first insulating barrier 7 is faced Interlayer 8, then extrudes the outside formation second in the first insulating barrier 7 exhausted by ethylene-tetrafluoroethylene copolymer The water-proof cable that edge layer 9 is filled with prepared neoprene.
In the preparation process in accordance with the present invention, silver-plated aramid fiber yarn wired tube 6 can be by this area any one Plant conventional method to be prepared, but in order to improve the capability of electromagnetic shielding of silver-plated aramid fiber yarn wired tube 6, Preferably, in step 1) before, the method also includes: is soaked in acid solution by aramid fiber yarn, then takes Go out and plate on the outer surface of aramid fiber yarn silver layer with prepare silver-plated aramid fiber yarn, then silver-plated aramid fiber yarn is compiled It is made into silver-plated aramid fiber yarn wired tube 6.
It addition, the kind of acid solution and concentration can also select in wide scope, but in order to carry further The anti-electromagnetic interference capability of the high silver-plated aramid fiber yarn wired tube 6 prepared, it is preferable that acid solution is molten selected from hydrochloric acid One or more in liquid, salpeter solution and sulfuric acid solution;Further, the concentration of acid solution is 50-70 weight %.
The present invention is further illustrated by the following examples.
Preparation example 1
The aramid fiber yarn of a diameter of 0.10mm is soaked in the acid solution (hydrochloric acid solution) of 60 weight %, connects Taking-up and on the outer surface of aramid fiber yarn, plate silver layer (thickness of silver coating is 1.5 μm) with prepared plating Silver aramid fiber yarn, is then woven into silver-plated aramid fiber yarn wired tube 6 (a diameter of 0.88mm) by silver-plated aramid fiber yarn.
Embodiment 1
1) by multiply silver-gilt copper wire 2 (a diameter of 0.07mm, the thickness of silver coating 3 is 0.7 μm) phase The most stranded, then polystyrene is extruded and form protective layer 4 (diameter in the outside of multiply silver-gilt copper wire 2 For 0.25mm) with prepared core unit;
2) by the most stranded for multi cord core unit, then silver-plated aramid fiber yarn wired tube is sheathed on multi cord The outside of core unit, then fills neoprene with the inside of extremely silver-plated aramid fiber yarn wired tube (with silver-plated virtue On the basis of the area of the cross section of synthetic fibre silk wired tube 6, neoprene in the cross section of silver-plated aramid fiber yarn wired tube 6 The area that rubber 5 occupies is 40%);
3) acrylonitrile methyl meth acrylat copolymer is extruded in the outside of silver-plated aramid fiber yarn wired tube with Form the first insulating barrier 7 (thickness is 0.18mm), then nano-zirconium carbide is embedded at the first insulating barrier Surface formed critical layer 8 (thickness is 0.08mm), then ethylene-tetrafluoroethylene copolymer is extruded The second insulating barrier 9 (thickness is 0.22mm) is formed with prepared neoprene in the outside of the first insulating barrier The water-proof cable A1 filled.
Embodiment 2
1) by multiply silver-gilt copper wire 2 (a diameter of 0.05mm, the thickness of silver coating 3 is 0.5 μm) phase The most stranded, then polystyrene is extruded and form protective layer 4 (diameter in the outside of multiply silver-gilt copper wire 2 For 0.20mm) with prepared core unit;
2) by the most stranded for multi cord core unit, then silver-plated aramid fiber yarn wired tube is sheathed on multi cord The outside of core unit, then fills neoprene with the inside of extremely silver-plated aramid fiber yarn wired tube (with silver-plated virtue On the basis of the area of the cross section of synthetic fibre silk wired tube 6, neoprene in the cross section of silver-plated aramid fiber yarn wired tube 6 The area that rubber 5 occupies is 35%);
3) acrylonitrile methyl meth acrylat copolymer is extruded in the outside of silver-plated aramid fiber yarn wired tube with Form the first insulating barrier 7 (thickness is 0.15mm), then nano-zirconium carbide is embedded at the first insulating barrier Surface formed critical layer 8 (thickness is 0.05mm), then ethylene-tetrafluoroethylene copolymer is extruded The second insulating barrier 9 (thickness is 0.20mm) is formed with prepared neoprene in the outside of the first insulating barrier The water-proof cable A2 filled.
Embodiment 3
1) by multiply silver-gilt copper wire 2 (a diameter of 0.08mm, the thickness of silver coating 3 is 0.9 μm) phase The most stranded, then polystyrene is extruded and form protective layer 4 (diameter in the outside of multiply silver-gilt copper wire 2 For 0.30mm) with prepared core unit;
2) by the most stranded for multi cord core unit, then silver-plated aramid fiber yarn wired tube is sheathed on multi cord The outside of core unit, then fills neoprene with the inside of extremely silver-plated aramid fiber yarn wired tube (with silver-plated virtue On the basis of the area of the cross section of synthetic fibre silk wired tube 6, neoprene in the cross section of silver-plated aramid fiber yarn wired tube 6 The area that rubber 5 occupies is 45%);
3) acrylonitrile methyl meth acrylat copolymer is extruded in the outside of silver-plated aramid fiber yarn wired tube with Form the first insulating barrier 7 (thickness is 0.20mm), then nano-zirconium carbide is embedded at the first insulating barrier Surface formed critical layer 8 (thickness is 0.12mm), then ethylene-tetrafluoroethylene copolymer is extruded The second insulating barrier 9 (thickness is 0.25mm) is formed with prepared neoprene in the outside of the first insulating barrier The water-proof cable A3 filled.
Comparative example 1
Carry out preparing water-proof cable B1 according to the method for embodiment 1, except that, in step 3) in Do not use nano-zirconium carbide.
Comparative example 2
Carry out preparing water-proof cable B2 according to the method for embodiment 1, except that, in step 2) in Do not use neoprene.
Detection example 1
1) comprcssive strength (σ of above-mentioned cable is detectedbc/ MPa), concrete outcome is shown in Table 1;
2) (hydraulic pressure is 9.8 × 10 above-mentioned cable to be placed in water deep for 100m5Pa) in 3 months, then The error of wired signal transmission speed is put in detection againWherein, Transmission speed 1 be placed in water for cable before transmission speed, transmission speed 2 is placed in water 3 for cable Transmission speed after individual month;Concrete outcome is shown in Table 1.
Table 1
σbc/MPa Δ/%
A1 6.2 0.4
A2 6.4 0.2
A3 6.5 0.3
B1 4.1 2.0
B2 4.0 2.2
By above-described embodiment, comparative example and detection example, the cable that the present invention provides has excellent anti- Aqueous energy and stability.
The preferred embodiment of the present invention is described in detail above in association with accompanying drawing, but, the present invention does not limit Detail in above-mentioned embodiment, in the technology concept of the present invention, can be to the present invention Technical scheme carry out multiple simple variant, these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.

Claims (10)

1. the water-proof cable that a neoprene is filled, it is characterised in that described water-proof cable includes phase The most stranded multi cord core unit (1), the outer cover of described multi cord core unit (1) is provided with silver-plated virtue Synthetic fibre silk wired tube (6), is filled with neoprene (5) in described silver-plated aramid fiber yarn wired tube (6);Institute The outside stating silver-plated aramid fiber yarn wired tube (6) is disposed with the first insulation along direction from inside to outside Layer (7), critical layer (8) and the second insulating barrier (9);Described first insulating barrier (7) be acrylonitrile- Methylmethacrylate copolymer layer, described critical layer (8) is filled with nano-zirconium carbide, and described second Insulating barrier (9) is ethylene-tetrafluoroethylene copolymer layer.
Water-proof cable the most according to claim 1, it is characterised in that described silver-plated aramid fiber yarn is compiled Knitting a diameter of 0.85-0.90mm of set (6), the thickness of described first insulating barrier (7) is 0.15-0.20mm, The thickness of described critical layer (8) is 0.05-0.12mm, and the thickness of described second insulating barrier (9) is 0.20-0.25mm。
Water-proof cable the most according to claim 1 and 2, wherein, described silver-plated aramid fiber yarn is worked out The thickness of the silver coating on the outer surface of the silver-plated aramid fiber yarn in set is 1-2 μm.
Water-proof cable the most according to claim 3, it is characterised in that with described silver-plated aramid fiber yarn On the basis of the area of the cross section of wired tube (6), the cross section of described silver-plated aramid fiber yarn wired tube (6) The area that middle neoprene (5) occupies is 35-45%.
Water-proof cable the most according to claim 1 and 2, it is characterised in that described core unit (1) including the most stranded multiply silver-gilt copper wire (2), the outside of described multiply silver-gilt copper wire (2) sets Being equipped with protective layer (4), described protective layer (4) is filled by polystyrene and is formed.
Water-proof cable the most according to claim 5, it is characterised in that described silver-gilt copper wire (2) A diameter of 0.05-0.08mm, a diameter of 0.20-0.30mm of described protective layer (4).
Water-proof cable the most according to claim 6, it is characterised in that described multiply silver-gilt copper wire (2) thickness of the silver coating (3) of outer surface is 0.5-0.9 μm.
8. the water-proof cable that a neoprene as described in any one in claim 1-7 is filled Preparation method, it is characterised in that described preparation method includes:
1) by the most stranded for described multi cord core unit (1), then by described silver-plated aramid fiber yarn wired tube (6) it is sheathed on the outside of described multi cord core unit (1), then described neoprene (5) is filled out It is charged to the inside of described silver-plated aramid fiber yarn wired tube (6);
2) described acrylonitrile methyl meth acrylat copolymer is extruded in described silver-plated aramid fiber yarn wired tube (6) described nano-zirconium carbide, to form described first insulating barrier (7), is then embedded at institute by outside The surface stating the first insulating barrier (7) forms described critical layer (8), then by described ethylene-tetrafluoroethylene Copolymer extrudes and forms the second insulating barrier (9) with prepared neoprene in the outside of described first insulating barrier (7) The water-proof cable of rubber filling.
Preparation method the most according to claim 8, it is characterised in that in step 1) before, institute Method of stating also includes: be soaked in acid solution by aramid fiber yarn, then taking-up the outer surface at described aramid fiber yarn On plate silver layer with prepare silver-plated aramid fiber yarn, then described silver-plated aramid fiber yarn is woven into described silver-plated aramid fiber Silk wired tube (6).
The most according to claim 8 or claim 9, preparation method, wherein, described acid solution is molten selected from hydrochloric acid One or more in liquid, salpeter solution and sulfuric acid solution;Further, the concentration of described acid solution is 50-70 Weight %.
CN201610522845.6A 2016-07-06 2016-07-06 Chloroprene rubber filled waterproof cable and preparation method thereof Pending CN105957598A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106920580A (en) * 2017-05-04 2017-07-04 湖北宇洪光电实业有限公司 A kind of data cable of communication equipment for being applied to 4G frequency ranges and preparation method thereof
CN108335798A (en) * 2018-01-19 2018-07-27 合肥宸翊商贸有限公司 A kind of water-proof cable of high intensity and preparation method thereof

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CN103886998A (en) * 2014-03-24 2014-06-25 江苏馨晟特种电缆有限公司 6 kV to 15 kV silicone rubber insulation power cable
CN104795135A (en) * 2014-01-17 2015-07-22 安徽华能电缆集团有限公司 Fluoroplastic insulation light cable for aerospace
CN204516432U (en) * 2015-03-18 2015-07-29 湖南湘江电缆有限公司 A kind of fire-resistant cable

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Publication number Priority date Publication date Assignee Title
CN104795135A (en) * 2014-01-17 2015-07-22 安徽华能电缆集团有限公司 Fluoroplastic insulation light cable for aerospace
CN103886998A (en) * 2014-03-24 2014-06-25 江苏馨晟特种电缆有限公司 6 kV to 15 kV silicone rubber insulation power cable
CN204516432U (en) * 2015-03-18 2015-07-29 湖南湘江电缆有限公司 A kind of fire-resistant cable

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106920580A (en) * 2017-05-04 2017-07-04 湖北宇洪光电实业有限公司 A kind of data cable of communication equipment for being applied to 4G frequency ranges and preparation method thereof
CN108335798A (en) * 2018-01-19 2018-07-27 合肥宸翊商贸有限公司 A kind of water-proof cable of high intensity and preparation method thereof

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