Summary of the invention
The present invention provides a kind of high-performance composite fibre brake block, in order to solve the technical problems such as poor thermal conductivity in prior art, the easy embrittlement in corner, heat fading, abrasiveness height.
nullIn order to solve above technical problem,The technical solution used in the present invention is: a kind of high-performance composite fibre brake block,Carry on the back including steel、Brake pad,It is characterized in that described brake pad is made up of the component proportion of following weight portion: basalt fibre 8~10 parts、Pre-oxidized polyacrylonitrile fiber 8~15 parts、Alkali-free bulk glass fiber 6~10 parts、Virtue logical sequence fiber 4~6 parts、Ceramic fibre 8~10 parts、Red copper fiber 5~7 parts、Nano aluminium oxide 5~7 parts、Nano silicon 6~10 parts、Nanometer barium ferrite 6~10 parts、Bamboo carbon fiber 5~6 parts、Calcium sulfate crystal whiskers 15~17 parts、Potassium titanate crystal whisker 3~6 parts、Crystalline flake graphite 5.5~7 parts、Cashew nut oil Frication powder 6~8 parts、Nitrile rubber 6~10 parts、PROMAXON-D calcium silicate particle 9~12 parts、Expanded vermiculite 5~6 parts、Boron nitride 1.5~2 parts、Molybdenum trioxide 1.5~2 parts、Boron bakelite resin 17~18 parts、Amino silane 2~3 parts、Isopropanol 0.5~1 part、Sodium lauryl sulphate 0.2~0.5 part.
The present invention has environmental protection, and high temperature resistance heat fading performance is good, and anti-wear performance is good, stable friction factor, service life the feature such as length.The present invention is by reasonably arranging in pairs or groups to Multiple components, it is ensured that the advantage of each material is fully played in friction material.And formula does not has heavy metal substance, the most friendly to environment.Multiple Fresh fats material in friction material composition, especially with basalt fibre, pre-oxidized polyacrylonitrile fiber, alkali-free bulk glass fiber, virtue logical sequence fiber, ceramic fibre, red copper fiber, nanometer ferrous acid, bamboo carbon fiber compound, can not only mutually make up the deficiency of its respective performance, also can synergism and form quick heat radiating, stablize coefficient of friction, reduce the contour performance of brake block deformation.In work process, brake block forms more excellent frictional layer and transfer membrane so that car brake is sensitive, and steadily, brakeless shriek, comfort property is preferable, and brake process is to brake disc not damaged in braking.
Specific embodiment two: this high-performance composite fibre brake block, carry on the back including steel, brake pad, described brake pad is made up of the component proportion of following weight portion: basalt fibre 8 parts, pre-oxidized polyacrylonitrile fiber 15 parts, alkali-free bulk glass fiber 6 parts, virtue logical sequence fiber 6 parts, ceramic fibre 8 parts, red copper fiber 7 parts, nano aluminium oxide 5 parts, nano silicon 10 parts, nanometer barium ferrite 6 parts, bamboo carbon fiber 6 parts, calcium sulfate crystal whiskers 15 parts, potassium titanate crystal whisker 6 parts, crystalline flake graphite 5.5 parts, cashew nut oil Frication powder 8 parts, nitrile rubber 6 parts, PROMAXON-D calcium silicate particle 9 parts, expanded vermiculite 6 parts, boron nitride 1.5 parts, molybdenum trioxide 2 parts, boron bakelite resin 17 parts, amino silane 3 parts, isopropanol 0.5 part, sodium lauryl sulphate 0.5 part.
The friction material converted is poured in high speed dispersor, stir into homodisperse powdered composition, then taking out this material compositions, to put into shaping dies compressing, vulcanizing press is put in high temperature 500 DEG C after being combined with the steel back of the body again, pressure is to keep 60 minutes under conditions of 35MPa, finally take out brake block, remove burr and become finished product.
nullSpecific embodiment three: this high-performance composite fibre brake block,Carry on the back including steel、Brake pad,Described brake pad is made up of the component proportion of following weight portion: basalt fibre 9 parts、Pre-oxidized polyacrylonitrile fiber 12 parts、Alkali-free bulk glass fiber 8 parts、Virtue logical sequence fiber 5 parts、Ceramic fibre 9 parts、Red copper fiber 6 parts、Nano aluminium oxide 6 parts、Nano silicon 9 parts、Nanometer barium ferrite 8 parts、Bamboo carbon fiber 5.5 parts、Calcium sulfate crystal whiskers 16 parts、Potassium titanate crystal whisker 5 parts、Crystalline flake graphite 6 parts、Cashew nut oil Frication powder 7 parts、Nitrile rubber 8 parts、PROMAXON-D calcium silicate particle 11 parts、Expanded vermiculite 5.5 parts、Boron nitride 1.8 parts、Molybdenum trioxide 1.8 parts、Boron bakelite resin 17 parts、Amino silane 2.3 parts、Isopropanol 0.8 part、Sodium lauryl sulphate 0.5 part.
The friction material converted is poured in high speed dispersor, stir into homodisperse powdered composition, then taking out this material compositions, to put into shaping dies compressing, vulcanizing press is put in high temperature 500 DEG C after being combined with the steel back of the body again, pressure is to keep 60 minutes under conditions of 35MPa, finally take out brake block, remove burr and become finished product.
Material explanation selected by the various embodiments described above:
Virtue logical sequence fiber has high intensity, high-modulus and high temperature resistant, acid-fast alkali-proof, the premium properties such as lightweight.Its intensity is 5~6 times of steel wire, and modulus is 2~3 times of steel wire or glass fibre, and toughness is 2 times of steel wire, and weight is only about the 1/5 of steel wire, at a temperature of 560 DEG C, does not decomposes, does not melts.The features such as the brake block using virtue logical sequence fiber to make has good thermostability and shearing resistance, bending strength, good braking effect.
PROMAXON D calcium silicate particle (U.S. chemical abstract services society (CAS) registration number PROMAXON D:1344-95-2) is the calcium silicate products of a kind of high porosity, PROMAXON D is produced by Europe Promat international corporation of Belgium, and LAPINUS fiber company limited of Holland is its whole world unique agent in friction material market.The crystallization processes special by it and the crystal growth of stability contorting, its white particle forms porous high permeability spherical state.Solid owing to PROMAXON D extra-granular density is high, and when being sheared by such as dry blending during thermoplastic, its shape keeps constant.Use PROMAXON-D can significantly improve noise performance.Its heat fading is low, and restorability is good, and under fast state, braking ability does not reduces, and braking automobile is sensitive, noiselessness, and comfort property is good, repeatedly occurs without braking atrophy phenomenon after braking.
Acrylonitrile pre-oxidized fibers has the pyridine ring trapezium structure of semi-conductor electricity resistance, and its thermostability, flame resistance compare common all increasing with electric conductivity etc..
Bamboo carbon fiber constructs fine and closely woven porous, has stronger adsorptivity, adsorbable various pulverulent materials, makes friction material steadiness strengthen.And it is thin that its distinctive vesicular structure can make other fiberous material fully open, pulverulent material mix homogeneously.
Expanded vermiculite (40 ~ 120 mesh) has light weight, wear-resisting, sound-absorbing, high temperature resistant and high porosity; it is used for improving high-temperature behavior and the damping effect of friction material; make automobile brake more steady; increase the comfort taken; its acoustic absorptivity is when sound frequency is 100 ~ 4000Hz; up to 0.06 ~ 0.6, to reducing noise pollution, protecting environment to serve great effect;After high-temperature heating, form grog add friction material as filler, the effect of reinforcing agent, heat stabilizer can be played.
Ceramic fibre uses the man-made mineral fiber that high-quality alumina silicate fibre processes through chopped.The advantage such as have lightweight, environmental protection, high temperature resistant, Heat stability is good, thermal conductivity are low, specific heat is little and mechanical resistant vibrations, tension rupture strength be high, can be greatly improved friction material stability during manufacturing and using.Ceramic fibre in above example can select high aluminium profiles (aluminium oxide >=65%) ceramic fibre that Changzhou, Jiangsu Province, China plump special fibre company limited produces.
The thermostability of boron bakelite resin, instantaneous heat-resisting quantity, ablation resistance and mechanical property are more much better than phenolic resin, make heat fading performance, restorability, polishing machine and the mechanical performance of material be improved.
Calcium sulfate crystal whiskers (1~6 μm, draw ratio >=30), integrate the advantage of both reinforcing fiber and ultra-fine inorganic filler, there is high intensity, high-modulus, high tenacity, high-insulativity, abrasion performance, high temperature resistant, acid and alkali-resistance, anticorrosive, infrared reflectivity good, is prone to surface processes, easily and many excellent physicochemical properties such as polymer is compound, nontoxic.Brake block prepared by calcium sulfate crystal whiskers has the heat fading phenomenon that the reduction Organic substance thermal decomposition when high temperature causes, its stable friction factor, brakes comfortable during use, and noiselessness produces, and product abrasion is little.Calcium sulfate crystal whiskers in above example can select the calcium sulfate crystal whiskers that Hefei in Anhui Jian Kun Chemical Co., Ltd. of China provides.
Potassium titanate crystal whisker can be used as adiabator, and compared with asbestos, abrasion loss about reduces 32%.
Crystalline flake graphite (60~80 mesh) can reduce the heat fading of friction material for friction material, stablizes the coefficient of friction of friction material.Crystalline flake graphite in above example can select the crystalline flake graphite that phosphorus content is 94.99% that river, road, Neixiang County, Henan, China graphite ore provides.
Amino silane is viscosifier, and its heat conductivity is good, and it has two kinds of functional groups, i.e. amino and ethyoxyl;Wherein three hydrolyzable groups (ethyoxyl), the most first hydrolysis generates silanol, and owing to silanol is unstable, the easily hydroxy combining with inorganic matter or metal surface is dehydrated, thus combines with inorganic matter or metal;Can react with various polymer with two active hydrogens on amino, thus by chemical bond combining material tight of different nature, make the combination between friction combined material more tight, thus improve the stability of friction material.
Boron nitride has that lubricity is good, thermal coefficient of expansion is little, chemical stability high, and especially its thermal conductivity is suitable with rustless steel.
Carborundum in above example can select the black silicon carbide that purity is 98.50% that Henan China Anyang Jia Xinnai material company limited provides.
In order to verify the effect of the present invention, by China GB5763~1998 national standards, the environment-friendly type high performance friction material composition being used for brake block embodiment 3 prepared is tested without metal brake block respectively with what certain company of Japan produced on constant speed tester for friction between, and its result is as follows:
The result shows: compare same kind of products at abroad, and the environment-friendly type high performance friction material composition for brake block using inventive formulation to prepare has more preferable friction and wear behavior and high temperature resistance heat fading performance.Additionally, the ceramic brake of embodiment 1,2 preparation is tested respectively, all there is excellent properties similar to Example 1.
In order to verify effect of the present invention further, it is to carry out skidding test on car that the brake block that the present invention is prepared by inventor is arranged on BMW 5, repeatedly brake through five drivers (driving age is all more than 15 years), all confirm that brake block prepared by the present invention is sensitive, braking is steadily, noiselessness simultaneously, that takes is comfortable splendid.
Finally it is pointed out that above detailed description of the invention is only the more representational example of the present invention.It is clear that the invention is not restricted to above-mentioned detailed description of the invention, it is also possible to there are many deformation.Every any simple modification, equivalent variations and modification made above detailed description of the invention according to the technical spirit of the present invention, is all considered as belonging to protection scope of the present invention.