CN105951449A - Composite multifunctional fabric - Google Patents
Composite multifunctional fabric Download PDFInfo
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- CN105951449A CN105951449A CN201610417409.2A CN201610417409A CN105951449A CN 105951449 A CN105951449 A CN 105951449A CN 201610417409 A CN201610417409 A CN 201610417409A CN 105951449 A CN105951449 A CN 105951449A
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- D—TEXTILES; PAPER
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
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- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
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- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M2200/30—Flame or heat resistance, fire retardancy properties
Abstract
The invention discloses a composite multifunctional fabric. The fabric is obtained by dipping grey cloth in a hydrophobic finishing agent and a flame retardant and antibacterial finishing agent, wherein the hydrophobic finishing agent is prepared from, by weight, 10%-35% of organic silicon modified acrylic emulsion, 5%-20% of modified polyethylene wax, 5%-15% of polysiloxane, 1%-10% of polyisocyanate emulsion and the balance water, and the flame retardant and antibacterial finishing agent is prepared from, by weight, 5%-10% of modified vermiculite, 5%-25% of chitosan, 2%-10% of halamine compounds, 5%-10% of polybasic carboxylic acid, 1%-5% of sodium monophosphate and the balance water. According to the composite multifunctional fabric, excellent hydrophobic, flame retardant and antibacterial effects are achieved simultaneously, and the fabric is environmentally friendly, healthy, prominent in performance and high in water-wash resistance.
Description
Technical field
The present invention relates to fabric technical field, particularly relate to a kind of composite multifunction fabric.
Background technology
In the past, it is used mostly the compound containing long fluorocarbon chain as hydrophobic finishing agent to obtain the face of low surface free energy
Material, although after the compound of fluorine-containing system arranges, effect is preferable, but this type of finishing agent is expensive, research the most in recent years
Find that fluorine-containing chemicals are difficult to biodegradation, environmental and human health impacts caused potentially hazardous therefore, how to make environmental friendliness
The finishing agent of type reaches the compound finishing effect of long fluorocarbon chain, is an important topic of current development function fabric.
Additionally, due to the hydrophobic finishing agent of fluorine-containing system and the compatibility of other functional finishing agents (such as fire retardant, antibacterial)
Property poor, it is unstable that finishing agent is added together the working solution that is configured to, it may appear that layering, floats oil condition, and working solution can not be used for
Arrange fabric, it is impossible to obtain the fabric with complex function.If using the method that substep arranges, as fire-retardant, antibacterial in first carried out
Arrange, then carry out hydrophobic finishing, although avoid the problem that working solution is unstable, but the final fabric obtained is fire-retardant, antibacterial
The poorest with hydrophobic effect, reason is the effect that fluorine-containing water-repelling agent can affect antiflaming finishing agent, and the most fire-retardant, antibacterial finishing agent also can
Affect the effect of fluorine-containing hydrophobic finishing agent.The most how to prepare a kind of has the compound of the effect such as hydrophobic, fire-retardant, antibacterial simultaneously
Multifunctional fabric, is also to be the important topic developing multifunctional fabric now.
Summary of the invention
The present invention proposes a kind of composite multifunction fabric, and it has hydrophobic, fire-retardant, the antibacterial effect of excellence the most simultaneously
Really, and environment protection health, performance are prominent, water-wash resistance is strong.
The present invention proposes a kind of composite multifunction fabric, and described fabric by padding hydrophobic finishing agent and fire-retardant by grey cloth
Antibacterial finishing agent obtains；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
Preferably, described grey cloth is to be formed through weaving by cotton, polyester-cotton blend or terylene.
Preferably, described organosilicon-modified acrylic emulsion is by butyl acrylate, styrene and vinyl trimethoxy
The copolymer emulsion that silane obtains after carrying out copolymerization, wherein, the weight of butyl acrylate, styrene and vinyltrimethoxy silane
Amount proportioning is 1:0.4-0.8:0.8-2.2.
Preferably, described modified polyethylene wax be the modified polyethylene wax containing hydroxyl and/or containing carboxyl modification gather
Ethylene waxes.
Preferably, the preparation technology of described PERFORMANCE OF MODIFIED VERMICULITE includes: Vermiculitum is ground to 200-400 mesh, and after adding water, stirring is mixed
Even, add CTA, at 80-100 DEG C, stirring reaction 6-8h, obtains organic-pillared vermiculite standby after washing；Cyclodextrin is added
In isopropanol, add the sodium hydroxide solution that content is 25-35wt% and stir, add described organic-pillared vermiculite,
40-60 DEG C of stirred in water bath reaction 2-4h, adds hydrochloric acid regulation to sucking filtration after neutrality, obtains PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA,
Cyclodextrin, isopropanol, the weight ratio of sodium hydroxide solution are 1:1-1.5:1-2:6-8:1.5-2.
Preferably, described chitosan is N, N, N-N-trimethyl chitosan TMC and/or diethylmethyl chitosan；Described halogen amine
Compound is the bromo-3-of 1-chloro-4,4,5,5-tetramethyl imidazolidin-2-one and/or 5,5-dimethyl-3-(3 '-triethoxysilicane third
Base)-glycolylurea.
Preferably, the concrete operations of " described fabric by grey cloth is padded water-proof aagent and antibacterial finishing agent obtains " are such as
Under: first by after grey cloth alkali immerging, obtain pretreatment grey cloth；Again described hydrophobic finishing agent and flame-retardant antibacterial finishing agent are led to successively
Crossing the method padded to be applied on described pretreatment grey cloth, obtaining padding has water-repelling agent and the grey cloth of flame-proof antibiotic agent；Then will
Described padding has the grey cloth of water-repelling agent and flame-proof antibiotic agent to dry, and obtains described composite multifunction fabric；Preferably, described grey cloth
It is 100:1-10 with the mass ratio of described hydrophobic finishing agent；Described grey cloth is 100 with the mass ratio of described flame-retardant antibacterial finishing agent:
1-10。
Preferably, the concrete operations of " by grey cloth alkali immerging " are as follows: grey cloth is padded soda bath, an immersing and rolling, leaching
Rolling temperature and be 60-80 DEG C, pick-up is 30-40%, and concentration of caustic soda is 40-200g/L；Then clear water rinsing at 30-45 DEG C
Bakee 20-30min at 30-40min, 130-140 DEG C, obtain pretreatment grey cloth.
Preferably, the concrete behaviour " described hydrophobic finishing agent being applied on described pretreatment grey cloth by the method padded "
Make as follows: pretreatment grey cloth is padded in by organosilicon-modified acrylic emulsion, modified polyethylene wax, polysiloxanes, poly-isocyanide
40-60min in the hydrophobic finishing agent of acid esters emulsion and water configuration, two soak two rolls, and pick-up is at 60-90%, 60-80 DEG C
Dry, solidify at 120-160 DEG C, dry at 30-50 DEG C, obtain padding the grey cloth having water-repelling agent.
Preferably, the tool " described flame-retardant antibacterial finishing agent being applied on described pretreatment grey cloth by the method padded "
Gymnastics make as follows: by pad the grey cloth having water-repelling agent be padded in by PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid,
10-50min in the flame-retardant antibacterial finishing agent solution of sodium hypophosphite and water configuration, two soak two rolls, and pick-up is 75-
Preliminary drying 2-5min at 95%, 60-80 DEG C, bakees 2-5min at 120-160 DEG C, after cold water is washed, dry, soaked at 60-80 DEG C
Rolled with water-repelling agent and the grey cloth of flame-proof antibiotic agent.
In the present invention, described composite multifunction fabric uses hydrophobic finishing agent and the flame-retardant antibacterial finishing agent leaching of specific composition
Roll and obtain, wherein, described hydrophobic finishing agent uses organosilicon-modified acrylic emulsion, combines containing organic on the surface of grey cloth
The hydrophobic group of silicon, its polarity is less than the polarity of Organic fluoride group, good with the compound property of other functional finishing agents；Pass through again
With modified polyethylene wax, polysiloxanes etc. and the hydroxy combining on grey cloth, further enhancing the hydrophobic performance of fabric；Described resistance
Combustion antibacterial finishing agent uses PERFORMANCE OF MODIFIED VERMICULITE, and owing to having air space between Vermiculitum synusia, interlayer is possibly together with water of crystallization, heat conduction simultaneously
Coefficient is low, is good flame resistant heat insulation material, and under high temperature, the volume energy of Vermiculitum expands rapidly several times to tens times, becomes expansion
Vermiculitum, its thermal isolation performance also becomes the most excellent；Heretofore described PERFORMANCE OF MODIFIED VERMICULITE by Vermiculitum is carried out quaternised modified,
Quaternary ammonium salt can exchange with Vermiculitum interlayer cation, after cetyl trimethylammonium bromide intercalation, and the sheet interlayer spacing of Vermiculitum
Increasing, pillared effect is obvious；Quaternary ammonium salt carries out etherification reaction with cyclodextrin more simultaneously so that on Vermiculitum, connection has Beta-cyclodextrin-based
Group, thus stability and the compatibility to Vermiculitum have carried out good improvement, good with the compound property of other functional finishing agents；Connect
By after polybasic carboxylic acid and sodium hypophosphite and the hydroxyl reaction on grey cloth, it is possible to the hydroxyl reaction on cyclodextrin, thus
By PERFORMANCE OF MODIFIED VERMICULITE essence anchor on grey cloth, while improving fabric fire resistance, do not interfere with the feel of fabric yet, have very simultaneously
Strong water-fastness fastness；Meanwhile, the chitosan, the halogen aminated compounds that add in flame-retardant antibacterial finishing agent have well
Anti-microbial property, avirulence and biocompatibility and biodegradability, while it has the fine compatibility with PERFORMANCE OF MODIFIED VERMICULITE,
Also can react with polybasic carboxylic acid and sodium hypophosphite, thus antibacterial is also integrated on grey cloth, compound thus without to other
The effect of agent and associativity produce impact.
The flame-retardant antibacterial finishing agent of specific non-fluorine water-repelling agent with specific composition and content is carried out compatibility by the present invention, described
Having collaborative facilitation between water-repelling agent and flame-proof antibiotic agent, the fabric finally given has that hydrophobicity is good, excellent flame retardancy,
The feature that antibiotic property is excellent.And the production method of the present invention is simple to operation, low cost, can be flexible according to different requirements
The consumption of regulatory function finishing agent and process technique.
Detailed description of the invention
Embodiment 1
In the present embodiment, a kind of composite multifunction fabric, described fabric by padding hydrophobic finishing agent and fire-retardant by grey cloth
Antibacterial finishing agent obtains, and described grey cloth is to be formed through weaving by cotton；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described organosilicon-modified acrylic emulsion is butyl acrylate, styrene and vinyltrimethoxy silane to be carried out
The copolymer emulsion obtained after copolymerization, wherein, the weight proportion of butyl acrylate, styrene and vinyltrimethoxy silane is
1:0.4:2.2；
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
The preparation technology of described PERFORMANCE OF MODIFIED VERMICULITE includes: Vermiculitum is ground to 200 mesh, and stirring and evenly mixing after adding water adds
CTA, at 100 DEG C, stirring reaction 6h, obtains organic-pillared vermiculite standby after washing；Cyclodextrin is added in isopropanol, add
Content is that the sodium hydroxide solution of 35wt% stirs, and adds described organic-pillared vermiculite, anti-40 DEG C of stirred in water bath
Answer 4h, add hydrochloric acid and regulate sucking filtration to neutrality, obtain PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA, cyclodextrin, isopropanol, hydroxide
The weight ratio of sodium solution is 1:1:2:6:2；
The concrete operations of " described fabric by grey cloth is padded water-proof aagent and antibacterial finishing agent obtains " are as follows: by base
Cloth pads soda bath, an immersing and rolling, and padding temperature is 60 DEG C, and pick-up is 40%, and concentration of caustic soda is 40g/L；Then 45
Clear water rinsing 30min at DEG C, bakees 20min, obtains pretreatment grey cloth at 140 DEG C；Pretreatment grey cloth is padded in by organosilicon
In the hydrophobic finishing agent of modified acrylic acid emulsion, modified polyethylene wax, polysiloxanes, polyisocyanate emulsion and water configuration
40min, two leachings two roll, and pick-up is 60%, dries at 80 DEG C, solidifies at 120 DEG C, dries at 50 DEG C, obtain padding have hydrophobic
The grey cloth of agent；It is padded in padding the grey cloth having water-repelling agent by PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid, secondary
10min in the flame-retardant antibacterial finishing agent solution of sodium phosphite and water configuration, two soak two rolls, and pick-up is 95%, at 80 DEG C
Preliminary drying 2min, bakees 2min at 160 DEG C, after cold water is washed, dry at 80 DEG C, and obtaining padding has water-repelling agent and the base of flame-proof antibiotic agent
Cloth；Then there is the grey cloth of water-repelling agent and flame-proof antibiotic agent to dry described padding, obtain described composite multifunction fabric；Wherein institute
The mass ratio stating grey cloth and described hydrophobic finishing agent is 100:1；Described grey cloth with the mass ratio of described flame-retardant antibacterial finishing agent is
100:10。
Embodiment 2
In the present embodiment, a kind of composite multifunction fabric, described fabric by padding hydrophobic finishing agent and fire-retardant by grey cloth
Antibacterial finishing agent obtains, and described grey cloth is to be formed through weaving by polyester-cotton blend；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described organosilicon-modified acrylic emulsion is butyl acrylate, styrene and vinyltrimethoxy silane to be carried out
The copolymer emulsion obtained after copolymerization, wherein, the weight proportion of butyl acrylate, styrene and vinyltrimethoxy silane is
1:0.8:0.8；Described modified polyethylene wax is the modified polyethylene wax containing hydroxyl or the modified polyethylene wax containing carboxyl；
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
The preparation technology of described PERFORMANCE OF MODIFIED VERMICULITE includes: Vermiculitum is ground to 400 mesh, and stirring and evenly mixing after adding water adds
CTA, at 80 DEG C, stirring reaction 8h, obtains organic-pillared vermiculite standby after washing；Being added by cyclodextrin in isopropanol, addition contains
Amount stirs for the sodium hydroxide solution of 25wt%, adds described organic-pillared vermiculite, reacts 60 DEG C of stirred in water bath
2h, adds hydrochloric acid and regulates sucking filtration to neutrality, obtain PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA, cyclodextrin, isopropanol, sodium hydroxide
The weight ratio of solution is 1:1.5:1:8:1.5；
The concrete operations of " described fabric by grey cloth is padded water-proof aagent and antibacterial finishing agent obtains " are as follows: by base
Cloth pads soda bath, an immersing and rolling, and padding temperature is 80 DEG C, and pick-up is 30%, and concentration of caustic soda is 200g/L；Then 30
Clear water rinsing 40min at DEG C, bakees 30min, obtains pretreatment grey cloth at 130 DEG C；Pretreatment grey cloth is padded in by organosilicon
In the hydrophobic finishing agent of modified acrylic acid emulsion, modified polyethylene wax, polysiloxanes, polyisocyanate emulsion and water configuration
60min, two leachings two roll, and pick-up is 90%, dries at 60 DEG C, solidifies at 160 DEG C, dries at 30 DEG C, obtain padding have hydrophobic
The grey cloth of agent；It is padded in padding the grey cloth having water-repelling agent by PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid, secondary
50min in the flame-retardant antibacterial finishing agent solution of sodium phosphite and water configuration, two soak two rolls, and pick-up is 75%, at 60 DEG C
Preliminary drying 5min, bakees 5min at 120 DEG C, after cold water is washed, dry at 60 DEG C, and obtaining padding has water-repelling agent and the base of flame-proof antibiotic agent
Cloth；Then there is the grey cloth of water-repelling agent and flame-proof antibiotic agent to dry described padding, obtain described composite multifunction fabric；Wherein institute
The mass ratio stating grey cloth and described hydrophobic finishing agent is 100:10；Described grey cloth with the mass ratio of described flame-retardant antibacterial finishing agent is
100:1。
Embodiment 3
In the present embodiment, a kind of composite multifunction fabric, described fabric by padding hydrophobic finishing agent and fire-retardant by grey cloth
Antibacterial finishing agent obtains, and described grey cloth is to be formed through weaving by terylene；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described organosilicon-modified acrylic emulsion is butyl acrylate, styrene and vinyltrimethoxy silane to be carried out
The copolymer emulsion obtained after copolymerization, wherein, the weight proportion of butyl acrylate, styrene and vinyltrimethoxy silane is
1:0.6:1.5；Described modified polyethylene wax is the modified polyethylene wax containing hydroxyl and the modified polyethylene wax containing carboxyl；
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
The preparation technology of described PERFORMANCE OF MODIFIED VERMICULITE includes: Vermiculitum is ground to 300 mesh, and stirring and evenly mixing after adding water adds
CTA, at 90 DEG C, stirring reaction 7h, obtains organic-pillared vermiculite standby after washing；Being added by cyclodextrin in isopropanol, addition contains
Amount stirs for the sodium hydroxide solution of 30wt%, adds described organic-pillared vermiculite, reacts 50 DEG C of stirred in water bath
3h, adds hydrochloric acid and regulates sucking filtration to neutrality, obtain PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA, cyclodextrin, isopropanol, sodium hydroxide
The weight ratio of solution is 1:1.2:1.5:7:1.7；
Described chitosan is N, N, N-N-trimethyl chitosan TMC and diethylmethyl chitosan；Described halogen aminated compounds is 1-
Bromo-3-chloro-4,4,5,5-tetramethyl imidazolidin-2-one and 5,5-dimethyl-3-(3 '-triethoxysilylpropyl)-glycolylurea；
The concrete operations of " described fabric by grey cloth is padded water-proof aagent and antibacterial finishing agent obtains " are as follows: by base
Cloth pads soda bath, an immersing and rolling, and padding temperature is 70 DEG C, and pick-up is 35%, and concentration of caustic soda is 120g/L；Then 38
Clear water rinsing 35min at DEG C, bakees 25min, obtains pretreatment grey cloth at 135 DEG C；Pretreatment grey cloth is padded in by organosilicon
In the hydrophobic finishing agent of modified acrylic acid emulsion, modified polyethylene wax, polysiloxanes, polyisocyanate emulsion and water configuration
50min, two leachings two roll, and pick-up is 75%, dries at 70 DEG C, solidifies at 140 DEG C, dries at 40 DEG C, obtain padding have hydrophobic
The grey cloth of agent；It is padded in padding the grey cloth having water-repelling agent by PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid, secondary
30min in the flame-retardant antibacterial finishing agent solution of sodium phosphite and water configuration, two soak two rolls, and pick-up is 85%, at 70 DEG C
Preliminary drying 3.5min, bakees 3.5min at 140 DEG C, after cold water is washed, dry at 70 DEG C, and obtaining padding has water-repelling agent and flame-proof antibiotic agent
Grey cloth；Then there is the grey cloth of water-repelling agent and flame-proof antibiotic agent to dry described padding, obtain described composite multifunction fabric；Its
Described in the mass ratio of grey cloth and described hydrophobic finishing agent be 100:5；Described grey cloth and the quality of described flame-retardant antibacterial finishing agent
Ratio is 100:6.
Embodiment 4
In the present embodiment, a kind of composite multifunction fabric, described fabric by padding hydrophobic finishing agent and fire-retardant by grey cloth
Antibacterial finishing agent obtains, and described grey cloth is to be formed through weaving by cotton；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described organosilicon-modified acrylic emulsion is butyl acrylate, styrene and vinyltrimethoxy silane to be carried out
The copolymer emulsion obtained after copolymerization, wherein, the weight proportion of butyl acrylate, styrene and vinyltrimethoxy silane is
1:0.5:1.8；Described modified polyethylene wax is the modified polyethylene wax containing hydroxyl；
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
The preparation technology of described PERFORMANCE OF MODIFIED VERMICULITE includes: Vermiculitum is ground to 300 mesh, and stirring and evenly mixing after adding water adds
CTA, at 85 DEG C, stirring reaction 7.5h, obtains organic-pillared vermiculite standby after washing；Cyclodextrin is added in isopropanol, add
Content is that the sodium hydroxide solution of 32wt% stirs, and adds described organic-pillared vermiculite, anti-55 DEG C of stirred in water bath
Answer 2.5h, add hydrochloric acid and regulate sucking filtration to neutrality, obtain PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA, cyclodextrin, isopropanol, hydrogen-oxygen
The weight ratio changing sodium solution is 1:1.3:1.8:7:1.8；
The concrete operations of " described fabric by grey cloth is padded water-proof aagent and antibacterial finishing agent obtains " are as follows: by base
Cloth pads soda bath, an immersing and rolling, and padding temperature is 65 DEG C, and pick-up is 30%, and concentration of caustic soda is 150g/L；Then 37
Clear water rinsing 38min at DEG C, bakees 26min, obtains pretreatment grey cloth at 136 DEG C；Pretreatment grey cloth is padded in by organosilicon
In the hydrophobic finishing agent of modified acrylic acid emulsion, modified polyethylene wax, polysiloxanes, polyisocyanate emulsion and water configuration
45min, two leachings two roll, and pick-up is 80%, dries at 65 DEG C, solidifies at 150 DEG C, dries at 45 DEG C, obtain padding have hydrophobic
The grey cloth of agent；It is padded in padding the grey cloth having water-repelling agent by PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid, secondary
25min in the flame-retardant antibacterial finishing agent solution of sodium phosphite and water configuration, two soak two rolls, and pick-up is 80%, at 65 DEG C
Preliminary drying 3min, bakees 4min at 130 DEG C, after cold water is washed, dry at 65 DEG C, and obtaining padding has water-repelling agent and the base of flame-proof antibiotic agent
Cloth；Then there is the grey cloth of water-repelling agent and flame-proof antibiotic agent to dry described padding, obtain described composite multifunction fabric；Wherein institute
The mass ratio stating grey cloth and described hydrophobic finishing agent is 100:6；Described grey cloth with the mass ratio of described flame-retardant antibacterial finishing agent is
100:5。
Composite multifunction fabric embodiment 1-4 obtained carries out following performance test:
1, antibiotic property test: with reference to AATCC100, the test organisms of test escherichia coli (ATCC NO.8099) reduces percentage
Rate, the test organisms of staphylococcus aureus (ATCC NO.6538) reduces percentage rate, Candida albicans (ATCC NO.10231)
Test organisms reduces percentage rate.
2, anti-flammability test: using vertical combustion experiment to test, test after flame time .s, glow time .s, melted,
Drippage situation.
3, hydrophobicity test: measure dip experiment standard, wherein, 1 grade with reference to GB 4745 textile fabric surface moisture resistance--
By drenching the whole moistening in surface；2 grades--being had a dewetting by drenching surface, this typically refers to the total of the unconnected wetting areas of fritter
With；3 grades--only had unconnected little area moistening by drenching surface；4 grades--be there is no moistening by drenching surface, but speckle with little water on surface
Pearl；5 grades--be there is no moistening by drenching surface, do not speckle with droplet on surface yet.
The performance test results of the composite multifunction fabric that above-described embodiment 1-4 obtains is as shown in the table:
In the present invention, described composite multifunction fabric uses hydrophobic finishing agent and the flame-retardant antibacterial finishing agent leaching of specific composition
Roll and obtain, wherein, described hydrophobic finishing agent uses organosilicon-modified acrylic emulsion, combines containing organic on the surface of grey cloth
The hydrophobic group of silicon, its polarity is less than the polarity of Organic fluoride group, good with the compound property of other functional finishing agents；Pass through again
With modified polyethylene wax, polysiloxanes etc. and the hydroxy combining on grey cloth, further enhancing the hydrophobic performance of fabric；Described resistance
Combustion antibacterial finishing agent uses PERFORMANCE OF MODIFIED VERMICULITE, and owing to having air space between Vermiculitum synusia, interlayer is possibly together with water of crystallization, heat conduction simultaneously
Coefficient is low, is good flame resistant heat insulation material, and under high temperature, the volume energy of Vermiculitum expands rapidly several times to tens times, becomes expansion
Vermiculitum, its thermal isolation performance also becomes the most excellent；Heretofore described PERFORMANCE OF MODIFIED VERMICULITE by Vermiculitum is carried out quaternised modified,
Quaternary ammonium salt can exchange with Vermiculitum interlayer cation, after cetyl trimethylammonium bromide intercalation, and the sheet interlayer spacing of Vermiculitum
Increasing, pillared effect is obvious；Quaternary ammonium salt carries out etherification reaction with cyclodextrin more simultaneously so that on Vermiculitum, connection has Beta-cyclodextrin-based
Group, thus stability and the compatibility to Vermiculitum have carried out good improvement, good with the compound property of other functional finishing agents；Connect
By after polybasic carboxylic acid and sodium hypophosphite and the hydroxyl reaction on grey cloth, it is possible to the hydroxyl reaction on cyclodextrin, thus
By PERFORMANCE OF MODIFIED VERMICULITE essence anchor on grey cloth, while improving fabric fire resistance, do not interfere with the feel of fabric yet, have very simultaneously
Strong water-fastness fastness；Meanwhile, the chitosan, the halogen aminated compounds that add in flame-retardant antibacterial finishing agent have well
Anti-microbial property, avirulence and biocompatibility and biodegradability, while it has the fine compatibility with PERFORMANCE OF MODIFIED VERMICULITE,
Also can react with polybasic carboxylic acid and sodium hypophosphite, thus antibacterial is also integrated on grey cloth, compound thus without to other
The effect of agent and associativity produce impact.
The flame-retardant antibacterial finishing agent of specific non-fluorine water-repelling agent with specific composition and content is carried out compatibility by the present invention, described
Having collaborative facilitation between water-repelling agent and flame-proof antibiotic agent, the fabric finally given has that hydrophobicity is good, excellent flame retardancy,
The feature that antibiotic property is excellent.And the production method of the present invention is simple to operation, low cost, can be flexible according to different requirements
The consumption of regulatory function finishing agent and process technique.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (10)
1. a composite multifunction fabric, it is characterised in that described fabric by padding hydrophobic finishing agent and fire-retardant anti-by grey cloth
Bacterium finishing agent obtains；Wherein,
Described hydrophobic finishing agent percentage composition by weight includes:
Described flame-retardant antibacterial finishing agent percentage composition by weight includes:
Composite multifunction fabric the most according to claim 1, it is characterised in that described grey cloth is by cotton, polyester-cotton blend or terylene
Form through weaving.
Composite multifunction fabric the most according to claim 1 and 2, it is characterised in that described organosilicon-modified acrylic breast
Liquid be butyl acrylate, styrene and vinyltrimethoxy silane are carried out copolymerization after the copolymer emulsion that obtains, wherein, third
The weight proportion of olefin(e) acid butyl ester, styrene and vinyltrimethoxy silane is 1:0.4-0.8:0.8-2.2.
4. according to the composite multifunction fabric described in any one of claim 1-3, it is characterised in that described modified polyethylene wax is
Modified polyethylene wax containing hydroxyl and/or the modified polyethylene wax containing carboxyl.
5. according to the composite multifunction fabric described in any one of claim 1-4, it is characterised in that the preparation of described PERFORMANCE OF MODIFIED VERMICULITE
Technique includes: Vermiculitum is ground to 200-400 mesh, and stirring and evenly mixing after adding water adds CTA, stirring reaction at 80-100 DEG C
6-8h, obtains organic-pillared vermiculite after washing；Being added by cyclodextrin in isopropanol, adding content is the hydroxide of 25-35wt%
Sodium solution stirs, and adds described organic-pillared vermiculite, reacts 2-4h 40-60 DEG C of stirred in water bath, adds hydrochloric acid and adjusts
Saving sucking filtration to neutrality, obtain PERFORMANCE OF MODIFIED VERMICULITE, wherein Vermiculitum, CTA, cyclodextrin, isopropanol, the weight ratio of sodium hydroxide solution are
1:1-1.5:1-2:6-8:1.5-2。
6. according to the composite multifunction fabric described in any one of claim 1-5, described chitosan is N, and N, N-front three base enclosure is gathered
Sugar and/or diethylmethyl chitosan；Described halogen aminated compounds is the bromo-3-of 1-chloro-4,4,5,5-tetramethyl imidazolidin-2-one
And/or 5,5-dimethyl-3-(3 '-triethoxysilylpropyl)-glycolylurea.
7. according to the composite multifunction fabric described in any one of claim 1-6, it is characterised in that " described fabric is by by base
Cloth pads water-proof aagent and antibacterial finishing agent obtains " concrete operations as follows: first by after grey cloth alkali immerging, obtain pretreatment
Grey cloth；Again described hydrophobic finishing agent and flame-retardant antibacterial finishing agent are passed sequentially through the method padded and be applied to described pretreatment grey cloth
On, obtaining padding has water-repelling agent and the grey cloth of flame-proof antibiotic agent；Then described padding there are water-repelling agent and the base of flame-proof antibiotic agent
Cloth is dried, and obtains described composite multifunction fabric；Preferably, described grey cloth is 100:1-with the mass ratio of described hydrophobic finishing agent
10；Described grey cloth is 100:1-10 with the mass ratio of described flame-retardant antibacterial finishing agent.
Composite multifunction fabric the most according to claim 7, it is characterised in that the concrete operations of " by grey cloth alkali immerging "
As follows: grey cloth is padded soda bath, an immersing and rolling, pad temperature and be 60-80 DEG C, pick-up is 30-40%, and concentration of caustic soda is
40-200g/L；Then clear water rinsing 30-40min at 30-45 DEG C, bakees 20-30min, obtains pretreatment at 130-140 DEG C
Grey cloth.
Composite multifunction fabric the most according to claim 7, it is characterised in that " by described hydrophobic finishing agent by padding
Method be applied on described pretreatment grey cloth " concrete operations as follows: pretreatment grey cloth is padded in by organic-silicon-modified third
40-in the hydrophobic finishing agent of olefin(e) acid emulsion, modified polyethylene wax, polysiloxanes, polyisocyanate emulsion and water configuration
60min, two soak two rolls, and pick-up is to dry at 60-90%, 60-80 DEG C, solidifies, dry at 30-50 DEG C at 120-160 DEG C,
To padding the grey cloth having water-repelling agent.
Hydrophobic fire-retardant composite multifunction composite multifunction fabric the most according to claim 7, it is characterised in that " by described
Flame-retardant antibacterial finishing agent is applied on described pretreatment grey cloth by the method padded " concrete operations as follows: will pad have thin
The grey cloth of water preparation is padded in by the configuration of PERFORMANCE OF MODIFIED VERMICULITE, chitosan, halogen aminated compounds, polybasic carboxylic acid, sodium hypophosphite and water
10-50min in the flame-retardant antibacterial finishing agent solution become, two soak two rolls, and pick-up is preliminary drying 2-at 75-95%, 60-80 DEG C
Bakeing 2-5min at 5min, 120-160 DEG C, after cold water is washed, dry at 60-80 DEG C, obtaining padding has water-repelling agent and flame-proof antibiotic
The grey cloth of agent.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486866A (en) * | 2018-04-08 | 2018-09-04 | 吴亚琴 | A kind of preparation method of fabric flame-retardant agent |
| CN109295700A (en) * | 2018-09-07 | 2019-02-01 | 安徽亚源印染有限公司 | A kind of flame-proof antibiotic fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103114433A (en) * | 2013-03-05 | 2013-05-22 | 南通大学 | Preparation method of open-fire resistance thermal insulation textile |
| CN104072805A (en) * | 2014-07-02 | 2014-10-01 | 新疆奥吉立节能科技股份有限公司 | Vermiculite-based composite flame retardant and preparation method thereof |
| CN104294583A (en) * | 2014-10-20 | 2015-01-21 | 南通大学 | Preparation method of composite functional fabric with antimicrobial, anti-ultraviolet, deodorization and self-cleaning functions |
| CN104328664A (en) * | 2014-10-30 | 2015-02-04 | 北京中纺化工股份有限公司 | Compound function fabric and preparation method thereof |
| CN104947281A (en) * | 2015-06-11 | 2015-09-30 | 芜湖市瑞都服装贸易有限公司 | Dyeing and finishing method of bamboo fiber jean fabric |
-
2016
- 2016-06-12 CN CN201610417409.2A patent/CN105951449B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103114433A (en) * | 2013-03-05 | 2013-05-22 | 南通大学 | Preparation method of open-fire resistance thermal insulation textile |
| CN104072805A (en) * | 2014-07-02 | 2014-10-01 | 新疆奥吉立节能科技股份有限公司 | Vermiculite-based composite flame retardant and preparation method thereof |
| CN104294583A (en) * | 2014-10-20 | 2015-01-21 | 南通大学 | Preparation method of composite functional fabric with antimicrobial, anti-ultraviolet, deodorization and self-cleaning functions |
| CN104328664A (en) * | 2014-10-30 | 2015-02-04 | 北京中纺化工股份有限公司 | Compound function fabric and preparation method thereof |
| CN104947281A (en) * | 2015-06-11 | 2015-09-30 | 芜湖市瑞都服装贸易有限公司 | Dyeing and finishing method of bamboo fiber jean fabric |
Non-Patent Citations (1)
| Title |
|---|
| 杨栋樑: "超分子结构环糊精及其在染整加工中的应用（三）", 《印染》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486866A (en) * | 2018-04-08 | 2018-09-04 | 吴亚琴 | A kind of preparation method of fabric flame-retardant agent |
| CN109295700A (en) * | 2018-09-07 | 2019-02-01 | 安徽亚源印染有限公司 | A kind of flame-proof antibiotic fabric |
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