CN105950906A - Antioxidant silicon phosphorus brass - Google Patents

Antioxidant silicon phosphorus brass Download PDF

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Publication number
CN105950906A
CN105950906A CN201610309472.4A CN201610309472A CN105950906A CN 105950906 A CN105950906 A CN 105950906A CN 201610309472 A CN201610309472 A CN 201610309472A CN 105950906 A CN105950906 A CN 105950906A
Authority
CN
China
Prior art keywords
silicon
phosphorus
pyrite
antioxidant
brass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610309472.4A
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Chinese (zh)
Inventor
张军
何孔田
唐兰花
何孔高
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
Original Assignee
ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd filed Critical ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
Priority to CN201610309472.4A priority Critical patent/CN105950906A/en
Publication of CN105950906A publication Critical patent/CN105950906A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent

Abstract

The invention provides antioxidant silicon phosphorus brass. The chemical compositions of the antioxidant silicon phosphorus brass include, by weight, 61.8-63.7% of copper, 3.2-4.5% of silicon, 3.5-4.1% of phosphorus, 0.01-0.03% of cadmium, 0.04-0.05% of calcium, 0.008-0.015% of tungsten, 0.008-0.015% of manganese, 0.15-0.22% of yttrium, 0.004-0.006% of carbon, 0.004-0.006% of boron, 0.004-0.006% of iodine, 0.001-0.002% of vanadium, 0.1-0.2% of iron, 0.3-0.4% of chromium, 0.05-0.1% of lithium, 0.05-0.1% of lanthanum, 0.05-0.1% of praseodymium, and the balance zinc and inevitable impurities, and the content of the inevitable impurities does not exceed 0.5%. The silicon phosphorus brass has quite good oxidation resistance, is superior in acid and alkali resistance, good in mechanical performance, easy to cut and machine, capable of being subjected to heat treatment and forging conveniently, strong in torsional performance and quite suitable for manufacturing output shafts.

Description

A kind of antioxidant silicon phosphorus pyrite
Technical field
The present invention relates to technical field of metal, be specifically related to a kind of antioxidant silicon phosphorus pyrite.
Background technology
Pyrite makees the copper alloy of main adding elements with zinc, has yellow attractive in appearance, is referred to as pyrite.Copper zinc Bianry alloy claims basis brass or claims simple pyrite.Pyrite more than ternary claims special brass or claims complicated yellow Copper.Brass alloys containing the low what of zinc 36% are made up of solid solution, have good cold-forming property, as containing zinc The pyrite of 30% is commonly used to make shell case, is commonly called as cartridge brass or carobrozne.Containing zinc between 36~42% Brass alloys formed by with solid solution, most common of which is six or four pyrite containing zinc 40%.In order to improve The performance of basis brass, often adds other elements, such as aluminum nickel manganese stannum silicon lead etc..Aluminum can carry The intensity hardness of high pyrite and corrosion resistance, but make plasticity reduce, it is suitable as seagoing vessel condensing tube and other are resistance to Erosion part.Stannum can improve the intensity of pyrite and the rotproofness to sea water, therefore claims admirality brass, as boats and ships Thermal Equipment and propeller etc..Lead can improve the cutting ability of pyrite;This free-cutting brass is commonly used for clock Table part.Brassing is commonly used to make valve and pipe fitting etc..The fire hydrant explosion-proof moon that boats and ships are conventional Tooth spanner, it is simply that pyrite adds aluminum casting and forms.
Silicon phosphorus pyrite is mainly addition silicon, P elements in pyrite so that brass alloys mechanical property is more preferable. But at present, silicon phosphorus pyrite is corrosion-resistant, antioxidation, shock resistance are general, it is impossible to some of adaptation market Demand.
Summary of the invention
The technical problem to be solved is to provide a kind of antioxygenic property good, and acid-proof alkaline is excellent More, good mechanical property, Cutting free processing, heat treatment forging is convenient, the antioxidant silicon that twisting property is powerful Phosphorus pyrite.
The technical problem to be solved realizes by the following technical solutions:
A kind of antioxidant silicon phosphorus pyrite, its chemical composition is: copper 61.8-63.7wt%, silicon 3.2-4.5wt%, Phosphorus 3.5-4.1wt%, cadmium 0.01-0.03wt%, calcium 0.04-0.05wt%, tungsten 0.008-0.015wt%, Manganese 0.008-0.015wt%, yttrium 0.15-0.22wt%, carbon 0.004-0.006wt%, boron 0.004-0.006wt%, iodine 0.004-0.006wt%, vanadium 0.001-0.002wt%, ferrum 0.1-0.2wt%, Chromium 0.3-0.4wt%, lithium 0.05-0.1wt%, lanthanum 0.05-0.1wt%, praseodymium 0.05-0.1wt%, surplus For zinc and inevitable impurity, wherein inevitably the content of impurity is less than 0.5wt%.
A kind of antioxidant silicon phosphorus pyrite, it is preferable that its chemical composition is: copper 62.6wt%, silicon 3.8wt%, Phosphorus 3.8wt%, cadmium 0.02wt%, calcium 0.04wt%, tungsten 0.012wt%, manganese 0.012wt%, yttrium 0.18wt%, carbon 0.005wt%, boron 0.005wt%, iodine 0.005wt%, vanadium 0.001wt%, ferrum 0.1wt%, chromium 0.3wt%, lithium 0.08wt%, lanthanum 0.08wt%, praseodymium 0.08wt%, surplus be zinc and Inevitably impurity, wherein inevitably the content of impurity is less than 0.5wt%.
The invention has the beneficial effects as follows: silicon phosphorus pyrite of the present invention has extraordinary antioxygenic property, acidproof Alkali superior performance, good mechanical property, Cutting free processing, heat treatment forging is convenient, and twisting property is powerful, It is especially suitable for doing output shaft.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of antioxidant silicon phosphorus pyrite, its chemical composition is: copper 62.6wt%, silicon 3.8wt%, phosphorus 3.8wt%, cadmium 0.02wt%, calcium 0.04wt%, tungsten 0.012wt%, manganese 0.012wt%, yttrium 0.18wt%, Carbon 0.005wt%, boron 0.005wt%, iodine 0.005wt%, vanadium 0.001wt%, ferrum 0.1wt%, chromium 0.3wt%, lithium 0.08wt%, lanthanum 0.08wt%, praseodymium 0.08wt%, surplus is zinc and the most miscellaneous Matter, wherein inevitably the content of impurity is less than 0.5wt%.
Embodiment 2
A kind of antioxidant silicon phosphorus pyrite, its chemical composition is: copper 61.8wt%, silicon 3.2wt%, phosphorus 3.5wt%, cadmium 0.01wt%, calcium 0.04wt%, tungsten 0.008wt%, manganese 0.008wt%, yttrium 0.15wt%, Carbon 0.004wt%, boron 0.004wt%, iodine 0.004wt%, vanadium 0.001wt%, ferrum 0.1wt%, chromium 0.3wt%, lithium 0.05wt%, lanthanum 0.05wt%, praseodymium 0.05wt%, surplus is zinc and the most miscellaneous Matter, wherein inevitably the content of impurity is less than 0.5wt%.
Embodiment 3
A kind of antioxidant silicon phosphorus pyrite, its chemical composition is: copper 63.7wt%, silicon 4.5wt%, phosphorus 4.1wt%, cadmium 0.03wt%, calcium 0.05wt%, tungsten 0.015wt%, manganese 0.015wt%, yttrium 0.22wt%, Carbon 0.006wt%, boron 0.006wt%, iodine 0.006wt%, vanadium 0.002wt%, ferrum 0.2wt%, chromium 0.4wt%, lithium 0.05-0.1wt%, lanthanum 0.05-0.1wt%, praseodymium 0.05-0.1wt%, surplus be zinc and Inevitably impurity, wherein inevitably the content of impurity is less than 0.5wt%.
Test
The silicon phosphorus pyrite using the embodiment of the present invention 1 is tested, and placing it in relative humidity is 60%, oxygen Gas concentration be 30% experimental enviroment in 3 months, its surface is not any change, and placing it in concentration is 10% Sour environment in, the corrosion-free speckle in its surface, test that its moment of torsion is ordinary silicon phosphorus pyrite 2 times.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. an antioxidant silicon phosphorus pyrite, it is characterised in that its chemical composition is: copper 61.8-63.7wt%, Silicon 3.2-4.5wt%, phosphorus 3.5-4.1wt%, cadmium 0.01-0.03wt%, calcium 0.04-0.05wt%, tungsten 0.008-0.015wt%, manganese 0.008-0.015wt%, yttrium 0.15-0.22wt%, carbon 0.004-0.006wt%, boron 0.004-0.006wt%, iodine 0.004-0.006wt%, vanadium 0.001-0.002wt%, ferrum 0.1-0.2wt%, chromium 0.3-0.4wt%, lithium 0.05-0.1wt%, lanthanum 0.05-0.1wt%, praseodymium 0.05-0.1wt%, surplus is zinc and inevitable impurity, wherein can not keep away The content of the impurity exempted from is less than 0.5wt%.
2. a kind of antioxidant silicon phosphorus pyrite as claimed in claim 1, it is characterised in that its chemical composition For: copper 62.6wt%, silicon 3.8wt%, phosphorus 3.8wt%, cadmium 0.02wt%, calcium 0.04wt%, tungsten 0.012wt%, manganese 0.012wt%, yttrium 0.18wt%, carbon 0.005wt%, boron 0.005wt%, iodine 0.005wt%, vanadium 0.001wt%, ferrum 0.1wt%, chromium 0.3wt%, lithium 0.08wt%, lanthanum 0.08wt%, Praseodymium 0.08wt%, surplus is zinc and inevitable impurity, and wherein inevitably the content of impurity does not surpasses Cross 0.5wt%.
CN201610309472.4A 2016-05-10 2016-05-10 Antioxidant silicon phosphorus brass Pending CN105950906A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610309472.4A CN105950906A (en) 2016-05-10 2016-05-10 Antioxidant silicon phosphorus brass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610309472.4A CN105950906A (en) 2016-05-10 2016-05-10 Antioxidant silicon phosphorus brass

Publications (1)

Publication Number Publication Date
CN105950906A true CN105950906A (en) 2016-09-21

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610309472.4A Pending CN105950906A (en) 2016-05-10 2016-05-10 Antioxidant silicon phosphorus brass

Country Status (1)

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CN (1) CN105950906A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108660335A (en) * 2018-06-11 2018-10-16 太仓鸿鑫精密压铸有限公司 Copper alloy

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108660335A (en) * 2018-06-11 2018-10-16 太仓鸿鑫精密压铸有限公司 Copper alloy

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160921

WD01 Invention patent application deemed withdrawn after publication