CN105925834A - Anti-corrosion copper molybdenum chromium alloy - Google Patents

Anti-corrosion copper molybdenum chromium alloy Download PDF

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Publication number
CN105925834A
CN105925834A CN201610309473.9A CN201610309473A CN105925834A CN 105925834 A CN105925834 A CN 105925834A CN 201610309473 A CN201610309473 A CN 201610309473A CN 105925834 A CN105925834 A CN 105925834A
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China
Prior art keywords
alloy
copper
molybdenum
corrosion
chromium
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Pending
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CN201610309473.9A
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Chinese (zh)
Inventor
张军
何孔田
唐兰花
何孔高
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ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
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ANHUI JIUHUA KIMRUN COPPER INDUSTRY Co Ltd
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Priority to CN201610309473.9A priority Critical patent/CN105925834A/en
Publication of CN105925834A publication Critical patent/CN105925834A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Conductive Materials (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

Disclosed is an anti-corrosion copper molybdenum chromium alloy. The anti-corrosion copper molybdenum chromium alloy is chemically composed of 60-63wt% of copper, 5.8-8.8wt% of molybdenum, 4.2-6.6wt% of chromium, 0.3-0.4wt% of titanium, 0.3-0.4wt% of ytterbium, 0.02-0.5wt% of cerium, 0.02-0.05wt% of tungsten, 0.03-0.06wt% of lutecium, 0.01-0.02wt% of boron, 0.01-0.02wt% of rhodium, 0.01-0.02wt% of ruthenium, 0.005-0.01wt% of barium, 0.03-0.09wt% of rubidium, 0.005-0.06wt% of phosphorus, 0.05-0.07wt% of thulium, 0.04-0.08wt% of protactinium, 0.08-0.1wt% of aluminum, 0.04-0.05wt% of osmium, and the balance zinc and unavoidable impurities. The content of the unavoidable impurities is not more than 0.6wt%. The alloy does not contain lead but contains trivalent chromium without harm to the human body and serves as a novel environment-friendly material; the alloy is high in chemical corrosion resistance, excellent in abrasion resistance and anti-blast capacity and applicable to special anti-explosion places; the thermal conductivity of the alloy is 25-30% higher than that of common copper alloys, and the electrical resistivity of the alloy is 70-80% of that of the common copper alloys; and besides, the resonance resistance of the alloy is good, and the alloy does not crack by the aid of high-temperature tempering.

Description

A kind of corrosion-resistant copper molybdenum evanohm
Technical field
The present invention relates to technical field of metal, be specifically related to a kind of corrosion-resistant copper molybdenum evanohm.
Background technology
Copper alloy adds, by matrix, the alloy that one or more other elements are constituted with fine copper.Fine copper is purple Red also known as red copper.Fine copper density is that 8.96 fusing points are 1083 DEG C and have excellent electric conductivity and lead Hot ductility and corrosion resistance.It is mainly used in making generator bus cable switch device to become The heat transfer devices such as the flat plate collector of the electrotechnical apparatus such as depressor and heat-exchanger pipeline solar heat collector Material.Conventional copper alloy is divided into the big class of yellow metal copper-nickel alloy 3.
Brass makees the copper alloy of main adding elements with zinc, has yellow attractive in appearance, is referred to as brass.Copper zinc Bianry alloy claims basis brass or claims simple brass.Brass more than ternary claims special brass or claims complicated yellow Copper.Brass alloys containing the low what of zinc 36% are made up of solid solution, have good cold-forming property, as containing zinc The brass of 30% is commonly used to make shell case, is commonly called as cartridge brass or carobrozne.Containing zinc between 36~42% Brass alloys formed by with solid solution, most common of which is six or four brass containing zinc 40%.In order to improve The performance of basis brass, often adds other elements, such as aluminium nickel manganese tin silicon lead etc..Aluminium can carry The intensity hardness of high brass and corrosion resistance, but make plasticity reduce, it is suitable as seagoing vessel condenser pipe and other are resistance to Erosion part.Tin can improve the intensity of brass and the rotproofness to seawater, therefore claims admirality brass, as boats and ships Thermal Equipment and screw etc..Lead can improve the cutting ability of brass;This free-cutting brass is commonly used for clock Table part.Brassing is commonly used to make valve and pipe fitting etc..The fire hydrant explosion-proof moon that boats and ships are conventional Tooth spanner, it is simply that brass adds aluminum casting and forms.
Current brass alloys kind is many, but its quality or environmental-protecting performance sometimes differ and meet requirement surely, Such as, ledrite is widely used in the decay resistance of its excellence, free cutting property and processability Every field, but lead easily comes off from matrix material, and in process and product abandonment After, lead all can enter human body by all means and work the mischief.Following satisfied society is growing to difference The demand of copper alloy, so it is more and more crucial to study high performance copper alloy.
Summary of the invention
The technical problem to be solved is to provide a kind of chemical resistance strong, and it is the best to have Wearability and antiknock ability, thermal conductivity is good, the corrosion-resistant copper molybdenum evanohm that resistivity is low.
The technical problem to be solved realizes by the following technical solutions:
A kind of corrosion-resistant copper molybdenum evanohm, its chemical composition is: copper 60-63wt%, molybdenum 5.8-8.8wt%, Chromium 4.2-6.6wt%, titanium 0.3-0.4wt%, ytterbium 0.3-0.4wt%, cerium 0.02-0.5wt%, tungsten 0.02-0.05wt%, lutetium 0.03-0.06wt%, boron 0.01-0.02wt%, rhodium 0.01-0.02wt%, Ruthenium 0.01-0.02wt%, barium 0.005-0.01wt%, rubidium 0.03-0.09wt%, phosphorus 0.005-0.06wt%, Thulium 0.05-0.07wt%, protactinium 0.04-0.08wt%, aluminium 0.08-0.1wt%, osmium 0.04-0.05wt%, Surplus is zinc and inevitable impurity, and wherein inevitably the content of impurity is less than 0.6wt%.
A kind of corrosion-resistant copper molybdenum evanohm, it is preferable that its chemical composition is: copper 61.5wt%, molybdenum 7.3wt%, Chromium 5.4wt%, titanium 0.3wt%, ytterbium 0.3wt%, cerium 0.03wt%, tungsten 0.03wt%, lutetium 0.05wt%, Boron 0.01wt%, rhodium 0.01wt%, ruthenium 0.01wt%, barium 0.008wt%, rubidium 0.06wt%, phosphorus 0.005wt%, thulium 0.06wt%, protactinium 0.06wt%, aluminium 0.09wt%, osmium 0.04wt%, surplus is zinc With inevitable impurity, wherein inevitably the content of impurity is less than 0.6wt%.
The invention has the beneficial effects as follows: alloy of the present invention is the most leaded, containing trivalent chromium, harmless, be A kind of Novel environment-friendlymaterial material, chemical resistance is strong, has extraordinary wearability and antiknock ability, suitable Share in extraordinary explosion-proof place, its thermal conductivity 25-30% stronger than ordinary copper alloy, its resistivity is ordinary copper The 70-80% of alloy, and its resistance to resonance function admirable, high temperature forges and does not ftracture.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of corrosion-resistant copper molybdenum evanohm, its chemical composition is: copper 61.5wt%, molybdenum 7.3wt%, chromium 5.4wt%, titanium 0.3wt%, ytterbium 0.3wt%, cerium 0.03wt%, tungsten 0.03wt%, lutetium 0.05wt%, Boron 0.01wt%, rhodium 0.01wt%, ruthenium 0.01wt%, barium 0.008wt%, rubidium 0.06wt%, phosphorus 0.005wt%, thulium 0.06wt%, protactinium 0.06wt%, aluminium 0.09wt%, osmium 0.04wt%, surplus is zinc With inevitable impurity, wherein inevitably the content of impurity is less than 0.6wt%.
Embodiment 2
A kind of corrosion-resistant copper molybdenum evanohm, its chemical composition is: copper 60wt%, molybdenum 5.8wt%, chromium 4.2wt%, titanium 0.3wt%, ytterbium 0.3wt%, cerium 0.02wt%, tungsten 0.02wt%, lutetium 0.03wt%, Boron 0.01wt%, rhodium 0.01wt%, ruthenium 0.01wt%, barium 0.005wt%, rubidium 0.03wt%, phosphorus 0.005wt%, thulium 0.05wt%, protactinium 0.04wt%, aluminium 0.08wt%, osmium 0.04wt%, surplus is zinc With inevitable impurity, wherein inevitably the content of impurity is less than 0.6wt%.
Embodiment 3
A kind of corrosion-resistant copper molybdenum evanohm, its chemical composition is: copper 63wt%, molybdenum 8.8wt%, chromium 6.6wt%, titanium 0.4wt%, ytterbium 0.4wt%, cerium 0.5wt%, tungsten 0.05wt%, lutetium 0.06wt%, Boron 0.02wt%, rhodium 0.02wt%, ruthenium 0.02wt%, barium 0.01wt%, rubidium 0.09wt%, phosphorus 0.06wt%, Thulium 0.07wt%, protactinium 0.08wt%, aluminium 0.1wt%, osmium 0.05wt%, surplus is that zinc is with inevitable Impurity, wherein inevitably the content of impurity is less than 0.6wt%.
The general principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (2)

1. a corrosion-resistant copper molybdenum evanohm, it is characterised in that its chemical composition is: copper 60-63wt%, Molybdenum 5.8-8.8wt%, chromium 4.2-6.6wt%, titanium 0.3-0.4wt%, ytterbium 0.3-0.4wt%, cerium 0.02-0.5wt%, tungsten 0.02-0.05wt%, lutetium 0.03-0.06wt%, boron 0.01-0.02wt%, rhodium 0.01-0.02wt%, ruthenium 0.01-0.02wt%, barium 0.005-0.01wt%, rubidium 0.03-0.09wt%, Phosphorus 0.005-0.06wt%, thulium 0.05-0.07wt%, protactinium 0.04-0.08wt%, aluminium 0.08-0.1wt%, Osmium 0.04-0.05wt%, surplus is zinc and inevitable impurity, wherein the content of inevitable impurity Less than 0.6wt%.
A kind of corrosion-resistant copper molybdenum evanohm the most as claimed in claim 1, it is characterised in that its chemical group Become: copper 61.5wt%, molybdenum 7.3wt%, chromium 5.4wt%, titanium 0.3wt%, ytterbium 0.3wt%, cerium 0.03wt%, tungsten 0.03wt%, lutetium 0.05wt%, boron 0.01wt%, rhodium 0.01wt%, ruthenium 0.01wt%, Barium 0.008wt%, rubidium 0.06wt%, phosphorus 0.005wt%, thulium 0.06wt%, protactinium 0.06wt%, aluminium 0.09wt%, osmium 0.04wt%, surplus is zinc and inevitable impurity, wherein inevitable impurity Content less than 0.6wt%.
CN201610309473.9A 2016-05-10 2016-05-10 Anti-corrosion copper molybdenum chromium alloy Pending CN105925834A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107414148A (en) * 2017-09-19 2017-12-01 张家港钻通设备有限公司 A kind of numerical control machining center hard drill bit
CN107858600A (en) * 2017-11-07 2018-03-30 刘兴满 Axial-flow pump impeller alloy material
CN110629066A (en) * 2019-09-27 2019-12-31 黄山市龙跃铜业有限公司 High-strength corrosion-resistant brass material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1688732A (en) * 2002-09-13 2005-10-26 奥林公司 Age-hardening copper-base alloy and processing
CN1930314A (en) * 2004-03-12 2007-03-14 住友金属工业株式会社 Copper alloy and process for producing the same
CN104342578A (en) * 2014-10-21 2015-02-11 大丰市南亚阀门有限公司 Bronze alloy material for valve casting and treatment process thereof
CN106119600A (en) * 2016-08-30 2016-11-16 芜湖楚江合金铜材有限公司 Copper alloy wire that a kind of environmental protection high-quality is wear-resisting and processing technique thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1688732A (en) * 2002-09-13 2005-10-26 奥林公司 Age-hardening copper-base alloy and processing
CN1930314A (en) * 2004-03-12 2007-03-14 住友金属工业株式会社 Copper alloy and process for producing the same
CN104342578A (en) * 2014-10-21 2015-02-11 大丰市南亚阀门有限公司 Bronze alloy material for valve casting and treatment process thereof
CN106119600A (en) * 2016-08-30 2016-11-16 芜湖楚江合金铜材有限公司 Copper alloy wire that a kind of environmental protection high-quality is wear-resisting and processing technique thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107414148A (en) * 2017-09-19 2017-12-01 张家港钻通设备有限公司 A kind of numerical control machining center hard drill bit
CN107858600A (en) * 2017-11-07 2018-03-30 刘兴满 Axial-flow pump impeller alloy material
CN110629066A (en) * 2019-09-27 2019-12-31 黄山市龙跃铜业有限公司 High-strength corrosion-resistant brass material and preparation method thereof

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Application publication date: 20160907

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