CN105949930A - High-ductility water-based glass paint - Google Patents
High-ductility water-based glass paint Download PDFInfo
- Publication number
- CN105949930A CN105949930A CN201610452996.9A CN201610452996A CN105949930A CN 105949930 A CN105949930 A CN 105949930A CN 201610452996 A CN201610452996 A CN 201610452996A CN 105949930 A CN105949930 A CN 105949930A
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- China
- Prior art keywords
- agent
- glass paint
- paint
- aqueous glass
- high ductibility
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a high-ductility water-based glass paint. The water-based glass paint is composed of the following main components in percentage by mass: 35-40 wt% of water-based phenolic resin, 5-10 wt% of pigment and filler, 2-4 wt% of pH value regulator, 10-15 wt% of amino resin, 2-5 wt% of attapulgite, 1-3 wt% of aid, 1-3 wt% of cosolvent, 0.1-0.3 wt% of mildew preventive, 0.2-0.5 wt% of mothproofing agent and the balance of deionized water, totaling 100%. The water-based glass paint has very high ductility, has moldproof and mothproof effects, and especially has excellent control effects on mosquitoes, termites and mold.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of high ductibility aqueous glass paint.
Background technology
For glass (silicates nonmetallic materials), we are the strangest, and in daily life, glass and goods thereof are ubiquitous.Most commonly used application is at building and furnishing fields (door and window, curtain wall, partition, eyeglass etc. are decorated), automobile manufacturing field, new energy field (solar product), household electrical appliances and Electronic products manufacturing, daily life (various Bottle & Can dish) etc..But glass has frangible, poor flexibility, broken after the shortcoming easily hurted sb.'s feelings.As the glass coating of protective layer, it is often subject to the effect of various power, as rubbed, impacting, stretching etc., therefore it is required that the mechanical property that paint film must have necessity just can play a protective role.In recent years, along with the various glass lacquer goods that develop of national economy occur in the middle of the life of people, home improvement, StoreFront finishing, sliding door, furniture item, sanitaryware, Glass Craft processing etc., nowhere without glass lacquer, allow glass lacquer industry be able to flourish.Glass lacquer divides from character can be divided into waterborne glass coatings and conventional oil-based glass lacquer；Divide can be divided into from construction: Freehandhand-drawing paint, spraying paint, showering paint, roller coating etc.；Temperature is divided and can be divided into: self-drying paint, low temperature baking vanish, high temperature baking vanish；Concrete paint kind is calculated, can be the most a feast for the eyes, and ratio is if any solid color enamel, the colored varnish, frosting paint, vertical stricture of vagina paint, hammer paint, pu glass lacquer, EP glass lacquer, aerolite paint, crackle paint, three-dimensional paint etc..Although, glass lacquer has the advantage that water-acid resistance is strong, but its ductility is not the most fine.Ductility is one of physical attribute of material, and it refers to forge can roll degree.The character that object can extend into filament under external force and not rupture is ductility；The character that can be ground into thin slice in external force (hammering or rolling) effect and do not rupture is malleability.
Summary of the invention
It is an object of the invention to provide a kind of high ductibility aqueous glass paint.This coating has the highest ductility, and has effect of mildew and insect proof, especially mosquito, Coptotermes formosanus Shtrari. and mycete is had splendid prevention effect.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of high ductibility aqueous glass paint, its composition is in parts by weight: resol resins 35-40wt%, color stuffing 5-10wt%, pH value regulator 2-4wt%, amino resins 10-15wt%, attapulgite 2-5 wt%, auxiliary agent 1-3wt%, cosolvent 1-3wt%, antifungus agent 0.1-0.3wt%, insect-proof agent 0.2-0.5wt%, remaining as deionized water, above each composition quality mark sum is 100%；
Described auxiliary agent includes defoamer, substrate wetting agents, levelling agent, thickening agent, adhesion promoter, one or more in coalescents.
Described color stuffing includes one or more in Pulvis Talci, magnesium silicate, calcium carbonate, silica glass powder, barium sulfate.
Described antifungus agent is that Kazon, BIT, probenazole mix for 2:1:5 in mass ratio.
Described insect-proof agent is that fenvalerate, Permethrin, biphenyl polyester mix for 1:3:3 in mass ratio.
Compared with prior art, present invention have the advantage that
1) main chain in the resol resins of the present invention and side base contain aromatic heterocycle; network structure is formed by the cross-linking reaction of appropriateness; improve and draw high intensity level impact strength; thus improve the ductility that paint film is overall; this aqueous glass paint has the highest ductility, plays a very good protection ground；
2) Kazon, BIT, probenazole are carried out science and compound, make aqueous glass paint have splendid control of mold effect；
3) fenvalerate, Permethrin, biphenyl polyester are carried out science and compound, make aqueous glass paint have splendid mosquito, termite control effect；
4) low-carbon environment-friendly, reduces the discharge of VOC.
Detailed description of the invention
For the openest rather than restriction present invention, below in conjunction with example, the present invention is described in further detail.
Embodiment
1
A kind of high ductibility aqueous glass paint, its composition is in parts by weight: resol resins 35wt%, color stuffing 5wt%, pH value regulator 2wt%, amino resins 10wt%, attapulgite 2 wt%, auxiliary agent 1wt%, cosolvent 1wt%, antifungus agent 0.1wt%, insect-proof agent 0.2wt%, remaining as deionized water, above each composition quality mark sum is 100%；
Described auxiliary agent is defoamer.
Described color stuffing includes Pulvis Talci, magnesium silicate, calcium carbonate.
Described antifungus agent is that Kazon, BIT, probenazole mix for 2:1:5 in mass ratio.
Described insect-proof agent is that fenvalerate, Permethrin, biphenyl polyester mix for 1:3:3 in mass ratio.
Embodiment
2
A kind of high ductibility aqueous glass paint, its composition is in parts by weight: resol resins 38wt%, color stuffing 8wt%, pH value regulator 3wt%, amino resins 12wt%, attapulgite 3wt%, auxiliary agent 2wt%, cosolvent 2wt%, antifungus agent 0.2wt%, insect-proof agent 0.4wt%, remaining as deionized water, above each composition quality mark sum is 100%；
Described auxiliary agent includes defoamer, substrate wetting agents, levelling agent.
Described color stuffing is magnesium silicate.
Described antifungus agent is that Kazon, BIT, probenazole mix for 2:1:5 in mass ratio.
Described insect-proof agent is that fenvalerate, Permethrin, biphenyl polyester mix for 1:3:3 in mass ratio.
Embodiment
3
A kind of high ductibility aqueous glass paint, its composition is in parts by weight: resol resins 40wt%, color stuffing 10wt%, pH value regulator 4wt%, amino resins 15wt%, attapulgite 5 wt%, auxiliary agent 3wt%, cosolvent 3wt%, antifungus agent 0.3wt%, insect-proof agent 0.5wt%, remaining as deionized water, above each composition quality mark sum is 100%；
Described auxiliary agent is coalescents.
Described color stuffing is barium sulfate.
Described antifungus agent is that Kazon, BIT, probenazole mix for 2:1:5 in mass ratio.
Described insect-proof agent is that fenvalerate, Permethrin, biphenyl polyester mix for 1:3:3 in mass ratio.
Anophelifuge is tested
Detection device: two wooden chests of a size of 200cm × 200cm × 200cm, chest top one side is clear glass, is provided with one and puts mosquito hole in the middle of glass, and chest side is provided with the dodge gate of the most a size of 100cm × 100cm；
Detection environment: temperature: 25 ± 2 DEG C；Humidity: 55 ± 5%；
Detection mosquito kind: culex pipiens pallens；
Detection model: the high ductibility aqueous glass paint (A) present invention prepared and the aqueous glass paint (B) prepared according to the present embodiment 1 without antifungus agent and remaining step of insect-proof agent are brushed on the glass plate of a size of 190cm × 190cm (polylith) and 190cm × 90cm (polylith) respectively uniformly, then being positioned over temperature is 25 ± 2 DEG C, humidity be in the environment of 55 ± 5% after dry 7 days, respectively temperature be 25 ± 2 DEG C, humidity be to place 1 day, one month, 1 year and 2 years in the environment of 55 ± 5%, indwelling is stand-by.
Detection method: by above-mentioned be 25 ± 2 DEG C in temperature respectively, humidity is to placed 1 day in the environment of 55 ± 5%, one month, each five pieces of the model of a year and 2 years is respectively put in detection device by suitably sized size, and it is individually fixed in chest surrounding and bottom with double faced adhesive tape, then close dodge gate and start timing, from rearging cage, draw 100 culex pipiens pallens respectively with mosquito sucking tube after one hour and put in two wooden chests at mosquito hole from putting simultaneously, immediately close and put mosquito hole, open the dodge gate of two wooden cases after one hour simultaneously, and simultaneously closed off dodge gate after 30 minutes, remaining in clear point detection device subsequently mosquito quantity (go down in device for eliminating and be unable to stir any more mosquito).
Employing following equation calculates: anophelifuge efficiency=(mosquito quantity remaining in 100-detection device)/100 × 100%.
Experimental result is as follows:
As shown in Table 1, high ductibility aqueous glass paint prepared by the present invention has splendid repelling effect, the especially aqueous glass paint of the present embodiment 1 preparation, and anophelifuge rate has reached 100%.
Being used by the coating that embodiment 1-3 obtains, test proves, the coating that the present invention prepares is nonpoisonous and tasteless, and VOC content, close to 0, uses safety, not injures human body.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent and modification, all should belong to the covering scope of the present invention.
Claims (5)
1. a high ductibility aqueous glass paint, it is characterized in that: the composition of aqueous glass paint is in parts by weight: resol resins 35-40wt%, color stuffing 5-10wt%, pH value regulator 2-4wt%, amino resins 10-15wt%, attapulgite 2-5 wt%, auxiliary agent 1-3wt%, cosolvent 1-3wt%, antifungus agent 0.1-0.3wt%, insect-proof agent 0.2-0.5wt%, remaining as deionized water, above each composition quality mark sum is 100%.
A kind of high ductibility aqueous glass paint the most according to claim 1, it is characterised in that: described auxiliary agent includes defoamer, substrate wetting agents, levelling agent, thickening agent, adhesion promoter, one or more in coalescents.
A kind of high ductibility aqueous glass paint the most according to claim 1, it is characterised in that: described color stuffing includes one or more in Pulvis Talci, magnesium silicate, calcium carbonate, silica glass powder, barium sulfate.
A kind of high ductibility aqueous glass paint the most according to claim 1, it is characterised in that: described antifungus agent is that Kazon, BIT, probenazole mix for 2:1:5 in mass ratio.
A kind of high ductibility aqueous glass paint the most according to claim 1, it is characterised in that: described insect-proof agent is that fenvalerate, Permethrin, biphenyl polyester mix for 1:3:3 in mass ratio.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610452996.9A CN105949930A (en) | 2016-06-22 | 2016-06-22 | High-ductility water-based glass paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610452996.9A CN105949930A (en) | 2016-06-22 | 2016-06-22 | High-ductility water-based glass paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105949930A true CN105949930A (en) | 2016-09-21 |
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ID=56906116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610452996.9A Pending CN105949930A (en) | 2016-06-22 | 2016-06-22 | High-ductility water-based glass paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105949930A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189591A (en) * | 2017-07-12 | 2017-09-22 | 合肥思博特软件开发有限公司 | A kind of computer room Environmental-friendantistatic antistatic noise reducing coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1878835A (en) * | 2005-02-11 | 2006-12-13 | 德古萨公司 | Aqueous compositions |
| CN104312336A (en) * | 2014-11-05 | 2015-01-28 | 德阳森华涂料化工有限公司 | Water-based glass baking paint |
-
2016
- 2016-06-22 CN CN201610452996.9A patent/CN105949930A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1878835A (en) * | 2005-02-11 | 2006-12-13 | 德古萨公司 | Aqueous compositions |
| CN104312336A (en) * | 2014-11-05 | 2015-01-28 | 德阳森华涂料化工有限公司 | Water-based glass baking paint |
Non-Patent Citations (2)
| Title |
|---|
| 张民照等: "《生物农药及其应用技术问答 第2版》", 31 January 2016, 中国农业大学出版社 * |
| 郑茂松等: "《凹凸棒石黏土应用研究》", 30 April 2007, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189591A (en) * | 2017-07-12 | 2017-09-22 | 合肥思博特软件开发有限公司 | A kind of computer room Environmental-friendantistatic antistatic noise reducing coating and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20160921 |