CN105949704A - Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof - Google Patents
Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof Download PDFInfo
- Publication number
- CN105949704A CN105949704A CN201610485161.3A CN201610485161A CN105949704A CN 105949704 A CN105949704 A CN 105949704A CN 201610485161 A CN201610485161 A CN 201610485161A CN 105949704 A CN105949704 A CN 105949704A
- Authority
- CN
- China
- Prior art keywords
- parts
- abs
- pbi
- plastic alloy
- shock resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and a preparation method thereof. The environment-friendly impact-resistant PA/ABS/PBI plastic alloy is prepared by the following raw materials in parts by weight: 40-50 parts of PA, 45-50 parts of ABS, 20-25 parts of PBI, 15-26 parts of poly butyl methacrylate, 8-20 parts of cellulose diacetate, 12-14 parts of ramie bones, 1-2 parts of 2,4-dihydroxy benaophenonel, 2-5 parts of zirconium carbide, 2-3 parts of bayberry wax, 2-5 parts of thiourea, 4-8 parts of kaolin and 30-40 parts of water. The environment-friendly impact-resistant PA/ABS/PBI plastic alloy prepared by the method has the characteristics of being safe and environment-friendly, strong in impact resistance, high in compressive strength, good in weather resistance and the like, is low in processing cost, simple in preparation process, easy for parameter control, safe and environment-friendly in production process and suitable for large-scale industrial production.
Description
Technical field
Present invention relates particularly to a kind of environmental protection shock resistance PA/ABS/PBI plastic alloy and preparation thereof
Method.
Background technology
Plastic alloy be to utilize physical blending or the method for chemical graft and obtain high-performance, merit
Energyization, a class new material of customizations.Plastic alloy product can be widely used for automobile, electronics,
The fields such as precision instrument, office equipment, packaging material, construction material.It can improve or improve
The performance of existing plastics also reduces cost, it has also become kind the most active in plastics industry it
One, increase the rapidest.Along with China's sustained and rapid development of economy, a few years from now on China moulds
The material alloy market demand potential is huge, and especially telecommunications, automobile, the high speed of building industry increases
Long, pull on China's engineering plastic alloy industry fast-developing.Expect 2008, China five
Large-engineering plastics aggregate demand is up to 1,000,000 tons, and the demand of five big synthetic resin is up to
52000000 tons, one of maximum importer of whole world plastic alloy will be become.More than ten years recently,
The average annual growth rate of demand of world's plastic alloy is about 10%, the engineering that wherein added value is the highest
The rate of increase of plastic alloy is more up to about 15%, becomes the kind of each multinational corporations active development.
In the U.S., Europe, Japan's the most industrialized plastic alloy kind, engineering plastic alloy accounts for absolutely
Great majority, alloying has become the main method of current engineering plastic modification.And China's engineering plastic
Material alloy kind is few, of poor quality, and annual import volume accounts for more than the 60% of total demand.
Polyamide (PA) is that one uses engineering plastic resin widely.It is on molecular backbone
Containing recurring amide radical group-[NHCO]-the general name of thermoplastic resin；Due to unique low ratio
Weight, high-tensile, wear-resisting, self lubricity good, impact flexibility is excellent, has hard and soft having both
Performance and win the attention of people, in addition its processing is easy, efficiency high, light specific gravity (only
The 1/7 of metal), various goods can be processed into replace metal, be widely used in automobile and friendship
Logical transport service.
PBI is the abbreviation of polybenzimidazoles, and English name Polybenzimidazoles belongs to nothing
The special engineering plastics of sizing.PBI is by US National Aeronautics and Space Administration and USAF material
The high performance resin material that laboratory joint development goes out, has the most excellent heat-resisting quantity, resistance to
Low temperature properties, mechanical property and fire resistance, have wear-resisting, radiation hardness, resistance to acids and bases simultaneously,
The high performance resin material of a kind of great application prospect, application relate to Aero-Space,
Many high-tech areas such as optics, microelectronics.Along with the needs of technology development, the application of PBI
Field is the most gradually to civilian transfer.But due to the axial tension stress of PBI fiber and anti-shearing poor,
Hinder its large-scale application.
Acrylonitrile-butadiene-phenylethylene copolymer (ABS), has the resistance to impact, good of excellence
Good cryogenic property and chemical proofing, good stability of the dimension, lustrous surface property are good, flowing
Property good, it is easy to processing.The performance of ABS, between general-purpose plastics and engineering plastics, has very
Good mouldability, the product surface processed is bright and clean, additionally, also have higher impact strength
With preferable chemical stability, but its thermostability and toughness are the most poor.
In the market for have environmental protection, shock resistance plastic alloy demand the most all
Increase, but do not have corresponding product the most corresponding.Rare environmental protection impact resistance plastics on domestic market
Alloy, sells on a small quantity and public praise is preferably substantially imported product, and the market of home products accounts for
There is rate less.To this end, we set about from formula and the technique of product, develop new high-performance material
Material, it is provided that a kind of environmental protection shock resistance PA/ABS/PBI plastic alloy and preparation method thereof.
Summary of the invention
To achieve these goals, the invention provides a kind of environmental protection shock resistance PA/ABS/PBI
Plastic alloy and preparation method thereof.
It is an object of the invention to be achieved through the following technical solutions:
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy, by the raw material system of following weight portion
Become: PA 40-50 part, ABS 45-50 part, PBI 20-25 part, polybutyl methacrylate
15-26 part, cellulose diacetate 8-20 part, Boehmeria boon 12-14 part, 2,4-dihydroxy
Benzophenone 1-2 part, zirconium carbide 2-5 part, bayberry wax 2-3 part, thiourea 2-5 part, kaolinite
Soil 4-8 part, water 30-40 part.
Described environmental protection shock resistance PA/ABS/PBI plastic alloy is by the raw material system of following weight portion
Become: PA 40 parts, ABS 45 parts, PBI 20 parts, polybutyl methacrylate 15 parts, two
Cellulose acetate 8 parts, Boehmeria boon 12 parts, 2,4-DihydroxyBenzophenone 1 part, carbonization
Zirconium 2 parts, bayberry wax 2 parts, thiourea 2 parts, Kaolin 4 parts, 30 parts of water.
Described environmental protection shock resistance PA/ABS/PBI plastic alloy is by the raw material system of following weight portion
Become: PA 50 parts, ABS 50 parts, PBI 25 parts, polybutyl methacrylate 26 parts, two
Cellulose acetate 20 parts, Boehmeria boon 14 parts, 2,4-DihydroxyBenzophenone 2 parts, carbon
Change zirconium 5 parts, bayberry wax 3 parts, thiourea 5 parts, Kaolin 8 parts, 40 parts of water.
Described environmental protection shock resistance PA/ABS/PBI plastic alloy is by the raw material system of following weight portion
Become: PA 45 parts, ABS 47 parts, PBI 23 parts, polybutyl methacrylate 19 parts, two
Cellulose acetate 12 parts, Boehmeria boon 13 parts, 2,4-DihydroxyBenzophenone 2 parts, carbon
Change zirconium 3 parts, bayberry wax 3 parts, thiourea 3 parts, Kaolin 6 parts, 35 parts of water.
The preparation method of described environmental protection shock resistance PA/ABS/PBI plastic alloy, prepared by the method
Step is as follows: weighs each raw material by described parts by weight and adds in mixing and blending machine, carries out point
Dissipate mixed processing, then the batch mixing being dispersed through mixed processing joined in double screw extruder,
Carry out extruding pelletization.
Beneficial effect: the environmental protection shock resistance PA/ABS/PBI plastics that the inventive method prepares
Alloy has the feature such as safety and environmental protection, impact resistance is strong, compressive resistance is high, good weatherability, adds
Work low cost, preparation technology is simple, parameter is easily-controllable, production process safety and environmental protection, is suitable for big rule
The industrialized production of mould.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention,
Although the present invention being described in detail with reference to previous embodiment, for the technology of this area
For personnel, the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it
In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention
Within the scope of.
Embodiment 1
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy, by the raw material system of following weight portion
Become: PA 40 parts, ABS 45 parts, PBI 20 parts, polybutyl methacrylate 15 parts, two
Cellulose acetate 8 parts, Boehmeria boon 12 parts, 2,4-DihydroxyBenzophenone 1 part, carbonization
Zirconium 2 parts, bayberry wax 2 parts, thiourea 2 parts, Kaolin 4 parts, 30 parts of water.
Its preparation methods steps is as follows: weighs the addition mixing of each raw material by described parts by weight and stirs
Mix in machine, carry out dispersion mixing process, then the batch mixing being dispersed through mixed processing is joined double
In screw extruder, carry out extruding pelletization.
Embodiment 2
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy, by the raw material system of following weight portion
Become: PA 50 parts, ABS 50 parts, PBI 25 parts, polybutyl methacrylate 26 parts, two
Cellulose acetate 20 parts, Boehmeria boon 14 parts, 2,4-DihydroxyBenzophenone 2 parts, carbon
Change zirconium 5 parts, bayberry wax 3 parts, thiourea 5 parts, Kaolin 8 parts, 40 parts of water.
Its preparation methods steps is as follows: weighs the addition mixing of each raw material by described parts by weight and stirs
Mix in machine, carry out dispersion mixing process, then the batch mixing being dispersed through mixed processing is joined double
In screw extruder, carry out extruding pelletization.
Embodiment 3
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy, by the raw material system of following weight portion
Become: PA 45 parts, ABS 47 parts, PBI 23 parts, polybutyl methacrylate 19 parts, two
Cellulose acetate 12 parts, Boehmeria boon 13 parts, 2,4-DihydroxyBenzophenone 2 parts, carbon
Change zirconium 3 parts, bayberry wax 3 parts, thiourea 3 parts, Kaolin 6 parts, 35 parts of water.
Its preparation methods steps is as follows: weighs the addition mixing of each raw material by described parts by weight and stirs
Mix in machine, carry out dispersion mixing process, then the batch mixing being dispersed through mixed processing is joined double
In screw extruder, carry out extruding pelletization.
Claims (5)
1. an environmental protection shock resistance PA/ABS/PBI plastic alloy, it is characterised in that described ring
Protect shock resistance PA/ABS/PBI plastic alloy to be prepared by the raw materials in: PA 40-50
Part, ABS 45-50 part, PBI 20-25 part, polybutyl methacrylate 15-26 part, two
Cellulose acetate 8-20 part, Boehmeria boon 12-14 part, 2,4-DihydroxyBenzophenone 1-2
Part, zirconium carbide 2-5 part, bayberry wax 2-3 part, thiourea 2-5 part, Kaolin 4-8 part, water
30-40 part.
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy,
It is characterized in that, described environmental protection shock resistance PA/ABS/PBI plastic alloy is by following weight portion
Raw material is made: PA 40 parts, ABS 45 parts, PBI 20 parts, polybutyl methacrylate 15
Part, cellulose diacetate 8 parts, Boehmeria boon 12 parts, 2,4-DihydroxyBenzophenone 1 part,
Zirconium carbide 2 parts, bayberry wax 2 parts, thiourea 2 parts, Kaolin 4 parts, 30 parts of water.
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy,
It is characterized in that, described environmental protection shock resistance PA/ABS/PBI plastic alloy is by following weight portion
Raw material is made: PA 50 parts, ABS 50 parts, PBI 25 parts, polybutyl methacrylate 26
Part, cellulose diacetate 20 parts, Boehmeria boon 14 parts, 2,4-DihydroxyBenzophenone 2
Part, zirconium carbide 5 parts, bayberry wax 3 parts, thiourea 5 parts, Kaolin 8 parts, 40 parts of water.
A kind of environmental protection shock resistance PA/ABS/PBI plastic alloy,
It is characterized in that, described environmental protection shock resistance PA/ABS/PBI plastic alloy is by following weight portion
Raw material is made: PA 45 parts, ABS 47 parts, PBI 23 parts, polybutyl methacrylate 19
Part, cellulose diacetate 12 parts, Boehmeria boon 13 parts, 2,4-DihydroxyBenzophenone 2
Part, zirconium carbide 3 parts, bayberry wax 3 parts, thiourea 3 parts, Kaolin 6 parts, 35 parts of water.
5. the environmental protection shock resistance PA/ABS/PBI plastics according to any one of claim 1-4 close
The preparation method of gold, it is characterised in that the method preparation process is as follows: by described weight portion
Number weighs each raw material and adds in mixing and blending machine, carries out dispersion mixing process, then will be dispersed through
The batch mixing of mixed processing joins in double screw extruder, carries out extruding pelletization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485161.3A CN105949704A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485161.3A CN105949704A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105949704A true CN105949704A (en) | 2016-09-21 |
Family
ID=56904377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610485161.3A Pending CN105949704A (en) | 2016-06-23 | 2016-06-23 | Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105949704A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109852055A (en) * | 2019-01-29 | 2019-06-07 | 江苏常源新材料科技有限公司 | A kind of preparation method of polybenzimidazoles plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007000382A1 (en) * | 2005-06-25 | 2007-01-04 | Evonik Degussa Gmbh | Thermoplastic compound/matrix |
| CN102850782A (en) * | 2011-06-29 | 2013-01-02 | 合肥杰事杰新材料股份有限公司 | PA/ABS alloy material and preparation method thereof |
| CN104893228A (en) * | 2015-06-29 | 2015-09-09 | 蔡恩扬 | High-strength and high-hardness PA (polyamide)/ABS (acrylonitrile butadiene styrene)/PBI (polybenzimidazole) plastic alloy and method for manufacturing same |
-
2016
- 2016-06-23 CN CN201610485161.3A patent/CN105949704A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007000382A1 (en) * | 2005-06-25 | 2007-01-04 | Evonik Degussa Gmbh | Thermoplastic compound/matrix |
| CN102850782A (en) * | 2011-06-29 | 2013-01-02 | 合肥杰事杰新材料股份有限公司 | PA/ABS alloy material and preparation method thereof |
| CN104893228A (en) * | 2015-06-29 | 2015-09-09 | 蔡恩扬 | High-strength and high-hardness PA (polyamide)/ABS (acrylonitrile butadiene styrene)/PBI (polybenzimidazole) plastic alloy and method for manufacturing same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109852055A (en) * | 2019-01-29 | 2019-06-07 | 江苏常源新材料科技有限公司 | A kind of preparation method of polybenzimidazoles plate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101508817B (en) | High-light ABS alloy and method for producing the same | |
| CN101555341B (en) | High-strength fiber glass reinforced ABS composite material and preparation method thereof | |
| CN108504089B (en) | High-strength wear-resistant plastic material and preparation method thereof | |
| CN102241846A (en) | Calcium sulfate whisker modified high density polyethylene composite material and preparation method thereof | |
| CN106519530B (en) | A kind of composite material and preparation method | |
| CN109762327A (en) | A kind of bamboo fiber reinforcement nylon composite materials and preparation method thereof | |
| CN103435950A (en) | PMMA/ABS composite material, and preparation method and application thereof | |
| CN103374198A (en) | Basalt fiber-reinforced thermoplastic polyether-ether-ketone/polyimide composite material and preparation method thereof | |
| CN103819829A (en) | High-performance engineering plastic/polyester type TPU (thermoplastic polyurethane) alloy material and preparation method thereof | |
| CN102964678A (en) | Basalt fiber reinforced polypropylene composite material and preparation method thereof | |
| CN102796336A (en) | Modified polymethyl methacrylate transparent material and preparation method thereof | |
| CN102391605B (en) | Preparation method of polyformaldehyde toughening agent, toughening polyformaldehyde and toughening agent | |
| CN112708196A (en) | Reinforced polypropylene material and preparation method and application thereof | |
| CN105949704A (en) | Environment-friendly impact-resistant PA (Polyamide)/ABS (Acrylonitrile Butadiene Styrene)/PBI (Protein Bound Iodine) plastic alloy and preparation method thereof | |
| CN109897569A (en) | A kind of conductive adhesive resin of colliery wire pipe and preparation method thereof and steel wire tube | |
| CN104725755A (en) | PMMA (polymethyl methacrylate)/ABS (acrylonitrile-butadiene-styrene) alloy material with high blackness and brightness and preparation method of PMMA/ABS alloy material | |
| CN105086162A (en) | Fibrilia-reinforced polypropylene engineering composite as well as preparation method and application of fibrilia-reinforced polypropylene engineering composite | |
| CN103374222A (en) | Composite toughened reinforced nylon and preparation method thereof | |
| CN102850745A (en) | Glass fiber reinforced polycarbonate composite material | |
| CN106118037A (en) | A kind of high-strength corrosion-resisting PA/ABS/PBI plastic alloy and preparation method thereof | |
| CN106398090A (en) | An impact-resistant toughened PA/ABS/PBI plastic alloy and a preparing method thereof | |
| CN105754319A (en) | Vehicle polyphenyl ether alloy material and preparation method thereof | |
| CN104974511A (en) | Diatomite/nylon-6 composite material and preparation method thereof | |
| CN109957200A (en) | Home appliance panel bloom high-fluidity high-toughness intermingling material and preparation method thereof | |
| CN109503971A (en) | A kind of SAN/PMMA composite material and preparation method for bathroom |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160921 |
|
| RJ01 | Rejection of invention patent application after publication |