CN105949607A - Solar cell back plate material - Google Patents
Solar cell back plate material Download PDFInfo
- Publication number
- CN105949607A CN105949607A CN201610588829.7A CN201610588829A CN105949607A CN 105949607 A CN105949607 A CN 105949607A CN 201610588829 A CN201610588829 A CN 201610588829A CN 105949607 A CN105949607 A CN 105949607A
- Authority
- CN
- China
- Prior art keywords
- agent
- solar cell
- prepares
- cell backboard
- maleic anhydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 47
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 69
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 31
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000003381 stabilizer Substances 0.000 claims abstract description 26
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims abstract description 26
- -1 compatilizer Substances 0.000 claims abstract description 25
- 239000007822 coupling agent Substances 0.000 claims abstract description 25
- 239000002562 thickening agent Substances 0.000 claims abstract description 25
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 238000005189 flocculation Methods 0.000 claims abstract description 19
- 230000016615 flocculation Effects 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 239000004014 plasticizer Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003365 glass fiber Substances 0.000 claims abstract description 13
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims abstract description 13
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims abstract description 13
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 13
- 239000011591 potassium Substances 0.000 claims abstract description 13
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 13
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 36
- 239000004606 Fillers/Extenders Substances 0.000 claims description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- 239000012745 toughening agent Substances 0.000 claims description 18
- 229940125725 tranquilizer Drugs 0.000 claims description 18
- 239000003204 tranquilizing agent Substances 0.000 claims description 18
- 230000002936 tranquilizing effect Effects 0.000 claims description 18
- FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical compound CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 229920000388 Polyphosphate Polymers 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 12
- XCJXQCUJXDUNDN-UHFFFAOYSA-N chlordene Chemical compound C12C=CCC2C2(Cl)C(Cl)=C(Cl)C1(Cl)C2(Cl)Cl XCJXQCUJXDUNDN-UHFFFAOYSA-N 0.000 claims description 12
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 claims description 12
- 239000001205 polyphosphate Substances 0.000 claims description 12
- 235000011176 polyphosphates Nutrition 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- CDINNLUJIQAPRY-UHFFFAOYSA-N 5-chloropent-1-enylbenzene Chemical compound ClCCCC=CC1=CC=CC=C1 CDINNLUJIQAPRY-UHFFFAOYSA-N 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 6
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical group FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 229920003086 cellulose ether Polymers 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000010074 rubber mixing Methods 0.000 claims description 6
- 150000004756 silanes Chemical class 0.000 claims description 6
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 6
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 6
- 230000032683 aging Effects 0.000 abstract description 8
- 230000015556 catabolic process Effects 0.000 abstract description 7
- 230000007935 neutral effect Effects 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 7
- VOMZBQULILVGPN-UHFFFAOYSA-N 1,1,2,2,3,3-hexachlorocyclododecane Chemical compound ClC1(Cl)CCCCCCCCCC(Cl)(Cl)C1(Cl)Cl VOMZBQULILVGPN-UHFFFAOYSA-N 0.000 abstract 1
- KVQKJZWDZSTDEF-UHFFFAOYSA-N 1,1-dichloropent-1-en-2-ylbenzene Chemical compound C(CC)C(=C(Cl)Cl)C1=CC=CC=C1 KVQKJZWDZSTDEF-UHFFFAOYSA-N 0.000 abstract 1
- QFXSWGXWZXSGLC-UHFFFAOYSA-N 3-methylpent-2-en-1-ol Chemical compound CCC(C)=CCO QFXSWGXWZXSGLC-UHFFFAOYSA-N 0.000 abstract 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 abstract 1
- 239000003595 mist Substances 0.000 abstract 1
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 235000019830 sodium polyphosphate Nutrition 0.000 abstract 1
- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 6
- 239000003925 fat Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229920002313 fluoropolymer Polymers 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 206010073306 Exposure to radiation Diseases 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/049—Protective back sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/204—Applications use in electrical or conductive gadgets use in solar cells
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The invention discloses a solar cell back plate material. The material is prepared from EVA resin, ethylene glycol monostearate, glyceryl tristearate, tris(2,4-di-tert-butylphenyl)phosphate, n-butyl acetate, maleic anhydride grafted ethylene propylene diene monomer, propyldichloro styrene, maleic anhydride grafted polypropylene, hexachlorcyclododecane, 3-ethylbut-2-en-1-ol, magnesium oxide, zinc oxide, chlorinated paraffin, sodium stearate, sodium polyphosphate, hydroxymethyl cellulose potassium, glass fiber, body pigment, coupling agent, compatilizer, antioxidant, stabilizer, bridging agent, regulator, reinforcing agent, flocculation agent, flexibilizer, plasticizer, thickener, stabilizer and terminator. The prepared solar cell back plate material has high mechanical performance, neutral salt mist resistance and ageing resistance, also has excellent breakdown voltage intensity and can be widely adopted as the solar cell back plate material.
Description
[technical field]
The invention belongs to environmental technology field and battery back-sheet technical field of material, be specifically related to a kind of solar cell backboard material.
[background technology]
Solar energy backboard is positioned at the back side of solar panel, it is fluorocarbon coating prepared by matrix resin with fluororesin transnational enterprise (such as Japan AGC, great Jin and the France A Kema etc.) PVDF of Development and Production, CTFE, PTFE resin, it is widely used in the surfacecti proteon of bridge, mansion, railway, communications facility, and subjected to the outdoor ordeal of more than 40 years, show splendid weather resistance.Meanwhile, the material surface modifying technology including low-temperature plasma modified technology, radiation modification technology, vacuum plasma Chemical Grafting Technique is the most ripe at present.Therefore, fluorocarbon coating, pet sheet face modification technology, fluorine coating process for modifying surface etc. are applied to the exploitation of solar cell notacoria, thus it is feasible for realizing not using adhesive and having the low-cost high-quality application type notacoria product of excellent long-term weatherability performance, also it is back membrane material development from now on and the only way domesticized.Owing to domestic re-glue type notacoria manufacturing enterprise does not possess the advantage of cost and quality in terms of main raw material(s) and core technology, the core competitiveness causing product overall is relatively low with profit margin.
Application No. 2012102564391, the Chinese patent application of entitled " a kind of solar cell backboard and preparation method " discloses a kind of solar cell backboard, it is characterized in that solar cell backboard is symmetrical structure, centre is polyethylene terephthalate layer 40, centre be outwards followed successively by adhesive layer 30, silicon oxide layer 20 and fluoroplastic layer 10.The described solar cell backboard of this invention has gas permeation rate and the low feature of water transmitance, has alkali resistance, weather resisteant, feature that mechanical strength is high simultaneously.This invention is fluorine-containing, easily causes environmental pollution, and relatively costly.
Application No. 2013106903110, the Chinese patent application of entitled " a kind of solar cell backboard and manufacture method thereof " discloses a kind of solar cell backboard and manufacture method thereof, including middle substrate layer, the upper and lower faces of described substrate layer is equipped with fluoropolymer membrane；Connected by adhesive layer between described fluoropolymer membrane and substrate layer；Wherein, described substrate layer is made up of the component of following parts by weight: polyethylene terephthalate 80-90 part, uvioresistant additive 5-15 part；Described fluoropolymer membrane is made up of the component of following parts by weight: Kynoar 70-80 part, polymethyl methacrylate 5-10 part, titanium dioxide 5-10 part, bismuth oxide 1-2 part.Solar cell backboard prepared by this inventive method is simple and reasonable, and barrier property is excellent.The uvioresistant additive of this invention is only capable of uvioresistant, and the resistance for extraneous hygrothermal environment is relatively low.
EVA product of rubber and plastic is novel environment friendly plastics packaging material, has the advantages such as good buffering, antidetonation, ecsomatics corrosion heat insulation, moistureproof, anti-, have nontoxic, do not absorb water.EVA product of rubber and plastic can shape through design, and its shockproof properties is better than the conventional packaging material such as polystyrene (foam), and meets environmental requirement, is the optimum selection of exported product.Can cut relative to Shockproof packaging, molding；Because density variation is bigger, it is also possible to there is purposes the most widely.The feature of EVA: resistance to water: closedcells structure, do not absorb water, moistureproof, water resistance is good.Corrosion resistance: the chemicals corrosion such as sea water resistance, oils and fats, acid, alkali, antibacterial, nontoxic, tasteless, pollution-free.Processability: non junction, and be prone to carry out hot pressing, cut out, gluing, the processing such as laminating.Against shock: resilience and tension stress are high, and toughness is high, has good shockproof cushioning performance.Heat insulating ability: heat insulation, heat-insulating and cold and low temperature performance excellent, can be cold-resistant and tan by the sun.Sound-proofing: closedcells, soundproof effect is good.
The feature of EVA resin is to have good flexibility, the elasticity as rubber, still is able to have preferable pliability at-50 DEG C, and the transparency and lustrous surface property are good, and chemical stability is good, and aging resistance and resistance to ozone intensity are good, avirulence.Good with the miscibility of filler, coloring and molding processibility are good.EVA resin is had many uses.Generally, vinyl acetate content EVA below 5%, its major product is thin film, electric wire, LDPE modifying agent, adhesive etc.；Vinyl acetate content is elastic film etc. at the EVA product of 5%-10%；Vinyl acetate content, at the EVA of 20%-28%, is mainly used in hotmelt and coated article；Vinyl acetate content is at 5%-
45%, major product is thin film (including agricultural film) and sheet material, injection, moulding article, foaming product, hotmelt etc..
Therefore EVA resin is widely used owing to there being the character of uniqueness.In recent years, in area of solar cell, EVA material is widely used, but owing to the EVA mechanical strength of one-component is inadequate, ageing-resistant performance and electric property can not meet the application requirement of field of solar thermal power generation simultaneously, therefore it is accomplished by carrying out composite modified to it, develops a kind of solar cell backboard composite with good mechanical properties, ageing-resistant performance and electric property, meet the needs in solar cell device field.
[summary of the invention]
The present invention provides a kind of solar cell backboard material, and to solve the mechanical performance of existing solar cell backboard material and resistance to neutral salt spray and loss of properties on aging, breakdown voltage strength is little, and material is fluorine-containing, and toxicity is big, easily causes the problems such as environmental pollution.The solar cell backboard material that the present invention prepares not only has good mechanical performance and resistance to neutral salt spray and ageing-resistant performance, and has excellent breakdown voltage strength, can be widely applied in solar cell backboard material.
For solve above technical problem, the present invention by the following technical solutions:
nullA kind of solar cell backboard material，In units of weight，It is made up of following raw material: EVA resin 110-195 part、Ethylene glycol monostearate 34-48 part、Glyceryl tristearate 28-38 part、Three (2，4-di-tert-butyl-phenyl) phosphite ester 24-32 part、N-butyl acetate 16-20 part、Maleic anhydride grafting ethylene propylene diene rubber 18-22 part、Chloropropyl styrene 16-24 part、Maleic anhydride inoculated polypropylene 15-20 part、Chlordene cyclododecane 10-16 part、3-ethyl-2-butylene-1-alcohol 12-18 part、Magnesium oxide 6-10 part、Zinc oxide 6-10 part、Chlorinated paraffin 16-25 part、Sodium stearate 10-20 part、Polyphosphate sodium 8-15 part、Hydroxymethyl cellulose potassium 9-15 part、Glass fibre 4-8 part、Extender pigment 18-24 part、Coupling agent 1-2 part、Compatilizer 1-2 part、Antioxidant 0.8-1.4 part、Tranquilizer 0.8-1.4 part、Bridging agent 0.6-1.2 part、Regulator 0.5-0.9 part、Hardening agent 0.4-0.6 part、Flocculation agent 0.4-0.6 part、Toughener 0.3-0.5 part、Plasticizer 0.3-0.5 part、Thickening agent 0.3-0.5 part、Stabilizer 0.2-0.4 part、Terminator 0.1-0.3 part；
Described extender pigment is calcium carbonate；
Described coupling agent is epoxy silane class coupling agent；
Described compatilizer is that maleic anhydride is grafted compatilizer；
Described antioxidant is antioxidant 1010；
Described tranquilizer constituent is ardealite, ferrum oxide；
Described bridging agent is acrylic type bridging agent；
Described regulator is processing aids acrylic resin；
Described hardening agent is 701 powder hardening agents；
The preparation method of described solar cell backboard material, comprises the following steps:
S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, it is 750-780 DEG C in temperature, rotating speed is stirring 5-10min under 200-300r/min, prepares mixture I；
S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 100-300W at microwave power; temperature is 650-700 DEG C; rotating speed is stirring 3-6h under 100-400r/min, prepares mixture II；
S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 350-450 DEG C in temperature, rotating speed is stirring 0.4-0.8h under 100-300r/min, prepares mixture III；
S4: being dried the mixture III that step 3 prepares to moisture content≤20ppm, in the double screw extruder that screw slenderness ratio is 10:1, be 200-220 DEG C in temperature, rotating speed is extrusion molding under 20-50r/min, prepares solar cell backboard material after being cooled to room temperature.
Further, described flocculation agent is aluminium polychlorid.
Further, described toughener is carborundum whisker.
Further, described plasticizer is dioctyl adipate.
Further, described thickening agent is cellulose ethers thickening agent.
Further, described stabilizer is fat acids stabilizer.
Further, described terminator is styrene.
The method have the advantages that
(1) the solar cell backboard material that the present invention prepares has good combination property, wherein impact strength has reached more than 69.68MPa, percentage elongation has reached more than 17.21%, elongation at break has reached more than 369.21%, it is without exception that resistance to neutral salt spray test has reached more than 1440h, breakdown voltage strength has reached more than 30.92KV/mm, man-made radiation's exposure test reaches more than 2380h, there is good mechanical performance and resistance to neutral salt spray and ageing-resistant performance, there is excellent breakdown voltage strength simultaneously, can be widely applied in solar cell backboard material.
(2) the solar cell backboard material that the present invention prepares is the most fluorine-containing, and toxicity is minimum, does not easily cause environmental pollution, and production cost is low simultaneously, beneficially popularization and application.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to protection scope of the present invention, but are not intended to protection scope of the present invention.
nullIn an embodiment，Described solar cell backboard material，In units of weight，It is made up of following raw material: EVA resin 110-195 part、Ethylene glycol monostearate 34-48 part、Glyceryl tristearate 28-38 part、Three (2，4-di-tert-butyl-phenyl) phosphite ester 24-32 part、N-butyl acetate 16-20 part、Maleic anhydride grafting ethylene propylene diene rubber 18-22 part、Chloropropyl styrene 16-24 part、Maleic anhydride inoculated polypropylene 15-20 part、Chlordene cyclododecane 10-16 part、3-ethyl-2-butylene-1-alcohol 12-18 part、Magnesium oxide 6-10 part、Zinc oxide 6-10 part、Chlorinated paraffin 16-25 part、Sodium stearate 10-20 part、Polyphosphate sodium 8-15 part、Hydroxymethyl cellulose potassium 9-15 part、Glass fibre 4-8 part、Extender pigment 18-24 part、Coupling agent 1-2 part、Compatilizer 1-2 part、Antioxidant 0.8-1.4 part、Tranquilizer 0.8-1.4 part、Bridging agent 0.6-1.2 part、Regulator 0.5-0.9 part、Hardening agent 0.4-0.6 part、Flocculation agent 0.4-0.6 part、Toughener 0.3-0.5 part、Plasticizer 0.3-0.5 part、Thickening agent 0.3-0.5 part、Stabilizer 0.2-0.4 part、Terminator 0.1-0.3 part；
Described extender pigment is calcium carbonate, described coupling agent is epoxy silane class coupling agent, described compatilizer is that maleic anhydride is grafted compatilizer, described antioxidant is antioxidant 1010, described tranquilizer constituent is ardealite, ferrum oxide, described bridging agent is acrylic type bridging agent, described regulator is processing aids acrylic resin, described hardening agent is 701 powder hardening agents, described flocculation agent is aluminium polychlorid, described toughener is carborundum whisker, described plasticizer is dioctyl adipate, described thickening agent is cellulose ethers thickening agent, described stabilizer is fat acids stabilizer, described terminator is styrene；
The preparation method of described solar cell backboard material, comprises the following steps:
S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, it is 750-780 DEG C in temperature, rotating speed is stirring 5-10min under 200-300r/min, prepares mixture I；
S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 100-300W at microwave power; temperature is 650-700 DEG C; rotating speed is stirring 3-6h under 100-400r/min, prepares mixture II；
S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 350-450 DEG C in temperature, rotating speed is stirring 0.4-0.8h under 100-300r/min, prepares mixture III；
S4: being dried the mixture III that step 3 prepares to moisture content≤20ppm, in the double screw extruder that screw slenderness ratio is 10:1, be 200-220 DEG C in temperature, rotating speed is extrusion molding under 20-50r/min, prepares solar cell backboard material after being cooled to room temperature.
Embodiment 1
nullA kind of solar cell backboard material，In units of weight，It is made up of following raw material: EVA resin 150 parts、Ethylene glycol monostearate 40 parts、Glyceryl tristearate 32 parts、Three (2，4-di-tert-butyl-phenyl) phosphite ester 26 parts、N-butyl acetate 18 parts、Maleic anhydride grafting ethylene propylene diene rubber 20 parts、Chloropropyl styrene 20 parts、Maleic anhydride inoculated polypropylene 18 parts、Chlordene cyclododecane 13 parts、3-ethyl-2-butylene-1-alcohol 15 parts、Magnesium oxide 8 parts、Zinc oxide 8 parts、Chlorinated paraffin 20 parts、Sodium stearate 15 parts、Polyphosphate sodium 12 parts、12 parts of hydroxymethyl cellulose potassium、Glass fibre 6 parts、Extender pigment 12 parts、Coupling agent 1.5 parts、Compatilizer 1.5 parts、Antioxidant 1.2 parts、Tranquilizer 1.2 parts、Bridging agent 0.8 part、Regulator 0.7 part、Hardening agent 0.5 part、Flocculation agent 0.5 part、Toughener 0.4 part、Plasticizer 0.4 part、Thickening agent 0.4 part、Stabilizer 0.3 part、Terminator 0.2 part；
Described extender pigment is calcium carbonate, described coupling agent is epoxy silane class coupling agent, described compatilizer is that maleic anhydride is grafted compatilizer, described antioxidant is antioxidant 1010, described tranquilizer constituent is ardealite, ferrum oxide, described bridging agent is acrylic type bridging agent, described regulator is processing aids acrylic resin, described hardening agent is 701 powder hardening agents, described flocculation agent is aluminium polychlorid, described toughener is carborundum whisker, described plasticizer is dioctyl adipate, described thickening agent is cellulose ethers thickening agent, described stabilizer is fat acids stabilizer, described terminator is styrene；
The preparation method of described solar cell backboard material, comprises the following steps:
S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, being 770 DEG C in temperature, rotating speed is stirring 8min under 250r/min, prepares mixture I；
S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 200W at microwave power; temperature is 680 DEG C; rotating speed is stirring 4.5h under 300r/min, prepares mixture II；
S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 400 DEG C in temperature, rotating speed is stirring 0.6h under 200r/min, prepares mixture III；
S4: being dried the mixture III that step 3 prepares to moisture content is 20ppm, in the double screw extruder that screw slenderness ratio is 10:1, is 210 DEG C in temperature, and rotating speed is extrusion molding under 35r/min, prepares solar cell backboard material after being cooled to room temperature.
Embodiment 2
nullA kind of solar cell backboard material，In units of weight，It is made up of following raw material: EVA resin 110 parts、Ethylene glycol monostearate 34 parts、Glyceryl tristearate 28 parts、Three (2，4-di-tert-butyl-phenyl) phosphite ester 24 parts、N-butyl acetate 16 parts、Maleic anhydride grafting ethylene propylene diene rubber 18 parts、Chloropropyl styrene 16 parts、Maleic anhydride inoculated polypropylene 15 parts、Chlordene cyclododecane 10 parts、3-ethyl-2-butylene-1-alcohol 12 parts、Magnesium oxide 6 parts、Zinc oxide 6 parts、Chlorinated paraffin 16 parts、Sodium stearate 10 parts、Polyphosphate sodium 8 parts、9 parts of hydroxymethyl cellulose potassium、Glass fibre 4 parts、Extender pigment 18 parts、Coupling agent 1 part、Compatilizer 1 part、Antioxidant 0.8 part、Tranquilizer 0.8 part、Bridging agent 0.6 part、Regulator 0.5 part、Hardening agent 0.4 part、Flocculation agent 0.4 part、Toughener 0.3 part、Plasticizer 0.3 part、Thickening agent 0.3 part、Stabilizer 0.2 part、Terminator 0.1 part；
Described extender pigment is calcium carbonate, described coupling agent is epoxy silane class coupling agent, described compatilizer is that maleic anhydride is grafted compatilizer, described antioxidant is antioxidant 1010, described tranquilizer constituent is ardealite, ferrum oxide, described bridging agent is acrylic type bridging agent, described regulator is processing aids acrylic resin, described hardening agent is 701 powder hardening agents, described flocculation agent is aluminium polychlorid, described toughener is carborundum whisker, described plasticizer is dioctyl adipate, described thickening agent is cellulose ethers thickening agent, described stabilizer is fat acids stabilizer, described terminator is styrene；
The preparation method of described solar cell backboard material, comprises the following steps:
S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, being 750 DEG C in temperature, rotating speed is stirring 10min under 200r/min, prepares mixture I；
S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 100W at microwave power; temperature is 650 DEG C; rotating speed is stirring 6h under 100r/min, prepares mixture II；
S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 350 DEG C in temperature, rotating speed is stirring 0.8h under 100r/min, prepares mixture III；
S4: being dried the mixture III that step 3 prepares to moisture content is 18ppm, in the double screw extruder that screw slenderness ratio is 10:1, is 200 DEG C in temperature, and rotating speed is extrusion molding under 20r/min, prepares solar cell backboard material after being cooled to room temperature.
Embodiment 3
nullA kind of solar cell backboard material，In units of weight，It is made up of following raw material: EVA resin 195 parts、Ethylene glycol monostearate 48 parts、Glyceryl tristearate 38 parts、Three (2，4-di-tert-butyl-phenyl) phosphite ester 32 parts、N-butyl acetate 20 parts、Maleic anhydride grafting ethylene propylene diene rubber 22 parts、Chloropropyl styrene 24 parts、Maleic anhydride inoculated polypropylene 20 parts、Chlordene cyclododecane 16 parts、3-ethyl-2-butylene-1-alcohol 18 parts、Magnesium oxide 10 parts、Zinc oxide 10 parts、Chlorinated paraffin 25 parts、Sodium stearate 20 parts、Polyphosphate sodium 15 parts、15 parts of hydroxymethyl cellulose potassium、Glass fibre 8 parts、Extender pigment 24 parts、Coupling agent 2 parts、Compatilizer 2 parts、Antioxidant 1.4 parts、Tranquilizer 1.4 parts、Bridging agent 1.2 parts、Regulator 0.9 part、Hardening agent 0.6 part、Flocculation agent 0.6 part、Toughener 0.5 part、Plasticizer 0.5 part、Thickening agent 0.5 part、Stabilizer 0.4 part、Terminator 0.3 part；
Described extender pigment is calcium carbonate, described coupling agent is epoxy silane class coupling agent, described compatilizer is that maleic anhydride is grafted compatilizer, described antioxidant is antioxidant 1010, described tranquilizer constituent is ardealite, ferrum oxide, described bridging agent is acrylic type bridging agent, described regulator is processing aids acrylic resin, described hardening agent is 701 powder hardening agents, described flocculation agent is aluminium polychlorid, described toughener is carborundum whisker, described plasticizer is dioctyl adipate, described thickening agent is cellulose ethers thickening agent, described stabilizer is fat acids stabilizer, described terminator is styrene；
The preparation method of described solar cell backboard material, comprises the following steps:
S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, being 780 DEG C in temperature, rotating speed is stirring 5min under 300r/min, prepares mixture I；
S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 300W at microwave power; temperature is 700 DEG C; rotating speed is stirring 3h under 400r/min, prepares mixture II；
S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 450 DEG C in temperature, rotating speed is stirring 0.4h under 300r/min, prepares mixture III；
S4: being dried the mixture III that step 3 prepares to moisture content is 15ppm, in the double screw extruder that screw slenderness ratio is 10:1, is 220 DEG C in temperature, and rotating speed is extrusion molding under 50r/min, prepares solar cell backboard material after being cooled to room temperature.
Embodiment 1-3 preparing solar cell backboard material and carries out performance test, result is as shown in the table.
Can be seen that from upper table result, the solar cell backboard material that the present invention prepares has good combination property, wherein impact strength has reached more than 69.68MPa, percentage elongation has reached more than 17.21%, elongation at break has reached more than 369.21%, it is without exception that resistance to neutral salt spray test has reached more than 1440h, breakdown voltage strength has reached more than 30.92KV/mm, man-made radiation's exposure test reaches more than 2380h, there is good mechanical performance and resistance to neutral salt spray and ageing-resistant performance, there is excellent breakdown voltage strength simultaneously, can be widely applied in solar cell backboard material.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations; for general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (7)
- null1. a solar cell backboard material，It is characterized in that，In units of weight，It is made up of following raw material: EVA resin 110-195 part、Ethylene glycol monostearate 34-48 part、Glyceryl tristearate 28-38 part、Three (2，4-di-tert-butyl-phenyl) phosphite ester 24-32 part、N-butyl acetate 16-20 part、Maleic anhydride grafting ethylene propylene diene rubber 18-22 part、Chloropropyl styrene 16-24 part、Maleic anhydride inoculated polypropylene 15-20 part、Chlordene cyclododecane 10-16 part、3-ethyl-2-butylene-1-alcohol 12-18 part、Magnesium oxide 6-10 part、Zinc oxide 6-10 part、Chlorinated paraffin 16-25 part、Sodium stearate 10-20 part、Polyphosphate sodium 8-15 part、Hydroxymethyl cellulose potassium 9-15 part、Glass fibre 4-8 part、Extender pigment 18-24 part、Coupling agent 1-2 part、Compatilizer 1-2 part、Antioxidant 0.8-1.4 part、Tranquilizer 0.8-1.4 part、Bridging agent 0.6-1.2 part、Regulator 0.5-0.9 part、Hardening agent 0.4-0.6 part、Flocculation agent 0.4-0.6 part、Toughener 0.3-0.5 part、Plasticizer 0.3-0.5 part、Thickening agent 0.3-0.5 part、Stabilizer 0.2-0.4 part、Terminator 0.1-0.3 part；Described extender pigment is calcium carbonate；Described coupling agent is epoxy silane class coupling agent；Described compatilizer is that maleic anhydride is grafted compatilizer；Described antioxidant is antioxidant 1010；Described tranquilizer constituent is ardealite, ferrum oxide；Described bridging agent is acrylic type bridging agent；Described regulator is processing aids acrylic resin；Described hardening agent is 701 powder hardening agents；The preparation method of described solar cell backboard material, comprises the following steps:S1: by EVA resin, ethylene glycol monostearate, glyceryl tristearate, three (2,4-di-tert-butyl-phenyl) phosphite ester, n-butyl acetate, maleic anhydride grafting ethylene propylene diene rubber mixing, it is 750-780 DEG C in temperature, rotating speed is stirring 5-10min under 200-300r/min, prepares mixture I；S2: under nitrogen protection; chloropropyl styrene, maleic anhydride inoculated polypropylene, chlordene cyclododecane, 3-ethyl-2-butylene-1-alcohol, chlorinated paraffin, sodium stearate, polyphosphate sodium, hydroxymethyl cellulose potassium, coupling agent, compatilizer, tranquilizer, bridging agent, regulator, hardening agent, flocculation agent, toughener, plasticizer, thickening agent is added in the mixture I that step 1 prepares; it is 100-300W at microwave power; temperature is 650-700 DEG C; rotating speed is stirring 3-6h under 100-400r/min, prepares mixture II；S3: add magnesium oxide, zinc oxide, glass fibre, extender pigment, antioxidant, stabilizer, terminator in the mixture II that step 2 prepares, be 350-450 DEG C in temperature, rotating speed is stirring 0.4-0.8h under 100-300r/min, prepares mixture III；S4: being dried the mixture III that step 3 prepares to moisture content≤20ppm, in the double screw extruder that screw slenderness ratio is 10:1, be 200-220 DEG C in temperature, rotating speed is extrusion molding under 20-50r/min, prepares solar cell backboard material after being cooled to room temperature.
- Solar cell backboard material the most according to claim 1, it is characterised in that described flocculation agent is aluminium polychlorid.
- Solar cell backboard material the most according to claim 1, it is characterised in that described toughener is carborundum whisker.
- Solar cell backboard material the most according to claim 1, it is characterised in that described plasticizer is dioctyl adipate.
- Solar cell backboard material the most according to claim 1, it is characterised in that described thickening agent is cellulose ethers thickening agent.
- Solar cell backboard material the most according to claim 1, it is characterised in that described stabilizer is fat acids stabilizer.
- Solar cell backboard material the most according to claim 1, it is characterised in that described terminator is styrene.
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| CN201610588829.7A CN105949607A (en) | 2016-07-25 | 2016-07-25 | Solar cell back plate material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479136A (en) * | 2016-10-17 | 2017-03-08 | 蒙宇 | A kind of high-performance notebook computer casing composite |
| CN107298954A (en) * | 2017-05-19 | 2017-10-27 | 江苏东昇光伏科技有限公司 | A kind of ageing-resistant glued membrane used for solar batteries and preparation method thereof |
| CN107316913A (en) * | 2017-05-15 | 2017-11-03 | 江苏东昇光伏科技有限公司 | Modified solar battery back-sheet and preparation method thereof |
-
2016
- 2016-07-25 CN CN201610588829.7A patent/CN105949607A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106479136A (en) * | 2016-10-17 | 2017-03-08 | 蒙宇 | A kind of high-performance notebook computer casing composite |
| CN107316913A (en) * | 2017-05-15 | 2017-11-03 | 江苏东昇光伏科技有限公司 | Modified solar battery back-sheet and preparation method thereof |
| CN107298954A (en) * | 2017-05-19 | 2017-10-27 | 江苏东昇光伏科技有限公司 | A kind of ageing-resistant glued membrane used for solar batteries and preparation method thereof |
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Application publication date: 20160921 |