CN105949570A - Cable material with excellent mechanical performance - Google Patents

Cable material with excellent mechanical performance Download PDF

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Publication number
CN105949570A
CN105949570A CN201610387748.0A CN201610387748A CN105949570A CN 105949570 A CN105949570 A CN 105949570A CN 201610387748 A CN201610387748 A CN 201610387748A CN 105949570 A CN105949570 A CN 105949570A
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parts
mechanical performance
excellent mechanical
cable materials
phthalimide
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刘龙
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Fanchang Feide Communication Material Design Co Ltd
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Fanchang Feide Communication Material Design Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a cable material with excellent mechanical performance. The cable material is prepared from, by weight, 10-30 parts of metallocene polyethylene, 10-20 parts of medium-density polyethylene, 10-20 parts of polystyrene, 20-40 parts of polyvinyl chloride, 20-50 parts of modified feather protein viscose fibers, 1-4 parts of caprolactam, 2-7 parts of methyltrimethoxysilane, 0.5-1.5 parts of 2-mercaptobenzimidazol zinc salt, 0.5-1.5 parts of bis(tert-butyldioxyisopropyl)benzene, 1-3 parts of dicumyl peroxide, 1-3 parts of phthalimide, 1-3 parts of N-salicylamide phthalimide, 10-20 parts of medical stone, 5-12 parts of mica powder, 10-20 parts of barium sulfate, 5-14 parts of nano-silica, 1-2 parts of magnesium oxide, 0.2-1.2 parts of coumarone-indene resin, 0.5-1.5 parts of dibutyl phthalate, 0.8-1.6 parts of dioctyl adipate, 1-3 parts of a fire retardant, 1-3 parts of butyl oleate, 1-3 parts of N-phenyl-2-naphthylamine and 1-3 parts of a stabilizer. The cable material is good in mechanical performance and excellent in heat resistance and ageing resistance.

Description

A kind of CABLE MATERIALS with excellent mechanical performance
Technical field
The present invention relates to CABLE MATERIALS technical field, particularly relate to a kind of CABLE MATERIALS with excellent mechanical performance.
Background technology
CABLE MATERIALS belongs to a kind of composite, and it is typically to be equipped with suitable filler by matrix resin and forms, Require, in addition to the mechanical property except having excellence, also should have the heat-resisting and ageing-resistant performance that comparison is excellent, If the mechanical property of CABLE MATERIALS, heat-resisting and ageing-resistant performance can not meet requirement, meeting in service life will be caused Reduce, even cause sheath to ftracture, how the hidden danger that formation accident occurs, can improve CABLE MATERIALS simultaneously Heat-resisting, ageing-resistant and mechanical property, it has also become those skilled in the art institute problem demanding prompt solution.
Summary of the invention
The present invention proposes a kind of CABLE MATERIALS with excellent mechanical performance, and mechanical property is good, heat-resisting and resistance to always Change excellent performance.
A kind of CABLE MATERIALS with excellent mechanical performance that the present invention proposes, its raw material includes by weight: cyclopentadienyl Metal polyethylene 10-30 part, medium density polyethylene 10-20 part, polystyrene 10-20 part, polrvinyl chloride 20-40 part, modified fish oil albumen gluing fiber 20-50 part, caprolactam 1-4 part, methyl trimethoxy epoxide silicon Alkane 2-7 part, zinc salt of 2 mercaptobenzimidazole 0.5-1.5 part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 0.5-1.5 Part, cumyl peroxide 1-3 part, phthalimide 1-3 part, N-salicyloyl amino phthalyl Imines 1-3 part, Maifanitum 10-20 part, mica powder 5-12 part, barium sulfate 10-20 part, nanometer titanium dioxide Silicon 5-14 part, magnesium oxide 1-2 part, coumarone indene resin 0.2-1.2 part, dibutyl phthalate 0.5-1.5 Part, dioctyl adipate 0.8-1.6 part, fire retardant 1-3 part, butyl oleate 1-3 part, N-phenyl-2-naphthalene Amine 1-3 part, stabilizer 1-3 part.
Preferably, modified fish oil albumen gluing fiber uses following technique to prepare: by weight by 5-15 part plumage Hairless protein, 1-2 part sodium hydroxide, 40-60 part water mix and blend 20-50min, whipping temp is 50-58 DEG C, Filter, add 2-6 part cellulose sulfonate stirring 15-30min, add 0.5-1.2 part sodium sulfate, 10-20 Part concentration is 5-12wt% sulfuric acid solution, 10-20 part zinc sulfate, 0.2-0.6 part cross-linking agent EDC mix and blend 10-30min, whipping temp is 55-65 DEG C, filters, washing, and under nitrogen protection, adding 2-6 part concentration is 0.1-0.15mol/L strontium nitrate solution, 5-15 part native fibroin, 8-16 part Kaolin, 1-2 part are prevented Old agent MB, 1-2 part hydrogenated rosin, 1-2 Tissuemat E, 20-60 part water mix and blend 30-60min, regulation System pH continues stirring 20-35min to 7.5-8.2, adds 10-20 part polycaprolactone, 1-5 part poly-three Carbonate, 5-15 part hydroxyapatite stirring 30-70min, mixing speed is 300-400r/min, Whipping temp is 50-70 DEG C, cooling, obtains modified natural fibroin glue.
Preferably, metallocene PE, medium density polyethylene, polystyrene, the weight ratio of polrvinyl chloride are 20-26:16-18:14-17:30-35.
Preferably, caprolactam, the weight ratio of MTMS are 2-3:3-5.
Preferably, modified fish oil albumen gluing fiber, coumarone indene resin, dibutyl phthalate, oneself two The weight ratio of dioctyl phthalate is 30-40:0.8-1:0.8-1.2:1.2-1.4.
Preferably, Maifanitum, mica powder, barium sulfate, the weight ratio of nano silicon are 14-17:8-10: 14-18:6-10.
Preferably, fire retardant, butyl oleate, N-phenyl-2-naphthylamine, the weight ratio of stabilizer are 2-2.6: 1.5-2:2-2.5:2-2.5.
Preferably, the described CABLE MATERIALS with excellent mechanical performance, it is characterised in that its raw material is by weight Part includes: metallocene PE 20-26 part, medium density polyethylene 16-18 part, polystyrene 14-17 part, Polrvinyl chloride 30-35 part, modified fish oil albumen gluing fiber 30-40 part, caprolactam 2-3 part, methyl Trimethoxy silane 3-5 part, zinc salt of 2 mercaptobenzimidazole 1-1.3 part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl Base benzene 0.8-1.2 part, cumyl peroxide 1.5-2 part, phthalimide 2-2.8 part, N-water Poplar acylamino-phthalimide 1.5-2.2 part, Maifanitum 14-17 part, mica powder 8-10 part, barium sulfate 14-18 part, nano silicon 6-10 part, magnesium oxide 1.5-1.8 part, coumarone indene resin 0.8-1 part, Dibutyl phthalate 0.8-1.2 part, dioctyl adipate 1.2-1.4 part, fire retardant 2-2.6 part, Butyl oleate 1.5-2 part, N-phenyl-2-naphthylamine 2-2.5 part, stabilizer 2-2.5 part.
In the present invention, use metallocene PE, medium density polyethylene, polystyrene, polrvinyl chloride, change Sex feathers hairless protein gluing fiber can be effectively improved as base material, addition caprolactam, MTMS The compatibility each other, mechanical property is good, and ageing-resistant performance is good, and heat-resistant stability is good, and at modified fish oil egg White glue sticks in fiber, feather protein after treatment ,-the CO-NH-in protein fibre and cellulose sulfonate In-OH, sulfuric acid solution, zinc sulfate, cross-linking agent EDC effect under, formed network structure, further Add native fibroin, Kaolin, antioxidant MB, butyl oleate mating reaction, form interpenetrating structure, And the amino residue of native fibroin is combined with strontium nitrate, and a large amount of beta sheets that native fibroin contains Structure, hydrophilic group is at molecular surface, and not only self condenses under certain condition, and can be with follow-up addition Polycaprolactone, PTMC the compatibility good, further with hydroxyapatite effect, can induce Hydroxy phosphorus Calx nucleation crystalline growth, comprehensive function, Mechanical Properties of Products is good, and ageing-resistant performance is excellent, Heat-resistant stability is good, and cheap, and raw material sources are wide；Modified fish oil albumen gluing fiber and coumarone tree Fat, dibutyl phthalate, dioctyl adipate mating reaction, mutual good dispersion, extrusion processing Property is good, and the intrastitial Tissuemat E of modified fish oil albumen gluing can be with coumarone indene resin, phthalic acid two Butyl ester, dioctyl adipate formed synergism, inside and outside take into account, the Maifanitum of interpolation, cloud can be effectively facilitated Female powder, barium sulfate, nano silicon fine dispersion in system, and at caprolactam, methyl trimethoxy Under the effect of TMOS, filling capacity is good, and storeroom can form stable combination, Mechanical Properties of Products and Thermally-stabilised can further enhance.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of CABLE MATERIALS with excellent mechanical performance, its raw material includes by weight: metallocene PE 30 Part, medium density polyethylene 10 parts, polystyrene 20 parts, polrvinyl chloride 20 parts, modified fish oil albumen gluing Fiber 50 parts, caprolactam 1 part, MTMS 7 parts, zinc salt of 2 mercaptobenzimidazole 0.5 Part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 1.5 parts, cumyl peroxide 1 part, phthalyl is sub- Amine 3 parts, N-salicyloyl amino phthalimide 1 part, Maifanitum 20 parts, mica powder 5 parts, barium sulfate 20 parts, nano silicon 5 parts, magnesium oxide 2 parts, coumarone indene resin 0.2 part, phthalic acid two fourth Ester 1.5 parts, dioctyl adipate 0.8 part, fire retardant 3 parts, butyl oleate 1 part, N-phenyl-2-naphthylamine 3 parts, stabilizer 1 part.
Embodiment 2
A kind of CABLE MATERIALS with excellent mechanical performance, its raw material includes by weight: metallocene PE 10 Part, medium density polyethylene 20 parts, polystyrene 10 parts, polrvinyl chloride 40 parts, modified fish oil albumen gluing Fiber 20 parts, caprolactam 4 parts, MTMS 2 parts, zinc salt of 2 mercaptobenzimidazole 1.5 Part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 0.5 part, cumyl peroxide 3 parts, phthalyl is sub- Amine 1 part, N-salicyloyl amino phthalimide 3 parts, Maifanitum 10 parts, mica powder 12 parts, sulphuric acid Barium 10 parts, nano silicon 14 parts, magnesium oxide 1 part, coumarone indene resin 1.2 parts, phthalic acid Dibutyl ester 0.5 part, dioctyl adipate 1.6 parts, fire retardant 1 part, butyl oleate 3 parts, N-phenyl-2- Naphthylamines 1 part, stabilizer 3 parts.
Embodiment 3
A kind of CABLE MATERIALS with excellent mechanical performance, its raw material includes by weight: metallocene PE 20 Part, medium density polyethylene 18 parts, polystyrene 14 parts, polrvinyl chloride 35 parts, modified fish oil albumen gluing Fiber 30 parts, caprolactam 3 parts, MTMS 3 parts, zinc salt of 2 mercaptobenzimidazole 1.3 Part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 0.8 part, cumyl peroxide 2 parts, phthalyl is sub- Amine 2 parts, N-salicyloyl amino phthalimide 2.2 parts, Maifanitum 14 parts, mica powder 10 parts, sulfur Acid barium 14 parts, nano silicon 10 parts, magnesium oxide 1.5 parts, coumarone indene resin 1 part, O-phthalic Dibutyl phthalate 0.8 part, dioctyl adipate 1.4 parts, fire retardant 2 parts, butyl oleate 2 parts, N-phenyl -2-naphthylamines 2 parts, stabilizer 2.5 parts.
Modified fish oil albumen gluing fiber use following technique prepare: by weight by 5 parts of feather proteins, 2 parts Sodium hydroxide, 40 parts of water mix and blend 50min, whipping temp is 50 DEG C, filters, adds 6 parts of celluloses Sulphonic acid ester stirring 15min, adds 1.2 parts of sodium sulfate, 10 parts of concentration are 12wt% sulfuric acid solution, 10 parts of sulfur Acid zinc, 0.6 part of cross-linking agent EDC mix and blend 10min, whipping temp is 65 DEG C, filters, washing, nitrogen Under protection, add 2 parts of concentration be 0.15mol/L strontium nitrate solution, 5 parts of native fibroin, 16 parts high Ridge soil, 1 part of antioxidant MB, 2 parts of hydrogenated rosins, 1 Tissuemat E, 60 parts of water mix and blend 30min, adjust Joint system pH continues stirring 20min to 8.2, adds 20 parts of polycaprolactones, 1 part of polytrimethylene carbonic acid Ester, 15 parts of hydroxyapatite stirring 30min, mixing speed is 400r/min, and whipping temp is 50 DEG C, cold But, modified natural fibroin glue is obtained.
Embodiment 4
A kind of CABLE MATERIALS with excellent mechanical performance, its raw material includes by weight: metallocene PE 26 Part, medium density polyethylene 16 parts, polystyrene 17 parts, polrvinyl chloride 30 parts, modified fish oil albumen gluing Fiber 40 parts, caprolactam 2 parts, MTMS 5 parts, zinc salt of 2 mercaptobenzimidazole 1 part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 1.2 parts, cumyl peroxide 1.5 parts, phthalimide 2.8 parts, N-salicyloyl amino phthalimide 1.5 parts, Maifanitum 17 parts, mica powder 8 parts, sulphuric acid Barium 18 parts, nano silicon 6 parts, magnesium oxide 1.8 parts, coumarone indene resin 0.8 part, phthalic acid Dibutyl ester 1.2 parts, dioctyl adipate 1.2 parts, fire retardant 2.6 parts, butyl oleate 1.5 parts, N-benzene Base-2-naphthylamines 2.5 parts, stabilizer 2 parts.
Modified fish oil albumen gluing fiber use following technique prepare: by weight by 15 parts of feather proteins, 1 Part sodium hydroxide, 60 parts of water mix and blend 20min, whipping temp is 58 DEG C, filters, adds 2 parts of fibers Element sulphonic acid ester stirring 30min, adds 0.5 part of sodium sulfate, 20 parts of concentration are 5wt% sulfuric acid solution, 20 parts of sulfur Acid zinc, 0.2 part of cross-linking agent EDC mix and blend 30min, whipping temp is 55 DEG C, filters, washing, nitrogen Under protection, adding 6 parts of concentration is 0.1mol/L strontium nitrate solution, 15 parts of native fibroin, 8 parts of kaolinites Soil, 2 parts of antioxidant MBs, 1 part of hydrogenated rosin, 2 Tissuemat Es, 20 parts of water mix and blend 60min, regulation System pH continues stirring 35min to 7.5, add 10 parts of polycaprolactones, 5 parts of PTMC, 5 parts of hydroxyapatite stirring 70min, mixing speed is 300r/min, and whipping temp is 70 DEG C, cooling, Obtain modified natural fibroin glue.
Embodiment 5
A kind of CABLE MATERIALS with excellent mechanical performance, its raw material includes by weight: metallocene PE 23 Part, medium density polyethylene 17 parts, polystyrene 16 parts, polrvinyl chloride 32 parts, modified fish oil albumen gluing Fiber 36 parts, caprolactam 2.6 parts, MTMS 4 parts, zinc salt of 2 mercaptobenzimidazole 1.15 Part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 0.95 part, cumyl peroxide 1.8 parts, phthalyl Imines 2.4 parts, N-salicyloyl amino phthalimide 1.85 parts, Maifanitum 16 parts, mica powder 9 parts, 16 parts of barium sulfate, nano silicon 8 parts, magnesium oxide 1.65 parts, coumarone indene resin 0.92 part, adjacent benzene Dibutyl carboxylic acid 0.95 part, dioctyl adipate 1.32 parts, fire retardant 2.3 parts, butyl oleate 1.8 Part, N-phenyl-2-naphthylamine 2.2 parts, stabilizer 2.3 parts.
Modified fish oil albumen gluing fiber use following technique prepare: by weight by 12 parts of feather proteins, 1.6 Part sodium hydroxide, 52 parts of water mix and blend 32min, whipping temp is 54 DEG C, filters, adds 4 parts of fibers Element sulphonic acid ester stirring 24min, add 0.85 part of sodium sulfate, 15 parts of concentration is 8wt% sulfuric acid solution, 14 parts Zinc sulfate, 0.425 part of cross-linking agent EDC mix and blend 18min, whipping temp is 62 DEG C, filters, washing, Under nitrogen protection, add 4 parts of concentration be 0.13mol/L strontium nitrate solution, 8 parts of native fibroin, 12 Part Kaolin, 1.4 parts of antioxidant MBs, 1.5 parts of hydrogenated rosins, 1.6 Tissuemat Es, 35 parts of water mix and blends 40min, regulation system pH value to 7.8 continue stirring 31min, add 16 parts of polycaprolactones, 3 parts poly-three Carbonate, 12 parts of hydroxyapatite stirring 60min, mixing speed is 340r/min, whipping temp It is 62 DEG C, cooling, obtain modified natural fibroin glue.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (8)

1. a CABLE MATERIALS with excellent mechanical performance, it is characterised in that its raw material includes by weight: Metallocene PE 10-30 part, medium density polyethylene 10-20 part, polystyrene 10-20 part, polychlorostyrene second Alkene 20-40 part, modified fish oil albumen gluing fiber 20-50 part, caprolactam 1-4 part, methyl trimethoxy oxygen Base silane 2-7 part, zinc salt of 2 mercaptobenzimidazole 0.5-1.5 part, Isosorbide-5-Nitrae-dual-tert-butyl peroxy isopropyl base benzene 0.5-1.5 part, cumyl peroxide 1-3 part, phthalimide 1-3 part, N-salicyloyl amino Phthalimide 1-3 part, Maifanitum 10-20 part, mica powder 5-12 part, barium sulfate 10-20 part, Nano silicon 5-14 part, magnesium oxide 1-2 part, coumarone indene resin 0.2-1.2 part, phthalic acid two Butyl ester 0.5-1.5 part, dioctyl adipate 0.8-1.6 part, fire retardant 1-3 part, butyl oleate 1-3 part, N-phenyl-2-naphthylamine 1-3 part, stabilizer 1-3 part.
The CABLE MATERIALS with excellent mechanical performance the most according to claim 1, it is characterised in that modified Feather protein gluing fiber uses following technique to prepare: by weight by 5-15 part feather protein, 1-2 part hydrogen Sodium oxide, 40-60 part water mix and blend 20-50min, whipping temp is 50-58 DEG C, filters, and adds 2-6 Part cellulose sulfonate stirring 15-30min, addition 0.5-1.2 part sodium sulfate, 10-20 part concentration are 5-12wt% Sulfuric acid solution, 10-20 part zinc sulfate, 0.2-0.6 part cross-linking agent EDC mix and blend 10-30min, stirring Temperature is 55-65 DEG C, filters, washing, and under nitrogen protection, adding 2-6 part concentration is 0.1-0.15mol/L Strontium nitrate solution, 5-15 part native fibroin, 8-16 part Kaolin, 1-2 part antioxidant MB, 1-2 part Hydrogenated rosin, 1-2 Tissuemat E, 20-60 part water mix and blend 30-60min, regulation system pH value is extremely 7.5-8.2 continues stirring 20-35min, adds 10-20 part polycaprolactone, 1-5 part polytrimethylene carbonic acid Ester, 5-15 part hydroxyapatite stirring 30-70min, mixing speed is 300-400r/min, whipping temp For 50-70 DEG C, cooling, obtain modified natural fibroin glue.
The CABLE MATERIALS with excellent mechanical performance the most according to claim 1 and 2, it is characterised in that Metallocene PE, medium density polyethylene, polystyrene, the weight ratio of polrvinyl chloride are 20-26:16-18: 14-17:30-35.
4., according to the CABLE MATERIALS with excellent mechanical performance described in any one of claim 1-3, its feature exists In, caprolactam, the weight ratio of MTMS are 2-3:3-5.
5., according to the CABLE MATERIALS with excellent mechanical performance described in any one of claim 1-4, its feature exists In, modified fish oil albumen gluing fiber, coumarone indene resin, dibutyl phthalate, dioctyl adipate Weight ratio be 30-40:0.8-1:0.8-1.2:1.2-1.4.
6., according to the CABLE MATERIALS with excellent mechanical performance described in any one of claim 1-5, its feature exists In, Maifanitum, mica powder, barium sulfate, the weight ratio of nano silicon are 14-17:8-10:14-18: 6-10。
7., according to the CABLE MATERIALS with excellent mechanical performance described in any one of claim 1-6, its feature exists In, fire retardant, butyl oleate, N-phenyl-2-naphthylamine, the weight ratio of stabilizer are 2-2.6:1.5-2: 2-2.5:2-2.5.
8., according to the CABLE MATERIALS with excellent mechanical performance described in any one of claim 1-7, its feature exists In, its raw material includes by weight: metallocene PE 20-26 part, medium density polyethylene 16-18 part, Polystyrene 14-17 part, polrvinyl chloride 30-35 part, modified fish oil albumen gluing fiber 30-40 part, oneself Lactams 2-3 part, MTMS 3-5 part, zinc salt of 2 mercaptobenzimidazole 1-1.3 part, Isosorbide-5-Nitrae- Dual-tert-butyl peroxy isopropyl base benzene 0.8-1.2 part, cumyl peroxide 1.5-2 part, phthalyl is sub- Amine 2-2.8 part, N-salicyloyl amino phthalimide 1.5-2.2 part, Maifanitum 14-17 part, Muscovitum Powder 8-10 part, barium sulfate 14-18 part, nano silicon 6-10 part, magnesium oxide 1.5-1.8 part is ancient Horse grand resin 0.8-1 part, dibutyl phthalate 0.8-1.2 part, dioctyl adipate 1.2-1.4 part, Fire retardant 2-2.6 part, butyl oleate 1.5-2 part, N-phenyl-2-naphthylamine 2-2.5 part, stabilizer 2-2.5 Part.
CN201610387748.0A 2016-06-03 2016-06-03 Cable material with excellent mechanical performance Pending CN105949570A (en)

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Cited By (7)

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CN106674810A (en) * 2016-12-20 2017-05-17 安徽新立电缆材料有限公司 Polyvinyl chloride cable material with excellent mechanical properties
CN106750800A (en) * 2016-12-20 2017-05-31 安徽新立电缆材料有限公司 A kind of heat endurance is good and excellent in mechanical performance PE cable material
CN106751089A (en) * 2016-12-20 2017-05-31 安徽新立电缆材料有限公司 A kind of shock resistance high temperature resistant polystyrene cable material
CN106800693A (en) * 2016-12-20 2017-06-06 安徽新立电缆材料有限公司 A kind of anti-good hydrothermal stability PE cable material
CN106832632A (en) * 2016-12-20 2017-06-13 安徽新立电缆材料有限公司 A kind of waterproof tensile strength high-polystyrene cable material
CN112661949A (en) * 2019-10-15 2021-04-16 万华化学集团股份有限公司 Low-yellowness polycarbonate material and preparation method thereof
CN112920487A (en) * 2021-01-26 2021-06-08 江苏新长峰线缆有限公司 Low-temperature-resistant antibacterial flame-retardant color development early warning cable material and preparation method thereof

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106674810A (en) * 2016-12-20 2017-05-17 安徽新立电缆材料有限公司 Polyvinyl chloride cable material with excellent mechanical properties
CN106750800A (en) * 2016-12-20 2017-05-31 安徽新立电缆材料有限公司 A kind of heat endurance is good and excellent in mechanical performance PE cable material
CN106751089A (en) * 2016-12-20 2017-05-31 安徽新立电缆材料有限公司 A kind of shock resistance high temperature resistant polystyrene cable material
CN106800693A (en) * 2016-12-20 2017-06-06 安徽新立电缆材料有限公司 A kind of anti-good hydrothermal stability PE cable material
CN106832632A (en) * 2016-12-20 2017-06-13 安徽新立电缆材料有限公司 A kind of waterproof tensile strength high-polystyrene cable material
CN112661949A (en) * 2019-10-15 2021-04-16 万华化学集团股份有限公司 Low-yellowness polycarbonate material and preparation method thereof
CN112661949B (en) * 2019-10-15 2022-08-05 万华化学集团股份有限公司 Low-yellowness polycarbonate material and preparation method thereof
CN112920487A (en) * 2021-01-26 2021-06-08 江苏新长峰线缆有限公司 Low-temperature-resistant antibacterial flame-retardant color development early warning cable material and preparation method thereof

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Application publication date: 20160921