CN106832632A - A kind of waterproof tensile strength high-polystyrene cable material - Google Patents
A kind of waterproof tensile strength high-polystyrene cable material Download PDFInfo
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- CN106832632A CN106832632A CN201611181945.3A CN201611181945A CN106832632A CN 106832632 A CN106832632 A CN 106832632A CN 201611181945 A CN201611181945 A CN 201611181945A CN 106832632 A CN106832632 A CN 106832632A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
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- C—CHEMISTRY; METALLURGY
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- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
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Abstract
The invention discloses a kind of waterproof tensile strength high-polystyrene cable material, its raw material includes by weight：20 28 parts of polystyrene, 5 12 parts of polyether-ketone, 26 parts of chlorosulfonated polyethylene, 13 parts of polyethylene, 13 parts of modified cotton fiber, 5 12 parts of glass microballoon, 36 parts of sodium antimonate, 14 parts of apatite, 26 parts of ceramic microsphere, 13 parts of liquid coumarone indene resin, 12 parts of diisononyl phthalate, 12 parts of adipic acid propylene glycol ester, 12 parts of triphenyl phosphite, 12 parts of triphenyl phosphate, 12 parts of crosslinking agent, 12 parts of stabilizer, 0.5 1.2 parts of antioxidant, 13 parts of antistatic additive.High temperature resistant of the present invention, ageing-resistant performance are excellent, and water resistance is outstanding, and mechanical property is fabulous.
Description
Technical field
The present invention relates to cable material technical field, more particularly to a kind of waterproof tensile strength high-polystyrene cable material
Material.
Background technology
With the extensive use of China's cable product, the demand of cable material also gradually increases.Many enterprises are sharp at present
Cable material is produced with waste polyethylene, while in order to adapt to different working environment and use demands, so can be to cable
Material is improved performance, but only has the cable material of single function in more and more fierce market is competed now, more
Inferior position is highlighted to get over.Therefore need to be modified cable material, more than one characteristic is made it have, so as to strengthen in market
Competitiveness.
The cable material tensile strength produced using MPS cable material in the prior art is small, shock resistance
Power is weak, poor waterproof properties, so as to influence to use scope.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of waterproof tensile strength high-polystyrene cable
Material, high temperature resistant, ageing-resistant performance are excellent, and water resistance is outstanding, and mechanical property is fabulous.
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
Styrene 20-28 parts, polyether-ketone 5-12 parts, chlorosulfonated polyethylene 2-6 parts, polyethylene 1-3 parts, modified cotton fiber 1-3 parts, glass
Microballon 5-12 parts, sodium antimonate 3-6 parts, apatite 1-4 parts, ceramic microsphere 2-6 parts, 1-3 parts of liquid coumarone indene resin, O-phthalic
Sour dinonyl 1-2 parts, 1-2 parts of adipic acid propylene glycol ester, triphenyl phosphite 1-2 parts, triphenyl phosphate 1-2 parts, crosslinking agent
1-2 parts, stabilizer 1-2 parts, antioxidant 0.5-1.2 parts, antistatic additive 1-3 parts.
Preferably, modified cotton fiber is prepared using following technique：Ludox is placed in water-bath, six are added dropwise under stirring
Methyl disilazane, after being added dropwise completely, continues to stir, and is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；Cotton is fine
Dimension, sodium hydroxide solution are mixed, and are heated up, and add sodium sulfite stirring to obtain pre-processing cotton fiber；To pretreatment cotton fiber
Middle addition formaldehyde, pretreatment Ludox stirring, are cooled to room temperature, and spray drying obtains modified cotton fiber.
Preferably, modified cotton fiber is prepared using following technique：Ludox is placed in temperature in 60-70 DEG C of water-bath, silicon
The pH value of colloidal sol is 3.5-4.5, and HMDS is added dropwise under stirring, and mixing speed is 400-500r/min, is added dropwise
After completely, continue to stir 1-2h, 80-88 DEG C is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；By cotton fiber, hydrogen-oxygen
Change sodium solution and mix 40-50min, whipping temp is 55-65 DEG C, is warming up to 120-130 DEG C, add sodium sulfite stirring 1-
3h, obtains pre-processing cotton fiber；To formaldehyde, pretreatment Ludox stirring 2-5h is added in pretreatment cotton fiber, room temperature is cooled to,
Spray drying obtains modified cotton fiber.
Preferably, modified cotton fiber is prepared using following technique：It is 10-12wt%'s by weight by 40-60 parts of concentration
Ludox is placed in temperature in 60-70 DEG C of water-bath, the pH value of Ludox is 3.5-4.5, and 20-28 parts of pregnancy is added dropwise under stirring
Base disilazane, mixing speed is 400-500r/min, after being added dropwise completely, continues to stir 1-2h, and 80-88 DEG C is dried under vacuum to perseverance
Weight, crushing obtains pre-processing Ludox；It is the hydroxide of 1-1.6mol/L by weight by 2-8 parts of cotton fiber, 25-35 parts of concentration
Sodium solution mixes 40-50min, and whipping temp is 55-65 DEG C, is warming up to 120-130 DEG C, adds 1-2 parts of sodium sulfite to stir
1-3h is mixed, obtains pre-processing cotton fiber；By weight to added in 14-20 parts of pretreatment cotton fiber 5-10 part formaldehyde, 2-7 parts in advance
Treatment Ludox stirring 2-5h, is cooled to room temperature, and spray drying obtains modified cotton fiber.
Preferably, polystyrene, polyether-ketone, chlorosulfonated polyethylene, polyethylene, the weight ratio of modified cotton fiber are 22-26：
6-10：3-5：1.5-2.5：1.5-2.5.
Preferably, modified cotton fiber, glass microballoon, sodium antimonate, apatite, ceramic microsphere, liquid coumarone indene resin, adjacent benzene
The weight ratio of dioctyl phthalate dinonyl is 1.5-2.5：8-10：4-5：2-3：3-5：1.5-2.5：1.2-1.8.
Preferably, its raw material includes by weight：Polystyrene 22-26 parts, polyether-ketone 6-10 parts, chlorosulfonated polyethylene 3-
5 parts, polyethylene 1.5-2.5 parts, modified cotton fiber 1.5-2.5 parts, glass microballoon 8-10 parts, sodium antimonate 4-5 parts, apatite 2-3
Part, ceramic microsphere 3-5 parts, 1.5-2.5 parts of liquid coumarone indene resin, diisononyl phthalate 1.2-1.8 parts, adipic acid third
Diol ester 1.3-1.7 parts, triphenyl phosphite 1.4-1.6 parts, triphenyl phosphate 1.3-1.7 parts, crosslinking agent 1.4-1.8 parts, surely
Determine agent 1.6-1.8 parts, antioxidant 0.6-1 parts, antistatic additive 1.5-2.5 parts.
The present invention is obtained using conventional fabrication process.
In modified cotton fiber of the invention, using intermolecular dehydration by the-Si (CH in HMDS3)3Base
Group is grafted on Ludox molecule, and Ludox surface is covered with-Si (CH3)3Group, hydrophobic performance is good, can also effectively improve titanium dioxide
Compatibility between silicon and pretreatment cotton fiber；And through sulfonation, condensation after cotton fiber alkalization, its high temperature resistant, resistance to acids and bases are fabulous, then pass through
Sodium sulfite boiling, forms a large amount of phenolic hydroxyl groups, and the adhesion with prefabricated material is strong, and comprehensive function makes modified cotton fiber heat endurance
Good, water resistance is excellent；The present invention is using modified cotton fiber and polystyrene, polyether-ketone, chlorosulfonated polyethylene, polyethylene compatible
Property is good, is difficult to migrate and separates out, and comprehensive function makes mechanical property of the invention fabulous, and high temperature resistant, ageing-resistant performance are excellent；
And modified cotton fiber, glass microballoon, sodium antimonate, apatite, ceramic microsphere coordinate, in liquid coumarone indene resin, phthalic acid
In the presence of dinonyl, with polystyrene, polyether-ketone, chlorosulfonated polyethylene, polyethylene good dispersion, can be effectively dispersed in poly-
Styrene, polyether-ketone, chlorosulfonated polyethylene, polyethylene surface, mutual combination degree are high, and gap is minimum, make of the invention resistance to
Aqueous energy, ageing-resistant performance and mechanical property are further enhanced.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
20 parts of styrene, 12 parts of polyether-ketone, 2 parts of chlorosulfonated polyethylene, 3 parts of polyethylene, 1 part of modified cotton fiber, 12 parts of glass microballoon, antimony
3 parts of sour sodium, 4 parts of apatite, 2 parts of ceramic microsphere, 3 parts of liquid coumarone indene resin, 1 part of diisononyl phthalate, adipic acid
2 parts of propylene glycol ester, 1 part of triphenyl phosphite, 2 parts of triphenyl phosphate, 1 part of crosslinking agent, 2 parts of stabilizer, 0.5 part of antioxidant resists
3 parts of electrostatic agent.
Embodiment 2
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
28 parts of styrene, 5 parts of polyether-ketone, 6 parts of chlorosulfonated polyethylene, 1 part of polyethylene, 3 parts of modified cotton fiber, 5 parts of glass microballoon, metaantimmonic acid
6 parts of sodium, 1 part of apatite, 6 parts of ceramic microsphere, 1 part of liquid coumarone indene resin, 2 parts of diisononyl phthalate, adipic acid third
1 part of diol ester, 2 parts of triphenyl phosphite, 1 part of triphenyl phosphate, 2 parts of crosslinking agent, 1 part of stabilizer, 1.2 parts of antioxidant resists quiet
1 part of electric agent.
Modified cotton fiber is prepared using following technique：Ludox is placed in water-bath, hexamethyl two is added dropwise under stirring
Silazane, after being added dropwise completely, continues to stir, and is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；By cotton fiber, hydrogen-oxygen
Change sodium solution to mix, heat up, add sodium sulfite stirring to obtain pre-processing cotton fiber；To pretreatment cotton fiber in add first
Aldehyde, pretreatment Ludox stirring, are cooled to room temperature, and spray drying obtains modified cotton fiber.
Embodiment 3
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
22 parts of styrene, 10 parts of polyether-ketone, 3 parts of chlorosulfonated polyethylene, 2.5 parts of polyethylene, 1.5 parts of modified cotton fiber, glass microballoon 10
Part, 4 parts of sodium antimonate, 3 parts of apatite, 3 parts of ceramic microsphere, 2.5 parts of liquid coumarone indene resin, diisononyl phthalate 1.2
Part, 1.7 parts of adipic acid propylene glycol ester, 1.4 parts of triphenyl phosphite, 1.7 parts of triphenyl phosphate, 1.4 parts of crosslinking agent, stabilizer
1.8 parts, 0.6 part of antioxidant, 2.5 parts of antistatic additive.
Modified cotton fiber is prepared using following technique：By weight by 60 parts of concentration for the Ludox of 10wt% is placed in temperature
For in 70 DEG C of water-baths, the pH value of Ludox is 3.5-4.5, and 20 parts of HMDSs, mixing speed are added dropwise under stirring
It is 500r/min, after being added dropwise completely, continues to stir 1h, 88 DEG C is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；By weight
By 2 parts of cotton fibers, 35 parts of concentration for the sodium hydroxide solution of 1mol/L mixes 50min, whipping temp is 55 DEG C to amount part, is risen
Temperature adds 1 part of sodium sulfite stirring 3h to 130 DEG C, obtains pre-processing cotton fiber；By weight in 14 parts of pretreatment cotton fibers
10 parts of formaldehyde, 2 parts of pretreatment Ludox stirring 5h are added, room temperature is cooled to, spray drying obtains modified cotton fiber.
Embodiment 4
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
26 parts of styrene, 6 parts of polyether-ketone, 5 parts of chlorosulfonated polyethylene, 1.5 parts of polyethylene, 2.5 parts of modified cotton fiber, 8 parts of glass microballoon,
5 parts of sodium antimonate, 2 parts of apatite, 5 parts of ceramic microsphere, 1.5 parts of liquid coumarone indene resin, 1.8 parts of diisononyl phthalate,
1.3 parts of adipic acid propylene glycol ester, 1.6 parts of triphenyl phosphite, 1.3 parts of triphenyl phosphate, 1.8 parts of crosslinking agent, stabilizer 1.6
Part, 1 part of antioxidant, 1.5 parts of antistatic additive.
Modified cotton fiber is prepared using following technique：By weight by 40 parts of concentration for the Ludox of 12wt% is placed in temperature
For in 60 DEG C of water-baths, the pH value of Ludox is 3.5-4.5, and 28 parts of HMDSs, mixing speed are added dropwise under stirring
It is 400r/min, after being added dropwise completely, continues to stir 2h, 80 DEG C is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；By weight
By 8 parts of cotton fibers, 25 parts of concentration for the sodium hydroxide solution of 1.6mol/L mixes 40min, whipping temp is 65 DEG C to amount part,
120 DEG C are warming up to, 2 parts of sodium sulfite stirring 1h are added, obtain pre-processing cotton fiber；By weight to 20 parts of pretreatment cotton fibers
It is middle to add 5 parts of formaldehyde, 7 parts of pretreatment Ludox stirring 2h, room temperature is cooled to, spray drying obtains modified cotton fiber.
Embodiment 5
A kind of waterproof tensile strength high-polystyrene cable material proposed by the present invention, its raw material includes by weight：It is poly-
24 parts of styrene, 8 parts of polyether-ketone, 4 parts of chlorosulfonated polyethylene, 2 parts of polyethylene, 2 parts of modified cotton fiber, 9 parts of glass microballoon, metaantimmonic acid
4.5 parts of sodium, 2.3 parts of apatite, 4 parts of ceramic microsphere, 2 parts of liquid coumarone indene resin, 1.5 parts of diisononyl phthalate, oneself
Two 1.5 parts of acid propylene glycol esters, 1.5 parts of triphenyl phosphite, 1.5 parts of triphenyl phosphate, 1.6 parts of crosslinking agent, 1.7 parts of stabilizer,
0.8 part of antioxidant, 2 parts of antistatic additive.
Modified cotton fiber is prepared using following technique：Ludox is placed in temperature in 65 DEG C of water-baths, the pH value of Ludox
It is that HMDS is added dropwise under 3.5-4.5, stirring, mixing speed is 450r/min, after being added dropwise completely, continues to stir
1.5h, 84 DEG C are dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；Cotton fiber, sodium hydroxide solution are mixed
45min, whipping temp is 60 DEG C, is warming up to 125 DEG C, adds sodium sulfite stirring 2h, obtains pre-processing cotton fiber；To pretreatment
Formaldehyde, pretreatment Ludox stirring 3.5h are added in cotton fiber, room temperature is cooled to, spray drying obtains modified cotton fiber.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of waterproof tensile strength high-polystyrene cable material, it is characterised in that its raw material includes by weight：Polyphenyl second
Alkene 20-28 parts, polyether-ketone 5-12 parts, chlorosulfonated polyethylene 2-6 parts, polyethylene 1-3 parts, modified cotton fiber 1-3 parts, glass microballoon
5-12 parts, sodium antimonate 3-6 parts, apatite 1-4 parts, ceramic microsphere 2-6 parts, 1-3 parts of liquid coumarone indene resin, phthalic acid two
1-2 parts of different nonyl ester, 1-2 parts of adipic acid propylene glycol ester, triphenyl phosphite 1-2 parts, triphenyl phosphate 1-2 parts, crosslinking agent 1-2
Part, stabilizer 1-2 parts, antioxidant 0.5-1.2 parts, antistatic additive 1-3 parts.
2. waterproof tensile strength high-polystyrene cable material according to claim 1, it is characterised in that modified cotton fiber is adopted
Prepared with following technique：Ludox is placed in water-bath, HMDS is added dropwise under stirring, after being added dropwise completely, after
Continuous stirring, is dried under vacuum to constant weight, and crushing obtains pre-processing Ludox；Cotton fiber, sodium hydroxide solution are mixed, is risen
Temperature, adds sodium sulfite stirring to obtain pre-processing cotton fiber；Stirred to formaldehyde, pretreatment Ludox is added in pretreatment cotton fiber
Mix, be cooled to room temperature, spray drying obtains modified cotton fiber.
3. waterproof tensile strength high-polystyrene cable material according to claim 1 or claim 2, it is characterised in that modified cotton is fine
Dimension is prepared using following technique：Ludox is placed in temperature in 60-70 DEG C of water-bath, the pH value of Ludox is 3.5-4.5, stirring
HMDS is added dropwise under state, mixing speed is 400-500r/min, after being added dropwise completely, continues to stir 1-2h, 80-88
Constant weight DEG C is dried under vacuum to, crushing obtains pre-processing Ludox；Cotton fiber, sodium hydroxide solution are mixed into 40-50min,
Whipping temp is 55-65 DEG C, is warming up to 120-130 DEG C, adds sodium sulfite stirring 1-3h, obtains pre-processing cotton fiber；To pre-
Formaldehyde, pretreatment Ludox stirring 2-5h are added in treatment cotton fiber, room temperature is cooled to, spray drying obtains modified cotton fiber.
4. the waterproof tensile strength high-polystyrene cable material according to claim any one of 1-3, it is characterised in that modified
Cotton fiber is prepared using following technique：By weight by 40-60 parts of concentration for the Ludox of 10-12wt% is placed in temperature for 60-
In 70 DEG C of water-baths, the pH value of Ludox is 3.5-4.5, and 20-28 parts of HMDS, mixing speed are added dropwise under stirring
It is 400-500r/min, after being added dropwise completely, continues to stir 1-2h, 80-88 DEG C is dried under vacuum to constant weight, and crushing obtains pre-processing silicon
Colloidal sol；By weight by 2-8 parts of cotton fiber, 25-35 parts of concentration for the sodium hydroxide solution of 1-1.6mol/L mixes 40-
50min, whipping temp is 55-65 DEG C, is warming up to 120-130 DEG C, adds 1-2 parts of sodium sulfite stirring 1-3h, is pre-processed
Cotton fiber；By weight to 5-10 parts of formaldehyde of addition, 2-7 parts of pretreatment Ludox stirring 2- in 14-20 parts of pretreatment cotton fiber
5h, is cooled to room temperature, and spray drying obtains modified cotton fiber.
5. the waterproof tensile strength high-polystyrene cable material according to claim any one of 1-4, it is characterised in that polyphenyl
Ethene, polyether-ketone, chlorosulfonated polyethylene, polyethylene, the weight ratio of modified cotton fiber are 22-26：6-10：3-5：1.5-2.5：
1.5-2.5。
6. the waterproof tensile strength high-polystyrene cable material according to claim any one of 1-5, it is characterised in that modified
Cotton fiber, glass microballoon, sodium antimonate, apatite, ceramic microsphere, liquid coumarone indene resin, the weight of diisononyl phthalate
Amount is than being 1.5-2.5：8-10：4-5：2-3：3-5：1.5-2.5：1.2-1.8.
7. the waterproof tensile strength high-polystyrene cable material according to claim any one of 1-6, it is characterised in that it is former
Material includes by weight：Polystyrene 22-26 parts, polyether-ketone 6-10 parts, chlorosulfonated polyethylene 3-5 parts, polyethylene 1.5-2.5
Part, modified cotton fiber 1.5-2.5 parts, glass microballoon 8-10 parts, sodium antimonate 4-5 parts, apatite 2-3 parts, ceramic microsphere 3-5 parts,
1.5-2.5 parts of liquid coumarone indene resin, diisononyl phthalate 1.2-1.8 parts, 1.3-1.7 parts of adipic acid propylene glycol ester,
Triphenyl phosphite 1.4-1.6 parts, triphenyl phosphate 1.3-1.7 parts, crosslinking agent 1.4-1.8 parts, stabilizer 1.6-1.8 parts, resist
0.6-1 parts, antistatic additive 1.5-2.5 parts of oxygen agent.
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| CN201611181945.3A CN106832632A (en) | 2016-12-20 | 2016-12-20 | A kind of waterproof tensile strength high-polystyrene cable material |
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| CN107353522A (en) * | 2017-06-20 | 2017-11-17 | 安徽瑞侃电缆科技有限公司 | A kind of preparation method of ageing-resistant computer control cable sheath |
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Application publication date: 20170613 |