CN105949550A - Adhesive for industrial shoes and industrial shoes prepared from adhesive - Google Patents
Adhesive for industrial shoes and industrial shoes prepared from adhesive Download PDFInfo
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- CN105949550A CN105949550A CN201610313379.0A CN201610313379A CN105949550A CN 105949550 A CN105949550 A CN 105949550A CN 201610313379 A CN201610313379 A CN 201610313379A CN 105949550 A CN105949550 A CN 105949550A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/405—Thioureas; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses an adhesive for industrial shoes. The adhesive is prepared from components in percentage by weight as follows: 67%-72% of latex, 1.2%-1.5% of an antioxidant, 1.2%-1.5% of accelerator CA, 0.5%-0.8% of accelerator ZDBC, 1.2%-1.5% of sulfur, 0.2%-0.5% of an antifoaming agent, 0.5%-0.8% of a stabilizer, 12%-15% of pottery clay and 9%-12% of a thickener. The invention further discloses industrial shoes prepared from the adhesive. The industrial shoes have good skid resistance good oil resistance and long service life.
Description
Technical field
The present invention relates to rubber cement and footwear product field, be specifically related to a kind of industry footwear rubber cement and the industrial footwear of preparation thereof.
Background technology
The generation of footwear is inseparable with the wisdom of natural environment, the mankind.Ancient times, being uneven of soil, weather in freezing winter and in sultry summer, to be protected to human instinct the both feet of oneself, then occur as soon as footwear.Along with expanding economy, footwear product also achieves significant progress, occurs in that various functional footwear, such as playshoes, climbing boot, sport shoes etc..Wherein, industry footwear are accompanied by what commercial production produced, building, lumber, weld, carry and in the industry such as machinery, manufacture, metallurgy, harbour, and work personnel extremely value for the ruggedness of footwear, skid resistance, oil-stain-preventing, the performance of the aspect such as waterproof.But existing industry footwear, due to problems such as rubber cement used in preparation process and preparation technologies, it is impossible to meet labourer's requirement that skid resistance is good, oil-stain-preventing, ruggedness are good for industry footwear.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of industry footwear rubber cement, this rubber cement can be effectively improved skid resistance and the ability of oil rub resistance of industry footwear.
Another object of the present invention is to provide a kind of industry footwear, industry footwear skid resistance is good, wearability is good for this, oil rub resistance ability is strong.
Realize the purpose of the present invention to reach by adopting the following technical scheme that:
A kind of industry footwear rubber cement, described industry footwear rubber cement is made up of the following component of percentage: latex 67～72%, antioxidant 1.2～1.5%, accelerant C A 1.2～1.5%, accelerator ZDBC 0.5～0.8%, sulfur 1.2～1.5%, defoamer 0.2～0.5%, stabilizer 0.5～0.8%, potter's clay 12～15%, thickening agent 9～12%, the summation of the percetage by weight of described component is 100%.
Preferably, described industry footwear rubber cement is made up of the following component of mark meter by weight: latex 69.69%, antioxidant 1.39%, accelerant C A 1.39%, accelerator ZDBC 0.70%, sulfur 1.39%, defoamer 0.35%, stabilizer 0.70%, potter's clay 13.94%, thickening agent 10.45%.
Preferably, described latex is polychloroprene latex LA-710, and described antioxidant is antioxidant Wingstay-L-60, and described accelerant C A is vulcanization accelerator CA-50, and described accelerator ZDBC is vulcanization accelerator ZDBC-50, and described sulfur is sulfur dispersion S-60.
In this programme, described polychloroprene latex LA-710, antioxidant Wingstay-L-60, vulcanization accelerator CA-50, vulcanization accelerator ZDBC-50 and sulfur dispersion S-60 are what Dongguan City Xiang Fa rubber-plastics material company produced.
A kind of industry footwear, described industry footwear are to be prepared from the following components: industry footwear sizing material and above-mentioned industry footwear rubber cement.
In the present invention, preferably scheme is, described industry footwear sizing material is made up of following component in parts by weight: mark glue 15～20 parts, butadiene rubber 10～15 parts, butyronitrile 10～15 parts, white carbon 10～15 parts, activated Calcium carbonate 25～30 parts, Petropols 2～2.5 parts, tackifying resin 1～1.5 parts, dioctyl adipate 3～5 parts, age resistor 1～1.5 parts, stearic acid 0.3～0.5 part, Polyethylene Glycol 1～1.5 parts, zinc oxide 2～3 parts, rubber vulcanization accelerant MBT S 0.5～0.6 part, rubber vulcanization accelerant MBT 0.1～0.2 part, TS-80 accelerator 0.04～0.05 part, insoluble sulfur powder 0.7～0.8 part.
nullPreferably，Described mark glue is the mark glue that trophy factory of rubber head office of rubber industry group of Vietnam produces，Described butadiene rubber is the butadiene rubber that Maoming Petrochemical branch company of middle petrochemical industry limited company produces，Described butyronitrile is the butyronitrile that Shandong Ju Ding Chemical Co., Ltd. produces，Described white carbon is the white carbon that Sanming City, Fujian Province positive element Chemical Co., Ltd. produces，Described activated Calcium carbonate is the activated Calcium carbonate that Heng great chemical plant, Yangshan produces，Described Petropols are the Petropols that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces，Described DEOTACK RS tackifier is the DEOTACK RS tackifier that Nan Yang, Jiangsu Jingjiang City chemical industry goods and materials company limited produces，Described dioctyl adipate is the dioctyl adipate that Shandong Lan Fan Chemical Co., Ltd. produces，Described age resistor is the age resistor that Shanghai rubber chemicals Co., Ltd., Factory produces，Described microwax is the microwax that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces，Described stearic acid is the stearic acid that polite oils and fats company of Indonesia produces，Described Polyethylene Glycol is the Polyethylene Glycol that Jilin Chemical Industrial Co. Ltd. produces，Described zinc oxide is the zinc oxide that Liuzhou Zhong Sexin product Co., Ltd produces，Described rubber vulcanization accelerant MBT S is the rubber vulcanization accelerant MBT S that Shenyang new oceangoing voyage Chemical Co., Ltd. produces，Described rubber vulcanization accelerant MBT is the rubber vulcanization accelerant MBT that Shenyang new oceangoing voyage Chemical Co., Ltd. produces，Described TS-80 accelerator is the TS-80 accelerator that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces，Described insoluble sulfur powder is the insoluble sulfur powder that Lian Zheng rubber and plastic Science and Technology Ltd. of Foshan City produces.
In the present invention, described industry footwear are prepared from by following preparation method:
Utilize mill refining industry footwear sizing material, then sheet rubber is made through rubber film-discharging machine, it is cut into lining, rear enclosure, center benefit, foxing before footwear body sheet, toe-cap the most respectively, before described footwear body sheet, toe-cap, lining, rear enclosure, center benefit, the thickness of foxing are 0.8mm～1.0mm, follow the steps below the most successively:
A. take shoe last, find out the shoe last corresponding with ankle socks from shoe last room；Take ankle socks, shoe last is inserted in ankle socks, then in shoe last end, ankle socks is fixed；Finish the height point that at least two is identical with footwear height degree before and after utilizing the clamp identical with footwear height degree on ankle socks, then finish the connecting line between height point according to height point；
B. uniformly spray white glue with spray gun on ankle socks surface, be subsequently placed in the drying in oven of 60～65 DEG C；
C. serve as a contrast before taking toe-cap, lining before toe-cap is carried out, attaches it to the relevant position for the wrapping foot back side on the toe-cap of ankle socks；
D. it is coated with a layer binder uniformly on exposed ankle socks surface, is subsequently placed in the drying in oven of 60～65 DEG C；
E. take footwear body large stretch of, footwear body sheet is carried out, is attached to footwear body relevant position on ankle socks, then carry out wheel load process by the footwear body sheet through over cleaning followed by binding agent；
F. taking rear enclosure, be carried out rear enclosure, then the upper binding agent of brush, is then placed in the drying in oven of 60～65 DEG C, then is fitted in heel relevant position on ankle socks, then carry out wheel load process, obtain shoes；
G. putting into immersion in the container containing rubber cement after clean for shoes surface clean, shoes nozzle, from rubber cement liquid level 5～8mm, takes out after soaking 3～5 minutes, and the rubber cement thickness on shoes surface is 0.3～0.5mm；
H. being put into by shoes in the container containing coagulator and soak, shoes nozzle, from coagulator liquid level 5～8mm, takes out to be placed on to keep away after soaking 3～5 minutes and naturally dries at the moon；
I. the bottom of shoes is carried out, then by middle backplate surface brush coating, and is affixed on bottom shoes, then center is mended brush coating after cleaning, is affixed on the middle base plate bottom shoes；
J. take the big end, core at the big end is carried out, then three binding agents of even spread in core within the big end, after coating, the big end is placed in the drying in oven of 60～65 DEG C every time, then utilizes binding agent to be filled at the center that the big end is affixed on bottom shoes；
K. taking foxing, be carried out foxing surface, then uniform brush coating, is then attached to foxing vamp and border, junction, the big end, carries out wheel load process, upper and lower press the most successively；
L. being carried out shoes surface, then carry out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, and the time of described sulfur adding treatment is 90 minutes, then carries out delasting, cutting, bound edge process, it is thus achieved that industry footwear.
Preferably, in step b, d, f, j, the time of described drying be 2 points 30 seconds.
In the present invention, described industry footwear can also be made up of following preparation method:
Utilize mill refining industry footwear sizing material, then sheet rubber is made through rubber film-discharging machine, it is cut into lining, rear enclosure, center benefit, foxing before footwear body sheet, toe-cap the most respectively, before described footwear body sheet, toe-cap, the thickness of lining, rear enclosure, center benefit and foxing is 0.8mm～1.0mm, follows the steps below the most successively:
A. take shoe last, find out the shoe last corresponding with ankle socks from shoe last room；Take ankle socks, shoe last is inserted in ankle socks, then in shoe last end, ankle socks is fixed；Finish the height point that at least two is identical with footwear height degree before and after utilizing the clamp identical with footwear height degree on ankle socks, then finish the connecting line between height point according to height point；
B. uniformly spray white glue with spray gun on the whole surface of ankle socks, be subsequently placed in the drying in oven of 60～65 DEG C；
C. serve as a contrast before taking toe-cap, lining before toe-cap is carried out, attaches it to the relevant position for the wrapping foot back side on the toe-cap of ankle socks；
D. it is coated with a layer binder uniformly on exposed ankle socks surface, is subsequently placed in the drying in oven of 60～65 DEG C；
E. take footwear body large stretch of, footwear body sheet is carried out, is attached to footwear body relevant position on ankle socks, then carry out wheel load process by footwear body sheet followed by binding agent；
F. taking rear enclosure, be carried out rear enclosure, then the upper binding agent of brush, is then placed in the drying in oven of 60～65 DEG C, then is fitted in heel relevant position on ankle socks, then carry out wheel load process, obtain shoes；
G. putting into immersion in the container containing rubber cement after clean for shoes surface clean, shoes nozzle, from rubber cement liquid level 5～8mm, takes out after soaking 3～5 minutes, and the rubber cement thickness on shoes surface is 0.3mm～0.5mm；
H. the shoes after soaking are put in the container containing coagulator and are soaked, and shoes nozzle, from coagulator liquid level 5～8mm, takes out to be placed on to keep away after soaking 3～5 minutes and naturally dries at the moon；
I. being carried out shoes surface, then carry out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, and the time of described sulfur adding treatment is 90 minutes；
J. after the shoes natural cooling after sulfur adding treatment, it is carried out bottom shoes, then by middle backplate surface brush coating, is affixed on bottom shoes；Then center is mended brush coating after cleaning, in being affixed on bottom shoes on base plate；
K. take the big end, successively core at the big end is polished, dust removal, cleaning treatment, then three binding agents of uniform coating in core within the big end, are placed in the big end drying in oven of 60～65 DEG C every time, are then filled at the center that the big end is affixed on bottom shoes after coating；
L. take foxing, foxing surface is carried out, and uniformly brush coating, attach it to vamp and border, junction, the big end, carry out wheel load process, upper and lower press the most successively；
M. shoes are put into freezing 3～5 minutes in the household freezer of-5 DEG C to-10 DEG C, then takes out shoes and carry out delasting, cutting, bound edge process, it is thus achieved that industry footwear.
Preferably, in step b, d, f, k, the time of described drying be 2 points 30 seconds.
In two kinds of preparation methoies of the industrial footwear of this programme, described coagulator is the aqueous solution of the calcium chloride of 13.04wt%.
Compared to existing technology, the beneficial effects of the present invention is:
Industry footwear rubber cement of the present invention, by selecting rational proportioning between unique component and each component, then industry footwear are immersed in industry footwear rubber cement, industry footwear rubber cement is made to be attached to industry footwear surface and solidify, thus obtained industrial footwear, there is good wearability, skid resistance, oil rub resistance performance and ageing-resistant performance, extend the service life of industry footwear.
Detailed description of the invention
Below, in conjunction with detailed description of the invention, the present invention is described further:
Embodiment 1
A kind of industry footwear rubber cement, is made up of the following component of percentage: polychloroprene latex LA-710 69.69%, antioxidant Wingstay-L-60 1.39%, vulcanization accelerator CA-50 1.39%, vulcanization accelerator ZDBC-50 0.70%, sulfur dispersion S-601.39%, defoamer 0.35%, stabilizer 0.70%, potter's clay 13.94%, thickening agent 10.45%.
The preparation method of rubber cement, for above each component is polished into powdery, then joins in container by proportioning, obtains rubber cement of the present invention.
Embodiment 2
A kind of industry footwear rubber cement, is made up of the following component of percentage: polychloroprene latex LA-710 67%, antioxidant Wingstay-L-60 1.5%, vulcanization accelerator CA-50 1.5%, vulcanization accelerator ZDBC-50 0.8%, sulfur dispersion S-60 1.5%, defoamer 0.5%, stabilizer 0.8%, potter's clay 15%, thickening agent 11.4%.
The preparation method of rubber cement, for above each component is polished into powdery, then joins in container by proportioning, obtains rubber cement of the present invention.
Embodiment 3
A kind of industry footwear rubber cement, is made up of the following component of percentage: polychloroprene latex LA-710 72%, antioxidant Wingstay-L-60 1.2%, vulcanization accelerator CA-501.2%, vulcanization accelerator ZDBC-50 0.5%, sulfur dispersion S-60 1.2%, defoamer 0.2%, stabilizer 0.5%, potter's clay 14.2%, thickening agent 9%.
The preparation method of rubber cement, for above each component is polished into powdery, then joins in container by proportioning, obtains rubber cement of the present invention.
Embodiment 4
A kind of industry footwear rubber cement, is made up of the following component of percentage: polychloroprene latex LA-710 70.5%, antioxidant Wingstay-L-60 1.3%, vulcanization accelerator CA-501.3%, vulcanization accelerator ZDBC-50 0.6%, sulfur dispersion S-60 1.3%, defoamer 0.4%, stabilizer 0.6%, potter's clay 12%, thickening agent 12%.
The preparation method of rubber cement, for above each component is polished into powdery, then joins in container by proportioning, obtains rubber cement of the present invention.
Embodiment 5
A kind of industry footwear rubber cement, is made up of the following component of percentage: polychloroprene latex LA-710 69%, antioxidant Wingstay-L-60 1.5%, vulcanization accelerator CA-501.5%, vulcanization accelerator ZDBC-50 0.7%, sulfur dispersion S-60 1.5%, defoamer 0.5%, stabilizer 0.8%, potter's clay 14%, thickening agent 10.5%.
The preparation method of rubber cement, for above each component is polished into powdery, then joins in container by proportioning, obtains rubber cement of the present invention.
Embodiment 6
A kind of industry footwear, its manufacture method is to utilize mill refining industry footwear sizing material, then sheet rubber is made through rubber film-discharging machine, it is cut into lining, rear enclosure, center benefit, foxing before footwear body sheet, toe-cap the most respectively, before described footwear body sheet, toe-cap, lining, rear enclosure, center benefit, the thickness of foxing are 0.8mm～1.0mm, follow the steps below the most successively:
A. take shoe last, find out the shoe last corresponding with ankle socks from shoe last room；Take ankle socks, shoe last is inserted in ankle socks, then in shoe last end, ankle socks is fixed；Finish the height point that at least two is identical with footwear height degree before and after utilizing the clamp identical with footwear height degree on ankle socks, then finish the connecting line between height point according to height point；
B. uniformly spray white glue with spray gun on ankle socks surface, be subsequently placed in 2 points 30 seconds in the baking oven of 60～65 DEG C；
C. serve as a contrast before taking toe-cap, lining before toe-cap is carried out, attaches it on the toe-cap of ankle socks for relevant position, the wrapping foot back side；
D. it is coated with a layer binder uniformly on exposed ankle socks surface, is subsequently placed in 2 points 30 seconds in the baking oven of 60～65 DEG C；
E. take footwear body large stretch of, footwear body sheet is carried out, is attached to footwear body relevant position on ankle socks, then carry out wheel load process by the footwear body sheet through over cleaning followed by binding agent；
F. take rear enclosure, rear enclosure is carried out, then the upper binding agent of brush, be then placed in 2 points 30 seconds in the baking oven of 60～65 DEG C, then be fitted in heel relevant position on ankle socks, then carry out wheel load process, obtain shoes；
G. putting into immersion in the container of the rubber cement containing embodiment 1 after clean for shoes surface clean, shoes nozzle, from rubber cement liquid level 5～8mm, takes out after soaking 3～5 minutes, and the rubber cement thickness on shoes surface is 0.3～0.5mm；
H. the shoes after soaking are put in the container containing coagulator and are soaked, and shoes nozzle, from coagulator liquid level 5～8mm, takes out to be placed on to keep away after soaking 3～5 minutes and naturally dries at the moon, and described coagulator is the calcium chloride water of 13.04wt%；
The bottom of the shoes after i. drying carries out surface clean, then by middle backplate surface brush coating, is affixed on bottom shoes, center is then mended brush coating after cleaning, in being affixed on bottom shoes on base plate；
J. take the big end, be carried out core at the big end processing, then three binding agents of even spread in core within the big end, after coating, the big end is placed in 2 points 30 seconds in the baking oven of 60～65 DEG C every time, then utilizes binding agent to be filled at the center that the big end is affixed on bottom shoes；
K. taking foxing, be carried out foxing surface, then uniform brush coating, is then attached to foxing vamp and border, junction, the big end, carries out wheel load process, upper and lower press the most successively；
L. being carried out shoes surface, then carry out sulfur adding treatment, the temperature of described sulfur adding treatment is 110 DEG C, and the time of described sulfur adding treatment is 90 minutes, then carries out delasting, cutting, bound edge process, it is thus achieved that industry footwear.
Described industry footwear sizing material is made up of following component in parts by weight: mark glue 15～20 parts, butadiene rubber 10～15 parts, butyronitrile 10～15 parts, white carbon 10～15 parts, activated Calcium carbonate 25～30 parts, Petropols 2～2.5 parts, tackifying resin 1～1.5 parts, dioctyl adipate 3～5 parts, age resistor 1～1.5 parts, stearic acid 0.3～0.5 part, Polyethylene Glycol 1～1.5 parts, zinc oxide 2～3 parts, rubber vulcanization accelerant MBT S 0.5～0.6 part, rubber vulcanization accelerant MBT 0.1～0.2 part, TS-80 accelerator 0.04～0.05 part, insoluble sulfur powder 0.7～0.8 part.
Performance detects:
Below according to ASTM D 471-2012 and ASTM F 1677-2005, the industrial footwear in embodiment 6 are carried out performance detection.
1, grease resistance
The oils and fats used in this test is No. 903 oil of IRM, and test temperature is 23 DEG C, and the testing time is 22 hours.Test result shows, the volume of the industrial shoe pattern product of the present invention adds 8.4%, less than in standard the 12% of regulation, illustrates that the industrial footwear of the present invention has good grease resistance.
2, skid resistance
Testing the industrial shoe pattern product in embodiment 6 according to ASTM F 1677-2005, result is as shown in table 1.Data the biggest expression skid resistance is the best.
The skid resistance test result of 6 samples implemented by table 1
From table 1 it follows that in all of test event, the test data of the industrial shoe pattern product of the present invention are both greater than the data of standard, show that the industrial footwear of the present invention has the skid resistance of excellence.
For a person skilled in the art, can technical scheme as described above and design, make other various corresponding changes and deformation, and within all these changes and deformation all should belong to the protection domain of the claims in the present invention.
Claims (10)
1. an industrial footwear rubber cement, it is characterised in that described industry footwear rubber cement is by by weight hundred
The following component of mark meter is made: latex 67～72%, antioxidant 1.2～1.5%, promote
Agent CA 1.2～1.5%, accelerator ZDBC 0.5～0.8%, sulfur 1.2～1.5%, froth breaking
Agent 0.2～0.5%, stabilizer 0.5～0.8%, potter's clay 12～15%, thickening agent 9～12%,
The summation of the percetage by weight of described component is 100%.
2. industry footwear rubber cement as claimed in claim 1, it is characterised in that described industry footwear
Rubber cement is made up of the following component of mark meter by weight: latex 69.69%, antioxidant 1.39%,
Accelerant C A 1.39%, accelerator ZDBC 0.70%, sulfur 1.39%, defoamer
0.35%, stabilizer 0.70%, potter's clay 13.94%, thickening agent 10.45%.
3. industry footwear rubber cement as claimed in claim 1 or 2, it is characterised in that described glue
Breast is polychloroprene latex LA-710, and described antioxidant is antioxidant Wing stay-L-60, institute
Stating accelerant C A is vulcanization accelerator CA-50, and described accelerator ZDBC is vulcanization accelerator
ZDBC-50, described sulfur is sulfur dispersion S-60.
4. industrial footwear, it is characterised in that described industry footwear be prepared by following components and
Become: the industrial footwear rubber cement described in industry footwear sizing material and any one of claims 1 to 3.
5. industry footwear as claimed in claim 4, it is characterised in that described industry footwear sizing material
Be made up of following component in parts by weight: mark glue 15～20 parts, butadiene rubber 10～
15 parts, butyronitrile 10～15 parts, white carbon 10～15 parts, activated Calcium carbonate 25～30 parts,
Petropols 2～2.5 parts, tackifying resin 1～1.5 parts, dioctyl adipate 3～5 parts, anti-
Old agent 1～1.5 parts, stearic acid 0.3～0.5 part, Polyethylene Glycol 1～1.5 parts, zinc oxide 2～
3 parts, rubber vulcanization accelerant MBT S 0.5～0.6 part, rubber vulcanization accelerant MBT
0.1～0.2 part, TS-80 accelerator 0.04～0.05 part, insoluble sulfur powder 0.7～0.8 part.
6. the industrial footwear as described in claim 4 or 5, it is characterised in that described industry footwear
It is prepared from by following preparation method:
Utilize mill refining industry footwear sizing material, then make sheet rubber through rubber film-discharging machine, then
Being cut into lining, rear enclosure, center benefit, foxing before footwear body sheet, toe-cap respectively, described footwear body is big
Before sheet, toe-cap, lining, rear enclosure, center benefit, the thickness of foxing are 0.8mm～1.0mm, so
After follow the steps below successively:
A. take shoe last, find out the shoe last corresponding with ankle socks from shoe last room；Take ankle socks, by shoe last
It is inserted in ankle socks, then in shoe last end, ankle socks is fixed；Utilize identical with footwear height degree
Clamp front and back finishes the height point that at least two is identical with footwear height degree, then basis on ankle socks
Highly finish the connecting line between height point；
B. uniformly spray white glue with spray gun on ankle socks surface, be subsequently placed in the baking oven of 60～65 DEG C
Interior drying；
C. serve as a contrast before taking toe-cap, lining before toe-cap is carried out, attaches it to the footwear of ankle socks
For the relevant position at the wrapping foot back side on head；
D. be coated with a layer binder uniformly on exposed ankle socks surface, be subsequently placed in 60～
The drying in oven of 65 DEG C；
E. take footwear body large stretch of, footwear body sheet is carried out, will pass through followed by binding agent
The footwear body sheet cleaned is attached to footwear body relevant position on ankle socks, then carry out wheel load process；
F. take rear enclosure, rear enclosure be carried out, then the upper binding agent of brush, be then placed in 60～
The drying in oven of 65 DEG C, then it is fitted in heel relevant position on ankle socks, then carry out at wheel load
Reason, obtains shoes；
G. after clean for shoes surface clean, immersion, shoes cylinder in the container containing rubber cement are put into
Mouth, from rubber cement liquid level 5～8mm, takes out after soaking 3～5 minutes, and the rubber cement on shoes surface is thick
Degree is 0.3～0.5mm；
H. being put into by shoes in the container containing coagulator and soak, shoes nozzle is from coagulator liquid
Face 5～8mm, takes out to be placed on to keep away after soaking 3～5 minutes and naturally dries at the moon；
I. the bottom of shoes is carried out, then by middle backplate surface brush coating, and is affixed on shoes
Bottom, then mends center brush coating after cleaning, is affixed on the middle base plate bottom shoes；
J. take the big end, core at the big end is carried out, then even spread three in core within the big end
Secondary binding agent, is placed in the drying in oven of 60～65 DEG C, then profit every time by the big end after coating
With binding agent, the center that the big end is affixed on bottom shoes is filled；
K. take foxing, foxing surface is carried out, then uniform brush coating, then by foxing
It is attached to vamp and border, junction, the big end, carries out wheel load process, upper and lower press the most successively；
L. shoes surface is carried out, then carries out sulfur adding treatment, the temperature of described sulfur adding treatment
Degree is 110 DEG C, and the time of described sulfur adding treatment is 90 minutes, then carry out delasting, cutting,
Bound edge processes, it is thus achieved that industry footwear.
7. industry footwear as claimed in claim 6, it is characterised in that step b, d, f,
In j, the time of described drying be 2 points 30 seconds.
8. the industrial footwear as described in claim 4 or 5, it is characterised in that described industry footwear
It is made up of following preparation method:
Utilize mill refining industry footwear sizing material, then make sheet rubber through rubber film-discharging machine, then
Being cut into lining, rear enclosure, center benefit, foxing before footwear body sheet, toe-cap respectively, described footwear body is big
Before sheet, toe-cap, the thickness of lining, rear enclosure, center benefit and foxing is 0.8mm～1.0mm, so
After follow the steps below successively:
A. take shoe last, find out the shoe last corresponding with ankle socks from shoe last room；Take ankle socks, by shoe last or hat block
Headgear enters in ankle socks, is then fixed by ankle socks in shoe last end；Utilize identical with footwear height degree
Clamp on ankle socks before and after finish the height point that at least two is identical with footwear height degree, then root
The connecting line between height point is finished according to height point；
B. uniformly spray white glue with spray gun on the whole surface of ankle socks, be subsequently placed in 60～65 DEG C
Drying in oven；
C. serve as a contrast before taking toe-cap, lining before toe-cap is carried out, attaches it to the footwear of ankle socks
For the relevant position at the wrapping foot back side on head；
D. be coated with a layer binder uniformly on exposed ankle socks surface, be subsequently placed in 60～
The drying in oven of 65 DEG C；
E. take footwear body large stretch of, footwear body sheet is carried out, followed by binding agent by footwear body
Sheet is attached to footwear body relevant position on ankle socks, then carry out wheel load process；
F. take rear enclosure, rear enclosure be carried out, then the upper binding agent of brush, be then placed in 60～
The drying in oven of 65 DEG C, then it is fitted in heel relevant position on ankle socks, then carry out at wheel load
Reason, obtains shoes；
G. after clean for shoes surface clean, immersion, shoes cylinder in the container containing rubber cement are put into
Mouth, from rubber cement liquid level 5～8mm, takes out after soaking 3～5 minutes, and the rubber cement on shoes surface is thick
Degree is 0.3mm～0.5mm；
H. will soak after shoes put in the container containing coagulator soak, shoes nozzle from
Coagulator liquid level 5～8mm, takes out to be placed on to keep away after soaking 3～5 minutes and naturally dries at the moon；
I. shoes surface is carried out, then carries out sulfur adding treatment, the temperature of described sulfur adding treatment
Being 110 DEG C, the time of described sulfur adding treatment is 90 minutes；
J. after the shoes natural cooling after sulfur adding treatment, it is carried out bottom shoes, then will
Middle backplate surface brush coating, is affixed on bottom shoes；Then center is mended brush coating after cleaning, is affixed on footwear
In bottom son on base plate；
K. take the big end, successively core at the big end is polished, dust removal, cleaning treatment, then
Three binding agents of uniform coating in core within the big end, after coating, the big end, is placed in every time 60～
The drying in oven of 65 DEG C, then fills the center that the big end is affixed on bottom shoes；
L. take foxing, foxing surface is carried out, and uniformly brush coating, attach it to footwear
Face and border, junction, the big end, carry out wheel load process, upper and lower press the most successively；
M. shoes are put into freezing 3～5 minutes in the household freezer of-5 DEG C to-10 DEG C, then takes
Go out shoes and carry out delasting, cutting, bound edge process, it is thus achieved that industry footwear.
9. industry footwear as claimed in claim 8, it is characterised in that step b, d, f,
In k, the time of described drying be 2 points 30 seconds.
10. the industrial footwear as described in claim 6 or 8, it is characterised in that in step h,
Described coagulator is the aqueous solution of the calcium chloride of 13.04wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313379.0A CN105949550A (en) | 2016-05-11 | 2016-05-11 | Adhesive for industrial shoes and industrial shoes prepared from adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313379.0A CN105949550A (en) | 2016-05-11 | 2016-05-11 | Adhesive for industrial shoes and industrial shoes prepared from adhesive |
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| Publication Number | Publication Date |
|---|---|
| CN105949550A true CN105949550A (en) | 2016-09-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313379.0A Pending CN105949550A (en) | 2016-05-11 | 2016-05-11 | Adhesive for industrial shoes and industrial shoes prepared from adhesive |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115304831A (en) * | 2022-06-20 | 2022-11-08 | 芜湖三鼎鞋业有限公司 | Fast-setting latex and preparation method thereof, wear-resistant felt shoe and production method thereof |
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| JPH0751102A (en) * | 1993-08-11 | 1995-02-28 | Moon Star Co | Antislip shoe sole |
| CN104479177A (en) * | 2014-11-28 | 2015-04-01 | 刘中华 | Fishing shoe rubber, anti-skid fishing shoes and preparation method of fishing shoe rubber |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0751102A (en) * | 1993-08-11 | 1995-02-28 | Moon Star Co | Antislip shoe sole |
| CN104479177A (en) * | 2014-11-28 | 2015-04-01 | 刘中华 | Fishing shoe rubber, anti-skid fishing shoes and preparation method of fishing shoe rubber |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115304831A (en) * | 2022-06-20 | 2022-11-08 | 芜湖三鼎鞋业有限公司 | Fast-setting latex and preparation method thereof, wear-resistant felt shoe and production method thereof |
| CN115304831B (en) * | 2022-06-20 | 2024-02-02 | 芜湖三鼎鞋业有限公司 | Quick-setting emulsion and preparation method thereof, and wear-resistant felt shoe and production method thereof |
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Application publication date: 20160921 |