CN105948622A - Shale bronze-imitating sculpture powder - Google Patents
Shale bronze-imitating sculpture powder Download PDFInfo
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- CN105948622A CN105948622A CN201610276543.5A CN201610276543A CN105948622A CN 105948622 A CN105948622 A CN 105948622A CN 201610276543 A CN201610276543 A CN 201610276543A CN 105948622 A CN105948622 A CN 105948622A
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- shale
- bronze
- powder
- sculpture powder
- bronze sculpture
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00956—Uses not provided for elsewhere in C04B2111/00 for making sculptures or artistic casts
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a shale bronze-imitating sculpture powder. The main points of a technical scheme of the invention are as follows: the shale bronze-imitating sculpture powder is composed of shale, acidized zeolite particles, naturally-weathered attapulgite clay, white cement, white carbon black, bronze powder, iron oxide yellow, lemon yellow, rock wool, bronze pearlescent powder and glitter powder. The shale bronze-imitating sculpture powder is prepared through the following steps: subjecting ingredients of a semi-finished shale bronze-imitating sculpture powder to stirring and carrying out milling, then carrying out co-mixing with the ingredients of the shale bronze-imitating sculpture powder under stirring, and carrying out packaging so as to obtain the shale bronze-imitating sculpture powder. By adopting the shale bronze-imitating sculpture powder to manufacture a bronze-imitating sculpture, a bronze-imitating sculpture craft with pure color is obtained after maintenance and hardening; the obtained bronze-imitating sculpture craft has the characteristics of good smooth finish, brightness, high strength, small shrinkage rate, wear resistance and corrosion resistance, can be placed at a variety of places like outdoors, squares, gardens or indoors, is adaptable to weather exposure, and does not deform under exposure to wind and rain; meanwhile, the shale bronze-imitating sculpture powder is applicable to manufacturing of a variety of bronze-imitating sculpture crafts.
Description
Technical field
The present invention relates to sculpture, be specifically related to a kind of shale and imitate bronze sculpture powder.
Background technology
Various ancient times and the imitative bronze sculpture of modern personage, child or animal is had in numerous parks, welcome by traveller very much, due to hold up touch, ride carry on the arm, weather exposure and exposing to wind and rain, these imitative bronze sculptures all can be by than more serious infringement from color to moulding.
China Patent Publication No.: CN 104446286A, publication date: on 03 25th, 2015, entitled " composition of raw materials of a kind of imitative bronze sculpture ", disclose that " composition of raw materials of a kind of imitative bronze sculpture; wherein, is made up of the material of following components by weight percent: paraffin 40-50 part；Pulvis Talci 20-30 part；Cu-Zn alloy powder 15-20 part；Colophonium 5-8 part；Magnesium oxide 10-15 part；Toughener 2-5 part；And catalyst 1-3 part.Wherein, described catalyst is selected from phosphate, sulfate and oxalic acid.Described toughener is selected from plant stalk fine powder, glass fibre and organic fiber.The method have the advantages that the present invention realizes imitative bronze effect Billy the most time saving and energy saving by the mode carrying out manual polishing after aqueous clay making sculpture again, and viscosity is good, it is not easy to be dry and cracked, it is simple to preserve for a long time ".
Above-mentioned patent weak point: using the sculpture that " composition of raw materials of imitative bronze sculpture " makes, color and intensity are all difficult to reach bronzy effect, are not also suitable for being placed on outdoor environment.
Summary of the invention
It is an object of the invention to overcome weak point in prior art, it is provided that a kind of shale imitates bronze sculpture powder.
Shale is imitated bronze sculpture powder and is made up of the zeolite granular after shale, acidifying, attapulgite clay after weathering, white cement, white carbon, bronze powder, iron oxide yellow, lemon yellow, rock wool, bronze pearl essence and glitter powder.
Shale imitates the production method of bronze sculpture powder: the dispensing that shale is first imitated bronze sculpture powder semi-finished product is stirred and pulverizing, then is packaged as shale after the common mix and blend of dispensing that shale is imitated bronze sculpture powder and imitates bronze sculpture powder.
Shale is a kind of sedimentary rock, complicated, but all there is thin laminated or the joint of thin slice stratiform, the rock formed through pressure and temperature is mainly deposited by clay, but wherein it is contaminated with quartz, the chip of Anhydrite and other chemical substances, the product utilizing shale to be produced has that body is light, insulation, the feature such as energy-conservation, the present invention selects the shale after pulverizing, granularity≤2 millimeter of shale.
Zeolite has powerful adsorption function, to polar molecule such as H2O、NH3、H2S、CO2Etc. there being the highest affinity, even if remaining to active adsorption under low relative humidity, low concentration, higher temperature conditions, therefore it is stable performance, adsorbent that adsorption effect is good, it is adaptable to exhaust-gas treatment and air cleaning.
Zeolite granular after acidifying be zeolite is pulverized laggard row roasting, be acidified, dry and sieve after for acidifying after zeolite granular.
Attapulgite has another name called Paligorskite or Palygorskite, be a kind of layer of chain structure containing Shuifu County's zeopan clay mineral, attapulgite clay have uniqueness layer chain structure feature, crystal is needle-like, threadiness or fiber collection shape.Attapulgite clay has the dispersion of uniqueness, good colloidal nature and the higher absorbability such as saline and alkaline high temperature resistant, anti-, and has certain plasticity and cohesive force.
Attapulgite clay after weathering is by attapulgite clay raw ore time weathering more than two winters, attapulgite clay after the weathering that raw ore disintegrate is fine particle of large block compact, picking and be evident that barren rock block, Plant fiber and other earth impurity, the present invention selects granularity≤5 millimeter of the attapulgite clay after weathering.
Being added Gypsum Fibrosum, the levigate hydraulic cementing materials made by white portland cement clinker, be typically characterised by and have the highest whiteness, bright color, quality needs to meet the standard of " GB/T2015-2005 white portland cement ".
White carbon is a kind of ultra tiny inorganic porous property material, owing to its particle diameter is the least, has the special performances such as the stability that specific surface area is big, superficial attractive forces is strong, chemical purity is high, dispersive property is good, superior, reinforcing, thickening property, adhesive force and thixotropy.
Bronze powder is a kind of signal bronze complex Cu-Zn alloy powder, through special machining and chemical surface treatment prepare have sclay texture, can in cohering material floating, present inaurate, there are a kind of metallic pigments of pigment property.
Iron oxide yellow is a kind of lemon yellow to the powder of brown, and powder is fine and smooth, is the iron oxide hydrate of crystal, has preferable tinting strength, tinting power, covering power, light resistance, acid resistance, alkali resistance and thermostability.
Lemon yellow is a kind of bright-coloured bright yellow powder, and being dissolved in water is yellow, and its aqueous solution meets sulphuric acid, nitric acid, hydrochloric acid and sodium hydroxide still in yellow.
Rock wool is with natural rock such as basalt, gabbro, dolomite, iron ore, bauxite etc. as primary raw material, the inorganic fibre made through high temperature melting, fibrosis, and the present invention selects the length 5 of rock wool fibers～8 millimeters.
Pearl essence is the nacreous novel pigment covering metal-oxide outside natural mica thin skin and producing, and it can reproduce nature Margarita, shell, the gorgeous and color that Corallium Japonicum Kishinouye and metal are had, and the present invention selects granularity≤0.044 millimeter of bronze pearl essence.
Glitter powder, by PET, PVC, OPP metallic aluminium film material plating of the essence high different-thickness of brightness, is coated with and forms through precision cutting.Glitter powder bright in color, to weather, the mild corrosion chemicals of temperature has certain resistance and temperature tolerance, and the present invention selects golden glitter powder, granularity≤0.044 millimeter of glitter powder.
The technical scheme is that:
1, shale is imitated the dispensing of bronze sculpture powder and is made up of following component by weight percentage: shale imitates the zeolite granular after bronze sculpture powder semi-finished product 25～60%, white cement 20～45%, acidifying 5～25%, rock wool 1～10%, bronze pearl essence 0.5～5% and glitter powder 0.5～5%.
2, shale is imitated the dispensing of bronze sculpture powder semi-finished product and is made up of following component by weight percentage: shale 30～60%, attapulgite clay after weathering 10～40%, white carbon 1～20%, bronze powder 1～20%, iron oxide yellow 1～10% and lemon yellow 0.5～5%.
3, shale imitates the production method of bronze sculpture powder: (1) shale imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder semi-finished product, and inputting pulverizing in grinding machine after stirring is that shale imitates bronze sculpture powder semi-finished product, granularity≤0.044 millimeter；(2) shale is imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder, is packaged as shale after stirring and imitates bronze sculpture powder.
4, the production method of the zeolite granular after acidifying: the most first carrying out zeolite pulverizing and screening for the first time, the Task-size Controlling of the zeolite granular after screening is at 0.149～0.42 millimeter；2. by the zeolite granular input revolution roasting in kilns after screening, sintering temperature controls at 420～480 DEG C, and roasting time controlled at 60～120 minutes；3. being inputted in dilute sulfuric acid pond by the zeolite granular after roasting and carry out acidification, the preparation of dilute sulfuric acid includes following component by weight percentage: the sulphuric acid 6～10% of concentration 98, water 90～94%, and the acidification time controlled at 4～12 hours；4. the zeolite granular after acidified process is taken out and drain away the water, zeolite granular semi-finished product after drying as acidifying in input rotary dryer, drying temperature and control at 150～250 DEG C, drying time controls at 30～60 minutes, and the zeolite granular semi-finished product water content after acidifying is less than 2.0%；5. carrying out after second time is sieved being the zeolite granular after being acidified by the zeolite granular semi-finished product after acidifying, the Task-size Controlling of the zeolite granular after acidifying is at 0.125～0.42 millimeter.
Zeolite granular after acidifying is to use by " having the zeolite colour-wash powder of air purification function " filed in 14 days November in 2015 of the applicant, and China Patent Publication No. is: CN 105272114A, publication date: on 01 27th, 2016.
Attapulgite clay, white carbon, bronze powder, iron oxide yellow and lemon yellow after shale, weathering is stirred together for rear pulverizing, be conducive to the dispensing that shale is imitated bronze sculpture powder semi-finished product sufficiently to be disperseed, promote that white carbon, bronze powder, iron oxide yellow and lemon yellow will be supported on the surface of shale and attapulgite clay uniformly.
Zeolite granular after acidifying uses to be pulverized, screening for the first time, roasting, is acidified, drains, dries and technological process that second time is sieved, substantially increase acidifying quality and the acidification rate of zeolite, strengthen shale imitate the absorption of bronze sculpture powder and purify the efficiency of air, the Task-size Controlling of the zeolite granular after acidifying is at 0.125～0.42 millimeter, the function of aggregate can be played, be conducive to increasing the intensity of imitative bronze sculpture product.
Zeolite is after 420～480 DEG C of roastings, then carries out acidification, and zeolite has obtained further activation, forms loose porous spongy body, and its adsorption effect is in optimum.
Rock wool plays the effect increasing tensile strength in shale imitates the dispensing of bronze sculpture powder, it can be ensured that will not crack when making imitative bronze sculpture product.
Being imitated by shale after the shale granule after bronze sculpture powder semi-finished product, white cement, acidifying, rock wool, bronze pearl essence and glitter powder carry out mix and blend, it is a kind of imitative powder bronzy that shale imitates bronze sculpture powder finished product.
Shale imitates the using method of bronze sculpture powder: making scene, first shale is imitated bronze sculpture powder and adds in the blender operated, slowly spray into spray water, input after stirring in vacuum-extruder, extruding a kind of sculpture clay for making imitative bronze sculpture, the soft plasticity in imitative bronze sculpture shale ground is good.
Use shale to imitate bronze sculpture powder and make imitative bronze sculpture, after maintenance hardening, it it is the pure carving handicraft product imitative bronzy of a kind of color, have that fineness is good, bright, intensity high, shrinkage factor is little, rub resistance and corrosion resistant feature, can be placed on the places such as open air, square, park or indoor for a long time, beautify the environment, appreciate for traveller, adapt to weather exposure and expose to wind and rain indeformable.
Imitative carving handicraft product bronzy is placed on indoor, not only there is higher artistic appreciation and classical collection is worth, moreover it is possible to the air in absorption and clean room.
Shale is imitated bronze sculpture powder and is applicable to make various imitative bronze sculpture artware.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
1, shale is imitated the dispensing of bronze sculpture powder and is made up of following component by weight percentage: shale imitates the zeolite granular 16% after bronze sculpture powder semi-finished product 40%, white cement 34%, acidifying, rock wool 5%, bronze pearl essence 3% and glitter powder 2%.
2, shale is imitated the dispensing of bronze sculpture powder semi-finished product and is made up of following component by weight percentage: attapulgite clay 34%, white carbon 6%, bronze powder 6%, iron oxide yellow 3% and the lemon yellow 1% after shale 50%, weathering.
3, shale imitates the production method of bronze sculpture powder: (1) shale imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder semi-finished product, and inputting pulverizing in grinding machine after stirring is that shale imitates bronze sculpture powder semi-finished product, granularity≤0.044 millimeter；(2) shale is imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder, is packaged as shale after stirring and imitates bronze sculpture powder.
Claims (4)
1. a shale imitates bronze sculpture powder, it is characterized in that, shale is imitated the dispensing of bronze sculpture powder and is made up of following component by weight percentage: shale imitates the zeolite granular after bronze sculpture powder semi-finished product 25～60%, white cement 20～45%, acidifying 5～25%, rock wool 1～10%, bronze pearl essence 0.5～5% and glitter powder 0.5～5%；
Described shale is imitated the dispensing of bronze sculpture powder semi-finished product and is made up of following component by weight percentage: shale 30～60%, attapulgite clay after weathering 10～40%, white carbon 1～20%, bronze powder 1～20%, iron oxide yellow 1～10% and lemon yellow 0.5～5%；
The production method of the zeolite granular after described acidifying: the most first carrying out zeolite pulverizing and screening for the first time, the Task-size Controlling of the zeolite granular after screening is at 0.149～0.42 millimeter；2. by the zeolite granular input revolution roasting in kilns after screening, sintering temperature controls at 420～480 DEG C, and roasting time controlled at 60～120 minutes；3. being inputted in dilute sulfuric acid pond by the zeolite granular after roasting and carry out acidification, the preparation of dilute sulfuric acid includes following component by weight percentage: the sulphuric acid 6～10% of concentration 98, water 90～94%, and the acidification time controlled at 4～12 hours；4. the zeolite granular after acidified process is taken out and drain away the water, zeolite granular semi-finished product after drying as acidifying in input rotary dryer, drying temperature and control at 150～250 DEG C, drying time controls at 30～60 minutes, and the zeolite granular semi-finished product water content after acidifying is less than 2.0%；5. carrying out after second time is sieved being the zeolite granular after being acidified by the zeolite granular semi-finished product after acidifying, the Task-size Controlling of the zeolite granular after acidifying is at 0.125～0.42 millimeter.
Shale the most according to claim 1 imitates bronze sculpture powder, it is characterized in that, shale imitates the production method of bronze sculpture powder: (1) shale imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder semi-finished product, inputting pulverizing in grinding machine after stirring is that shale imitates bronze sculpture powder semi-finished product, granularity≤0.044 millimeter；(2) shale is imitated the dispensing input stirrer for mixing stirring of bronze sculpture powder, is packaged as shale after stirring and imitates bronze sculpture powder.
Shale the most according to claim 1 imitates bronze sculpture powder, it is characterized in that, attapulgite clay after weathering is by attapulgite clay raw ore time weathering more than two winters, attapulgite clay after the weathering that raw ore disintegrate is fine particle of large block compact, pick and be evident that barren rock block, Plant fiber and other earth impurity, granularity≤5 millimeter of the attapulgite clay after weathering.
Shale the most according to claim 1 imitates bronze sculpture powder, it is characterised in that granularity≤2 millimeter of shale, the length 5 of rock wool fibers～8 millimeters, granularity≤0.044 millimeter of bronze pearl essence, granularity≤0.044 millimeter of glitter powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610276543.5A CN105948622A (en) | 2016-04-29 | 2016-04-29 | Shale bronze-imitating sculpture powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610276543.5A CN105948622A (en) | 2016-04-29 | 2016-04-29 | Shale bronze-imitating sculpture powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105948622A true CN105948622A (en) | 2016-09-21 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610276543.5A Withdrawn CN105948622A (en) | 2016-04-29 | 2016-04-29 | Shale bronze-imitating sculpture powder |
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| Country | Link |
|---|---|
| CN (1) | CN105948622A (en) |
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2016
- 2016-04-29 CN CN201610276543.5A patent/CN105948622A/en not_active Withdrawn
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Application publication date: 20160921 |