CN105948570B - A kind of energy conservation and environmental protection thermal insulation material and preparation method thereof - Google Patents

A kind of energy conservation and environmental protection thermal insulation material and preparation method thereof Download PDF

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Publication number
CN105948570B
CN105948570B CN201610260500.8A CN201610260500A CN105948570B CN 105948570 B CN105948570 B CN 105948570B CN 201610260500 A CN201610260500 A CN 201610260500A CN 105948570 B CN105948570 B CN 105948570B
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parts
thermal insulation
insulation material
magnesium silicate
environmental protection
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CN105948570A (en
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姚春龙
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Hunan Guangfu Technology Co.,Ltd.
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Suzhou Neng Hua Energy-Conserving And Environment-Protective Science And Technology Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/28Polysaccharides or derivatives thereof
    • C04B26/285Cellulose or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Building Environments (AREA)
  • Thermal Insulation (AREA)

Abstract

The invention discloses a kind of energy conservation and environmental protection thermal insulation material, including following component:Polystyrene foam particles;Hydroxypropyl methyl cellulose;Polypropylene fibre;Hollow glass micropearl;Hydrophobicity aluminium-magnesium silicate;Zinc stearate;Maleic acrylic copolymer;Acrylamide acrylic acid salt crosslinking copolymerization thing;Dispersed latex powder;Perforate expanded perlite;Deionized water.The present invention provides a kind of with insulation, heat-insulated, sound insulation, self-cleaning, anti-ray, waterproof, energy conservation and environmental protection and the high thermal insulation material of effect of intensity and preparation method thereof.

Description

A kind of energy conservation and environmental protection thermal insulation material and preparation method thereof
Technical field
The present invention relates to Material Field, and specifically, the present invention relates to a kind of energy conservation and environmental protection thermal insulation material and its preparation side Method.
Background technology
Thermal insulation material is the necessity in the fields such as thermoelectricity, chemical fibre, petrochemical industry.The existing thermal insulation material of existing market is very much, generally Inorganic heat insulation material be monolithic entity, as perlite, calcium silicates etc., although thermal insulation, hardness are good, intensity is poor, Er Qiebao Warm layer gap is more, joining seam is more.As traditional thermal insulation material of rock wool, mineral wool, alumina silicate fibre or the like, then since it keeps the temperature Body space is not closed, and heat loss through convection causes heat insulation effect not live, but also shorter, easy to aging, brittle there is service life Split, is of high cost and do not reach many defects such as energy saving.
The Chinese patent of publication number CN103043984B, discloses a kind of energy-saving and heat-insulating material, and the patent is mainly with brick The building waste of block and ceramic tile is base-material, rationally using resource, but by brick and ceramic tile ball grinds heavy workload, and Applied after invention shaping, the work efficiency of installation personnel is low;The Chinese patent of publication number CN104556843A, A kind of fire-retardant heat-insulation material is disclosed, which is with white floating bead, ostreae testa pulverata, centrifugal glass fibre, ceramic wool, Peng Run Soil, polyacrylamide, bleeding agent, rare earth addition, pearl flyash, rock wool are prepared for raw material, and wherein rock wool has The shortcomings that strong thermal conductivity factor of water imbibition is high, is easy to cause the hydraulic performance decline of the thermal insulation material.Insulation disclosed in this two patents Material does not have sound insulation and the effect of radioactive ray, its performance is easily reduced under the long-term irradiation of the sun.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of thermal insulation material, reached insulation, heat-insulated, sound insulation, it is self-cleaning, Anti- ray, waterproof, energy conservation and environmental protection and the high effect of intensity.
The technical solution adopted by the present invention is:A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:
Polystyrene foam particles:10~35 parts;Hydroxypropyl methyl cellulose:5~20 parts;
Polypropylene fibre:3~8 parts;Hollow glass micropearl:1~5 part;
Hydrophobicity aluminium-magnesium silicate:2~5 parts;Zinc stearate:1~5 part;
Maleic acid-acrylic acid copolymer:3~8 parts;
Acrylamide and acrylic acid salt crosslinking copolymerization thing:1~5 part;Dispersed latex powder:1~3 part;
Perforate expanded perlite:3~8 parts;Deionized water:8~20 parts.
Preferably, the hydrophobicity aluminium-magnesium silicate is the hydrophobicity aluminium-magnesium silicate that cationic surfactant is modified, and Hydrophobicity aluminium-magnesium silicate is the powdery that mesh number is 200~400.
Preferably, the dispersed latex powder is cold soluble pva powder, vinylacetate and ethylene copolymer rubber powder At least one of.
Preferably, the EPS particles are polystyrene foam particles, its particle diameter is 2~5mm, and density is 10~15kg/ m3
Preferably, the consumption proportion of the zinc stearate and acrylamide and acrylic acid salt crosslinking copolymerization thing is 1:1.
It is a further object to provide a kind of preparation method of energy conservation and environmental protection thermal insulation material, include the following steps:
Step 1):Powder stirrer is opened, perforate expanded perlite, hydroxypropyl are sequentially added according to corresponding parts by weight Methylcellulose, polyacrylic fibre, hollow glass micropearl and hydrophobicity aluminium-magnesium silicate, stir 30-60min, up to component 1;
Step 2):Ionized water is removed, the copolymerization of acrylamide and acrylic acid salt is sequentially added under the stirring of 300-400rpm and is handed over Join thing, maleic acid-acrylic acid copolymer, zinc stearate, then under 300-400rpm after stirring 5-10min, in 800-1000rpm Lower stirring 20-30min;The dispersed latex powder of corresponding parts by weight is sequentially added, 30-60min is stirred under 800-1000rpm; Corrresponding quality number polystyrene foam particles are added under 300-400rpm stirrings, continue to stir 5-10min, up to component 2;
Step 3):Component 1 is added in component 2 under continuous stirring, and stirs into paste, is got product.
The present invention includes at least following beneficial effect:
1st, inventive formulation is reasonable, and a variety of thermal insulation materials such as hollow glass micropearl, polystyrene foam particles are added to In the present invention, hydrophobicity aluminium-magnesium silicate is added, density is low, and intensity is high;Add acrylamide and acrylic acid salt crosslinking copolymerization thing, tool There are good crack resistance and resistance to elevated temperatures, the cracking resistance fire protection flame retarding of product can be strengthened, present invention burning rank is high, protects Temp effect is high, construction is simple, and when use, which is watered to stir evenly, can be used;
2nd, the present invention is by rationally screening the granularity of polystyrene foam particles and than part, substantially increasing the guarantor of compound material Warm nature energy;The high molecular polymer rubber powder caking ability of selection is high, and dosage 30% is saved than general rubber powder.
Embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby Art means solve technical problem, and reach technique effect realizes that process can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art Section, used raw material is also available commercial.The various processes and method not being described in detail are as known in the art Conventional method.
Embodiment 1
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:10 parts of polystyrene foam particles;Hydroxypropyl 5 parts of methylcellulose;3 parts of polypropylene fibre;1 part of hollow glass micropearl;2 parts of hydrophobicity aluminium-magnesium silicate;1 part of zinc stearate;Horse Carry out sour -3 parts of acrylic copolymer;1 part of acrylamide and acrylic acid salt crosslinking copolymerization thing;1 part of dispersed latex powder;Perforate expansion is precious 3 parts of pearl rock;8 parts of deionized water.
Embodiment 2
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:25 parts of polystyrene foam particles;Hydroxypropyl 15 parts of methylcellulose;5 parts of polypropylene fibre;3 parts of hollow glass micropearl;3 parts of hydrophobicity aluminium-magnesium silicate;2 parts of zinc stearate;Horse Carry out sour -5 parts of acrylic copolymer;2 parts of acrylamide and acrylic acid salt crosslinking copolymerization thing;2 parts of dispersed latex powder;Perforate expansion is precious 5 parts of pearl rock;15 parts of deionized water.
Embodiment 3
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:35 parts of polystyrene foam particles;Hydroxypropyl 20 parts of methylcellulose;8 parts of polypropylene fibre;5 parts of hollow glass micropearl;5 parts of hydrophobicity aluminium-magnesium silicate;5 parts of zinc stearate;Horse Carry out sour -8 parts of acrylic copolymer;5 parts of acrylamide and acrylic acid salt crosslinking copolymerization thing;3 parts of dispersed latex powder;Perforate expansion is precious 8 parts of pearl rock;20 parts of deionized water.
Comparative example 1
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:10 parts of polystyrene foam particles;Hydroxypropyl 5 parts of methylcellulose;3 parts of polypropylene fibre;1 part of hollow glass micropearl;2 parts of hydrophobicity aluminium-magnesium silicate;1 part of zinc stearate;Horse Carry out sour -3 parts of acrylic copolymer;6 parts of acrylamide and acrylic acid salt crosslinking copolymerization thing;1 part of dispersed latex powder;Perforate expansion is precious 3 parts of pearl rock;8 parts of deionized water.
Comparative example 2
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:10 parts of polystyrene foam particles;Hydroxypropyl 5 parts of methylcellulose;3 parts of polypropylene fibre;1 part of hollow glass micropearl;Hydrophobicity aluminium-magnesium silicate is (without cation surface activating Agent is modified) 2 parts;1 part of zinc stearate;3 parts of maleic acid-acrylic acid copolymer;1 part of acrylamide and acrylic acid salt crosslinking copolymerization thing; 1 part of dispersed latex powder;3 parts of perforate expanded perlite;8 parts of deionized water.
Comparative example 3
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:10 parts of polystyrene foam particles;Hydroxypropyl 5 parts of methylcellulose;3 parts of polypropylene fibre;1 part of hollow glass micropearl;Hydrophobicity aluminium-magnesium silicate is (through anion surfactant It is modified) 2 parts;1 part of zinc stearate;3 parts of maleic acid-acrylic acid copolymer;1 part of acrylamide and acrylic acid salt crosslinking copolymerization thing;Point Dissipate 1 part of latex powder;3 parts of perforate expanded perlite;8 parts of deionized water.
Comparative example 4
A kind of energy conservation and environmental protection thermal insulation material, includes the component of following parts by weight:5 parts of polystyrene foam particles;Hydroxypropyl 2 parts of methylcellulose;1 part of polypropylene fibre;1 part of hollow glass micropearl;2 parts of hydrophobicity aluminium-magnesium silicate;1 part of zinc stearate;Horse Carry out sour -3 parts of acrylic copolymer;1 part of acrylamide and acrylic acid salt crosslinking copolymerization thing;1 part of dispersed latex powder;Perforate expansion is precious 3 parts of pearl rock;8 parts of deionized water.
The preparation method of energy conservation and environmental protection thermal insulation material is in embodiment and comparative example:
Step 1):Powder stirrer is opened, perforate expanded perlite, hydroxypropyl are sequentially added according to corresponding parts by weight Methylcellulose, polyacrylic fibre, hollow glass micropearl and hydrophobicity aluminium-magnesium silicate, stir 30min, up to component 1;
Step 2):Ionized water is removed, acrylamide and acrylic acid salt crosslinking copolymerization is sequentially added under the stirring of 300rpm Thing, maleic acid-acrylic acid copolymer, zinc stearate, then 20min is stirred at 800 rpm after stirring 5min at 300 rpm;According to The secondary dispersed latex powder for adding corresponding parts by weight, stirs 30min at 800 rpm;Corrresponding quality is added under 300rpm stirrings Number polystyrene foam particles, continue to stir 5min, up to component 2;
Step 3):Component 1 is added in component 2 under continuous stirring, and stirs into paste, is got product.
Embodiment 1~3 and the obtained thermal insulation material of comparative example 1~4 are tested for the property, test result is shown in Table 1.
The performance test results of 1 embodiment 1~3 of table and comparative example 1~4
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art Realize other modification, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited In details described herein.

Claims (1)

1. a kind of energy conservation and environmental protection thermal insulation material, it is characterised in that include the component of following parts by weight:
Polystyrene foam particles:10~35 parts;Hydroxypropyl methyl cellulose:5~20 parts;
Polypropylene fibre:3~8 parts;Hollow glass micropearl:1~5 part;
Hydrophobicity aluminium-magnesium silicate:2~5 parts;Zinc stearate:1~5 part;
Maleic acid-acrylic acid copolymer:3~8 parts;
Acrylamide and acrylic acid salt crosslinking copolymerization thing:1~5 part;Dispersed latex powder:1~3 part;
Perforate expanded perlite:3~8 parts;Deionized water:8~20 parts;
The hydrophobicity aluminium-magnesium silicate that the hydrophobicity aluminium-magnesium silicate is modified for cationic surfactant, and hydrophobicity aluminium-magnesium silicate The powdery for being 200~400 for mesh number;
The dispersed latex powder is at least one of cold soluble pva powder, vinylacetate and ethylene copolymer rubber powder;
The polystyrene foam particles, its particle diameter are 2~5mm, and density is 10~15kg/m3;The zinc stearate and acryloyl The consumption proportion of amine-acrylates crosslinking copolymerization thing is 1:1;
The energy conservation and environmental protection thermal insulation material is prepared by following preparation methods:
Step 1):Powder stirrer is opened, perforate expanded perlite, hydroxypropyl methyl are sequentially added according to corresponding parts by weight Cellulose, polyacrylic fibre, hollow glass micropearl and hydrophobicity aluminium-magnesium silicate, stir 30-60min, up to component 1;
Step 2):Ionized water is removed, acrylamide and acrylic acid salt crosslinking copolymerization is sequentially added under the stirring of 300-400rpm Thing, maleic acid-acrylic acid copolymer, zinc stearate, then under 300-400rpm after stirring 5-10min, under 800-1000rpm Stir 20-30min;The dispersed latex powder of corresponding parts by weight is sequentially added, 30-60min is stirred under 800-1000rpm; 300-400rpm stirrings are lower to add corrresponding quality number polystyrene foam particles, continues to stir 5-10min, up to component 2;
Step 3):Component 1 is added in component 2 under continuous stirring, and stirs into paste, is got product.
CN201610260500.8A 2016-04-25 2016-04-25 A kind of energy conservation and environmental protection thermal insulation material and preparation method thereof Active CN105948570B (en)

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CN106866055A (en) * 2017-03-24 2017-06-20 河北圣达节能建材有限公司 A kind of composite heat insulatant thermal insulation material
CN107140936A (en) * 2017-06-04 2017-09-08 杜耀均 A kind of preparation method of the hollow glass microballoon base insulation material of suitable industrialized mass production
CN107540769A (en) * 2017-09-17 2018-01-05 葛彬斌 A kind of polymer overmold type building thermal insulation material and preparation method thereof
CN109161280B (en) * 2018-06-28 2021-02-02 浙江金华市顺泰水电建设有限公司 Heat-resistant energy-saving heat-insulating building coating and preparation method thereof
CN110628277B (en) * 2019-09-09 2021-05-11 青岛科技大学 Heat insulation functional material for fire scene and preparation method thereof
CN111635649A (en) * 2020-05-25 2020-09-08 广东合胜实业股份有限公司 Waterproof heat-insulation material and preparation method thereof

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DE102010029513A1 (en) * 2010-05-31 2011-02-24 Wacker Chemie Ag Insulation with layer structure
CN104058681B (en) * 2014-05-28 2016-03-02 安徽阜阳富龙建筑材料有限责任公司 Anti-cracking heat insulation mortar
CN104402324A (en) * 2014-10-27 2015-03-11 昆山艾士比高分子科技有限公司 Environment-friendly type interior-wall thermal-insulation material
CN105399380B (en) * 2015-12-09 2017-09-22 重庆兴渝涂料股份有限公司 One pack system efficient light external-wall heat-insulation material and preparation method thereof

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Effective date of registration: 20221230

Address after: Group 23, Weiwu Village, Batang Town, Ningxiang City, Changsha City, Hunan Province 410625

Patentee after: Ningxiang Juxing Superhard Materials Co.,Ltd.

Address before: South side of Yunlong West Road, Wujiang Economic and Technological Development Zone, Wujiang District, Suzhou City, Jiangsu Province, 215200

Patentee before: SUZHOU NENGHUA ENERGY SAVING ENVIRONMENTAL PROTECTION SCIENCE & TECHNOLOGY CO.,LTD.

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Effective date of registration: 20230612

Address after: 410625 Floor 1, Building A, Ningxiang Juxing Superhard material Co., Ltd., Group 24, Weiwu Village, Batang Town, Ningxiang, Changsha City, Hunan Province

Patentee after: Hunan Guangfu Technology Co.,Ltd.

Address before: Group 23, Weiwu Village, Batang Town, Ningxiang City, Changsha City, Hunan Province 410625

Patentee before: Ningxiang Juxing Superhard Materials Co.,Ltd.

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