CN105948337A - Treatment device and process for water for power generation of biomass fuel - Google Patents

Treatment device and process for water for power generation of biomass fuel Download PDF

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Publication number
CN105948337A
CN105948337A CN201610535176.6A CN201610535176A CN105948337A CN 105948337 A CN105948337 A CN 105948337A CN 201610535176 A CN201610535176 A CN 201610535176A CN 105948337 A CN105948337 A CN 105948337A
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China
Prior art keywords
water
reverse osmosis
level
grade
fresh
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Pending
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CN201610535176.6A
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Chinese (zh)
Inventor
邵兵
陈亚
苏永亚
李小红
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EVERBRIGHT BIOFUELS ENERGY (HANSHAN) Co Ltd
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EVERBRIGHT BIOFUELS ENERGY (HANSHAN) Co Ltd
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Priority to CN201610535176.6A priority Critical patent/CN105948337A/en
Publication of CN105948337A publication Critical patent/CN105948337A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4691Capacitive deionisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a treatment device and process for water for power generation of a biomass fuel. The device comprises a water taking device, an ultra-filtration device, an ultra-filtration water tank, a first-grade reverse osmosis water feeding pump, a first-grade security filter, a first-grade reverse osmosis high-pressure pump, a first-grade reverse osmosis device, a first-grade fresh-water tank, a second-grade reverse osmosis high-pressure pump, a second-grade reverse osmosis device, a second-grade fresh-water tank, a second-grade fresh-water pump, an EDI device, a desalting water tank, a desalting water pump and a deoxidization device, wherein the water taking device is arranged on a natural river channel; the water taking device is connected with the ultra-filtration device through a pipeline and then is connected with the ultra-filtration water tank, the first-grade reverse osmosis water feeding pump, the first-grade security filter, the first-grade reverse osmosis high-pressure pump, the first-grade reverse osmosis device, the first-grade fresh-water tank, the second-grade reverse osmosis high-pressure pump, the second-grade reverse osmosis device, the second-grade fresh-water tank, the second-grade fresh-water pump, the EDI device, the desalting water tank, the desalting water pump and the deoxidization device in sequence. With the adoption of the water treatment device and process, the quality of the water for the power generation is improved and the power generation is carried out orderly.

Description

A kind of biomass fuel generating water treatment facilities and technique
Technical field
The invention belongs to industrial water utility technical field, particularly relate to a kind of biomass fuel generating water and process Device, further relates to the process technique of this device a kind of.
Background technology
Along with economic fast development, power consumption is also presenting ascendant trend, and China mainly uses hydroelectric generation, core Generating and coal-fired thermal power generation, hydroelectric generation is restricted by rainwater, and nuclear power generation cost is the highest, and coal fired power generation is more general And, but a series of environmental problem can be caused, it is, thus, sought for one can substitute coal-fired thermal power generation, biomass fuel Generating is operated and is given birth to.At present, biomass fuel generating drives steam turbine to rotate generating by Boiler Steam, fetches in effluent road Containing substantial amounts of impurity particle in natural water, impurity can be divided into by the size of its discrete particles: float, colloid and solute Matter, when the compounds content of aluminum, ferrum and silicon is higher in boiler water, can form incrustation scale, at height in the boiler tube that thermic load is the highest In pressure boiler, silicic acid can be dissolved in steam, takes boiler therewith out of, is finally deposited in steam turbine, causes fault;In addition in boiler water Oxygen content require the harshest, it is therefore desirable to generating water is processed.
Summary of the invention
In order to overcome the defect of prior art, it is an object of the invention to provide a kind of biomass fuel generating water and process Device, improves the quality of generating water, ensures carrying out in order of generating.
In order to realize foregoing invention purpose, the technical solution used in the present invention is as follows:
A kind of biomass fuel generating water treatment facilities of the present invention, is characterized in including water fetching device, ultrafiltration apparatus, ultrafiltration Water tank, first-stage reverse osmosis feed pump, one-level cartridge filter, first-stage reverse osmosis high-pressure pump, first-stage reverse osmosis device, one-level fresh water Case, two-pass reverse osmosis high-pressure pump, second level reverse osmosis apparatus, two grades of fresh-water tanks, two grades of fresh water pumps, EDI device, sweet-water tanks, remove Brine pump and deaerating plant, described water fetching device is placed on natural river course, and water fetching device passes through pipeline ultrafiltration apparatus, then depends on Secondary connection ultrafiltration water tank, first-stage reverse osmosis feed pump, one-level cartridge filter, first-stage reverse osmosis high-pressure pump, first-stage reverse osmosis fill Put, one-level fresh-water tank, two-pass reverse osmosis high-pressure pump, second level reverse osmosis apparatus, two grades of fresh-water tanks, two grades of fresh water pumps, EDI device, Sweet-water tank, desalination water pump, deaerating plant, treated water enters biomass boiler.
The present invention improves further, and described water fetching device includes carrying pumping water pontoon and triangle buoyancy tank, is provided with in cabin Water pump, water inlet is located on floor, and described triangle buoyancy tank is placed in hull head and passes through hawser and spud pile with hull admittedly Fixed, the central axis of triangle buoyancy tank and hull keeps on the same line, and the drift angle of triangle buoyancy tank is towards upland water side To, the scratch resistant cylinder that two anchor chains set respectively on triangle buoyancy tank two waist is anchored in offshore riverbed farther out, current direction two Side shunts, and drives pasture and water, branch and rubbish to take advantage of a situation to both sides with water and flows away, reduces rubbish and pasture and water that pontoon fore is piled up.
The present invention improves further, and the first-stage reverse osmosis film of described first-stage reverse osmosis device selects pollution-resistant membrane element, can Think that one-level RO uses U.S.'s imported with original packaging Tao Shi antipollution BW30-400FR type film core;Two grades of described second level reverse osmosis apparatus Reverse osmosis membrane selects imported with original packaging ultralow pressure membrane component, can be that two grades of RO use U.S.'s imported with original packaging Tao Shi BW30-400 type film Core.
The present invention improves further, and the reverse osmosis membrane assembly of described first-stage reverse osmosis device and second level reverse osmosis apparatus is all pressed One-level two segmented mode arranges.
The present invention improves further, also includes that reverse osmosis chemically-cleaning device, reverse osmosis chemically-cleaning device connect respectively Ultrafiltration apparatus, first-stage reverse osmosis device and second level reverse osmosis apparatus, be used in conjunction with for ultrafiltration apparatus and reverse osmosis unit, the most clearly Except the attachment in three kinds of devices.
The present invention improves further, and described EDI device uses U.S.'s GE company imported with original packaging EDI or uses Siemens original-pack Import EDI product, model is Ionpure LX-Z industrial continuous electrodeionization CEDI membrane stack type EDI device, EDI system The water quality of design system to be guaranteed and water yield requirement.
Present invention also offers a kind of biomass fuel generating water treatment technology, by said apparatus, first carry out river Fetching water in road, staticly settles river the most successively, single filter, cascade filtration, desalination and deoxygenation, obtains generating water.
Compared with prior art, the invention have the advantages that
1), assembly of the invention structure cohesion compact, take up an area space little, saved land resource;
2), assembly of the invention river can be carried out fine process, obtain the generating water of high request, improve generating water Quality, ensure generating carry out in order.
Accompanying drawing explanation
The present invention will be described below in conjunction with the accompanying drawings.
Fig. 1 is the structural representation of biomass fuel generating water treatment facilities of the present invention;
Fig. 2 is the structural representation of the water fetching device of biomass fuel generating water treatment facilities of the present invention.
Detailed description of the invention
Firstly, it is necessary to explanation, biomass fuel generating water of the present invention below will be illustrated by way of example The concrete structure of processing means, feature and advantage etc., but what all of description was intended merely to illustrate, and should not be managed Solve as the present invention being formed any restriction.Additionally, be described by mentioned each embodiment herein or implicit the most single Technical characteristic, or shown or implicit any single technical characteristic in the drawings, still can these technical characteristics (or Its equivalent) between proceed combination in any or delete, thus obtain and be likely not to have the present invention the most directly mentioned Other embodiments more.It addition, for the sake of simplifying drawing, same or like parts and feature are in the same figure May be only at one or some places indicate.
Incorporated by reference to reference to Fig. 1 and Fig. 2, below just come biomass fuel generating water of the present invention by the embodiment be given Processing means is illustrative.
Biomass fuel generating water handling principle illustrates: containing substantial amounts of float, dissolved and colloidal substances in river, Wherein float is the particle of particle diameter 10 more than 4mm, and they are unstable in water, can remove under the effect of gravity or buoyancy, It is often sand, clay compounds and the product of animal-plant kind;The particle diameter of colloid, at 10 6~10 4mm, is often water-fast point Son is formed, and colloidal particle specific surface is big, activity is big and with negative charge, they are often ferrum, aluminum, the inorganic compound of silicon and have Machine colloid, colloid can use coagulation, clarification to remove with filtering technique;Dissolve material refer to particle diameter be less than the ion of 10 6mm and some Dissolved gas, uses ion exchange, electrodialysis, the technique of reverse osmosis to remove it, the dissolving such as carbon dioxide in water, oxygen Gas is also the impurity that water treatment technology need to remove.
As seen from Figure 1, a kind of biomass fuel generating water treatment facilities, it is characterized in including water fetching device 1, surpassing Filter device 2, ultrafiltration water tank 3, first-stage reverse osmosis feed pump 4, one-level cartridge filter 5, first-stage reverse osmosis high-pressure pump 6, one-level are anti- Permeability apparatus 7, one-level fresh-water tank 8, two-pass reverse osmosis high-pressure pump 9,10, two grades of fresh-water tanks of second level reverse osmosis apparatus 11, two grades are light Water pump 12, EDI device 13, sweet-water tank 14, desalination water pump 15 and deaerating plant 16, described water fetching device is placed in natural river course On, water fetching device passes through pipeline ultrafiltration apparatus, is then sequentially connected with ultrafiltration water tank, first-stage reverse osmosis feed pump, one-level were ensured public security Filter, first-stage reverse osmosis high-pressure pump, first-stage reverse osmosis device, one-level fresh-water tank, two-pass reverse osmosis high-pressure pump, two-pass reverse osmosis fill Put, two grades of fresh-water tanks, two grades of fresh water pumps, EDI device, sweet-water tank, desalination water pump, deaerating plants, treated water enter Biomass boiler.
In the present embodiment, as in figure 2 it is shown, described water fetching device 1 includes carrying pumping water pontoon 11 and triangle buoyancy tank 12, Being provided with water pump in cabin, water inlet is located on floor, and described triangle buoyancy tank is placed in hull head and by hawser with fixing Stake is fixed with hull, the holding of the central axis of triangle buoyancy tank and hull on the same line, the drift angle of triangle buoyancy tank towards Upland water direction, the scratch resistant cylinder that two anchor chains set respectively on triangle buoyancy tank two waist is anchored at offshore riverbed farther out In, current direction both sides shunt, and drive pasture and water, branch and rubbish to take advantage of a situation to both sides with water and flow away, reduce the rubbish that pontoon fore is piled up Rubbish and pasture and water.
In the present embodiment, the first-stage reverse osmosis film of described first-stage reverse osmosis device 7 selects pollution-resistant membrane element, Ke Yiwei One-level RO uses U.S.'s imported with original packaging Tao Shi antipollution BW30-400FR type film core;Two grades of described second level reverse osmosis apparatus 10 are anti- Permeable membrane selects imported with original packaging ultralow pressure membrane component, can be that two grades of RO use U.S.'s imported with original packaging Tao Shi BW30-400 type film Core.
In the present embodiment, the reverse osmosis membrane assembly of described first-stage reverse osmosis device 7 and second level reverse osmosis apparatus 10 is all pressed One-level two segmented mode arranges.
In the present embodiment, also include that reverse osmosis chemically-cleaning device 17, reverse osmosis chemically-cleaning device connect super respectively Filter device 2, first-stage reverse osmosis device 7 and second level reverse osmosis apparatus 10, be used in conjunction with for ultrafiltration apparatus and reverse osmosis unit, effectively Remove the attachment in three kinds of devices.
In the present embodiment, described EDI device 13 use U.S.'s GE company imported with original packaging EDI or use Siemens original-pack enter Mouth EDI product, model is Ionpure LX-Z industrial continuous electrodeionization CEDI membrane stack type EDI device, setting of EDI system The water quality of meter system to be guaranteed and water yield requirement.
Present invention also offers a kind of biomass fuel generating water treatment technology, by said apparatus, first carry out river Fetching water in road, staticly settles river the most successively, single filter, cascade filtration, desalination and deoxygenation, obtains generating water.
After assembly of the invention uses, the relevant parameter after corresponding water processes is as follows:
1.2.1 the response rate of ultrafiltration apparatus and product water water quality
The response rate: >=90%
Product water water quality: SDI≤3
1.2.2 one-level RO produces water water quality and the response rate of water
In system salt rejection rate: >=98%(3 years)
Produce water water quality: TDS < 10mg/L(in 3 years)
SiO2< in 1 mg/L(3 years)
System recycle-water rate: >=75%
1.2.3 two grades of RO produce water water quality and the response rate of water
In system salt rejection rate: >=98%(3 years)
Produce water water quality: TDS < 3mg/L(in 3 years)
SiO2< in 0.1mg/L(3 years)
System recycle-water rate: >=90%
1.2.4 EDI produces water water quality and the response rate of water
Produce water water quality: in electrical conductivity (25 DEG C)≤0.10us/cm(5)
SiO2In≤10ug/L(5)
In hardness ≈ 0ummol/L(5), in sodium ion≤5ug/L(5), in Cu ion≤3ug/L(5), chlorine≤5 μ g/L In (in 5 years), Fe ion≤10ug/L(5), system recycle-water rate >=90%.
Below the biomass fuel generating water treatment facilities of the present invention, these a few examples are elaborated the most by way of example It is intended for illustrating that the principle of the present invention and embodiment thereof are used, rather than limitation of the present invention, in the spirit without departing from the present invention In the case of scope, those skilled in the art can also make various deformation and improvement.Therefore, the technical scheme of all equivalents Scope of the invention all should be belonged to and the every claim by the present invention is limited.

Claims (7)

1. a biomass fuel generating water treatment facilities, it is characterised in that include water fetching device (1), ultrafiltration apparatus (2), Ultrafiltration water tank (3), first-stage reverse osmosis feed pump (4), one-level cartridge filter (5), first-stage reverse osmosis high-pressure pump (6), one-level are anti- Permeability apparatus (7), one-level fresh-water tank (8), two-pass reverse osmosis high-pressure pump (9), second level reverse osmosis apparatus (10), two grades of fresh-water tanks (11), two grades of fresh water pumps (12), EDI device (13), sweet-water tank (14), desalination water pump (15) and deaerating plant (16), described Water fetching device be placed on natural river course, water fetching device passes through pipeline ultrafiltration apparatus, is then sequentially connected with ultrafiltration water tank, one-level anti- Infiltration feed pump, one-level cartridge filter, first-stage reverse osmosis high-pressure pump, first-stage reverse osmosis device, one-level fresh-water tank, two grades of reverse osmosis High-pressure pump, second level reverse osmosis apparatus, two grades of fresh-water tanks, two grades of fresh water pumps, EDI device, sweet-water tank, desalination water pump, deoxygenations thoroughly Device, treated water enters biomass boiler.
Biomass fuel generating water treatment facilities the most according to claim 1, it is characterised in that described water fetching device (1) including carrying pumping water pontoon (11) and triangle buoyancy tank (12), be provided with water pump in cabin, water inlet is located on floor, institute State triangle buoyancy tank be placed in hull head and fixed with hull by hawser and spud pile, triangle buoyancy tank and the central shaft of hull Line keeps on the same line, and the drift angle of triangle buoyancy tank is towards upland water direction, and two anchor chains are respectively through triangle buoyancy tank The scratch resistant cylinder set on two waists is anchored in offshore riverbed farther out.
Biomass fuel generating water treatment facilities the most according to claim 1 and 2, it is characterised in that described one-level is anti- The first-stage reverse osmosis film of permeability apparatus (7) selects pollution-resistant membrane element, uses U.S.'s imported with original packaging Tao Shi antipollution for one-level RO BW30-400FR type film core;The two-pass reverse osmosis film of described second level reverse osmosis apparatus (10) selects imported with original packaging ultralow pressure membrane element Part, is that two grades of RO use U.S.'s imported with original packaging Tao Shi BW30-400 type film core.
Biomass fuel generating water treatment facilities the most according to claim 1 and 2, it is characterised in that described one-level is anti- The reverse osmosis membrane assembly of permeability apparatus (7) and second level reverse osmosis apparatus (10) is all arranged by one-level two segmented mode.
Biomass fuel generating water treatment facilities the most according to claim 1 and 2, it is characterised in that also include reverse osmosis Thoroughly chemically-cleaning device (17), reverse osmosis chemically-cleaning device connect respectively ultrafiltration apparatus (2), first-stage reverse osmosis device (7) and Second level reverse osmosis apparatus (10), is used in conjunction with for ultrafiltration apparatus and reverse osmosis unit.
Biomass fuel generating water treatment facilities the most according to claim 1 and 2, it is characterised in that described EDI device (13) using U.S.'s GE company imported with original packaging EDI or use Siemens's imported with original packaging EDI product, model is Ionpure LX-Z Industrial continuous electrodeionization CEDI membrane stack type EDI device.
7. a biomass fuel generating water treatment technology, by the biomass fuel described in any one of the claims 1 to 6 Material generating water treatment facilities, first carry out river course water intaking, the most successively river is staticly settled, single filter, two grades Filtration, desalination and deoxygenation, obtain generating water.
CN201610535176.6A 2016-07-08 2016-07-08 Treatment device and process for water for power generation of biomass fuel Pending CN105948337A (en)

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Cited By (7)

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JP2019098229A (en) * 2017-11-30 2019-06-24 オルガノ株式会社 Reverse osmosis treatment method, reverse osmosis treatment system, sodium removal device, and sodium removal method
WO2022143272A1 (en) * 2020-12-29 2022-07-07 中海油天津化工研究设计院有限公司 Seawater desalination process system for supplying boiler supplemental water for thermal recovery of heavy oil in offshore oil fields
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
CN115947415A (en) * 2023-01-17 2023-04-11 西安热工研究院有限公司 Automatic start-stop control system and method for two-stage reverse osmosis and EDI device
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump
US12040517B2 (en) 2022-11-15 2024-07-16 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof

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