CN105948334A - Plug flow type heavy metal wastewater treatment method and complete equipment thereof - Google Patents

Plug flow type heavy metal wastewater treatment method and complete equipment thereof Download PDF

Info

Publication number
CN105948334A
CN105948334A CN201610562268.3A CN201610562268A CN105948334A CN 105948334 A CN105948334 A CN 105948334A CN 201610562268 A CN201610562268 A CN 201610562268A CN 105948334 A CN105948334 A CN 105948334A
Authority
CN
China
Prior art keywords
flow type
stage
waste water
type process
metal waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610562268.3A
Other languages
Chinese (zh)
Inventor
刘羽翼
姚理为
阳韬
蔡鹏�
熊瑛
李思怡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNAN XINLIHENG ENVIRONMENT TECHNOLOGY Co Ltd
Original Assignee
HUNAN XINLIHENG ENVIRONMENT TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUNAN XINLIHENG ENVIRONMENT TECHNOLOGY Co Ltd filed Critical HUNAN XINLIHENG ENVIRONMENT TECHNOLOGY Co Ltd
Priority to CN201610562268.3A priority Critical patent/CN105948334A/en
Publication of CN105948334A publication Critical patent/CN105948334A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

The invention discloses a plug flow type heavy metal wastewater treatment method and complete equipment thereof. A water inlet valve (2) is arranged at one end of a box (1), a water outlet valve (7) is arranged at the other end of the box (1), a plurality of sets of partition plates (11) are arranged in the box (1) and partition the interior of the box (1) into a plurality of reaction intervals (12) connected in series, adjustment agent addition holes (3), a pH instrument probe (8) and a sludge discharge/emergency valve (4) are arranged in each reaction interval (12), and a flow meter (5) is arranged at each adjustment agent addition hole (3). According to the plug flow type heavy metal wastewater treatment method and the complete equipment thereof, the PH is adjusted stage by stage, a reaction is performed stage by stage, the influence of precipitate on an agent is avoided, and the cost is lowered while the effect is achieved; the process is simple, the treatment effect is good, operation and management are convenient, and the treatment cost is low.

Description

Pulling flow type process for treating heavy-metal waste water and complete set of equipments thereof
Technical field
The present invention relates to a kind of method of wastewater treatment, particularly relate to a kind of pulling flow type heavy metal Method of wastewater treatment.The one-tenth that the invention still further relates to realize the waste water process containing various heavy is sheathed Standby.
Background technology
Science and technology is a double-edged sword, and since 20th century, science and technology fast development, promotes economy Development, improve the living standard of the people, but, meanwhile, the mankind have also paid disastrously The cost of weight.Heavy metal wastewater thereby drenches immersion, ore dressing plant tail essentially from mine drainage, waste-rock yard Ore deposit draining, non-ferrous metals smelting works' dedusting draining, Non-ferrous Metals Processing Factory's acid washing water, Electroplate Factory Plating piece washings, steel plant's pickling draining, and electrolysis, pesticide, medicine, paint, pigment Deng the waste water of industry, the kind of heavy metal ions in wastewater, content and existing forms thereof are with difference Produce kind and different, widely different.
Heavy metal pickling waste water affects Fish and aquatic organism growth, hinders fish production.Heavy metal Waste water enters soil, and plant heavy metal of body progressively accumulates, and causes plant root suppressed, blade Move back green jaundice.Growth and development of plants can be caused to be obstructed even dead, cause agricultural, the forestry underproduction.
Process for treating heavy-metal waste water mainly have electrolysis, bioanalysis, membrane separation process, absorption method, Ion exchange, chemical precipitation method etc..The present invention is similar to chemical precipitation method.
Traditional chemical precipitation method includes neutralization precipitation method, sulphide precipitation and the barium salt sedimentation method Neutralization precipitation method Application comparison is extensive at present.Neutralization precipitation method is to alkalescence by wastewater pH regulation, Metal ion in waste water reacts with precipitant, is converted into insoluble solid precipitation, common metal It is precipitated out from solution with the form of hydroxide.Conventional precipitant has Calx, hydroxide Sodium etc..The existing sedimentation method add alkali and disposably adjust pH, are unfavorable for the heavy metal wastewater thereby of complicated component Process, also can cause the waste of alkali.Heavy metal ion and OH-Whether ion generates the hydrogen of indissoluble Oxide precipitation, depends on concentration and the OH of heavy metal ion in solution-Concentration.
PH is disposably adjusted in place, then by traditional sewage chemical processing method typically exactly Dosing, carries out reaction precipitation, reaches wastewater treatment efficiency.Traditional chemical precipitation method is not examined Considering Optimal pH and the response time removing all kinds of pollution factors, treatment effect is undesirable.
Summary of the invention
First technical problem to be solved by this invention is to provide that a kind of flow process is simple, processes Pulling flow type process for treating heavy-metal waste water effective, that operation management is convenient, processing cost is cheap.
Second technical problem to be solved by this invention is to provide one and realizes this pulling flow type weight The complete set of equipments of metallic wastewater processing method.
In order to solve above-mentioned first technical problem, the pulling flow type heavy metal that the present invention provides is given up Method for treating water, adjusts pH, the most stage by stage dosing stage by stage, carries out reaction precipitation stage by stage, Reach wastewater treatment efficiency.
In order to solve above-mentioned second technical problem, what the present invention provided realizes a pulling flow type huge sum of money Belonging to the complete set of equipments of method of wastewater treatment, one end of casing is provided with inlet valve, and the other end is provided with Flowing water Valve, is provided with in described casing and organizes dividing plate more, and the dividing plate described in many groups is by described It is partitioned into the reaction interval of multiple series connection in casing, in each described reaction interval, is provided with regulation Medicine feeding hole, pH instrument probe and spoil disposal/emergency valve, each described regulation medicine feeding hole is provided with stream Gauge.
Adjacent described dividing plate is crisscross arranged up and down.
Described regulation medicine feeding hole is located at the porch of each described reaction interval.
The bottom of each described reaction interval is provided with V-shaped groove, and described spoil disposal/emergency valve sets Bottom at described V-shaped groove.
Described v-gutter lean angle 60 degree.
Described flowing water Valve is three-way valve, and entrance point connects with described casing, an outlet End connects discharge end, and another port of export connects sewage regulating reservoir.
The bottom of described casing is provided with heelpiece.
The top of described casing is provided with manhole.
Described pH instrument probe is arranged on the top of described casing.
Use pulling flow type process for treating heavy-metal waste water and the complete set of equipments thereof of technique scheme, PH is disposably adjusted in place by traditional sewage chemical processing method typically exactly, then dosing, Carry out reaction precipitation, reach wastewater treatment efficiency.Traditional chemical precipitation method does not accounts for removing The optimal PH of all kinds of pollution factors and response time.The present invention uses and adjusts pH stage by stage, Carry out stage by stage reacting the impact avoiding precipitate to medicament, also save while reaching effect Cost.This reactor arranges adjustment hole number, and corresponding reactive tank according to the water yield, water quality.
Adjusting pH stage by stage, carrying out reaction stage by stage is to utilize various metal hydroxides in difference The characteristic of Precipitation under pH value condition, segment processing metal hydroxides.The method processes It is simple that heavy metal wastewater thereby has flow process, high treating effect, and operation management is convenient, and processing cost is low Honest and clean feature.
In sum, the present invention be that a kind of flow process is simple, high treating effect, operation management just The pulling flow type process for treating heavy-metal waste water sharp, processing cost is cheap and complete set of equipments thereof.
Accompanying drawing explanation
Fig. 1 is the structural representation front view of the complete set of equipments of the present invention.
Fig. 2 is the structural representation top view of the complete set of equipments of the present invention.
Detailed description of the invention
The invention will be further described below in conjunction with the accompanying drawings.
See Fig. 1 and Fig. 2, the pulling flow type process for treating heavy-metal waste water that the present invention provides, point Stage adjusts pH, the most stage by stage dosing, carries out reaction precipitation stage by stage, reaches sewage disposal Effect.
The complete set of equipments realizing pulling flow type process for treating heavy-metal waste water that the present invention provides, case One end of body 1 is provided with inlet valve 2, and the other end is provided with flowing water Valve 7, sets in casing 1 There are many group dividing plates 11, many group dividing plates 11 will to be partitioned into the reaction interval of multiple series connection in casing 1 12, it is provided with regulation medicine feeding hole 3, pH instrument probe 8 and spoil disposal/emergent in each reaction interval 12 Valve 4, each regulation medicine feeding hole 3 is provided with effusion meter 5.
Specifically, adjacent dividing plate about 11 is crisscross arranged.
Preferably, regulation medicine feeding hole 3 is located at the porch of each reaction interval 12.
Further, the bottom of each reaction interval 12 is provided with V-shaped groove 6, spoil disposal/emergency valve 4 bottoms being located at V-shaped groove 6.60 degree of V-shaped groove 6 angle of inclination.
Flowing water Valve 7 is three-way valve, and entrance point connects with casing 1, and a port of export connects row Putting end, another port of export connects sewage regulating reservoir.
The bottom of casing 1 is provided with heelpiece 10.
The top of casing 1 is provided with manhole 9.
PH instrument probe 8 is arranged on the top of casing 1.
See Fig. 1 and Fig. 2, the present invention and the process of traditional sewage chemical to have any different, traditional PH is disposably adjusted in place by sewage chemical processing method typically exactly, and then dosing is carried out Reaction precipitation, reaches wastewater treatment efficiency.Traditional chemical precipitation method does not accounts for removing all kinds of The Optimal pH of pollution factor and response time.The present invention uses and adjusts pH, sublevel stage by stage Duan Jinhang reaction avoids the precipitate impact on medicament, also saves into while reaching effect This.This complete set of equipments arranges according to the water yield, water quality and regulates medicine feeding hole 3 number, and accordingly Reaction interval 12.
Every section of reaction interval 12 arranges the number of regulation medicine feeding hole 3, regulation according to water quality situation Medicine feeding hole 3 is arranged on the porch of each section of reaction interval 12, beneficially regulator and water It is sufficiently mixed.Regulation medicine feeding hole 3 is provided with effusion meter 5, can control to adjust agent flux size.
Water (flow) direction is big waveform, reduces the flow velocity of water, also improves mixing efficiency simultaneously, Effect of settling strengthens.V-shaped groove 6, the angle of inclination of V-shaped groove 6 it is provided with bottom reaction interval 12 60 degree, the beneficially precipitation of mud.
Flowing water Valve 7 is threeway, and sewage reaches standard after treatment and just can get rid of, if water outlet water Matter does not reaches standard, then flow to sewage regulating reservoir, process again.
Spoil disposal/emergency valve 4, water outlet it is provided with bottom the precipitation zone of every section of reaction interval 12 When mud is arranged at the bottom of valve 7, mud can be discharged from spoil disposal/emergency valve 4.Need maintenance or Person is in an emergency and is, can open spoil disposal/emergency valve 4 draining.
PH instrument probe 8 is arranged on the top of casing 1, uses sealing ring to seal, convenient The maintenance of pH instrument probe 8.PH instrument probe 8 may detect the pH of fixing point, and then automatically adjusts The amount of joint PH regulator.
It is provided with heelpiece 10 bottom casing 1, facilitates the handling of casing 1.

Claims (10)

1. a pulling flow type process for treating heavy-metal waste water, is characterized in that: adjust pH stage by stage, Dosing the most stage by stage, carries out reaction precipitation stage by stage, reaches wastewater treatment efficiency.
2. the one-tenth realizing pulling flow type process for treating heavy-metal waste water described in claim 1 is sheathed Standby, it is characterized in that: one end of casing (1) is provided with inlet valve (2), and the other end is provided with outlet valve Door (7), is provided with in described casing (1) and organizes dividing plate (11) more, the dividing plate (11) described in many groups The reaction interval (12) of multiple series connection will be partitioned in described casing (1), each described anti- Regulation medicine feeding hole (3), pH instrument probe (8) and spoil disposal/emergency valve (4) should be provided with in interval (12), Each described regulation medicine feeding hole (3) is provided with effusion meter (5).
The one-tenth realizing pulling flow type process for treating heavy-metal waste water the most according to claim 2 Complete equipment, is characterized in that: adjacent described dividing plate (11) is crisscross arranged up and down.
4. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: described regulation medicine feeding hole (3) is located at each described reaction The porch of interval (12).
5. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: the bottom of each described reaction interval (12) is provided with V-shaped groove (6), described spoil disposal/emergency valve (4) is located at the bottom of described V-shaped groove (6).
The one-tenth realizing pulling flow type process for treating heavy-metal waste water the most according to claim 5 Complete equipment, is characterized in that: 60 degree of the angle of inclination of described V-shaped groove (6).
7. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: described flowing water Valve (7) is three-way valve, entrance point and institute Casing (1) connection stated, a port of export connects discharge end, and another port of export connects sewage and adjusts Joint pond.
8. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: the bottom of described casing (1) is provided with heelpiece (10).
9. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: the top of described casing (1) is provided with manhole (9).
10. according to realizing pulling flow type process for treating heavy-metal waste water described in Claims 2 or 3 Complete set of equipments, it is characterized in that: described pH instrument probe (8) is arranged on described casing (1) Top.
CN201610562268.3A 2016-07-15 2016-07-15 Plug flow type heavy metal wastewater treatment method and complete equipment thereof Pending CN105948334A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610562268.3A CN105948334A (en) 2016-07-15 2016-07-15 Plug flow type heavy metal wastewater treatment method and complete equipment thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610562268.3A CN105948334A (en) 2016-07-15 2016-07-15 Plug flow type heavy metal wastewater treatment method and complete equipment thereof

Publications (1)

Publication Number Publication Date
CN105948334A true CN105948334A (en) 2016-09-21

Family

ID=56900837

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610562268.3A Pending CN105948334A (en) 2016-07-15 2016-07-15 Plug flow type heavy metal wastewater treatment method and complete equipment thereof

Country Status (1)

Country Link
CN (1) CN105948334A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115806336A (en) * 2022-12-01 2023-03-17 中国市政工程华北设计研究总院有限公司 High-efficient dephosphorization system of honeycomb type step

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7105094B1 (en) * 2005-10-06 2006-09-12 The United States Of America As Represented By The Secretary Of The Navy Method for the removal of heavy metals from acidic wastewater and chemical solutions
CN101628763A (en) * 2009-08-06 2010-01-20 河南豫光锌业有限公司 Processing equipment and technique for waste acid and water
CN102757147A (en) * 2012-07-31 2012-10-31 中国航天建设集团有限公司 Electroplating wastewater comprehensive treatment process
CN103641210A (en) * 2013-11-08 2014-03-19 华南理工大学 Method for treating chromium-containing electroplating waste water in composite electrolytic tank
CN103693770A (en) * 2012-09-28 2014-04-02 宝钢工程技术集团有限公司 Purifying device for wet-process flue gas desulfurization wastewater and using method thereof
CN103880206A (en) * 2012-12-20 2014-06-25 深圳职业技术学院 Sludge dynamic nucleation flocculated heavy metal wastewater advanced treatment method
CN203999225U (en) * 2014-08-06 2014-12-10 湖南鑫力恒环保科技有限公司 The complete treatment facility of a kind of heavy metal-containing waste water
CN104211223A (en) * 2014-09-03 2014-12-17 上海丰信环保科技有限公司 Treatment method of chromium-containing and nickel-containing wastewater
CN105293766A (en) * 2015-10-26 2016-02-03 北京东方协和医药生物技术有限公司 Heavy metal industrial sewage treatment fundamental process
CN205241415U (en) * 2015-12-14 2016-05-18 株洲冶炼集团股份有限公司 Contain little electrolysis of thallium heavy metal wastewater processing apparatus that thoughtlessly links with fixed attention
CN105600900A (en) * 2015-11-10 2016-05-25 山东建筑大学 Device and method used for removing lead ions in industrial wastewater via gamma-polyglutamic acid adsorption

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7105094B1 (en) * 2005-10-06 2006-09-12 The United States Of America As Represented By The Secretary Of The Navy Method for the removal of heavy metals from acidic wastewater and chemical solutions
CN101628763A (en) * 2009-08-06 2010-01-20 河南豫光锌业有限公司 Processing equipment and technique for waste acid and water
CN102757147A (en) * 2012-07-31 2012-10-31 中国航天建设集团有限公司 Electroplating wastewater comprehensive treatment process
CN103693770A (en) * 2012-09-28 2014-04-02 宝钢工程技术集团有限公司 Purifying device for wet-process flue gas desulfurization wastewater and using method thereof
CN103880206A (en) * 2012-12-20 2014-06-25 深圳职业技术学院 Sludge dynamic nucleation flocculated heavy metal wastewater advanced treatment method
CN103641210A (en) * 2013-11-08 2014-03-19 华南理工大学 Method for treating chromium-containing electroplating waste water in composite electrolytic tank
CN203999225U (en) * 2014-08-06 2014-12-10 湖南鑫力恒环保科技有限公司 The complete treatment facility of a kind of heavy metal-containing waste water
CN104211223A (en) * 2014-09-03 2014-12-17 上海丰信环保科技有限公司 Treatment method of chromium-containing and nickel-containing wastewater
CN105293766A (en) * 2015-10-26 2016-02-03 北京东方协和医药生物技术有限公司 Heavy metal industrial sewage treatment fundamental process
CN105600900A (en) * 2015-11-10 2016-05-25 山东建筑大学 Device and method used for removing lead ions in industrial wastewater via gamma-polyglutamic acid adsorption
CN205241415U (en) * 2015-12-14 2016-05-18 株洲冶炼集团股份有限公司 Contain little electrolysis of thallium heavy metal wastewater processing apparatus that thoughtlessly links with fixed attention

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115806336A (en) * 2022-12-01 2023-03-17 中国市政工程华北设计研究总院有限公司 High-efficient dephosphorization system of honeycomb type step

Similar Documents

Publication Publication Date Title
CN106277427A (en) Electroplating comprehensive waste water Intelligent processing device and control method thereof
CN103935974B (en) A kind of method that sewage middle and high concentration ammonia nitrogen is recovered as high-purity big particle guanite
CN110386721B (en) Electroplating wastewater precise comprehensive treatment management system and implementation method thereof
CN104829014A (en) Short-distance membrane separation treatment process for lead-zinc industrial beneficiation and smelting wastewater
DE102013112269A1 (en) Apparatus for recovering microalgae biomass from a wastewater
CN106698759A (en) Chemical nickel-plating wastewater treatment method
CN104326620A (en) Tannery wastewater treatment method
CN204689833U (en) Laboratory wastewater treatment system
CN105948334A (en) Plug flow type heavy metal wastewater treatment method and complete equipment thereof
CN204454779U (en) Chromate waste water process integration apparatus
CN210855500U (en) Sewage treatment and recycling system
CN205603369U (en) Electroplating wastewater treatment system device
CN104478118A (en) Intelligent catalytic oxidation waste water treatment device
CN105858991A (en) Chrome-containing wastewater treatment device
CN204689788U (en) A kind of short distance membrane separation system of plumbous Zn Cr coating beneficiation wastewater
CN109111034A (en) Electroplating waste water high-efficiency processing system and its processing method
CN105906168B (en) A kind of mine wastewater recovery and treatment method
CN107902839A (en) A kind of modularization integrated system and technique suitable for composite waste of electrolytic plating processing
CN210528702U (en) Electroplating effluent regeneration and reuse integrates processing apparatus
CN211770669U (en) Paint sewage treatment plant
CN209567947U (en) The processing of mine acid waste water containing heavy metal and purification system
CN208980532U (en) Electroplating waste water high-efficiency processing system
CN204369629U (en) A kind of particle phosphorus retrieving arrangement of Internal Circulating Fluidized Bed
CN114262097A (en) Wastewater dechlorination system and method based on electrolytic aluminum coupling chemical precipitation
CN104529046B (en) Process high concentrated organic wastewater RO concentrated solution equipment and group technology

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160921

RJ01 Rejection of invention patent application after publication