CN105906168B - A kind of mine wastewater recovery and treatment method - Google Patents

A kind of mine wastewater recovery and treatment method Download PDF

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Publication number
CN105906168B
CN105906168B CN201610495311.9A CN201610495311A CN105906168B CN 105906168 B CN105906168 B CN 105906168B CN 201610495311 A CN201610495311 A CN 201610495311A CN 105906168 B CN105906168 B CN 105906168B
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treatment
layer
pond
filter screen
coagulation
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CN105906168A (en
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秦月琴
任飞
孙忠伟
明桂林
吴海东
王前
张传琦
牛杏杏
王赞
王代飞
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ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd
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ANHUI JINLIAN GEOLOGY AND MINERAL RESOURCES TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a kind of mine wastewater recovery and treatment methods, the described method comprises the following steps: coagulation, two stage treatment, tertiary treatment, level Four processing.The present invention continuously can carry out overall treatment to mine wastewater, treatment effeciency is high, speed is fast, not only the acidic materials in waste water are removed, effectively comprehensive cleaning further has been carried out to heavy metal therein, the influence to ambient enviroment and resident living is reduced by non-pollution discharge after the heavy metal processing in waste water into natural environment by the level Four treatment process of classification setting.

Description

A kind of mine wastewater recovery and treatment method
Technical field
The invention belongs to waste water treatment field more particularly to a kind of mine wastewater recovery and treatment methods.
Background technique
Mine industry is the pillar industries of the national economy, and during mining and ore processing, forms a large amount of lifes Produce waste water, including acid wastewater in mine and flotation processing waste water.The acid wastewater in mine wherein generated low, coloration with pH value Height contains a large amount of heavy metal ion, if can cause great harm to ambient enviroment without processing, lower pH value can make water quality And soil acidification, cause aquatic animal extinction and crop production reduction, especially heavy metal ion once to enter water body and soil, just It is difficult to be removed, can be enriched in animal and plant body, and then human body is entered by food chain, and it is long to endanger the period in incubation period, It is difficult to show in short time.In famous " the eight big public hazards " contamination accident in the whole world, " minamata disease event " and " Itai-itai diseases " event are just As caused by heavy metal Hg and cadmium, it is therefore necessary to carry out harmless treatment to waste water.
Summary of the invention
It is an object of the invention to overcome problem above of the existing technology, a kind of mine wastewater recovery processing side is provided Method effectively clears up the harmful substance in mine wastewater, reduces direct pollution of the waste water to natural environment.
To realize above-mentioned technical purpose and the technique effect, the invention is realized by the following technical scheme:
A kind of mine wastewater recovery and treatment method, the described method comprises the following steps:
(1) coagulation: introducing coagulation pond for mine wastewater, and four layers of filtering are arranged in coagulation pond inlet Net, first layer are set to equally distributed bentonite, the second layer is provided between second layer filter screen between third layer filter screen It is equipped with equally distributed active carbon, third layer is provided with equally distributed zeolite between the 4th layer of filter screen, in first layer mistake Strainer and the 4th layer of filter screen outer surface are covered with geotextiles, are equipped with microfiltration membranes in coagulation pond exit, the nanofiltration fenestra At 0.3~0.5 micron, outlet pressure is controlled in 0.3~0.5MPa for diameter control;
(2) two stage treatment: introducing two stage treatment pond for the waste water after coagulation, is arranged at the both ends in two stage treatment pond There are cathode plate and anode plate, several cathodic coatings and anode film being alternately placed is provided between cathode plate and anode plate, and two Grade processing pond outlet end and arrival end are provided with nanofiltration membrane, and the pore size control of the nanofiltration membrane is in 0.1~0.3nm, inlet pressure Control is in 0.5~0.7MPa;
(3) tertiary treatment: the waste water after two stage treatment is introduced into tertiary treatment pond, is sequentially added in tertiary treatment pond Aluminium polychloride, polyaluminium sulfate, ferrous sulfate are simultaneously uniformly mixed, and sequentially add polyacrylamide after 20~30 minutes Amine, lignin derivative and 60~70 DEG C at a temperature of be mixed 10~15 minutes, sodium hydroxide is then added, is filled Divide and is mixed 5~10 minutes and stands 30~45 minutes;
(4) level Four is handled: waste water after tertiary treatment being introduced into clean water treatment area, which is tertiary treatment pond Transition region between natural water, in the region in upstream region uniform kind be implanted with duckweed, the wherein planting density control of duckweed System is implanted with cattail for uniform kind in 20~25 plants/square metre, the region midstream region, and wherein the planting density of cattail is controlled 25 ~30 plants/square metre are implanted with reed for uniform kind in the region Xia You of the region, and wherein the planting density of reed is controlled 35~40 Strain/square metre, entire clean water treatment area is evenly equipped with cyanobacteria and green alga.
Further, the aperture of each layer filter screen is identical in the coagulation and is 3~5mm.
Further, the mutual spacing of cathodic coating and anode film is 10~15cm in the two stage treatment.
The beneficial effects of the present invention are:
The present invention continuously can carry out overall treatment to mine wastewater, and treatment effeciency is high, and speed is fast, not only to useless Acidic materials in water are removed, and have further been carried out effectively comprehensive cleaning to heavy metal therein, have been set by classification The level Four treatment process set is reduced by non-pollution discharge after the heavy metal processing in waste water into natural environment to ambient enviroment And the influence of resident living.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention will be described in further detail with reference to the examples below, the embodiment For explaining only the invention, it is not intended to limit the scope of the present invention..
Embodiment 1:
A kind of mine wastewater recovery and treatment method, the described method comprises the following steps:
(1) coagulation: introducing coagulation pond for mine wastewater, and four layers of filtering are arranged in coagulation pond inlet Net, first layer are set to equally distributed bentonite, the second layer is provided between second layer filter screen between third layer filter screen It is equipped with equally distributed active carbon, third layer is provided with equally distributed zeolite between the 4th layer of filter screen, in first layer mistake Strainer and the 4th layer of filter screen outer surface are covered with geotextiles, are equipped with microfiltration membranes in coagulation pond exit, the nanofiltration fenestra At 0.3 micron, outlet pressure is controlled in 0.3MPa for diameter control;
(2) two stage treatment: introducing two stage treatment pond for the waste water after coagulation, is arranged at the both ends in two stage treatment pond There are cathode plate and anode plate, several cathodic coatings and anode film being alternately placed is provided between cathode plate and anode plate, and two Grade processing pond outlet end and arrival end are provided with nanofiltration membrane, and in 0.1nm, inlet pressure control exists the pore size control of the nanofiltration membrane 0.5MPa;
(3) tertiary treatment: the waste water after two stage treatment is introduced into tertiary treatment pond, is sequentially added in tertiary treatment pond Aluminium polychloride, polyaluminium sulfate, ferrous sulfate are simultaneously uniformly mixed, and sequentially add polyacrylamide, wood after 20 minutes Quality derivative and 60 DEG C at a temperature of be mixed 10 minutes, sodium hydroxide is then added, be sufficiently mixed 5 points of stirring Clock simultaneously stands 30 minutes;
(4) level Four is handled: waste water after tertiary treatment being introduced into clean water treatment area, which is tertiary treatment pond Transition region between natural water, in the region in upstream region uniform kind be implanted with duckweed, the wherein planting density control of duckweed System in 20 plants/square metre, the region midstream region uniform kind be implanted with cattail, wherein cattail planting density control 25 plants/ Square metre, reed is implanted with for uniform kind in the region Xia You of the region, and wherein the planting density control of reed is whole in 35 plants/square metre A clean water treatment area is evenly equipped with cyanobacteria and green alga.
Wherein, the aperture of each layer filter screen is identical in coagulation and is 3mm, cathodic coating and anode film in two stage treatment Mutual spacing be 10cm.
Embodiment 2:
A kind of mine wastewater recovery and treatment method, the described method comprises the following steps:
(1) coagulation: introducing coagulation pond for mine wastewater, and four layers of filtering are arranged in coagulation pond inlet Net, first layer are set to equally distributed bentonite, the second layer is provided between second layer filter screen between third layer filter screen It is equipped with equally distributed active carbon, third layer is provided with equally distributed zeolite between the 4th layer of filter screen, in first layer mistake Strainer and the 4th layer of filter screen outer surface are covered with geotextiles, are equipped with microfiltration membranes in coagulation pond exit, the nanofiltration fenestra At 0.5 micron, outlet pressure is controlled in 0.5MPa for diameter control;
(2) two stage treatment: introducing two stage treatment pond for the waste water after coagulation, is arranged at the both ends in two stage treatment pond There are cathode plate and anode plate, several cathodic coatings and anode film being alternately placed is provided between cathode plate and anode plate, and two Grade processing pond outlet end and arrival end are provided with nanofiltration membrane, and in 0.3nm, inlet pressure control exists the pore size control of the nanofiltration membrane 0.7MPa;
(3) tertiary treatment: the waste water after two stage treatment is introduced into tertiary treatment pond, is sequentially added in tertiary treatment pond Aluminium polychloride, polyaluminium sulfate, ferrous sulfate are simultaneously uniformly mixed, and sequentially add polyacrylamide, wood after 30 minutes Quality derivative and 70 DEG C at a temperature of be mixed 15 minutes, sodium hydroxide is then added, carries out being sufficiently mixed stirring 10 Minute simultaneously stands 45 minutes;
(4) level Four is handled: waste water after tertiary treatment being introduced into clean water treatment area, which is tertiary treatment pond Transition region between natural water, in the region in upstream region uniform kind be implanted with duckweed, the wherein planting density control of duckweed System in 25 plants/square metre, the region midstream region uniform kind be implanted with cattail, wherein cattail planting density control 30 plants/ Square metre, reed is implanted with for uniform kind in the region Xia You of the region, and wherein the planting density control of reed is whole in 40 plants/square metre A clean water treatment area is evenly equipped with cyanobacteria and green alga.
Wherein, the aperture of each layer filter screen is identical in coagulation and is 5mm, cathodic coating and anode film in two stage treatment Mutual spacing be 15cm.
The basic principles, main features and advantages of the present invention have been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.

Claims (1)

1. a kind of mine wastewater recovery and treatment method, which is characterized in that the described method comprises the following steps:
(1) coagulation: introducing coagulation pond for mine wastewater, and four layers of filter screen are arranged in coagulation pond inlet, First layer is provided with to equally distributed bentonite, the second layer is provided between second layer filter screen between third layer filter screen Equally distributed active carbon, third layer is provided with equally distributed zeolite between the 4th layer of filter screen, in first layer filter screen Geotextiles are covered with the 4th layer of filter screen outer surface, microfiltration membranes are installed in coagulation pond exit, the micro-filtration membrane aperture control At 0.3~0.5 micron, outlet pressure is controlled in 0.3~0.5MPa system;
(2) two stage treatment: introducing two stage treatment pond for the waste water after coagulation, and the both ends in two stage treatment pond are provided with yin Pole plate and anode plate are provided with several cathodic coatings and anode film being alternately placed between cathode plate and anode plate, and at second level The outlet end Li Chi and arrival end are provided with nanofiltration membrane, and the pore size control of the nanofiltration membrane is in 0.1~0.3nm, inlet pressure control In 0.5~0.7MPa;
(3) tertiary treatment: the waste water after two stage treatment is introduced into tertiary treatment pond, polymerization is sequentially added in tertiary treatment pond Aluminium chloride, polyaluminium sulfate, ferrous sulfate are simultaneously uniformly mixed, and polyacrylamide, wood are sequentially added after 20~30 minutes Quality derivative and 60~70 DEG C at a temperature of be mixed 10~15 minutes, be then added sodium hydroxide, carry out sufficiently mixed It closes stirring 5~10 minutes and stands 30~45 minutes;
(4) level Four is handled: waste water after tertiary treatment being introduced into clean water treatment area, the clean water treatment area is for tertiary treatment pond and certainly Transition region between right water body, in the region in upstream region uniform kind be implanted with duckweed, wherein the planting density control of duckweed exists 20~25 plants/square metre are implanted with cattail for uniform kind in the region midstream region, and wherein the planting density of cattail is controlled 25~30 Strain/square metre, be implanted with reed for uniform kind in the region downstream region, wherein the planting density control of reed 35~40 plants/it is flat Square rice, entire clean water treatment area are evenly equipped with cyanobacteria and green alga;
The aperture of each layer filter screen is identical in the coagulation and is 3~5mm;
The mutual spacing of cathodic coating and anode film is 10~15cm in the two stage treatment.
CN201610495311.9A 2016-06-27 2016-06-27 A kind of mine wastewater recovery and treatment method Active CN105906168B (en)

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Publication number Priority date Publication date Assignee Title
CN110038885A (en) * 2019-06-05 2019-07-23 湖南双晟科技信息咨询有限公司 A kind of restorative procedure of mine soil
CN114455711A (en) * 2022-02-10 2022-05-10 江西省生态环境科学研究与规划院 Filler and application thereof

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Publication number Priority date Publication date Assignee Title
CN104150688A (en) * 2014-07-25 2014-11-19 中国环境科学研究院 Device for classifying organic matters in underground water and purifying underground water by areas and purifying method
CN104944636A (en) * 2015-06-07 2015-09-30 长春黄金研究院 Non-ferrous metal mine acid wastewater treatment method
CN204918256U (en) * 2015-06-12 2015-12-30 长春黄金研究院 Acid effluent disposal system of mine copper -containing
CN105461184A (en) * 2015-11-30 2016-04-06 云南水务投资股份有限公司 Device for performing sludge reduction and stabilization by utilizing intercrop plants and process of device
CN105585146A (en) * 2014-10-23 2016-05-18 青岛百键城环保科技有限公司 A process of treating mine wastewater through applying a membrane technique

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CN104150688A (en) * 2014-07-25 2014-11-19 中国环境科学研究院 Device for classifying organic matters in underground water and purifying underground water by areas and purifying method
CN105585146A (en) * 2014-10-23 2016-05-18 青岛百键城环保科技有限公司 A process of treating mine wastewater through applying a membrane technique
CN104944636A (en) * 2015-06-07 2015-09-30 长春黄金研究院 Non-ferrous metal mine acid wastewater treatment method
CN204918256U (en) * 2015-06-12 2015-12-30 长春黄金研究院 Acid effluent disposal system of mine copper -containing
CN105461184A (en) * 2015-11-30 2016-04-06 云南水务投资股份有限公司 Device for performing sludge reduction and stabilization by utilizing intercrop plants and process of device

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