CN105948161A - Device and method for removing organic matters in ammonium sulfate solution and manufacturing method of device - Google Patents
Device and method for removing organic matters in ammonium sulfate solution and manufacturing method of device Download PDFInfo
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- CN105948161A CN105948161A CN201610422050.8A CN201610422050A CN105948161A CN 105948161 A CN105948161 A CN 105948161A CN 201610422050 A CN201610422050 A CN 201610422050A CN 105948161 A CN105948161 A CN 105948161A
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- ammonium sulfate
- shell
- electric treatment
- treatment device
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
The invention relates to a device and method for removing organic matters in an ammonium sulfate solution and a manufacturing method of the device. The device comprises a shell and an electric treatment device installed inside the shell coaxially. A water inlet pipe and a water outlet pipe at the two ends of the electric treatment device are connected to the shell. The electric treatment device comprises stacked and wound flexible materials. The flexible materials include two staggered stacked conductive adsorption layers and two insulation layers, wherein each conductive adsorption layer is connected with a plurality of electrode bars parallel to the axis of the electric treatment device, and when the flexible materials are stacked and wound already, the electrode bars on the same conductive adsorption layer are connected with the same lead, and the leads penetrate out of the shell. When the device is in use, the leads are connected with an external power source respectively and the device is powered on; an ammonium sulfate solution containing the organic matters is led into the shell and treated by the electric treatment device, and the conductive adsorption layers are arranged, so that the organic matters can be adsorbed, and the adsorbed organic matters can be catalyzed and degraded on the basis of the electrode bars.
Description
[technical field]
The present invention relates to water treatment field, be specifically related to a kind of remove organic apparatus and method and this device in ammonium sulfate
Manufacture method.
[background technology]
Certain company at the ammonium sulfate solution that by-product is higher concentration of production process, this solution can with ammonium sulfate product at condensing crystallizing,
But due to main production technology, make in ammonium sulfate solution containing larger amount of Organic substance, predominantly dispersed oil and dissolved oil.Due to
There is no effective way by these Impurity removals, cause content of organics in final crystalline sulfuric acid ammonium product too high, have a strong impact on
The quality of ammonium sulfate product.And owing in prime technique, it adds surfactant so that oils is very well dispersed in sulfur
In acid ammonium solution, define transparent homogeneous solution.
The separation having oily substance in water mainly has gravitational separation process, centrifugal separation, dissolved air flotation method, adsorption method of separation, air supporting
Partition method, membrane separation process and electrically separated method etc., the treatment effect of these methods high concentration ammonium sulfate solution to relating in this patent is non-
The most limited, or be to be unable to reach process requirement, or be that operating process is complicated, high cost.
[summary of the invention]
The purpose of the present invention is contemplated to overcome the deficiency of above technology, it is provided that a kind of remove in ammonium sulfate organic device and
Method and the manufacture method of this device, this device makes simple, and is used in water process, it is possible to effectively remove in ammonium sulfate
Organic substance.
Apparatus of the present invention are achieved through the following technical solutions:
Including vertical shell and be co-axially mounted electric treatment device in the enclosure；Connect water inlet pipe and outlet pipe on shell, and enter
Water pipe and outlet pipe lay respectively at the two ends of electric treatment device；
Electric treatment device includes the flexible material that stacking is wound around, and flexible material includes that the two-layer conduction adsorption layer of interfolded and two-layer are exhausted
Edge layer, wherein, every layer of conduction adsorption layer is all connected with being parallel to some electrode bars of electric treatment device axis, and at flexible material
When being in the state that stacking has been wound around, the electrode bar on same conduction adsorption layer connects same lead-in wire, and lead-in wire all passes shell.
Further, shell is the tubular of both ends open, and two ends are all connected with the sleeve pipe for end-blocking, and wherein water inlet pipe is connected to one
On end sleeve pipe, lead-in wire passes other end sleeve pipe；Outlet pipe is connected on side wall of outer shell.
Further, lead-in wire and outlet pipe are respectively positioned on the upper end of shell, and the contact point of lead-in wire and electrode bar is higher than outlet pipe.
Further, conduction adsorption layer all uses activity carbon cloth, activated carbon-fiber felt or activated carbon fiber；The material of electrode bar be titanium, two
Stannum oxide, platinum, ruthenium iridium or graphite；The material of insulating barrier is non-woven fabrics；The material of shell be politef, PVC, PPR,
Cast iron, rustless steel, glass or lucite.
Further, a diameter of the 5 of electric treatment device～100cm, a length of 30～300cm.
The manufacture method of apparatus of the present invention adopts the following technical scheme that and comprises the following steps:
First by dielectric layers together with two-layer conduction adsorption layer interfolded；Electrode bar is respectively placed on conduction adsorption layer,
With wherein one end as starting point, the electrode bar on conduction adsorption layer, insulating barrier and conduction adsorption layer is wound around to other end stacking；By layer
Electrode bar locking after folded winding, and the electrode bar on same conduction adsorption layer is connected same lead-in wire, form electric treatment device；
Then electric treatment device is co-axially mounted in the enclosure, and lead-in wire is drawn outside shell, complete in removal ammonium sulfate organic
The making of the device of thing.
The present invention removes the technical scheme of organic method in ammonium sulfate: comprise the following steps:
First by lead-in wire be connected with the both positive and negative polarity of external power supply respectively and be energized, then will containing organic ammonium sulfate pass through into
Water pipe enters shell, and carries out draining through electric treatment device arrival outlet pipe, completes organic removal in ammonium sulfate.
Further, in ammonium sulfate, organic concentration is 350～400mg/L.
Further, the flow velocity of ammonium sulfate is 1～50L/min.
Further, the voltage of external power supply is 1～18V.
Compared with prior art, the present invention has a following useful technique effect:
By arranging two-layer conduction adsorption layer in apparatus of the present invention, it is possible in the case of conduction, Organic substance is adsorbed, and combine electricity
Extremely rod carries out catalytic degradation to the Organic substance adsorbed；By insulating barrier two-layer conducts electricity adsorption layer to separate, prevent two conduction adsorption layers
Between short circuit；In the present invention, electric treatment device is vertically placed, it is ensured that solution is fully contacted with flexible material；Solution is through electric treatment
Device, first Organic substance is adsorbed in conduction adsorbing material surface, then ultimately generates carbon dioxide and water by Electrocatalysis Degradation, from
Solution removes.The present invention is by being respectively provided with some electrode bars on every layer of conduction adsorption layer, it is ensured that adsorption effect is uniform.This
Invent and absorption and Electrocatalysis Degradation are organically combined the Organic substance (mainly dispersed oil and dissolved oil) removed in ammonium sulfate solution, remove
Efficiency is high.
Further, electrode bar of the present invention and outlet pipe are installed on the upside of device, make pending solution bottom in and top out, are beneficial to carry
High treatment efficiency, and the contact point of lead-in wire and electrode bar is higher than outlet pipe, effectively prevents the solution corruption to electrode bar Yu wire bond pads
Erosion.
Further, the material of the conduction adsorption layer selected by the present invention has the feature such as oil resistant, acid and alkali-resistance, has good with Organic substance
Good affinity, specific surface area is big, and adsorption capacity is big, conducts electricity very well, and can repeatedly Reusability, it is not necessary to cleans, grasp
Make simple, low cost.
The manufacture method of apparatus of the present invention is simple.
Electrode both positive and negative polarity only need to be applied appropriate voltage by the method for organics removal of the present invention, make to lead to containing organic ammonium salt solution
Crossing this electric treatment device to filter, the organic principle absorption in solution is fallen on conduction adsorption layer and by electrolysis, and trickle is purer
Ammonium sulfate, can make follow-up condensing crystallizing, and improve the quality of crystallization ammonium sulfate products.The present invention is by conduction adsorption layer
Characterization of adsorption and electrode electrocatalysis combine so that processed water between plug and housing by time Organic substance be removed, warp
Crossing the inventive method and from 350～400mg/L, the TOC in ammonium sulfate solution can be dropped to 2～5mg/L, organic removal rate reaches
More than 98%, process convenient, step simple and efficiently, simple in processing procedure, low cost.
[accompanying drawing explanation]
Fig. 1 is conduction adsorption layer and the structural representation of electrode bar in the present invention；
Fig. 2 is the structural representation of insulating barrier in the present invention；
Fig. 3 is that the present invention conducts electricity the structural representation that adsorption layer, electrode bar and insulating barrier stack；
Fig. 4 is that electric treatment device of the present invention makes schematic diagram；
Fig. 5 is electric treatment apparatus structure schematic diagram of the present invention；
Fig. 6 is the structural representation of apparatus of the present invention.
Wherein: 11-first conducts electricity adsorption layer；21-the first electrode bar；22-the second electrode bar；23-the 3rd electrode bar；24-the 4th electricity
Extremely rod；31-the first insulating barrier；4-electric treatment device；5-goes between；6-sleeve pipe；7-outlet pipe；8-water inlet pipe；9-shell.
[detailed description of the invention]
Seeing Fig. 1 to Fig. 6, the present invention includes shell 9 and the electric treatment device 4 being coaxially mounted in shell 9.
Electric treatment device 4 includes the flexible material that stacking is wound around, and flexible material includes the first conduction absorption stacked the most successively
Layer the 11, first insulating barrier the 31, second conduction adsorption layer and the second insulating barrier；The present invention is at least connected with on every layer of conduction adsorption layer
A piece electrode bar, in order to improve adsorption efficiency and evening ratio, below as a example by every layer of conduction adsorption layer connects two electrode bars.
Wherein, the first conduction adsorption layer 11 is parallel to the two ends of electric treatment device 4 axis and connects the first electrode bar 21 and second respectively
Electrode bar 22, the second conduction adsorption layer is parallel to the two ends of electric treatment device 4 axis and connects the 3rd electrode bar 23 and the 4th electricity respectively
Extremely rod 24；And when flexible material is in the state that stacking has been wound around, two electrode bars on same conduction adsorption layer connect same
A piece lead-in wire 5, the i.e. first electrode bar 21 and the second electrode bar 22 connect a lead-in wire 5, the 3rd electrode bar 23 and the 4th electrode bar
24 connect another root lead-in wire 5, and lead-in wire 5 all passes shell 9, it is possible to be respectively connected with power positive cathode.
Shell 9 is the tubular of both ends open, and two ends be all connected with for end-blocking sleeve pipe 6, wherein connect on the sleeve pipe 6 of one end into
Water pipe 8；Lead-in wire 5 is through other end sleeve pipe 6；Connect outlet pipe 7 on shell 9 sidewall, and water inlet pipe 8 and outlet pipe 7 are respectively
It is positioned at the two ends of electric treatment device 4.
First conduction adsorption layer 11 and the second conduction adsorption layer all use in activity carbon cloth, activated carbon-fiber felt or activated carbon fiber etc.
Planting or several, wherein every layer of conduction adsorption layer can be single material, it is also possible to be that different materials is spliced to form, and first leads
Electro-adsorption layer 11 can be identical with the second conduction adsorption layer, it is also possible to different, can be in any combination；First electrode bar 21,
The material of the second electrode bar the 22, the 3rd electrode bar 23 and the 4th electrode bar 24 is titanium, tin ash, platinum, ruthenium iridium or graphite；
The material of the first insulating barrier 31 and the second insulating barrier is non-woven fabrics；The material of shell 9 be politef, PVC, PPR,
Cast iron, rustless steel, glass or lucite (PMMA), shape can be the shape of the easy molding such as cylindric, flat column.
A diameter of the 5 of electric treatment device 4～100cm, preferably 5～10cm；A length of 30～300cm, preferably 30～60cm.
The manufacture method of apparatus of the present invention comprises the following steps:
First successively rectangular first conduction adsorption layer the 11, first insulating barrier 31, second is conducted electricity by order from top to bottom and inhale
Attached layer and the second insulating barrier are stacked together, and make to be separated by non-woven fabrics in the middle of the first conduction adsorption layer 11 and the second conduction adsorption layer；
First electrode bar 21 and the second electrode bar 22 are respectively placed in the two ends of the first conduction adsorption layer 11, by the 3rd electrode bar 23 and
Four electrode bars 24 are respectively placed in the two ends of the second conduction adsorption layer, with wherein one end as starting point, will conduction adsorption layer, insulating barrier and
Two electrode bars of this end are wound around to other end stacking together, it is ensured that certain degree of packing, and buckle with band, make conduction adsorption layer
Between the electrode bar corresponding with this layer, conducting is good, and as a example by the first conduction adsorption layer 11, when device is energized, the first conduction is inhaled
Lead-in wire 5-first electrode bar 21 and the second electrode bar 22-first of attached layer 11 correspondence conducts electricity adsorption layer 11 and turns on, two conduction adsorption layers
Between due to non-woven fabrics isolation and mutually insulated, prevent short circuit；Then, two electrode bars on same conduction adsorption layer are connected same
A piece lead-in wire 5, forms electric treatment device 4.
Then electric treatment device 4 is coaxially mounted in shell 9, and lead-in wire 5 is drawn outside shell 9, complete to remove ammonium sulfate molten
The making of organic device in liquid.
The present invention removes organic method in ammonium sulfate, comprises the following steps:
First apparatus of the present invention are vertically placed so that water inlet pipe 8 is in downside, and outlet pipe 7 and lead-in wire 5 are all in upside, it is ensured that molten
Liquid is fully contacted with flexible material, and now electrode bar is respectively positioned on the top of electric treatment device 4, lead-in wire 5 and the contact of electrode bar
Point is higher than the horizontal line of outlet pipe 7, it is possible to effectively prevent the solution corrosion to electrode bar with lead-in wire 5 contact points；Will lead-in wire 5 difference
Being connected with the both positive and negative polarity of external power supply and be energized, regulation voltage is between 1～18V, then will be containing organic ammonium sulfate
Pump into shell 9 by water inlet pipe 8, make containing organic ammonium sulfate through electric treatment device 4, in the suction of conduction adsorption layer
Echoing electro-catalysis jointly to act on down, after making the Organic substance in ammonium sulfate solution adsorbed, degraded is removed, and ultimately generates carbon dioxide and water,
And carrying out draining from the outlet pipe 7 of lower end, water outlet is the ammonium sulfate after purification, completes organic in ammonium sulfate going
Remove.
In the ammonium sulfate processed in the present invention, the concentration of ammonium sulfate may be up to 30g/L, general 0.2～the ammonium sulfate of 30g/L,
Wherein containing organic concentration when being 350～400mg/L, flow velocity is 1～50L/min.
Embodiment 1
With activity carbon cloth for conduction adsorbing material, with non-woven fabrics as insulant, with ruthenium iridium material as electrode rod, it is prepared as diameter
The column electric treatment device of 10cm, long 60cm.Applied voltage is 2V, and the TOC concentration in ammonium sulfate solution is 356mg/L, stream
Being 2L/min through the flow velocity of electric treatment device, after process, the TOC concentration of sulfur ammonium is 4mg/L.
Embodiment 2
With activated carbon-fiber felt for conduction adsorbing material, with non-woven fabrics as insulant, with titanium material as electrode rod, it is prepared as diameter 10cm,
The column electric treatment device of long 50cm.Applied voltage is 2.5V, and the TOC concentration in ammonium sulfate solution is 383mg/L, flows through
The flow velocity of electric treatment device is 1.5L/min, and after process, the TOC concentration of sulfur ammonium is 3.6mg/L.
Embodiment 3
With activated carbon fiber for conduction adsorbing material, with non-woven fabrics as insulant, make electrode bar with graphite rod, be prepared as diameter 5
The column electric treatment device of cm, long 40cm.Applied voltage is 5V, and the TOC concentration in ammonium sulfate solution is 397mg/L, stream
Being 3L/min through the flow velocity of electric treatment device, after process, the TOC concentration of sulfur ammonium is 5mg/L.
Embodiment 4
With activated carbon fiber for conduction adsorbing material, with non-woven fabrics as insulant, make electrode bar with platinum filament, be prepared as diameter 5cm,
The column electric treatment device of long 30cm.Applied voltage is 10V, and the TOC concentration in ammonium sulfate solution is 361mg/L, flows through electricity
The flow velocity of processing means is 5L/min, and after process, the TOC concentration of sulfur ammonium is 3mg/L.
Embodiment 5
Using activity carbon cloth and activated carbon-fiber felt as the material of two-layer conduction adsorption layer, with non-woven fabrics as insulant, with titanium dioxide
Stannum makees electrode bar, is prepared as the column electric treatment device of diameter 100cm, long 300cm.Applied voltage is 18V, ammonium sulfate solution
In TOC concentration be 350mg/L, the flow velocity flowing through electric treatment device is 50L/min, and after process, the TOC concentration of sulfur ammonium is
2.6mg/L。
Embodiment 6
Uniformly splice with activity carbon cloth, activated carbon-fiber felt and activated carbon fiber, then as the material of two-layer conduction adsorption layer, with nonwoven
Cloth is insulant, makees electrode bar with graphite, is prepared as the column electric treatment device of diameter 50m, long 200cm.Applied voltage
For 16V, the TOC concentration in ammonium sulfate solution is 400mg/L, and the flow velocity flowing through electric treatment device is 40L/min, sulfur after process
The TOC concentration of ammonium is 2mg/L.
Embodiment 7
Using activity carbon cloth as the material of the first conduction adsorption layer, uniformly splice as the second conduction using activated carbon-fiber felt and activated carbon fiber
The material of adsorption layer, with non-woven fabrics as insulant, makees electrode bar with platinum, is prepared as the column electricity of diameter 80m, long 100cm
Processing means.Applied voltage is 12V, and the TOC concentration in ammonium sulfate solution is 370mg/L, and the flow velocity flowing through electric treatment device is
30L/min, after process, the TOC concentration of sulfur ammonium is 3.1mg/L.
The invention provides organic processing method, especially crystalline sulfuric acid ammonium salt solution production process in a kind of high-concentration ammonium salt solution
In organic purification；First design framework a set of electric treatment device, electrode is mainly based on active carbon fiber felt, and non-woven fabrics is
Insulating barrier, Ti/Ir-RuO2Electrode is that both positive and negative polarity lead-out wire combines.Absorption and electrocatalysis are combined by the present invention, have
Absorption and the assembly such as the material with carbon element of conducting function, electrode bar, non-woven fabrics and shell cavity, prepare and have absorption and electro-catalysis is dual
The electric treatment device of effect, then external power supply process are containing organic ammonium sulfate, make the Organic substance in ammonium sulfate
Drop to extremely low level；And the present invention removes the Organic substance in ammonium sulfate solution by the way of absorption and electro-catalysis combination, is beneficial to
Improve crystallization ammonium sulfate products quality.
Electrode bar, by being stacked with two panels conductive carbon material by positive and negative electrode, is respectively placed in rectangle conductive carbon material by the present invention
Material two ends；Centre two-layer nonwoven is separated, along tightly rolling to another side；Then by the electrode locking of parcel consolidation, and
Two positive poles (two negative poles) are connected, merge into one and draw.Put the electrodes in shell cavity, it is possible to appropriate processing beautifies
Device.Adsorption and electrocatalysis are combined by the present invention, develop organic efficient minimizing technology in a kind of ammonium sulfate solution.
Mainly including organic process two parts in the preparation of electric treatment device and ammonium sulfate solution, its core is electric treatment device.
Claims (10)
1. remove organic device in ammonium sulfate for one kind, it is characterised in that: include vertical shell (9) and coaxially pacify
The electric treatment device (4) being contained in shell (9)；Water inlet pipe (8) and outlet pipe (7), and water inlet pipe is connected on shell (9)
And outlet pipe (7) lays respectively at the two ends of electric treatment device (4) (8)；
Electric treatment device (4) includes the flexible material that stacking is wound around, flexible material include interfolded two-layer conduction adsorption layer and
Dielectric layers, wherein, every layer of conduction adsorption layer is all connected with being parallel to some electrode bars of electric treatment device (4) axis,
And when flexible material is in the state that stacking has been wound around, the electrode bar on same conduction adsorption layer connects same lead-in wire (5),
Lead-in wire (5) all passes shell (9).
Organic device in a kind of removal ammonium sulfate the most according to claim 1, it is characterised in that: shell (9)
For the tubular of both ends open, and two ends are all connected with the sleeve pipe (6) for end-blocking, and wherein water inlet pipe (8) is connected to one end sleeve pipe (6)
On, lead-in wire (5) passes other end sleeve pipe (6)；Outlet pipe (7) is connected on shell (9) sidewall.
Organic device in a kind of removal ammonium sulfate the most according to claim 1, it is characterised in that: lead-in wire (5)
With the upper end that outlet pipe (7) is respectively positioned on shell (9), and lead-in wire (5) and electrode bar contact point be higher than outlet pipe (7).
Organic device in a kind of removal ammonium sulfate the most according to claim 1, it is characterised in that: conduction absorption
Layer all uses activity carbon cloth, activated carbon-fiber felt or activated carbon fiber；The material of electrode bar is titanium, tin ash, platinum, ruthenium iridium or graphite；
The material of insulating barrier is non-woven fabrics；The material of shell (9) is politef, PVC, PPR, cast iron, rustless steel, glass
Or lucite.
Organic device in a kind of removal ammonium sulfate the most according to claim 1, it is characterised in that: electric treatment fills
Put a diameter of the 5～100cm of (4), a length of 30～300cm.
6. one kind based on removing the manufacture method of organic device in ammonium sulfate described in claim 1, it is characterised in that:
Comprise the following steps:
First by dielectric layers together with two-layer conduction adsorption layer interfolded；Electrode bar is respectively placed on conduction adsorption layer,
With wherein one end as starting point, the electrode bar on conduction adsorption layer, insulating barrier and conduction adsorption layer is wound around to other end stacking；By layer
Electrode bar locking after folded winding, and the electrode bar on same conduction adsorption layer is connected same lead-in wire (5), form electric treatment
Device (4)；
Then electric treatment device (4) is coaxially mounted in shell (9), and lead-in wire (5) is drawn shell (9) outward, complete
Remove the making of organic device in ammonium sulfate.
7. the device that a kind utilizes described in claim 1 removes organic method in ammonium sulfate, it is characterised in that: include
Following steps:
First lead-in wire (5) is connected with the both positive and negative polarity of external power supply respectively and is energized, then will be containing organic ammonium sulfate
Enter shell (9) by water inlet pipe (8), and carry out draining through electric treatment device (4) arrival outlet pipe (7), complete sulfur
Organic removal in acid ammonium solution.
Organic method in removal ammonium sulfate the most according to claim 7, it is characterised in that: in ammonium sulfate
Organic concentration is 350～400mg/L.
Organic method in removal ammonium sulfate the most according to claim 7, it is characterised in that: ammonium sulfate
Flow velocity is 1～50L/min.
Organic method in removal ammonium sulfate the most according to claim 7, it is characterised in that: the electricity of external power supply
Pressure is 1～18V.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610422050.8A CN105948161A (en) | 2016-06-13 | 2016-06-13 | Device and method for removing organic matters in ammonium sulfate solution and manufacturing method of device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610422050.8A CN105948161A (en) | 2016-06-13 | 2016-06-13 | Device and method for removing organic matters in ammonium sulfate solution and manufacturing method of device |
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| CN105948161A true CN105948161A (en) | 2016-09-21 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1201759A (en) * | 1997-06-05 | 1998-12-16 | 大连理工大学 | Continuously adsorbing-electrolyzing regenerated wastewater treating apparatus |
| WO2007044609A1 (en) * | 2005-10-06 | 2007-04-19 | Pionetics Corporation | Electrochemical ion exchange treatment of fluids |
| CN200988778Y (en) * | 2006-12-27 | 2007-12-12 | 黄樟焱 | Rolling type Electric adsorptive filter core |
| US20110042236A1 (en) * | 2009-08-21 | 2011-02-24 | Samsung Electronics Co., Ltd. | Drinking water filter system, method of regenerating the same, and water purifying device including the drinking water filter system |
| CN103112930A (en) * | 2013-02-26 | 2013-05-22 | 吴英 | Electrode group for electric ion replacement processing device |
| CN103626266A (en) * | 2012-08-27 | 2014-03-12 | 侯梦斌 | Electro-adsorption water treatment device and technology with activated carbon fiber cloth as electrode |
-
2016
- 2016-06-13 CN CN201610422050.8A patent/CN105948161A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1201759A (en) * | 1997-06-05 | 1998-12-16 | 大连理工大学 | Continuously adsorbing-electrolyzing regenerated wastewater treating apparatus |
| WO2007044609A1 (en) * | 2005-10-06 | 2007-04-19 | Pionetics Corporation | Electrochemical ion exchange treatment of fluids |
| CN200988778Y (en) * | 2006-12-27 | 2007-12-12 | 黄樟焱 | Rolling type Electric adsorptive filter core |
| US20110042236A1 (en) * | 2009-08-21 | 2011-02-24 | Samsung Electronics Co., Ltd. | Drinking water filter system, method of regenerating the same, and water purifying device including the drinking water filter system |
| CN103626266A (en) * | 2012-08-27 | 2014-03-12 | 侯梦斌 | Electro-adsorption water treatment device and technology with activated carbon fiber cloth as electrode |
| CN103112930A (en) * | 2013-02-26 | 2013-05-22 | 吴英 | Electrode group for electric ion replacement processing device |
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