CN202808446U - Circulating type electro-adsorption liquid purifying device - Google Patents

Circulating type electro-adsorption liquid purifying device Download PDF

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Publication number
CN202808446U
CN202808446U CN 201220157300 CN201220157300U CN202808446U CN 202808446 U CN202808446 U CN 202808446U CN 201220157300 CN201220157300 CN 201220157300 CN 201220157300 U CN201220157300 U CN 201220157300U CN 202808446 U CN202808446 U CN 202808446U
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liquid
battery lead
adsorption
lead plate
type electro
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CN 201220157300
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Chinese (zh)
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刘平
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Abstract

The utility model relates to a circulating type electro-adsorption liquid purifying device which comprises a shell provided with a liquid inlet pipe and a liquid outlet pipe, wherein a circulating type electro-adsorption liquid purifying component comprising a power distribution device, more than two electrode plates and an isolation layer is arranged in the shell; the isolation layer is located between two electrode plates with opposite polarities and provided with a liquid channel; the electrode plates and the isolation layer are arranged in a closed annular manner; a liquid inlet/outlet is formed on each electrode plate; and the space of the electrode plates (thickness of the isolation layer) is reduced along the liquid flowing direction. The liquid containing various ions is adsorbed on the electrode plates under the effect of a DC (direct current) electric field when flowing through the electrode plates. The device provided by the utility model is simple in structure and low in manufacturing cost, effectively improves the ability of removing charged particles of the electro-adsorption device, and is suitable for purifying various liquids with relatively high requirements on desalination rate.

Description

Circulation type electro-adsorption liquid cleaning device
Technical field
The utility model belongs to the fluid purification processing technology field, especially relates to a kind of circulation type electro-adsorption liquid cleaning device.
Background technology
Known fluid purification treatment process has: chemical method, Physical (distillation method and cold method), ion exchange method, electroosmose process, reverse osmosis method, EDI method and electro-adsorption method etc.Aforesaid method cuts both ways, and such as the chemical method reduced investment, but can only remove the ion of easy generation indissoluble salt; Distillation method is high to the impurities in liquid clearance, but energy consumption is high; Ion exchange method is removed various ions in the liquid by ion exchange resin, invest lowlyer, but the resin needs regularly regenerate with strong acid, highly basic, and the salkali waste spent acid solution of discharge has caused secondary pollution; Electrodialysis and reverse osmosis all are to utilize membrane technique treatment and purification liquid, different is that electrodialysis is to utilize electrode formation electric field to order about the liquid intermediate ion to pass through ionic membrane, liquid is purified, and reverse osmosis is to order about liquid with pressure to pass through reverse osmosis membrane, hold back salinity in the liquid, both high advantages of desalination rate, but also have the problems such as power consumption height, film vulnerable to pollution, life-span weak point, electrodialysis also has the problem of battery lead plate polarization; EDI is the fluid purification technology that combines electrodialysis and the development of ion exchange technique advantage, and it has avoided the chemical regeneration of ion exchange resin, does not have secondary pollution, and very high desalination rate is arranged, but the problem that ionic membrane easily pollutes, the life-span is short is arranged equally.
Electro-adsorption is fluid purification technology of new generation, it is that low voltage and direct current is applied on the opposite polarity pair of electrodes plate, when liquid by between battery lead plate during passage, the charged particle in the liquid is subjected to electric field action, mobile being adsorbed on the battery lead plate of opposed polarity, liquid is purified.After for some time, with battery lead plate discharge or reversal connection, be adsorbed on ion desorption on the battery lead plate in scavenging solution, battery lead plate is regenerated.The electro-adsorption technology has overcome electrodialysis and reverse osmosis membrane and has easily polluted, poisons, needs periodic replacement expense height, can not process the shortcoming that contains a small amount of organic liquid without ion diaphragm; And the battery lead plate life-span is long, not fragile, and current consumption is low, has greatly saved processing cost.But the clearance that a main drawback of electro-adsorption is exactly charged particle is lower than reverse osmosis and electrodialytic technique, and the former is generally 65-85% by clearance, and latter Ke Da is more than 95%.
In sum, the fluid purification technology respectively has relative merits, reach widely applicable, reduced investment, energy consumption is low, removal of impurity is high, equipment is durable in use, also needs constantly innovate improvement to above-mentioned technology.
China Patent No. is that 01127146.9 " liquid treatment purifying module " discloses a kind of technology of removing band ionization particle in the liquid.This module comprises end plate, distribution base plate, battery lead plate, insulation bulkhead and web member, a pair of distribution base plate above and row arrangement is fixed by end plate and insulation bulkhead by web member, the distribution base plate is connected with the distribution element, the distribution base plate that is connected with battery lead plate is provided with delivery hole, and be communicated with and consist of fluid passage with liquid in-out mouth and the space between the battery lead plate on the end plate, the filler that liquid is passed through also is housed in the space between battery lead plate.It utilizes the electro-adsorption principle can effectively remove the charged particle in the liquid and is dissolved in salinity in the liquid.Can also remove colloid charged in the liquid, organism, microorganism etc.Equipment life is long, and power consumption is especially far below other fluid purification technology.But because battery lead plate adopts parallel-plate structure in the described module of this patent, the module quantity of used parts is too many, and manufacturing accuracy requires high, and manufacturing cost is high.
For addressing the above problem, China Patent No. is the technology that 200610172589.9 " rolling type electric adsorption filter elements " disclose a kind of rolling electro-adsorption device and removal charged particle.This device is to be provided with rolling electro-adsorption assembly in the housing that is provided with fluid inlet, liquid outlet and electrode, this assembly is wound on mandrel on by the composite bed that conductive layer, adsorption layer, supporting layer, adsorption layer, conductive layer, adsorption layer, supporting layer and adsorption layer (8 layers) form totally, and by the immovable bed in the outside it is tightened to be fixed on the mandrel and make.When stoste enters filter core from fluid inlet, during supporting layer in passing rolling electro-adsorption assembly, under the effect of direct current field force, the charged particle of liquid is attracted in the electrostatic double layer on adsorption layer surface and is effectively removed, and liquid is purified.This invents more last invention, has that energy consumption is low, simple in structure, the advantage of low cost of manufacture.But the described rolling electro-adsorption of this patent assembly is from axial turnover liquid, causes the clearance of liquid flow weak point, charged particle low, needs a plurality of monomer series-connected combinations; And if the tangential direction feed liquor, the liquid treatment amount is little, and liquid is rotational flow in electric adsorption filter element, and resistance is larger.What is more important, in processing module, along with liquid-flow, charged particle in the liquid is constantly adsorbed by battery lead plate, and in other words, the charged particle concentration in the liquid constantly reduces, thereby cause battery lead plate adsorption efficiency degradation, need to keep reducing the spacing of adjacent electrode plates under the substantially constant prerequisite of liquid flow rate this moment, and above-mentioned patent can't be accomplished.
Summary of the invention
Technical problem to be solved in the utility model be provide for above-mentioned the deficiencies in the prior art that a kind of simple in structure, low cost of manufacture, energy consumption are low, the liquid treatment amount greatly, the electro-adsorption liquid cleaning device high to the charged particle clearance particularly.
Technical scheme to be solved in the utility model is: a kind of circulation type electro-adsorption liquid cleaning device, comprise the housing that is provided with liquid-inlet pipe, drain pipe, be provided with the circulation type electro-adsorption fluid purification assembly that comprises power distribution unit, plural battery lead plate and sealing coat in the housing, sealing coat is between two opposite polarity battery lead plates, and sealing coat is provided with fluid passage.It is characterized in that: battery lead plate and sealing coat are closed annular to be arranged, has liquid-inlet and liquid exit at battery lead plate.
Described housing has the structure of circulation type electro-adsorption assembly in the detachable shell, it comprises upper and lower bottom plate, side plate and ring-type shrouding, and above-mentioned upper and lower bottom plate, side plate, the ring-type shrouding form by bolt, nut, pad, sealing-ring is fixed and is tightly connected.
Described circulation type electro-adsorption fluid purification assembly is comprised of the plural battery lead plate that is the closed hoop layout and the sealing coat between the battery lead plate, battery lead plate can be that graphite, carbon nanotube or activated carbon fiber, granular carbon are made, between two electrode plate sealing coat is arranged, sealing coat is the netted or poroid plate that a large amount of fluid passages are arranged by the inside that insulating material is made.
Have for liquid flowing fluid import and liquid exit on each group battery lead plate (being formed by two electrode plate and a sealing coat) in the described circulation type electro-adsorption fluid purification assembly, and liquid-inlet and liquid exit are not all established gate, valve.
Between the liquid-inlet and liquid exit on each group battery lead plate (being formed by two electrode plate and a sealing coat) in the described circulation type electro-adsorption fluid purification assembly, be provided with the liquid barrier wall, the liquid barrier wall is made by the entity dielectric panel, its objective is and prevent that liquid is directly from the liquid-inlet crossfire to liquid exit, cause short circuit, without the loop between battery lead plate, thereby cause processing efficiency to descend.
Described battery lead plate, sealing coat are wrapped on the pipe core with closed annular, pipe core can be concentric circles, concentration ellipsis shape, also can be other closed hoop shapes, there be perforate the pipe core inboard, is connected with the fluid inlet (or liquid outlet) of innermost layer battery lead plate.
Described sealing coat is the poroid or reticular lamina that a large amount of fluid passages are arranged by the inside that insulating material is made, and especially is being provided with a large amount of through holes with the battery lead plate vertical direction, is leaving fluid passage with the battery lead plate parallel direction.
The spacing (thickness of sealing coat) of the battery lead plate in the described circulation type electro-adsorption fluid purification assembly is along with the liquid flow path direction diminishes.Fluid inlet on the battery lead plate after diminishing, liquid outlet adopt the mode of two or more than two co-located perforate, so that separating liquid, thereby keep the flow velocity of liquid between battery lead plate substantially constant.
Power distribution unit in the described circulation type electro-adsorption liquid cleaning device housing is that conducting plates is connected with battery lead plate by graphite film or corrosion resistant metal conducting plates, and the extension of conducting plates is connected with direct supply at housing external application plain conductor.Homopolarity battery lead plate in the housing can be connected in series by conducting plates, also can be connected in parallel by conducting plates.
Principle of work of the present utility model is: when direct supply is applied on the positive and negative electrode plate by conducting plates, pending liquid enters first group of sealing coat between battery lead plate by liquid-inlet pipe through the liquid-inlet of first group of battery lead plate, and mobile along the circular channel of (sealing coat) between battery lead plate, foreign ion in the liquid, charged particle move to the positive and negative electrode plate under the effect of electric field, and be stored in the electrostatic double layer of electrode plate surface, foreign ion, charged particle in the stoste are removed.Liquid by the sealing coat between second group of battery lead plate of liquid exit (both liquid-inlets of second group of battery lead plate) inflow of first group of battery lead plate, continues aforesaid scavenging process through all circulation.After purifying through N group battery lead plate, charged particle concentration obviously reduces in the liquid, the particle rate of adsorption is obviously slack-off, at this moment liquid enters N+1, N+2, the two channels electrode plate groups that the N+3 electrode plate forms, in this electrode plate groups, the battery lead plate spacing obviously diminishes, but because liquid flows from the mobile two channels (or hyperchannel) that becomes of single passage, the velocity of flow of liquid between battery lead plate can't be accelerated, reducing so that electro-adsorption efficient is improved of battery lead plate spacing, liquid continues to be purified between battery lead plate, and to the last one group of battery lead plate flows out the electro-adsorption module from liquid exit through drain pipe.When electro-adsorption module operation for some time, the electric charge that adsorbs on the positive-negative electrode plate is saturated or near after saturated, by pilot circuit direct supply is disconnected, the positive and negative electrode short circuit, while liquid influent valve closes, at this moment, because the disappearance of DC electric field and the formation of home loop, the ion and the charged particle that are stored in the electrode plate surface electrostatic double layer discharge in the liquid of getting back between battery lead plate, and this partially liq is discharged as dope, and electrode obtains regeneration.Behind the electrode regeneration, by pilot circuit positive-negative electrode plate apply and on opposite voltage of a cycle, the fluid purification process that can enter next cycle.
The utility model adopts the advantage after the technique scheme to be: 1, simple in structure.Use winding arrangement, can adopt flexible materials to make battery lead plate and sealing coat, avoided the electro-adsorption module pole plate of parallel-plate structure to make complexity, the problem that setting accuracy is had relatively high expectations, cost of manufacture is low.2, unique battery lead plate gap variable structure is so that electro-adsorption efficient improves the stoste lower to charged particle concentration particularly, good purification greatly.
Description of drawings
Fig. 1 is structural representation of the present utility model
Fig. 2 is the sectional view of Fig. 1
Fig. 3 is a kind of structural representation of the utility model sealing coat
Fig. 4 is the sectional view of Fig. 3
Embodiment
Embodiment is described in further detail the utility model below in conjunction with accompanying drawing, but the detailed description does not here consist of restriction of the present utility model.
Such as Fig. 1-shown in Figure 4, circulation type electro-adsorption liquid cleaning device of the present utility model comprises the housing that is provided with liquid-inlet pipe (10), drain pipe (11) and conducting plates (3), is provided with circulation type electro-adsorption fluid purification assembly in this housing.
Described housing comprises the structure with circulation type electro-adsorption assembly in the detachable shell, it comprises base plate (12), top board (13), side plate (8) and ring-type shrouding (9), and above-mentioned top board (13), base plate (12), side plate (8), ring-type shrouding (9) form by bolt, nut, pad, sealing-ring is fixed and is tightly connected.
Described circulation type electro-adsorption fluid purification assembly is comprised of the plural battery lead plate (1) that is the closed hoop layout and the sealing coat (2) between the battery lead plate, battery lead plate (1) can be that graphite, carbon nanotube or activated carbon fiber, granular carbon are made, and sealing coat (2) is arranged between two electrode plate.
Described battery lead plate (1), sealing coat (2) are wrapped on the pipe core (7) with closed annular, there is perforate pipe core (7) inboard, be connected with the fluid inlet (or liquid outlet) (4) of innermost layer battery lead plate, the top of pipe core (7) is connected with water inlet pipe (10).
Each group battery lead plate in the described circulation type electro-adsorption fluid purification assembly is comprised of two electrode plate (1) and a sealing coat (2), have for liquid flowing fluid import (4) and liquid exit (5) on the battery lead plate (1), and liquid-inlet (4) and liquid exit (5) are not all established gate, valve.
On the liquid-inlet (4) and the sealing coat (2) between the liquid exit (5) on each described group battery lead plate, be provided with liquid barrier wall (6), the liquid barrier wall is made by the entity dielectric panel.
Described sealing coat (2) is the poroid or reticular lamina that a large amount of fluid passages are arranged by the inside that insulating material is made, and especially is being provided with a large amount of through holes with battery lead plate (1) vertical direction, is leaving fluid passage with battery lead plate (1) parallel direction.Its structure formation is (Fig. 4 is the sectional view of Fig. 3) as shown in Figure 3: form numerous mesh (16) by two groups of interlaced horizontal ribs (14) and lengthways of rod (15), horizontal rib (14) and lengthways of rod (15) be not at same plane, thereby formation is parallel to the fluid passage of battery lead plate (1).
The thickness of the spacing of described battery lead plate (1) or sealing coat (2) is along with the liquid flow path direction diminishes.Fluid inlet on the battery lead plate after diminishing (4), liquid outlet (5) adopt the mode of two groups or more battery lead plate co-located perforate, so that separating liquid, thereby keep the flow velocity of liquid between battery lead plate substantially constant.
Power distribution unit in the described circulation type electro-adsorption fluid purification assembly housing, by graphite film or corrosion resistant metal conducting plates (3), conducting plates (3) is connected with battery lead plate (1), and the extension of conducting plates (3) is connected with direct supply at housing top board (13) external application plain conductor.Homopolarity battery lead plate in the housing can be connected in series by conducting plates (3), also can be connected in parallel by conducting plates (3).
Circulation type electro-adsorption liquid cleaning device of the present utility model can be processed water, wine, fruit juice, milk-product, medicine and the various chemical liquid in various sources.

Claims (10)

1. circulation type electro-adsorption liquid cleaning device, comprise the housing that is provided with liquid-inlet pipe, drain pipe, be provided with the circulation type electro-adsorption fluid purification assembly that comprises power distribution unit, plural battery lead plate and sealing coat in the housing, sealing coat is between two opposite polarity battery lead plates, sealing coat is provided with fluid passage, it is characterized in that: battery lead plate and sealing coat are closed annular to be arranged, has liquid-inlet and liquid exit at battery lead plate.
2. circulation type electro-adsorption liquid cleaning device as claimed in claim 1 is characterized in that: the center of circulation type electro-adsorption fluid purification assembly is provided with the pipe core that there is perforate circle or other closed annular inboards.
3. circulation type electro-adsorption liquid cleaning device as claimed in claim 1 is characterized in that: the pipe core inner top of circulation type electro-adsorption fluid purification assembly or bottom are connected with liquid-inlet pipe or drain pipe on the housing.
4. circulation type electro-adsorption liquid cleaning device as claimed in claim 1, it is characterized in that: battery lead plate and sealing coat are arranged in outside the pipe core with canoe.
5. circulation type electro-adsorption liquid cleaning device as claimed in claim 1, it is characterized in that: battery lead plate is provided with liquid-inlet and liquid exit.
6. circulation type electro-adsorption liquid cleaning device as claimed in claim 1, it is characterized in that: sealing coat is the poroid or reticular lamina of being made by insulating material, is being provided with a large amount of through holes with the battery lead plate vertical direction, is leaving fluid passage with the battery lead plate parallel direction.
7. circulation type electro-adsorption liquid cleaning device as claimed in claim 1 is characterized in that: the spacing of battery lead plate is that the thickness of sealing coat is along with the liquid flow path direction diminishes.
8. circulation type electro-adsorption liquid cleaning device as claimed in claim 1 is characterized in that: the spacing of battery lead plate is the liquid-inlet on the battery lead plate after the less thick of sealing coat, the mode that liquid exit adopts two above co-located perforates.
9. circulation type electro-adsorption liquid cleaning device as claimed in claim 1, it is characterized in that: the liquid-inlet on the battery lead plate and the sealing coat place between the liquid exit are provided with the liquid barrier wall.
10. circulation type electro-adsorption liquid cleaning device as claimed in claim 1 is characterized in that: the liquid barrier wall is made by the solid material of insulation.
CN 201220157300 2012-04-16 2012-04-16 Circulating type electro-adsorption liquid purifying device Expired - Fee Related CN202808446U (en)

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Application Number Priority Date Filing Date Title
CN 201220157300 CN202808446U (en) 2012-04-16 2012-04-16 Circulating type electro-adsorption liquid purifying device

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104229951A (en) * 2014-09-12 2014-12-24 陈昱如 Concentric ring type electro-adsorption water treatment technology
CN105731610A (en) * 2014-12-24 2016-07-06 伊德罗帕德尔园林清洗有限公司 Apparatus for purifying a fluid and method for the attainment thereof
CN106335973A (en) * 2016-11-04 2017-01-18 中海油天津化工研究设计院有限公司 Stepped low-pressure electrochemical assisted polymer-bearing wastewater demulsification treatment process method
CN111517430A (en) * 2020-05-14 2020-08-11 逸辰环保科技(厦门)有限公司 Electro-adsorption equipment, system and process for controlling salt discharge of wastewater

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104229951A (en) * 2014-09-12 2014-12-24 陈昱如 Concentric ring type electro-adsorption water treatment technology
CN105731610A (en) * 2014-12-24 2016-07-06 伊德罗帕德尔园林清洗有限公司 Apparatus for purifying a fluid and method for the attainment thereof
CN105731610B (en) * 2014-12-24 2021-04-20 伊德罗帕德尔园林清洗有限公司 Fluid purification device and implementation method thereof
CN106335973A (en) * 2016-11-04 2017-01-18 中海油天津化工研究设计院有限公司 Stepped low-pressure electrochemical assisted polymer-bearing wastewater demulsification treatment process method
CN106335973B (en) * 2016-11-04 2019-05-28 中海油天津化工研究设计院有限公司 A kind of auxiliary demulsification processing of ladder low pressure electrochemistry contains poly- waster water process method
CN111517430A (en) * 2020-05-14 2020-08-11 逸辰环保科技(厦门)有限公司 Electro-adsorption equipment, system and process for controlling salt discharge of wastewater
CN111517430B (en) * 2020-05-14 2022-04-15 逸辰环保科技(厦门)有限公司 Electro-adsorption equipment, system and process for controlling salt discharge of wastewater

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CF01 Termination of patent right due to non-payment of annual fee
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Granted publication date: 20130320

Termination date: 20160416