CN105947988B - The ozone generating-device of power adjustable occurs for ozone - Google Patents

The ozone generating-device of power adjustable occurs for ozone Download PDF

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Publication number
CN105947988B
CN105947988B CN201610276964.8A CN201610276964A CN105947988B CN 105947988 B CN105947988 B CN 105947988B CN 201610276964 A CN201610276964 A CN 201610276964A CN 105947988 B CN105947988 B CN 105947988B
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electric capacity
resistance
circuit
voltage stabilizing
chip microcomputer
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CN105947988A (en
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韩文智
光育芳
吕宝鹏
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Shanxi Dongyuan Huarui Ecological Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/10Preparation of ozone
    • C01B13/11Preparation of ozone by electric discharge
    • C01B13/115Preparation of ozone by electric discharge characterised by the electrical circuits producing the electrical discharge
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B20/00Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
    • Y02B20/30Semiconductor lamps, e.g. solid state lamps [SSL] light emitting diodes [LED] or organic LED [OLED]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

The invention belongs to the technical field of ozone generating-device;The technical problem of solution is:A kind of small volume, lighter in weight are provided, are easy to carry about with one, service time of battery controllable type ozone generating-device that is longer, and ozone generation power being adjusted;The technical scheme used for:The ozone generating-device of power adjustable, including concentration control apparatus and ozone generator occur for ozone, and concentration adjusting device includes housing and is arranged on the circuit board of enclosure interior, and circuit board includes:DC power voltage stabilizing circuit, PWM oscillating circuits, boosting transforming circuit, control protection electric circuit and display circuit; control protection electric circuit is connected with PWM oscillating circuits and display circuit respectively; DC power voltage stabilizing circuit is connected with boosting transforming circuit and PWM oscillating circuits respectively; boosting transforming circuit is connected with ozone generator, and air inlet pipe and escape pipe are provided with ozone generator;Display screen, alarm buzzer, powered controls and signal output interface are provided with the housing of concentration adjusting device.

Description

The ozone generating-device of power adjustable occurs for ozone
Technical field
The ozone generating-device of power adjustable occurs for ozone of the present invention, belongs to the technical field of ozone generating-device.
Background technology
Ozone is a kind of gas of colourless slightly stink, will turn into a kind of strong oxidizer after being dissolved in water, have to living cells Stronger killing action, by ozone generator can by the oxygen in air high pressure, high-frequency electrical ionization under be converted into Ozone, and then be used in production.
In agriculture sterilization field, ozone can realize that one applies multi-purpose, while prevent and treat a variety of disease pests, and expenses for prevention and control is low, with Spraying pesticide is compared, and release ozone is more convenient, efficient, safe, can greatly reduce the usage amount of agricultural chemicals, avoids vegetable grower from applying high Poison, persistent pesticide, so as to reduce drug cost;Nuisanceless and ozone is unstable in dry air, can decompose quickly also Originally it was oxygen, therefore pollution-free, noresidue in plant and in fruit, it is an important way for realizing pollution-free vegetable production Footpath.
With the popularization and application of domestic ozone air sterillization product, the development to whole ozone industry serves huge push away The appearance of the enterprise of action use, some production ozone generators and Related product like the mushrooms after rain, middle-size and small-size ozone generator And air sterillization product is also gradually improved in technology and performance;But there is also some problems for existing ozone generator;
Such as:Existing 220V alternating currents turn the ozone generating-device of high voltagehigh frequency alternating current, not only application scenarios it is narrow, it is necessary to Possess AC power, it is not portable, and security risk is high, and regulation device to power output without display, can not carry out accurately Ozone regulates and controls;In addition, existing 12V DC turns the ozone generating-device of high voltagehigh frequency alternating current, switch in 12V DC electricity thousands of During the high voltagehigh frequency alternating current of volt, without reliable and stable regulation device, usage time is of short duration, and power-efficient is low;Together When to realize miniaturization, in light weight, portable, safe and reliable, existing product does not overcome successfully because technical difficulty is high.
Due to different to the tolerance of ozone in growing process, concentration is too low not to be reached sterilization and goes out evil effect, concentration In itself, therefore, the ozone generating-device that power adjustable occurs for ozone is just particularly important too high then easy injury plant.
The content of the invention
The present invention overcomes the shortcomings of the prior art, and technical problem to be solved is:A kind of small volume, again is provided Amount is relatively light, be easy to carry about with one, service time of battery is longer, and the controllable type ozone that power is adjusted can occur to ozone and fill Put.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is:The ozone hair of power adjustable occurs for ozone Generating apparatus, including concentration control apparatus and ozone generator, the concentration adjusting device include housing and are arranged on enclosure interior Circuit board, the circuit board includes:DC power voltage stabilizing circuit, PWM oscillating circuits, boosting transforming circuit, control protection electricity Road and display circuit, the control protection electric circuit are connected with PWM oscillating circuits and display circuit respectively, the DC power voltage stabilizing Circuit is connected with the boosting transforming circuit and PWM oscillating circuits respectively, and the boosting transforming circuit is connected with ozone generator, Air inlet pipe and escape pipe are provided with the ozone generator;Display screen, report are provided with the housing of the concentration adjusting device Alert buzzer, powered controls, signal output interface, power supply indicator, the display screen are connected with display circuit, the report Alert buzzer is connected with control protection electric circuit, the power supply indicator and DC power voltage stabilizing circuit, the powered controls It is connected with PWM oscillating circuits, the ozone generator is connected by signal output interface with boosting transforming circuit.
Preferably, the structure of the DC power voltage stabilizing circuit is:Including fuse F1, one end of the fuse F1 with DC supply input interface is connected, the other end of the fuse F1 and resistance R1 one end, resistance R4 one end, electric capacity C1 One end, electric capacity C2 one end, the power output end A2 of DC power voltage stabilizing circuit are connected, the other end and electric capacity of the resistance R1 C3 one end, triode Q1 colelctor electrode, triode Q3 colelctor electrode are connected, emitter stage and the triode Q2 of the triode Q1 Colelctor electrode, resistance R2 one end, boost transforming circuit control signal input GATE1 be connected, the base of the triode Q1 Pole is connected with triode Q2 base stage, the output end PWM1 of PWM oscillating circuits, emitter stage and the triode Q4 of the triode Q3 Colelctor electrode, resistance R3 one end, boost transforming circuit control signal input GATE2 be connected, the base of the triode Q3 Pole is connected with triode Q4 base stage, the output end PWM2 of PWM oscillating circuits, the other end and light emitting diode of the resistance R4 LED1 positive pole is connected, the other end, the electric capacity C1 other end, the electric capacity C2 other end, the electric capacity of the LED 1 The C3 other end, triode Q2 colelctor electrode, the resistance R2 other end, triode Q4 colelctor electrode, resistance R3 the other end with The DC supply input interface H1 other end is grounded after being connected;The structure of the DC power voltage stabilizing circuit also includes fuse F2, fuse F3, one end of the fuse F2 and fuse F3 one end, the power output end A2 of DC power voltage stabilizing circuit It is connected, the 12V voltage output ends A0 of the other end of the fuse F2 and the DC power voltage stabilizing circuit, the one of electric capacity C5 End, electric capacity C6 one end, voltage stabilizing chip U1 input IN are connected, the output end OUT's and inductance L1 of the voltage stabilizing chip U1 One end, diode D1 negative pole are connected, the other end of the inductance L1 and voltage stabilizing chip U1 feedback end BACK, the one of electric capacity C7 End, electric capacity C8 one end, the 5V voltage output ends A1 of the DC power voltage stabilizing circuit are connected, the other end of the electric capacity C5, The electric capacity C6 other end, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 earth terminal GND, diode D1 positive pole, electric capacity The C7 other end, the electric capacity C8 other end is grounded;The other end of the fuse F3 and electric capacity C51 one end, voltage stabilizing chip U1 input IN is connected, the output end OUT and diode D51 of the voltage stabilizing chip U1 negative pole, diode D52 negative pole, Inductance L1 one end is connected, the other end and resistance R53 one end, electric capacity C52 one end, the one of electric capacity C53 of the inductance L2 End, electric capacity C54 one end, resistance R54 one end, the 9V voltage output ends A3 of the DC power voltage stabilizing circuit are connected, described After resistance R53 other end series resistor R52 with the electric capacity C52 other end, resistance R51 one end, voltage stabilizing chip U1 feedback End BACK is connected, the other end of resistance R51 ground connection, after the other end concatenation LED 2 of the resistance R54 with The electric capacity C53 other end, the electric capacity C54 other end, diode D51 positive pole, diode D52 positive pole, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 earth terminal GND, the electric capacity C51 other end are grounded after connecting;The electricity of the boosting transforming circuit Line structure is:Including FET FET1, the control signal of the grid and boosting transforming circuit of the FET FET1 inputs End GATE1 is connected, the drain electrode of the FET FET1 and resistance R5 one end, the input positive terminal phase of transformer T1 low-pressure sides Even, the other end of the resistance R5 is sequentially connected in series drain electrode after resistance R6, electric capacity C4 with FET FET2, transformer T1 low pressure The input negative terminal of side is connected, and the source electrode of the FET FET1 is grounded after being connected with FET FET2 source electrode, the change The tap terminals of depressor low-pressure side are connected with the power output end A2 of DC power voltage stabilizing circuit, and the high-pressure side of the transformer T1 is defeated Go out end with ozone generator to be connected.
Preferably, the circuit structure of the PWM oscillating circuits is:Including single-chip microcomputer IC1, the error of the single-chip microcomputer IC1 After amplifier input Noninv series resistors R11 in the same direction with electric capacity C11 one end, the interface H2, described of powered controls The output end CTR of PWM oscillating circuits is connected, and the one of the oscillator timing capacitor incoming end CT and resistance R12 of the single-chip microcomputer IC1 End, electric capacity C12 one end are connected, and the other end of the resistance R12 is connected with single-chip microcomputer IC1 oscillator discharge end Dis, described It is connected after single-chip microcomputer IC1 oscillator timing resistor incoming end RT series resistors R13 with slide rheostat R0 one end, the list Piece machine IC1 soft start capacitor incoming end So-sta is connected with electric capacity C13 one end, the error amplifier of the single-chip microcomputer IC1 After reverse input end Inv series resistors R14 with single-chip microcomputer IC1 PWM comparator thermal compensation signal inputs Com, electric capacity C14 one End is connected, external interrupt signal input Shut and electric capacity C15 one end, resistance R15 one end, the electricity of the single-chip microcomputer IC1 Resistance R16 one end is connected, the external interrupt signal input PRO phases of the other end of the resistance R16 and the PWM oscillating circuits Even, the reference power supply output end of the single-chip microcomputer IC1 and resistance R17 one end, resistance R18 one end, electric capacity C16 one end, The output end VREF of the PWM oscillating circuits is connected, the output end of the other end of the resistance R17 and the PWM oscillating circuits TEMP, electric capacity C18 one end, switch S1 one end are connected, the other end of the resistance R18 and connecing for the powered controls Mouth H2 is connected, the other end and electric capacity C17 one end, the electric capacity C18 other end, resistance R19 one end, the list of the electric capacity C16 It is grounded after piece machine IC1 earth terminal GND connections, the other end of the electric capacity C17 and single-chip microcomputer IC1 bias supply input Vcc, single-chip microcomputer IC1 output stage biased voltage input end Vc connections after power output end with the DC power voltage stabilizing circuit A2 is connected, and the other end of the resistance R19 is connected with the other end for the S1 that opens the light, the output end OUT1 of the single-chip microcomputer IC1, output The output end PWM1 with the PWM oscillating circuits, output end PWM2's end OUT2 are connected respectively, the powered controls Interface H2 is connected with resistance R110 one end, the other end of the resistance R110, the electric capacity C11 other end, electric capacity C12 it is another One end, slide rheostat R0 glissile segment, the slide rheostat R0 other end, the electric capacity C13 other end, electric capacity C14 it is another End, the electric capacity C151 other end, the resistance R15 other end are grounded.
Preferably, the circuit structure of the control protection electric circuit is:Including single-chip microcomputer IC2, the ADC1 of the single-chip microcomputer IC2 Input channel P1.0 is connected with resistance R21 one end, electric capacity C21 one end, the other end and the PWM vibration electricity of the resistance R21 The output end CTR on road is connected, the other end ground connection of the electric capacity C21, ADC2 input channels P1.1 and the electricity of the single-chip microcomputer IC2 Resistance R22 one end, resistance R23 one end, electric capacity C22 one end are connected, and the other end and the PWM of the resistance R22 vibrate The output end TEMP of circuit is connected, the other end of the resistance R23, one end of the electric capacity C22 other end and resistance R24, electric capacity It is grounded after C23 one end connection, the other end and resistance R25 one end, the electric capacity C23 other end, the single-chip microcomputer of the resistance R24 IC2 ADC3 input channels P1.2 is connected, the 12V voltages of the other end of the resistance R25 and the DC power voltage stabilizing circuit Output terminals A 0 is connected, the external interrupt output end P3.3 of the single-chip microcomputer IC2 and the PWM oscillating circuits external interrupt signal Input PRO is connected;The positive source VCC of the single-chip microcomputer IC2 and 5V voltage output ends A1, the electricity of DC power voltage stabilizing circuit The one end for holding C24 is connected, and the other end of the electric capacity C24 is grounded after being connected with single-chip microcomputer IC2 earth terminal GND;The monolithic It is connected after machine IC2 data output end P1.3 series resistors R26 with triode Q21 base stage, the colelctor electrode of the triode Q21 It is connected after series resistor R27 with the power cathode of alarm buzzer, the positive source and dc source of the alarm buzzer are steady The 5V voltage output ends A1 of volt circuit is connected, the grounded emitter of the triode Q21;The output end of the single-chip microcomputer IC2 P1.5, output end P1.6, output end P1.7 the serial data input SI with the display circuit, storage register clock respectively Input RCK, shift register clock input SCK are connected;It is the output end P3.4 of the single-chip microcomputer IC2, output end P3.5, defeated Go out to hold the input end of clock COM4, input end of clock COM3, input end of clock of P3.6, output end P3.7 respectively with display circuit COM2, input end of clock COM1 are connected.
Preferably, the circuit structure of the control protection electric circuit also includes:The external interface J1 of downloading, it is described it is external under The positive source for carrying routine interface J1 is connected with the 5V voltage output ends A1 of DC power voltage stabilizing circuit, described external to download The data output end P3.1 with single-chip microcomputer IC2, data output end P3.0 connect interface J1 the first data terminal, the second data segment respectively Connect, the earth terminal ground connection of the external interface J1 that downloads;The model LM2596 of the voltage stabilizing chip U1, the fuse F1, fuse F2 model are FRU600, and the FET FET1, FET FET2 model are Irf4468;Institute Single-chip microcomputer IC1 model KA3525A, the single-chip microcomputer IC2 model STC15F204EA are stated, the display screen shows for LED Display screen, the powered controls are power control knob.
The present invention has the advantages that compared with prior art:
1st, the exportable adjustable rectangular wave pulse of rectangle output duty cycle of PWM oscillating circuits in the present invention, passes through rotation Powered controls, output impulse wave that can be to PWM oscillating circuits is adjusted, in use, passing through the ripple to PWM oscillating circuits The control of shape and dutycycle, and then DC power voltage stabilizing circuit effective output percentage is controlled, and then to boosting The high-voltage ac power reality output efficiency of transforming circuit is controlled, and is eventually formed to ozone formation speed in ozone generator Effective control, described ozone generator is after electrion so that is converted to ozone by the air inputted in its air inlet pipe Gas exports from escape pipe;The present invention solves low-voltage DC and turns ozone in the ozone generating-device of high voltagehigh frequency alternating current The controllable problem of gasification speed, there is the advantages of in light weight, portable, safe and reliable, practicality is extremely strong.
2nd, the present invention in control protection electric circuit, for concentration adjusting device occur over-pressed, under-voltage and excess temperature when, PWM oscillating circuits are automatically cut off, realize corresponding safeguard measure, prevent failure from continuing expansion and the generation of potential safety hazard;Meanwhile When faulty generation, the alarm buzzer being arranged on housing can be piped, and prompt that user is faulty needs to shut down Maintenance, failure cause to be found out simultaneously excludes post-fault system and will continue normal operation, safe.
3rd, the present invention, can be convenient to use with real-time display ozone generator power percentage by display circuit and display screen Realtime power occurs for the ozone that family understands during use in time, effectively avoids because ozone concentration is too high or too low to farming Injury caused by thing.
Brief description of the drawings
The present invention will be further described in detail below in conjunction with the accompanying drawings.
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the electrical block diagram of concentration control apparatus in the present invention;
Fig. 3 is the circuit theory diagrams of DC power voltage stabilizing circuit and boosting transforming circuit in the present invention;
Fig. 4 is the circuit theory diagrams of PWM oscillating circuits in the present invention;
Fig. 5 is the circuit theory diagrams of control protection electric circuit in the present invention;
Fig. 6 is the circuit theory diagrams of display circuit in the present invention;
In figure:1 is concentration control apparatus, and 2 be ozone generator, and 3 be power supply indicator, and 4 be DC power voltage stabilizing circuit, 5 be PWM oscillating circuits, and 6 be boosting transforming circuit, and 7 be control protection electric circuit, and 8 be display circuit, and 9 be display screen, and 10 be alarm Buzzer, 11 be powered controls, and 12 be signal output interface.
Embodiment
As shown in Figures 1 to 6, the ozone generating-device of power adjustable, including concentration control apparatus 1 and ozone occur for ozone Generator 2, the concentration adjusting device 1 include housing and are arranged on the circuit board of enclosure interior, and the circuit board includes:Direct current Power supply stabilization circuit 4, PWM oscillating circuits 5, boosting transforming circuit 6, control protection electric circuit 7 and display circuit 8, the control are protected Protection circuit 7 is connected with PWM oscillating circuits 5 and display circuit 8 respectively, the DC power voltage stabilizing circuit 4 respectively with the boosting Transforming circuit 6 is connected with PWM oscillating circuits 5, and the boosting transforming circuit 6 is connected with ozone generator 2, the ozone generator Air inlet pipe and escape pipe are provided with 2;Be provided with the housing of the concentration adjusting device 1 display screen 9, alarm buzzer 10, Powered controls 11, signal output interface 12, power supply indicator 3, the display screen 9 are connected with display circuit 8, the alarm Buzzer 10 is connected with control protection electric circuit 7, the power supply indicator 3 and DC power voltage stabilizing circuit 4, the Power Control machine Structure 11 is connected with PWM oscillating circuits 5, and the ozone generator 2 is connected by signal output interface 12 with boosting transforming circuit 6.
The exportable adjustable rectangular wave pulse of rectangle output duty cycle of PWM oscillating circuits 5 in the present invention, passes through rotational work Rate controlling organization 11, output impulse wave that can be to PWM oscillating circuits 5 are adjusted, in use, by PWM oscillating circuits 5 The control of waveform and dutycycle, and then the effective output percentage of DC power voltage stabilizing circuit 4 is controlled, and then to rising The high-voltage ac power reality output efficiency of buckling volt circuit 6 is controlled, and eventually forms and ozone in ozone generator 2 is generated Effective control of speed, described ozone generator is after electrion so that by the air or oxygen inputted in its air inlet pipe The gas containing ozone is converted to export from escape pipe;The present invention solves low-voltage DC and turns the smelly of high voltagehigh frequency alternating current The controllable problem of speed occurs for ozone gas in oxygengenerating plant, has the advantages of in light weight, portable, safe and reliable.
In the present embodiment, as shown in figure 3, the structure of the DC power voltage stabilizing circuit 4 is:It is described including fuse F1 Fuse F1 one end is connected with DC supply input interface, the other end of the fuse F1 and resistance R1 one end, resistance R4 one end, electric capacity C1 one end, electric capacity C2 one end, the power output end A2 of DC power voltage stabilizing circuit 4 are connected, the electricity The resistance R1 other end is connected with electric capacity C3 one end, triode Q1 colelctor electrode, triode Q3 colelctor electrode, the triode Q1 Emitter stage and triode Q2 colelctor electrode, resistance R2 one end, the control signal input GATE1 phases for the transforming circuit 6 that boosts Even, the base stage of the triode Q1 is connected with the output end PWM1 of triode Q2 base stage, PWM oscillating circuits 5, the triode Q3 emitter stage and triode Q4 colelctor electrode, resistance R3 one end, the control signal input GATE2 for the transforming circuit 6 that boosts It is connected, the base stage of the triode Q3 is connected with the output end PWM2 of triode Q4 base stage, PWM oscillating circuits 5, the resistance The R4 other end is connected with the positive pole of LED 1, the other end of the LED 1, electric capacity C1 it is another End, the electric capacity C2 other end, the electric capacity C3 other end, triode Q2 colelctor electrode, the resistance R2 other end, triode Q4 collection Electrode, the resistance R3 other end are grounded after being connected with the DC supply input interface H1 other end;The DC power voltage stabilizing electricity The structure on road 4 also includes fuse F2, fuse F3, one end of the fuse F2 and fuse F3 one end, dc source The power output end A2 of mu balanced circuit 4 is connected, the 12V of the other end of the fuse F2 and the DC power voltage stabilizing circuit 4 Voltage output end A0, electric capacity C5 one end, electric capacity C6 one end, voltage stabilizing chip U1 input IN are connected, the voltage stabilizing chip U1 output end OUT and inductance L1 one end, diode D1 negative pole are connected, the other end and the voltage stabilizing chip U1 of the inductance L1 Feedback end BACK, electric capacity C7 one end, electric capacity C8 one end, the 5V voltage output ends A1 of the DC power voltage stabilizing circuit 4 It is connected, the other end of the electric capacity C5, the electric capacity C6 other end, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 ground connection End GND, diode D1 positive pole, the electric capacity C7 other end, the electric capacity C8 other end are grounded;The other end of the fuse F3 The input IN of one end, voltage stabilizing chip U1 with electric capacity C51 is connected, the output end OUT and diode D51 of the voltage stabilizing chip U1 Negative pole, diode D52 negative pole, inductance L1 one end be connected, the other end of the inductance L2 and resistance R53 one end, electricity Hold C52 one end, electric capacity C53 one end, electric capacity C54 one end, resistance R54 one end, the DC power voltage stabilizing circuit 4 9V voltage output ends A3 is connected, the other end, resistance R51 after the other end series resistor R52 of the resistance R53 with electric capacity C52 One end, voltage stabilizing chip U1 feedback end BACK be connected, the other end of resistance R51 ground connection, the other end of the resistance R54 Concatenate LED 2 after with the electric capacity C53 other end, the electric capacity C54 other end, diode D51 positive pole, diode The other end connection of D52 positive pole, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 earth terminal GND, electric capacity C51 is followed by Ground;Fuse F1 in the DC power voltage stabilizing circuit 4 plays a part of current protection, and electric capacity C1, electric capacity C2 are filtered electrical Hold, resistance R1 is back flow protection resistance, and triode Q1 to triode Q4 is increase driving oscillation circuit.
It is described boosting transforming circuit 6 circuit structure be:Including FET FET1, the grid of the FET FET1 It is connected with the control signal input GATE1 for the transforming circuit 6 that boosts, the drain electrode of the FET FET1 and the one of resistance R5 End, the input positive terminal of transformer T1 low-pressure sides are connected, and the other end of the resistance R5 is sequentially connected in series after resistance R6, electric capacity C4 and field Effect pipe FET2 drain electrode, the input negative terminal of transformer T1 low-pressure sides are connected, the source electrode of the FET FET1 and field-effect Pipe FET2 source electrode is grounded after being connected, and the tap terminals of the step down side export with the power supply of DC power voltage stabilizing circuit 4 End A2 is connected, and the high-pressure side output end of the transformer T1 is connected with ozone generator 2;Boosting transforming circuit 6 in the present invention Conversion of the low pressure to high pressure can be achieved.12v DC voltages are converted to 2000 to 7000V high tension voltage;Described boosting becomes Volt circuit 6 also has the function that protection FET and current reflux absorb, and described High voltage output voltage can be according to different Ozone generator is adjusted voltage parameter, in addition, the transformer T1 in the present invention is designed using high pressure dedicated transformer, and adopts Made of strong electric isolation type technique.
Wherein, the model LM2596 of the voltage stabilizing chip U1, the fuse F1, fuse F2 model are FRU600, the FET FET1, FET FET2 model are Irf4468, described Irf4468 high power tubes FET carrying load ability is powerful, and implementation result is good.
Specifically, as shown in figure 4, the PWM oscillating circuits 5 can realize generation concussion, control concussion waveform, and have and adjust The function for source power dutycycle of economizing on electricity, its circuit structure are:Single-chip microcomputer IC1 including model KA3525A, the single-chip microcomputer After IC1 error amplifier input Noninv series resistors R11 in the same direction with electric capacity C11 one end, powered controls 11 Interface H2, the output end CTR of the PWM oscillating circuits 5 are connected, the oscillator timing capacitor incoming end CT of the single-chip microcomputer IC1 One end, electric capacity C12 one end with resistance R12 are connected, the other end of the resistance R12 and single-chip microcomputer IC1 oscillator discharge End Dis is connected, with slide rheostat R0's after the oscillator timing resistor incoming end RT series resistors R13 of the single-chip microcomputer IC1 One end is connected, and the soft start capacitor incoming end So-sta of the single-chip microcomputer IC1 is connected with electric capacity C13 one end, the single-chip microcomputer PWM comparator thermal compensation signal inputs after IC1 error amplifier reverse input end Inv series resistors R14 with single-chip microcomputer IC1 Com, electric capacity C14 one end are connected, the external interrupt signal input Shut and electric capacity C15 of the single-chip microcomputer IC1 one end, electricity Resistance R15 one end, resistance R16 one end is connected, the external interrupt of the other end of the resistance R16 and the PWM oscillating circuits 5 Signal input part PRO is connected, the reference power supply output end of the single-chip microcomputer IC1 and resistance R17 one end, resistance R18 one end, Electric capacity C16 one end, the output end VREF of the PWM oscillating circuits 5 are connected, and the other end and the PWM of the resistance R17 shake Swing the output end TEMP of circuit 5, electric capacity C18 one end, one end for switching S1 are connected, the other end of the resistance R18 with it is described The interface H2 of powered controls 11 is connected, the other end of the electric capacity C16 and electric capacity C17 one end, electric capacity C18 it is another End, resistance R19 one end, single-chip microcomputer IC1 earth terminal GND connections after be grounded, the other end and single-chip microcomputer of the electric capacity C17 After IC1 bias supply input Vcc, single-chip microcomputer IC1 output stage biased voltage input end Vc connections with the dc source The power output end A2 of mu balanced circuit 4 is connected, and the other end of the resistance R19 is connected with the other end for the S1 that opens the light, the monolithic Machine IC1 output end OUT1, output end OUT2 the output end PWM1 with the PWM oscillating circuits 5, output end PWM2 phases respectively Even, the interface H2 of the powered controls 11 is connected with resistance R110 one end, the other end of the resistance R110, The electric capacity C11 other end, the electric capacity C12 other end, slide rheostat R0 glissile segment, slide rheostat the R0 other end, electricity Hold the C13 other end, the electric capacity C14 other end, the electric capacity C151 other end, the resistance R15 other end to be grounded.
Further, as shown in figure 5, the control protection electric circuit 7 has monitoring main power voltage, electric current, monitoring line Road plate environment temperature, the effect for realizing circuit protection, if internal temperature is too high, excess temperature control being carried out, control circuit works, Equipment is integrally closed, and is prevented the too high burning apparatus of temperature, is realized self-protection;Its circuit structure is:Including model STC15F204EA single-chip microcomputer IC2, the single-chip microcomputer IC2 ADC1 input channels P1.0 and resistance R21 one end, electric capacity C21 One end be connected, the other end of the resistance R21 is connected with the output end CTR of PWM oscillating circuits 5, and the electric capacity C21's is another End ground connection, the ADC2 input channels P1.1 of the single-chip microcomputer IC2 and resistance R22 one end, resistance R23 one end, electric capacity C22 One end is connected, and the other end of the resistance R22 is connected with the output end TEMP of the PWM oscillating circuits 5, the resistance R23's The other end, the electric capacity C22 other end are grounded after being connected with resistance R24 one end, electric capacity C23 one end, and the resistance R24's is another One end is connected with resistance R25 one end, the electric capacity C23 other end, single-chip microcomputer IC2 ADC3 input channels P1.2, the resistance The R25 other end is connected with the 12V voltage output ends A0 of the DC power voltage stabilizing circuit 4, in the outside of the single-chip microcomputer IC2 Disconnected output end P3.3 is connected with the external interrupt signal input PRO of the PWM oscillating circuits 5;The power supply of the single-chip microcomputer IC2 Positive pole VCC is connected with the 5V voltage output ends A1 of DC power voltage stabilizing circuit 4, electric capacity C24 one end, and the electric capacity C24's is another One end is grounded after being connected with single-chip microcomputer IC2 earth terminal GND;The data output end P1.3 series resistors R26 of the single-chip microcomputer IC2 The base stage with triode Q21 is connected afterwards, the electricity after the collector series connection resistance R27 of the triode Q21 with alarm buzzer 10 Source negative pole is connected, and the positive source of the alarm buzzer 10 is connected with the 5V voltage output ends A1 of DC power voltage stabilizing circuit 4, The grounded emitter of the triode Q21;The output end P1.5 of the single-chip microcomputer IC2, output end P1.6, output end P1.7 difference Serial data input SI, storage register input end of clock RCK, shift register clock input with the display circuit 8 End SCK is connected;The output end P3.4 of the single-chip microcomputer IC2, output end P3.5, output end P3.6, output end P3.7 respectively with it is aobvious Show that input end of clock COM4, input end of clock COM3, input end of clock COM2, the input end of clock COM1 of circuit 8 are connected.
In addition, the circuit structure of the control protection electric circuit 7 also includes:The external interface J1 of downloading, it is described it is external under The positive source for carrying routine interface J1 is connected with the 5V voltage output ends A1 of DC power voltage stabilizing circuit 4, the external download journey Sequence interface J1 the first data terminal, the second data segment the data output end P3.1 with single-chip microcomputer IC2, data output end P3.0 respectively Connection, the earth terminal ground connection of the external interface J1 that downloads;Described control protection electric circuit 7, filled for being adjusted in concentration When putting over-pressed 1 generation, under-voltage and excess temperature, PWM oscillating circuits 5 are automatically cut off, realize that corresponding safeguard measure prevents failure from continuing Expansion and the generation of potential safety hazard;Meanwhile when faulty generation control protection electric circuit 7 works, the report that is arranged on housing Alert buzzer 10 can be piped, and prompt that user is faulty to need maintenance down, and failure cause to be found out simultaneously is fixed a breakdown System will continue normal operation afterwards, safe.
As shown in fig. 6, the display screen 9 is LED display, the circuit structure of the display circuit 8 is:Including:LED drives Dynamic chip U2, charactron LED1 and charactron LED2, the LED drive chip U2 ternary output end Q0 ~ Q7 concatenate one respectively It is connected after individual resistance with charactron LED1, charactron LED2, the VCC power ends and LED drive chip of the LED drive chip U2 It is connected after U2 reset terminal connection with the 5V voltage output ends A1 of DC power voltage stabilizing circuit 4, the LED drive chip U2's is defeated Go out after data live end is connected with LED drive chip U2 earth terminal and be grounded, the serial date transfer of the LED drive chip U2 Hold SI, LED drive chip U2 storage register input end of clock RCK, LED drive chip U2 shift register clock input Hold SCK the output end P1.5 with single-chip microcomputer IC2, single-chip microcomputer IC2 output end P1.6, single-chip microcomputer IC2 output end P1.7 respectively It is connected;The output end P3.4 of the single-chip microcomputer IC2, output end P3.5, output end P3.6, output end P3.7 respectively with charactron LED2 input end of clock COM4, charactron LED2 input end of clock COM3, charactron LED1 input end of clock COM2, number Code pipe LED1 input end of clock COM1 is connected, with three after the input end of clock COM1 series resistors R41 of the charactron LED1 Pole pipe Q41 base stage is connected, the emitter stage of the triode Q41 and triode Q42 emitter stage, triode Q43 emitter stage, Triode Q44 emitter stage is grounded after being connected, the colelctor electrode of the triode Q41 and charactron LED1 signal input part dig1 It is connected;The colelctor electrode of the triode Q42 is connected with charactron LED1 signal input part dig2, the collection of the triode Q43 Electrode is connected with charactron LED2 signal input part dig1, the colelctor electrode of the triode Q44 and charactron LED2 signal Input dig2 is connected;After the base stage series resistor R42 of the triode Q42 with charactron LED1 input end of clock COM2 phases Even, it is connected after the base stage series resistor R43 of the triode Q43 with charactron LED2 input end of clock COM3, three pole It is connected after pipe Q44 base stage series resistor R44 with charactron LED2 input end of clock COM4;Specifically, the charactron LED1 and charactron LED2 model can be LED-WDP228, the model 74HC595 of the LED drive chip U2.
In the present embodiment, ternary output end Q0 ~ Q7 of the LED drive chip U2 concatenate respectively after a resistance with number Pipe LED1, charactron LED2 connected particular circuit configurations are:The ternary output end Q0 series resistors of the LED drive chip U2 It is connected with the input QA0 of the charactron LED1, charactron LED2 input QA0 after R30, the LED drive chip After U2 ternary output end Q1 series resistors R31 with the input QA1 of the charactron LED1, charactron LED2 input QA1 is connected, the input after the ternary output end Q2 series resistors R32 of the LED drive chip U2 with the charactron LED1 QA2, charactron LED2 input QA2 is held to be connected, the ternary output end Q3 series resistors R33 of the LED drive chip U2 The input QA3 with the charactron LED1, charactron LED2 input QA3 are connected afterwards, the LED drive chip U2's It is equal with the input QA4 of the charactron LED1, charactron LED2 input QA4 after the Q4 series resistors R34 of ternary output end Be connected, after the ternary output end Q5 series resistors R35 of the LED drive chip U2 with the input QA5 of the charactron LED1, Charactron LED2 input QA5 be connected, after the ternary output end Q6 series resistors R36 of the LED drive chip U2 with institute State charactron LED1 input QA6, charactron LED2 input QA6 is connected, the tri-state of the LED drive chip U2 is defeated It is connected with the input QA7 of the charactron LED1, charactron LED2 input QA7 after going out to hold Q7 series resistors R37;Institute Input QA0 ~ the QA7 for stating charactron LED input QA0 ~ QA71 and the charactron LED2 respectively lights with its corresponding d Pipe, e luminous tubes, c luminous tubes, b luminous tubes, g luminous tubes, Dp luminous tubes, a luminous tubes, f luminous tubes.
The present invention, can be convenient to use with the power percentage of real-time display ozone generator 2 by display circuit 8 and display screen 9 Realtime power occurs for the ozone that family understands during use in time, effectively avoids because ozone concentration is too high or too low to farming Injury caused by thing;In addition, the display screen 9 in the present invention has to supply voltage also by the connection with control protection electric circuit 7 Monitoring, i.e.,:Time interval is adjustable at regular intervals, such as shows supply voltage instantaneous value every 10S, facilitates user real-time The dump energy information of electrolytic cell, user is facilitated to carry out the arrangement for changing battery in advance;Device in the present invention is electric by 12V DC Source is designed as out-put supply, and its main advantage is:12V power supplys will not wound human body, and power supply product species is more, type It is in light weight more than number, it is easily changed and carries.
To sum up, the present invention has prominent substantive distinguishing features and significant progressive, the reality above in conjunction with accompanying drawing to the present invention Apply example to be explained in detail, but the present invention is not limited to above-described embodiment, in those of ordinary skill in the art's possessed knows In the range of knowledge, it can also be made a variety of changes on the premise of present inventive concept is not departed from.

Claims (8)

1. the ozone generating-device of power adjustable, including concentration control apparatus occur for ozone(1)And ozone generator(2), it is special Sign is:The concentration adjusting device(1)Including housing and the circuit board for being arranged on enclosure interior, the circuit board includes:Directly Flow power supply stabilization circuit(4), PWM oscillating circuits(5), boosting transforming circuit(6), control protection electric circuit(7)And display circuit (8), the control protection electric circuit(7)Respectively with PWM oscillating circuits(5)And display circuit(8)It is connected, the DC power voltage stabilizing Circuit(4)Respectively with the boosting transforming circuit(6)With PWM oscillating circuits(5)It is connected, the boosting transforming circuit(6)With it is smelly Oxygen Generator(2)It is connected, the ozone generator(2)On be provided with air inlet pipe and escape pipe;
The concentration adjusting device(1)Housing on be provided with display screen(9), alarm buzzer(10), powered controls (11), signal output interface(12), power supply indicator(3), the display screen(9)With display circuit(8)It is connected, the alarm honeybee Ring device(10)With control protection electric circuit(7)It is connected, the power supply indicator(3)With DC power voltage stabilizing circuit(4), the power Controlling organization(11)With PWM oscillating circuits(5)It is connected, the ozone generator(2)Pass through signal output interface(12)With boosting Transforming circuit(6)It is connected.
2. the ozone generating-device of power adjustable occurs for ozone according to claim 1, it is characterised in that:The direct current Source mu balanced circuit(4)Structure be:Including fuse F1, one end of the fuse F1 is connected with DC supply input interface, The other end of the fuse F1 and resistance R1 one end, resistance R4 one end, electric capacity C1 one end, electric capacity C2 one end, straight Flow power supply stabilization circuit(4)Power output end A2 be connected, the other end of the resistance R1 and electric capacity C3 one end, triode Q1 Colelctor electrode, triode Q3 colelctor electrode be connected, the emitter stage of the triode Q1 and triode Q2 colelctor electrode, resistance R2 One end, boosting transforming circuit(6)Control signal input GATE1 be connected, the base stage of the triode Q1 is with triode Q2's Base stage, PWM oscillating circuits(5)Output end PWM1 be connected, the emitter stage of the triode Q3 and triode Q4 colelctor electrode, electricity Hinder R3 one end, boosting transforming circuit(6)Control signal input GATE2 be connected, the base stage of the triode Q3 and three poles Pipe Q4 base stage, PWM oscillating circuits(5)Output end PWM2 be connected, the other end of the resistance R4 and LED 1 Positive pole be connected, the other end of the LED 1, the electric capacity C1 other end, the electric capacity C2 other end, electric capacity C3 The other end, triode Q2 colelctor electrode, the resistance R2 other end, triode Q4 colelctor electrode, resistance the R3 other end and direct current The power input interface H1 other end is grounded after being connected;
The DC power voltage stabilizing circuit(4)Structure also include fuse F2, fuse F3, one end of the fuse F2 with Fuse F3 one end, DC power voltage stabilizing circuit(4)Power output end A2 be connected, the other end of the fuse F2 and institute State DC power voltage stabilizing circuit(4)12V voltage output ends A0, electric capacity C5 one end, electric capacity C6 one end, voltage stabilizing chip U1 Input IN is connected, and output end OUT and inductance L1 one end of the voltage stabilizing chip U1, diode D1 negative pole are connected, described The inductance L1 other end and voltage stabilizing chip U1 feedback end BACK, electric capacity C7 one end, electric capacity C8 one end, the dc source Mu balanced circuit(4)5V voltage output ends A1 be connected, the other end of the electric capacity C5, the electric capacity C6 other end, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 earth terminal GND, diode D1 positive pole, the electric capacity C7 other end, the electric capacity C8 other end It is grounded;The other end of the fuse F3 is connected with electric capacity C51 one end, voltage stabilizing chip U1 input IN, the voltage stabilizing Chip U1 output end OUT is connected with diode D51 negative pole, diode D52 negative pole, inductance L1 one end, the inductance The L2 other end and resistance R53 one end, electric capacity C52 one end, electric capacity C53 one end, electric capacity C54 one end, resistance R54 One end, the DC power voltage stabilizing circuit(4)9V voltage output ends A3 be connected, the other end series resistor of the resistance R53 Feedback end BACK after R52 with the electric capacity C52 other end, resistance R51 one end, voltage stabilizing chip U1 is connected, the resistance R51's The other end is grounded, after the other end of resistance R54 concatenation LED 2 with the electric capacity C53 other end, electric capacity C54 The other end, diode D51 positive pole, diode D52 positive pole, voltage stabilizing chip U1 Enable Pin ON, voltage stabilizing chip U1 ground connection End GND, the electric capacity C51 other end are grounded after connecting;
The boosting transforming circuit(6)Circuit structure be:Including FET FET1, the grid of the FET FET1 with Boost transforming circuit(6)Control signal input GATE1 be connected, the drain electrode of the FET FET1 and the one of resistance R5 End, the input positive terminal of transformer T1 low-pressure sides are connected, and the other end of the resistance R5 is sequentially connected in series after resistance R6, electric capacity C4 and field Effect pipe FET2 drain electrode, the input negative terminal of transformer T1 low-pressure sides are connected, the source electrode of the FET FET1 and field-effect Pipe FET2 source electrode is grounded after being connected, tap terminals and the DC power voltage stabilizing circuit of the step down side(4)9V voltages Output terminals A 3 is connected, the high-pressure side output end and ozone generator of the transformer T1(2)It is connected.
3. the ozone generating-device of power adjustable occurs for ozone according to claim 1, it is characterised in that:The PWM shakes Swing circuit(5)Circuit structure be:Including single-chip microcomputer IC1, the error amplifier input Noninv in the same direction of the single-chip microcomputer IC1 One end, powered controls after series resistor R11 with electric capacity C11(11)Interface H2, the PWM oscillating circuits(5)It is defeated Go out to hold CTR to be connected, the oscillator timing capacitor incoming end CT and resistance R12 of the single-chip microcomputer IC1 one end, the one of electric capacity C12 End is connected, and the other end of the resistance R12 is connected with single-chip microcomputer IC1 oscillator discharge end Dis, and the single-chip microcomputer IC1's shakes It is connected after swinging device timing resistor incoming end RT series resistors R13 with slide rheostat R0 one end, the soft of single-chip microcomputer IC1 is opened Dynamic condenser incoming end So-sta is connected with electric capacity C13 one end, the error amplifier reverse input end Inv of the single-chip microcomputer IC1 It is connected after series resistor R14 with single-chip microcomputer IC1 PWM comparator thermal compensation signal inputs Com, electric capacity C14 one end, the list Piece machine IC1 external interrupt signal input Shut and electric capacity C15 one end, resistance R15 one end, resistance R16 one end phase Even, the other end of the resistance R16 and the PWM oscillating circuits(5)External interrupt signal input PRO be connected, the list Piece machine IC1 reference power supply output end is shaken with resistance R17 one end, resistance R18 one end, electric capacity C16 one end, the PWM Swing circuit(5)Output end VREF be connected, the other end of the resistance R17 and the PWM oscillating circuits(5)Output end TEMP, electric capacity C18 one end, switch S1 one end are connected, the other end and the powered controls of the resistance R18(11) Interface H2 be connected, the other end of the electric capacity C16 and electric capacity C17 one end, the electric capacity C18 other end, the one of resistance R19 Hold, be grounded after single-chip microcomputer IC1 earth terminal GND connections, the bias supply of the other end and single-chip microcomputer IC1 of the electric capacity C17 is defeated Enter to hold after Vcc, single-chip microcomputer IC1 output stage biased voltage input end Vc connections with the DC power voltage stabilizing circuit(4)Electricity Source output terminal A2 is connected, and the other end of the resistance R19 is connected with the other end for the S1 that opens the light, the output end of the single-chip microcomputer IC1 OUT1, output end OUT2 respectively with the PWM oscillating circuits(5)Output end PWM1, output end PWM2 be connected, the work( Rate controlling organization(11)Interface H2 be connected with resistance R110 one end, the other end of the resistance R110, electric capacity C11 it is another One end, the electric capacity C12 other end, slide rheostat R0 glissile segment, the slide rheostat R0 other end, electric capacity C13 it is another End, the electric capacity C14 other end, the electric capacity C151 other end, the resistance R15 other end are grounded;
The control protection electric circuit(7)Circuit structure be:Including single-chip microcomputer IC2, the ADC1 input channels of the single-chip microcomputer IC2 P1.0 is connected with resistance R21 one end, electric capacity C21 one end, the other end and the PWM oscillating circuits of the resistance R21(5)It is defeated Go out to hold CTR to be connected, the other end ground connection of the electric capacity C21, the ADC2 input channels P1.1 and resistance R22 of the single-chip microcomputer IC2 One end, resistance R23 one end, electric capacity C22 one end be connected, the other end of the resistance R22 and the PWM oscillating circuits (5)Output end TEMP be connected, the other end of the resistance R23, the electric capacity C22 other end and resistance R24 one end, electric capacity It is grounded after C23 one end connection, the other end and resistance R25 one end, the electric capacity C23 other end, the single-chip microcomputer of the resistance R24 IC2 ADC3 input channels P1.2 is connected, the other end of the resistance R25 and the DC power voltage stabilizing circuit(4)12V electricity Output terminals A 0 is pressed to be connected, the external interrupt output end P3.3 of the single-chip microcomputer IC2 and the PWM oscillating circuits(5)Outside in Break signal input PRO is connected;The positive source VCC of the single-chip microcomputer IC2 and DC power voltage stabilizing circuit(4)5V voltages it is defeated Go out to hold A1, electric capacity C24 one end to be connected, the other end of the electric capacity C24 is grounded after being connected with single-chip microcomputer IC2 earth terminal GND; It is connected after the data output end P1.3 series resistors R26 of the single-chip microcomputer IC2 with triode Q21 base stage, the triode Q21 Collector series connection resistance R27 after with alarm buzzer(10)Power cathode be connected, the alarm buzzer(10)Power supply Positive pole and DC power voltage stabilizing circuit(4)5V voltage output ends A1 be connected, the grounded emitter of the triode Q21;
The output end P1.5 of the single-chip microcomputer IC2, output end P1.6, output end P1.7 respectively with the display circuit(8)String Row data input pin SI, storage register input end of clock RCK, shift register clock input SCK are connected;The single-chip microcomputer IC2 output end P3.4, output end P3.5, output end P3.6, output end P3.7 respectively with display circuit(8)Input end of clock COM4, input end of clock COM3, input end of clock COM2, input end of clock COM1 are connected.
4. the ozone generating-device of power adjustable occurs for ozone according to claim 3, it is characterised in that:The control is protected Protection circuit(7)Circuit structure also include:The external interface J1 that downloads, the positive source of the external interface J1 that downloads With DC power voltage stabilizing circuit(4)5V voltage output ends A1 be connected, the first data terminal of the external interface J1 that downloads, The data output end P3.1 with single-chip microcomputer IC2, data output end P3.0 are connected second data segment respectively, described external to download Interface J1 earth terminal ground connection.
5. the ozone generating-device of power adjustable occurs for ozone according to claim 2, it is characterised in that:The voltage stabilizing core Piece U1 model LM2596, the fuse F1, fuse F2 model are FRU600, the FET FET1, field Effect pipe FET2 model is Irf4468.
6. the ozone generating-device of power adjustable occurs for ozone according to claim 3, it is characterised in that:The single-chip microcomputer IC1 model KA3525A, the model STC15F204EA of the single-chip microcomputer IC2.
7. the ozone generating-device of power adjustable occurs for ozone according to claim 1, it is characterised in that:The display screen (9)For LED display.
8. the ozone generating-device of power adjustable occurs for ozone according to claim 1, it is characterised in that:The power control Mechanism processed(11)For power control knob.
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CN109884961A (en) * 2019-04-03 2019-06-14 佛山市迪趣智能科技有限公司 A kind of control circuit of vehicle-mounted ozone generator
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Effective date of registration: 20190111

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Address before: 030006 Room 202, 0805, 8th floor, Block B, 89 Jinyang Street, Taiyuan High-tech Zone, Shanxi Province

Patentee before: Shanxi Dongyuan Huarui Agricultural Technology Co.,Ltd.