CN105925737A - Textile nanometer anion functional material and preparation method thereof - Google Patents
Textile nanometer anion functional material and preparation method thereof Download PDFInfo
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- CN105925737A CN105925737A CN201610308387.6A CN201610308387A CN105925737A CN 105925737 A CN105925737 A CN 105925737A CN 201610308387 A CN201610308387 A CN 201610308387A CN 105925737 A CN105925737 A CN 105925737A
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- elbaite
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
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- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a textile nanometer anion functional material and a preparation method thereof. The textile nanometer anion functional material is prepared from the following raw materials including, by weight, 30-40 parts of germanite, 25-35 parts of micrite, 4-8 parts of magnesium oxide, 13-24 parts of 5A molecular sieves, 16-24 parts of elbaite, 3-6 parts of ammonium sulfate, 18-29 parts of chlorite, 9-18 parts of seaweed carbon, 4-7 parts of sodium tungstate, 15-25 parts of flint clay and 10-20 parts of barite. By means of the nanometer anion functional material prepared from the germanite, the micrite, the elbaite, the chlorite, the seaweed carbon and other raw materials, textiles can be made to generate a thermal microwave massage effect, the regeneration capacity of cell tissue is enhanced, microcirculation is improved, metabolism is promoted, the body immunity is improved, body fatigue relief is facilitated, and refreshment is achieved; and besides, the absorption effect on bacteria and viruses is quite high, the activity of the bacteria and viruses can be effectively inhibited, and the good effects of sterilization, inflammation diminishing, deodorization and prevention of various skin diseases can be achieved.
Description
Technical field
The present invention relates to a kind of anion function material and preparation method thereof, be specifically related to a kind of weaving nanometer and bear
Ion functional material and preparation method thereof.
Background technology
Along with the further investigation that air ionization is theoretical, principle and application that negative aeroion is occurred by people cause
Interest greatly.It is known that the admixture of gas that air is made up of multiple gases, in some energy field
Under effect, in gas molecule, the outer-shell electron of some atom can leave track, becomes free electron, and free
Free electron can combine with the molecule of other neutrality so as to get the gas molecule of excess electron is negative electrode again
Property, it is referred to as " negative aeroion ".The anion Producing reason of nature, mainly cosmic ray, ore deposit
Thing lonizing radiation, corona discharge, current waterfall and the photosynthesis of forest plants.It is to say, anion produces
Exciting of energy is produced in the internal potential energy of Cucumber and the Nature meteorological activity.
Anion material, is the principle of human use's nature generation anion, synthetic or the one of proportioning
Plant complex mineral, because it has pyroelectricity and piezoelectricity, therefore in the case of having temperature and pressure change (i.e.
Make small change) electric potential difference between composition crystal can be caused, this electrostatic is up to 1,000,000 electron-volts,
So that air ionizes, that is hit is electronically attached to neighbouring water and oxygen molecule and makes it be converted into sky
Gas anion, i.e. negative oxygen ion.Negative oxygen ion has following functions: 1. can accelerate moisture movement, make general
Water flowing becomes activated water, so that the penetration of water, extension, dissolving power, metabolism power strengthen, and produces water
Protecting film.2. for blood circulation, expansion blood capillary can be played, strengthen blood circulation, promote new old generation
Thank, strengthen the effect of lymph circulation；For cell tissue, cell activation can be made, make the excretion of old dead cell or compose
Giving regeneration capacity, can strengthen cellular energy, function and the vigor etc. that strengthen cell act on, and improve asthma etc. and breathe
Systemic disease, improves anxious state of mind, depressed mood, confirmed fatigue, alleviates psychentonia situation etc., to people
Health, emotion, energy of great advantage, 3. chalk dust removing, except floating hair, eliminate the unusual smell, smoke abatement, sterilization, purify
Air, eliminates foreign flavor indoors and various harmful gas.
Along with the function of anion material is constantly recognized by people, the research to anion product is subject to the most day by day
To paying attention to.Anion function material functional textile high-grade for exploitation has important effect, becomes in recent years
For the focus of the market competition, application prospect is considerable.But, the most domestic for weaving anion function material
Research less, this just to exploitation anion leather bring certain difficulty.Therefore, a kind of leather of exploitation is used
Anion function material has important value and meaning.
Summary of the invention
Present invention aims to the deficiencies in the prior art, it is provided that a kind of weaving nano-negative ion function material
Material and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that:
Nano-negative ion functional material is used in a kind of weaving, is made up of the raw material of following weight portion: germanite 30-40,
Micrite 25-35, magnesium oxide 4-8,5A molecular sieve 13-24, elbaite 16-24, ammonium sulfate 3-6,
Chlorite 18-29, aethiops vegetabilis 9-18, sodium tungstate 4-7, flint clay 15-25, barite 10-20.
A kind of weaving uses the preparation method of nano-negative ion functional material, comprises the following steps:
(1) by germanite, micrite, elbaite, chlorite, flint clay, barite mixing,
Calcine 2-4h at 450-500 DEG C, be cooled to room temperature, be ground into the granule that particle diameter is 15-30 μm, add suitable
The suspension that concentration is 40-45% is made in the water stirring of amount, then with the sodium hydroxide solution regulation that concentration is 15%
PH of suspension is 300-500W to 7.5-8, microwave treatment 0.5-1.5h, microwave power, magnetic force vibration 1-3h,
Frequency of oscillation is 200-400Hz, then by the hydrochloric acid solution regulation pH of suspension that concentration is 20% to 5-5.5, micro-
Ripple processes 1-2h, and microwave power is 250-450W, sonic oscillation 1-2h, and frequency of oscillation is 40-50KHz,
It is that 15% sodium carbonate liquor is neutralized to neutrality by concentration afterwards, centrifugal under the rotating speed of 2500-3500r/min
15-20min, stands 15-20h, filters, and is dried and goes moisture removal to moisture content≤2%；
(2) raw mineral materials that step (1) prepares being carried out secondary clacining, calcining heat is 620-660 DEG C,
Calcination time is 2-3h, is cooled to room temperature, is then milled to granule under the rotating speed of 10000-12000r/min
Particle diameter is 5-10 μm；
(3) raw mineral materials that step (2) is prepared and magnesium oxide, 5A molecular sieve, aethiops vegetabilis, sodium tungstate
Mixing Deng raw material, being then milled to grain diameter under the rotating speed of 14000-16000r/min is 80-120nm,
Get product.
Beneficial effects of the present invention:
The nanometer that the present invention prepares with raw materials such as germanite, micrite, elbaite, chlorite, aethiops vegetabilises is born
Ion functional material is possible not only to make textile produce warm microwave massage effect, strengthens the Regenerated energy of cell tissue
Power, improves microcirculation, enhances metabolism, and improves body immunity, helps health allaying tiredness, recovers
Energy, also has the strongest adsorption to antibacterial and virus, it is possible to effectively suppression antibacterial and the activity of virus,
Can reach good sterilization, antiinflammatory, deodorization and effect of prevention multiple dermatosis, the ammonium sulfate simultaneously added,
The raw materials such as sodium tungstate, flint clay, barite, can improve fire prevention and the radiation resistance of textile.
Detailed description of the invention
Embodiment 1
Nano-negative ion functional material is used in a kind of weaving, is made up of the raw material of following weight (kg): germanite 30,
Micrite 25, magnesium oxide 4,5A molecular sieve 13, elbaite 16, ammonium sulfate 3, chlorite 18, sea
Algae charcoal 9, sodium tungstate 4, flint clay 15, barite 10.
A kind of weaving uses the preparation method of nano-negative ion functional material, comprises the following steps:
(1) by germanite, micrite, elbaite, chlorite, flint clay, barite mixing, at 450 DEG C
Lower calcining 4h, is cooled to room temperature, is ground into the granule that particle diameter is 15 μm, adds appropriate water stirring and makes
Concentration is the suspension of 40%, then by the sodium hydroxide solution regulation pH of suspension that concentration is 15% to 7.5,
Microwave treatment 0.5h, microwave power is 500W, and magnetic force vibration 1h, frequency of oscillation is 400Hz, then uses concentration
Be 20% hydrochloric acid solution regulation pH of suspension to 5, microwave treatment 1h, microwave power is 450W, Under Ultrasonic Vibration
Swinging 1h, frequency of oscillation is 50KHz, is finally that 15% sodium carbonate liquor is neutralized to neutrality, at 2500r/min by concentration
Rotating speed under centrifugal 15min, stand 15h, filter, be dried and go moisture removal to moisture content≤2%；
(2) raw mineral materials that step (1) prepares being carried out secondary clacining, calcining heat is 620 DEG C, calcining
Time is 3h, is cooled to room temperature, and being then milled to grain diameter under the rotating speed of 10000r/min is 5 μm；
(3) raw mineral materials that step (2) is prepared and magnesium oxide, 5A molecular sieve, aethiops vegetabilis, sodium tungstate
Mixing Deng raw material, being then milled to grain diameter under the rotating speed of 14000r/min is 80nm, gets product.
Embodiment 2
Nano-negative ion functional material is used in a kind of weaving, is made up of the raw material of following weight (kg): germanite 35,
Micrite 30, magnesium oxide 6,5A molecular sieve 18, elbaite 20, ammonium sulfate 4.5, chlorite 24,
Aethiops vegetabilis 12, sodium tungstate 5, flint clay 20, barite 15.
A kind of weaving uses the preparation method of nano-negative ion functional material, comprises the following steps:
(1) by germanite, micrite, elbaite, chlorite, flint clay, barite mixing, at 480 DEG C
Lower calcining 3h, is cooled to room temperature, is ground into the granule that particle diameter is 25 μm, adds appropriate water stirring and makes
Concentration is the suspension of 42%, then by the sodium hydroxide solution regulation pH of suspension that concentration is 15% to 7.7,
Microwave treatment 1h, microwave power is 400W, and magnetic force vibration 2h, frequency of oscillation is 300Hz, then by concentration is
The hydrochloric acid solution regulation pH of suspension of 20% is to 5.3, and microwave treatment 1.5h, microwave power is 350W, ultrasonic
Vibration 1.5h, frequency of oscillation is 45KHz, is finally that 15% sodium carbonate liquor is neutralized to neutrality by concentration,
Under the rotating speed of 3000r/min, centrifugal 18min, stands 16h, filters, and is dried and goes moisture removal to moisture content≤2%；
(2) raw mineral materials that step (1) prepares being carried out secondary clacining, calcining heat is 650 DEG C, calcining
Time is 2.5h, is cooled to room temperature, and being then milled to grain diameter under the rotating speed of 11000r/min is 8 μm；
(3) raw mineral materials that step (2) is prepared and magnesium oxide, 5A molecular sieve, aethiops vegetabilis, sodium tungstate
Mixing Deng raw material, being then milled to grain diameter under the rotating speed of 15000r/min is 100nm, gets product.
Embodiment 3
Nano-negative ion functional material is used in a kind of weaving, is made up of the raw material of following weight (kg): germanite 40,
Micrite 35, magnesium oxide 8,5A molecular sieve 24, elbaite 24, ammonium sulfate 6, chlorite 29, sea
Algae charcoal 18, sodium tungstate 7, flint clay 25, barite 20.
A kind of weaving uses the preparation method of nano-negative ion functional material, comprises the following steps:
(1) by germanite, micrite, elbaite, chlorite, flint clay, barite mixing, at 500 DEG C
Lower calcining 2h, is cooled to room temperature, is ground into the granule that particle diameter is 30 μm, adds appropriate water stirring and makes
Concentration is the suspension of 45%, then by the sodium hydroxide solution regulation pH of suspension that concentration is 15% to 8, micro-
Ripple processes 1.5h, and microwave power is 300W, and magnetic force vibration 1h, frequency of oscillation is 200Hz, then by concentration is
The hydrochloric acid solution regulation pH of suspension of 20% is to 5.5, and microwave treatment 2h, microwave power is 250W, Under Ultrasonic Vibration
Swinging 2h, frequency of oscillation is 40KHz, is finally that 15% sodium carbonate liquor is neutralized to neutrality, at 3500r/min by concentration
Rotating speed under centrifugal 15min, stand 20h, filter, be dried and go moisture removal to moisture content≤2%；
(2) raw mineral materials that step (1) prepares being carried out secondary clacining, calcining heat is 660 DEG C, calcining
Time is 2h, is cooled to room temperature, and being then milled to grain diameter under the rotating speed of 12000r/min is 10 μm；
(3) raw mineral materials that step (2) is prepared and magnesium oxide, 5A molecular sieve, aethiops vegetabilis, sodium tungstate
Mixing Deng raw material, being then milled to grain diameter under the rotating speed of 16000r/min is 120nm, gets product.
Take the nano-negative ion functional material that the 500g present invention prepares to be placed in seal box, uniformly spread out, airtight
24h, with Japan day intrinsic safety sky generation air-anion concentration tester ITC-201A every detection in 1 hour once,
Taking 20 data, the meansigma methods trying to achieve each data is shown in Table 1 as final detection result, test result every time.
Table 1 negative ion concentration test tables of data
| Negative ion concentration (individual/cm3) | |
| Embodiment 1 | 20126 |
| Embodiment 2 | 21014 |
| Embodiment 3 | 20565 |
Claims (2)
1. nano-negative ion functional material is used in a weaving, it is characterised in that be made up of the raw material of following weight portion:
Germanite 30-40, micrite 25-35, magnesium oxide 4-8,5A molecular sieve 13-24, elbaite 16-24,
Ammonium sulfate 3-6, chlorite 18-29, aethiops vegetabilis 9-18, sodium tungstate 4-7, flint clay 15-25, barite
10-20。
2. a preparation method for weaving nano-negative ion functional material as claimed in claim 1, its feature exists
In, comprise the following steps:
(1) by germanite, micrite, elbaite, chlorite, flint clay, barite mixing, at 450-500 DEG C
Lower calcining 2-4h, is cooled to room temperature, is ground into the granule that particle diameter is 15-30 μm, adds appropriate water stirring
Make the suspension that concentration is 40-45%, then by the sodium hydroxide solution regulation pH of suspension that concentration is 15%
To 7.5-8, microwave treatment 0.5-1.5h, microwave power is 300-500W, magnetic force vibration 1-3h, oscillation frequency
Rate is 200-400Hz, then by the hydrochloric acid solution regulation pH of suspension that concentration is 20% to 5-5.5, microwave treatment
1-2h, microwave power is 250-450W, sonic oscillation 1-2h, and frequency of oscillation is 40-50KHz, finally with dense
Degree is that 15% sodium carbonate liquor is neutralized to neutrality, centrifugal 15-20min under the rotating speed of 2500-3500r/min,
Stand 15-20h, filter, be dried and go moisture removal to moisture content≤2%；
(2) raw mineral materials that step (1) prepares being carried out secondary clacining, calcining heat is 620-660 DEG C, calcining
Time is 2-3h, is cooled to room temperature, is then milled to grain diameter under the rotating speed of 10000-12000r/min
For 5-10 μm；
(3) raw mineral materials step (2) prepared is former with magnesium oxide, 5A molecular sieve, aethiops vegetabilis, sodium tungstate etc.
Material mixing, being then milled to grain diameter under the rotating speed of 14000-16000r/min is 80-120nm, to obtain final product
Finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610308387.6A CN105925737A (en) | 2016-05-11 | 2016-05-11 | Textile nanometer anion functional material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610308387.6A CN105925737A (en) | 2016-05-11 | 2016-05-11 | Textile nanometer anion functional material and preparation method thereof |
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| CN105925737A true CN105925737A (en) | 2016-09-07 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040000112A (en) * | 2002-06-24 | 2004-01-03 | 박주민 | The processing method of natural leather |
| CN103708482A (en) * | 2013-12-23 | 2014-04-09 | 杨立新 | Preparation method of medicinal attapulgite powder preparation |
| CN104086165A (en) * | 2014-07-15 | 2014-10-08 | 任新年 | Anion ceramic ball and preparation method thereof |
-
2016
- 2016-05-11 CN CN201610308387.6A patent/CN105925737A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040000112A (en) * | 2002-06-24 | 2004-01-03 | 박주민 | The processing method of natural leather |
| CN103708482A (en) * | 2013-12-23 | 2014-04-09 | 杨立新 | Preparation method of medicinal attapulgite powder preparation |
| CN104086165A (en) * | 2014-07-15 | 2014-10-08 | 任新年 | Anion ceramic ball and preparation method thereof |
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Application publication date: 20160907 |