CN105923683A - Drinking water purifier - Google Patents
Drinking water purifier Download PDFInfo
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- CN105923683A CN105923683A CN201610269133.8A CN201610269133A CN105923683A CN 105923683 A CN105923683 A CN 105923683A CN 201610269133 A CN201610269133 A CN 201610269133A CN 105923683 A CN105923683 A CN 105923683A
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- drinking water
- water
- light shale
- powder body
- cleanser
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/4619—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Water Treatment By Sorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
The invention discloses a use of natural opals in drinking water purification. The invention also discloses a drinking water purifier. The purifier is prepared from lightweight shale ores through crushing, cleaning, roasting and post-processing, and roasting is carried out at 500-1200DEG C for 70-110min; and the drinking water purifier can efficiently remove chlorine, silts, organic matters and bacteria in drinking water, can regulate the pH value of the drinking water to make the drinking water be weakly alkaline, and can reduce the hardness of the water. The invention also discloses another drinking water purifier. The another drinking water purifier is prepared through high temperature extruding granulation of lightweight shale powder and a binder, wherein the inlet temperature of an extruder is 200-300DEG C, the outlet temperature is 60-80DEG C, and the lightweight shale powder is prepared through crushing the lightweight shale ores, cleaning the crushed ores, reducing the cleaned ores and screening the reduced ores; and the another drinking water purifier can efficiently remove chlorine, silts, organic matters and bacteria in drinking water, can regulate the pH value of the drinking water to make the drinking water be weakly alkaline, and can reduce the hardness of the water.
Description
Technical field
The present invention relates to water resource field of purification, particularly relate to drink water purifying field,
Especially, a kind of clean reagent in drinking water is related to.
Background technology
Along with industrial expansion, the pollution at existing water source is increasingly severe, and along with life
The raising that running water is flat, people are more and more higher to the prescription of drinking water, but,
From river, lake drinkable water in containing a large amount of antibacterials, microorganism, even mud
Husky etc., daily tap water exists some impurity and the antibacterial grown, and
Its preparation process can use disinfection by chlorine so that tap water has residual chlorine or
The harmful substances such as chloroform, and barreled drinking water exists two due to the water dispenser supporting with it
Secondary pollution, it is easy to polluted by antibacterial, and the existing bottled water general shelf-life be
24h, more than 24h can easy breed bacteria or other microorganism, meanwhile, existing barreled
In water, water macromolecular mass form exists, and is difficult to be absorbed by human body cell.Therefore, it is badly in need of
A kind of clean reagent in drinking water, it is possible to purify water, obtain aseptic, clean, and pH in
Alkalescence, present with subset form, the water that applicable human body is drunk,
Chinese patent CN 201310366305 disclose a kind of clean reagent in drinking water and
Preparation method, it is with activated carbon, coral sand, Water fish stone, bodied ferric sulfate, Gao Meng
Acid potassium and water are raw material, are sufficiently mixed prepared clean reagent in drinking water, and described drinking water is clean
Agent can remove the microorganism in water and antibacterial, and removal of bacteria rate reaches more than 98%,
After purification, water can reach standard for drinking.But, its needed raw material is complicated, and institute
Potassium permanganate there is toxicity and corrosivity, and expensive, and be not directed to institute
Stating cleanser and can regulate the pH value of water to alkalescence, being also not directed to described cleanser can
So that water presents with subset form, it is simple to cell absorbs.
Chinese patent CN 98103121 discloses a kind of clean reagent in drinking water and preparation thereof
Method, its first synthesis of acrylamide and acrylic acid graft copolymer, then with other thing
Matter is combined, and obtains potable water purifying agent, first in acrylamide grafted copolymer,
It is certain to more or less there is harmful initiator or monomer, human body is damaged,
Secondly, this acrylamide grafted copolymer preparation complexity, need to enter under nitrogen atmosphere
OK, being less prone to large-scale production and utilize, finally, described clean reagent in drinking water reaches
Purification purpose, obtains clean drinkable water, but, it is not directed to described equally
Cleanser can regulate the pH value of water to alkalescence, is also not directed to described cleanser permissible
Water is made to present with subset form, it is simple to cell absorbs.
Summary of the invention
In order to solve the problems referred to above, present inventor has performed and study with keen determination, found that:
Light shale ore deposit can carry out drink water purifying effectively, and can regulate the pH value of water
To alkalescence, and making water present with subset form, therefore, the present invention utilizes gently
Matter shale ore carries out drink water purifying, thus completes the present invention.
An object of the present invention is to provide a kind of native protein stone granule for purifying
The purposes of drinking water, is embodied in following several respects:
(1) a kind of native protein stone granule is for the purposes of purifying drinking water, wherein,
Described native protein stone granule by light shale ore deposit through crushing, clean, being dried,
Pulverize and screening prepares, and/or
The particle diameter of described native protein stone granule is 0.5～8mm, preferably 1～6mm,
More preferably 2～5mm；
(2) according to the purposes described in above-mentioned (1), wherein,
The inside in described light shale ore deposit has poriform micropore gap, described micropore
Aperture is 5～20nm, and/or
Obtaining light shale rubble after Po Sui, the particle diameter of described light shale rubble is
10～100mm, preferably 20～80mm, more preferably 40～60mm；
The two of the purpose of the present invention are to provide a kind of clean reagent in drinking water, specifically embody
In following several respects:
(3) a kind of clean reagent in drinking water, wherein,
Described cleanser by light shale ore deposit through broken, clean, roasting and post processing system
, and/or
The particle diameter of described cleanser is 0.5～8mm, preferably 1～6mm, more preferably
2～5mm；
(4) according to the cleanser described in above-mentioned (3), wherein, described light shale
The inside in ore deposit has poriform micropore gap, and the aperture of described micropore is 5～20nm；
(5) according to the cleanser described in above-mentioned (3) or (4), wherein,
Obtaining light shale rubble after Po Sui, the particle diameter of described light shale rubble is
10～100mm, preferably 20～80mm, more preferably 40～60mm；And/or
Described roasting is carried out as follows: carry out 70～110min at 500～1200 DEG C, excellent
Selection of land, carries out 80～100min at 800～1000 DEG C, it is highly preferred that at 900 DEG C
Carry out 90min；And/or
Described post processing includes cooling and screening successively；
The three of the purpose of the present invention are to provide a kind of clean reagent in drinking water, specifically embody
In following several respects:
(6) a kind of clean reagent in drinking water, wherein, described cleanser is following heavy by including
The raw material of amount percentage composition component is made:
Light shale powder body 75～95wt%,
Binding agent 5～25wt%；
Preferably:
Light shale powder body 80～90wt%,
Binding agent 10～20wt%；
More preferably:
Light shale powder body 85wt%,
Binding agent 15wt%；
(7) according to the cleanser described in above-mentioned (6), wherein,
Described light shale powder body carries out crushing by light shale ore deposit, cleans, levigate and
Screening prepares；And/or
The inside of described light shale powder body has poriform micropore gap, described micropore
Aperture be 5～20nm；And/or
The particle diameter of described light shale powder body is 50～2000 mesh, preferably 100～1000
Mesh, more preferably 200～500 mesh；And/or
Described binding agent is native selected from aluminosilicate or the ore deposit of salic composition, preferably selects
One or several in bentonite, kieselguhr, attapulgite, Kaolin and sheep Montmorillonitum
Kind, more preferably bentonite；
(8) according to the cleanser described in above-mentioned (6) or (7), wherein, described only
Agent is prepared by the method comprised the steps of:
Step 1, carry out light shale ore deposit crushing, clean, levigate and screening, obtain gently
Matter shale powder body；
Step 2, light shale powder body, binding agent are mixed with water, obtain compound；
Step 3, add mixture into extruder carry out extruding pelletization, then post processing,
Obtain clean reagent in drinking water；
(9) according to the cleanser above-mentioned (6) to one of (8) Suo Shu, wherein,
In step 2, weight based on light shale powder body and binding agent and, the use of water
Amount is 5～25wt%, preferably 10～20wt%, more preferably 15wt%；And/or
In step 3, the inlet temperature of extruder is 200～300 DEG C, is preferably
220～280 DEG C, more preferably 250 DEG C；And/or
In step 3, the outlet temperature of extruder is 60～80 DEG C, is preferably
65～75 DEG C, more preferably 70 DEG C；And/or
In step 3, described post processing includes being dried, cool down and sieving successively；
The four of the purpose of the present invention are to provide a kind of above-mentioned (3) to one of (5)
Clean reagent in drinking water or above-mentioned (6) are used to the clean reagent in drinking water one of (9) Suo Shu
Purposes in purifying drinking water.
Detailed description of the invention
Below by the present invention is described in detail, the features and advantages of the invention will
Become more apparent from, clearly along with these explanations.
According to an aspect of the present invention, it is provided that a kind of native protein stone granule is for clean
Change the purposes of drinking water.
According to one of the present invention preferred embodiment, described native protein stone granule by
Light shale ore deposit is prepared through crushing, clean, be dried, pulverize and sieving.
According to one of the present invention preferred embodiment, the inside in described light shale ore deposit
Having poriform micropore gap, the aperture of described micropore is 5～20nm, its inside
Nanoporous structure gives light shale ore deposit nano effect, wherein, above-mentioned quoted from " Liu Xin
Build, Li Qingshan. the discovery of a kind of natural nano-material and applied research .E nano material ".
In the present invention, described light shale ore deposit is selected from Inner Mongol Mo Qi E Er and border, township
Interior albumen shale ore.Wherein, albumen shale ore is the volcano formed by volcano eruption
Ash calcination in atmosphere is formed through falling into lake bed deposits after becoming tiny glower.
Wherein, described light shale ore deposit is a kind of natural nano-material, has laminated layer
The features such as reason, granularity fine uniform, structure conveying porous, it is internal containing large number of orifices
Gap so that it is specific surface area is up to 277.3cm2/ g, has the strongest adsorptivity.Above-mentioned
About light shale granule data quoted from " Liu Xinjian, Li Qingshan. a kind of natural nano
The discovery of material and applied research .E nano material ".
In the present invention, the inside in described light shale ore deposit has nanometer micropore, has
The strongest adsorptivity, when preparing clean reagent in drinking water with it: one, can remove
Silt, rust, antibacterial and Organic substance in water, improves water quality so that it is can be healthy
Drinking, and the water after improvement is not likely to produce incrustation scale after the heating, they are two years old, it is possible to inhale
Chlorine in attached tap water, thus change the acidity of water, making water is alkalescence；
In the present invention, described light shale ore deposit can anion releasing, when using it
When preparing clean reagent in drinking water: one, described anion can reduce and produce in water
Raw active oxygen (oxygen-derived free radicals), reduce the harm to human body of the too much active oxygen, its two,
Described anion has antibacterial effect, its three, described anion can regulate in water
PH in about 7.4 alkalescence, meanwhile, the reduction in surface tension of water, penetration increase
By force, and hardness of water can be reduced significantly, improve water quality；
In the present invention, described light shale ore deposit has weak current, when making with it
During standby clean reagent in drinking water: one, the electrolysis of weak current can eliminate in water
Abnormal flavour；Its two, weak current can make moment water occur faint electrolysis, become H+
And OH-, and H+Be combined with the anion of native protein stone granule release, the H in water+
Fewer and feweri, in water, pH is more and more higher, ultimately forms alkalescent water, with the body fluid of people
Close with the pH value of blood, it is more suitable for people and quotes, prevent human body fluid to be acidified.
In the present invention, far infrared can be launched in described light shale ore deposit, when using it
When preparing clean reagent in drinking water: one, it is possible to suppression bacteria breed.They are two years old, it is possible to
Produce the water of subset, specifically: under normal circumstances, light water is by up to
The big water clusters (hydrogen bond conclusion) that the associated water molecules of more than ten becomes, and far
The energy equivalence of hydrogen bond between photon energy and hydrone, produces resonance, so hydrogen can be made
Bond fission, makes the water of the macromolecular mass of intermolecular mutual conclusion become the water of subset,
Molecular number is about 6～8, and the micel of water is the least, and the energy of water is the biggest, oozing of water
Saturating power, dissolving power, metabolism power are the strongest, because its micel is little, it is easier to turnover cell
Film, transports nutrient, gets rid of poisonous and harmful substance, is good cell cleaning agent, promotees
Enter metabolism, cell activity enhancing, improve human activity, therefore, subset
Water be the water being best suitable for human body cell.
According to one of the present invention preferred embodiment, light shale is obtained after crushing broken
Stone, the particle diameter of described light shale rubble is 10～100mm, preferably 20～80mm,
More preferably 40～60mm.
According to one of the present invention preferred embodiment, described cleaning uses waterpower washup
Sieve, tubular washing screen, cylinder swaging machine or grooved log washer are carried out, and mainly remove
The earth on surface, light shale ore deposit or other impurity.
According to one of the present invention preferred embodiment, described be dried as naturally drying,
Oven for drying or lyophilization.
In further preferred embodiment, the temperature of described drying is 40～80 DEG C,
It is preferably 60 DEG C.
According to one of the present invention preferred embodiment, described native protein stone granule
Particle diameter is 0.5～8mm.
In further preferred embodiment, the particle diameter of described native protein stone granule
It is 1～6mm.
In the most preferred embodiment, the grain of described native protein stone granule
Footpath is 2～5mm.
Wherein, described native protein stone is prepared by light shale ore deposit, and it has lightweight page
The performance of rock ore deposit purifying drinking water, therefore it may be used for drink water purifying.
Second aspect present invention provides a kind of clean reagent in drinking water, and described cleanser is
Prepared through broken, cleaning, roasting and post processing by light shale ore deposit.
According to one of the present invention preferred embodiment, the inside in described light shale ore deposit
Having poriform micropore gap, the aperture of described micropore is 5～20nm, its inside
Nanoporous structure gives light shale ore deposit nano effect, wherein, above-mentioned quoted from " Liu Xin
Build, Li Qingshan. the discovery of a kind of natural nano-material and applied research .E nano material ".
In the present invention, described light shale ore deposit is selected from Inner Mongol Mo Qi E Er and border, township
Interior albumen shale ore.Wherein, albumen shale ore is the volcano formed by volcano eruption
Ash calcination in atmosphere is formed through falling into lake bed deposits after becoming tiny glower.
Wherein, described light shale ore deposit is a kind of natural nano-material, has laminated layer
The features such as reason, granularity fine uniform, structure conveying porous, it is internal containing large number of orifices
Gap so that it is specific surface area is up to 277.3cm2/ g, has the strongest adsorptivity.Above-mentioned
About light shale granule data quoted from " Liu Xinjian, Li Qingshan. a kind of natural nano
The discovery of material and applied research .E nano material ".
In the present invention, the inside in described light shale ore deposit has nanometer micropore, has
The strongest adsorptivity, when clean reagent in drinking water will be prepared with it, one, can remove
Silt, rust, antibacterial and Organic substance in water, improves water quality so that it is can be healthy
Quoting, and the water after improvement is not likely to produce incrustation scale after the heating, they are two years old, it is possible to inhale
Chlorine in attached tap water, thus change the acidity of water, making water is alkalescence；
In the present invention, described light shale ore deposit can anion releasing, when using it
When preparing clean reagent in drinking water: one, described anion can reduce and produce in water
Raw active oxygen (oxygen-derived free radicals), reduce the harm to human body of the too much active oxygen, its two,
Described anion has antibacterial effect, its three, described anion can regulate in water
PH in about 7.4 alkalescence, meanwhile, the reduction in surface tension of water, penetration increase
By force, and hardness of water can be reduced significantly, improve water quality；
In the present invention, described light shale ore deposit has weak current, when making with it
During standby clean reagent in drinking water, one, the electrolysis of weak current can eliminate in water
Abnormal flavour；Its two, weak current can make moment water occur faint electrolysis, become H+
And OH-, and H+Be combined with the anion of native protein stone granule release, the H in water+
Fewer and feweri, in water, pH is more and more higher, ultimately forms alkalescent water, with the body fluid of people
Close with the pH value of blood, it is more suitable for people and quotes, prevent human body fluid to be acidified.
In the present invention, far infrared can be launched in described light shale ore deposit, when using it
When preparing clean reagent in drinking water: one, it is possible to suppression bacteria breed；They are two years old, it is possible to
Produce the water of subset, specifically: under normal circumstances, light water is by up to
The big water clusters (hydrogen bond conclusion) that the associated water molecules of more than ten becomes, and far
The energy equivalence of hydrogen bond between photon energy and hydrone, produces resonance, so hydrogen can be made
Bond fission, makes the water of the macromolecular mass of intermolecular mutual conclusion become the water of subset,
Molecular number is about 6～8, and the micel of water is the least, and the energy of water is the biggest, oozing of water
Saturating power, dissolving power, metabolism power are the strongest, because its micel is little, it is easier to turnover cell
Film, transports nutrient, gets rid of poisonous and harmful substance, is good cell cleaning agent, promotees
Enter metabolism, cell activity enhancing, improve human activity, therefore, subset
Water be the water being best suitable for human body cell.
In the present invention, described clean reagent in drinking water is by the method system comprised the steps of
:
Step 1, carry out light shale ore deposit crushing, cleaning, obtain light shale rubble.
According to one of the present invention preferred embodiment, the grain of described light shale rubble
Footpath is 10～100mm.
In further preferred embodiment, the particle diameter of described light shale rubble is
20～80mm.
In the most preferred embodiment, the particle diameter of described light shale rubble
It is 40～60mm.
Wherein, the heat transfer in the particle size influences roasting process of rubble and mass transfer velocity, broken
The granularity of stone is the least, and specific grain surface is long-pending the biggest, and the contact area between gas-solid is relatively big,
Heat transfer, mass-transfer efficiency higher, but, from the economic viewpoint, rubble is the most preferably less than
10mm；If rubble granularity is excessive, often produces rubble top layer and internal roasting is uneven
Even phenomenon, higher than inside, there is " half-cooked " phenomenon in the roasting degree on its top layer,
The granularity of rubble is bigger, and non-uniform phenomenon is tighter, therefore, controls its particle diameter not higher than
100mm.Further, if the particle diameter of light shale rubble is too big, then the lightweight page obtained
The particle diameter of rock granule is also the biggest so that it is specific surface area diminishes, and reduces its later stage pair
The treatment effect of sewage.Therefore, the particle diameter controlling light shale rubble is 10～100
mm。
According to one of the present invention preferred embodiment, described cleaning uses waterpower washup
Sieve, tubular washing screen, cylinder swaging machine or grooved log washer are carried out, and mainly remove
The earth on light shale rubble surface or other impurity.
Step 2, light shale rubble is carried out roasting, then carry out post processing, obtain drink
Use water scavengine agent.
According to one of the present invention preferred embodiment, in step 2, described roasting in
70～110min are carried out at 500～1200 DEG C.
In further preferred embodiment, in step 2, described roasting in
80～100min are carried out at 800～1000 DEG C.
In the most preferred embodiment, in step 2, described roasting in
90min is carried out at 900 DEG C.
Wherein, at high temperature roasting: it is micro-that (1) is conducive within light shale rubble
Bore expansion；(2) impurity within light shale rubble is removed；(3) lightweight page is removed
Moisture within rock rubble；The light shale granule that above-mentioned three kinds of results all can make
Specific surface area increase, improve its absorbability, and then be conducive to improving its drinking water
Purification efficiency.
According to one of the present invention preferred embodiment, in step 2, described post processing
Include cooling and screening successively.
In further preferred embodiment, described in be cooled to room temperature cooling or low temperature
Cooling.
In the most preferred embodiment, described in be cooled to room temperature cooling.
Wherein, described room temperature is 10～30 DEG C, and described low temperature is about 5 DEG C.
According to one of the present invention preferred embodiment, described clean reagent in drinking water is
Granular, its particle diameter is 0.5～8mm.
In further preferred embodiment, the particle diameter of described clean reagent in drinking water is
1～6mm.
In the most preferred embodiment, the particle diameter of described clean reagent in drinking water
It is 2～5mm.
Wherein, the particle diameter of described clean reagent in drinking water should not be too big, if particle diameter is too big,
Its surface area diminishes, and affects its clean-up effect.
Third aspect present invention provides another kind of clean reagent in drinking water, described cleanser
It is made up through high temperature extruding pelletization of light shale powder body and binding agent.
According to one of the present invention preferred embodiment, with light shale powder body and bonding
The weight of agent and be 100% meter, the consumption of described light shale powder body is 75～95wt%.
In further preferred embodiment, with light shale powder body and binding agent
Weight and be 100% meter, the consumption of described light shale powder body is 80～90wt%.
In the most preferred embodiment, with light shale powder body and binding agent
Weight and be 100% meter, the consumption of described light shale powder body is 85wt%.
According to one of the present invention preferred embodiment, described light shale powder body is by gently
Matter shale ore is size-reduced, levigate and screening etc. processes and obtains, and has poriform inside it
Micropore gap, the aperture of described micropore is 5～20nm, quoted from " Liu Xinjian, Li Qingshan.
The discovery of a kind of natural nano-material and applied research .E nano material ".
In the present invention, described light shale ore deposit is selected from Inner Mongol Mo Qi E Er and border, township
Interior albumen shale ore.Wherein, albumen shale ore is the volcano formed by volcano eruption
Ash calcination in atmosphere is formed through falling into lake bed deposits after becoming tiny glower.
Wherein, described light shale ore deposit is a kind of natural nano-material, has laminated layer
The features such as reason, granularity fine uniform, structure conveying porous, it is internal containing large number of orifices
Gap so that it is specific surface area is up to 277.3cm2/ g, above-mentioned relevant light shale powder body
Data quoted from " Liu Xinjian, Li Qingshan. the discovery of a kind of natural nano-material is ground with application
Study carefully .E nano material ".
According to one of the present invention preferred embodiment, the grain of described light shale powder body
Footpath is 50～2000 mesh, preferably 100～1000 mesh, more preferably 200～500 mesh.
Wherein, due to the existence of internal nanometer micropore, though its particle diameter be 2000 mesh with
Under, it may have the strongest adsorption effect, need not accomplish that Nano grade also can reach to receive
Meter Xiao Ying.
In the present invention, the inside in described light shale ore deposit has nanometer micropore, has
The strongest adsorptivity, when using it for preparing clean reagent in drinking water: one, can remove
Silt, rust, antibacterial and Organic substance in anhydrating, improves water quality so that it is Ke Yijian
Water after Kang Yinyong, and improvement is not likely to produce incrustation scale after the heating, and they are two years old, it is possible to
Chlorine in absorption tap water, thus change the acidity of water, making water is alkalescence；
In the present invention, described light shale ore deposit can anion releasing, when being used
In time preparing clean reagent in drinking water: one, described anion can reduce in water
Produce active oxygen (oxygen-derived free radicals), reduce the harm to human body of the too much active oxygen, its
Two, described anion has antibacterial effect, its three, described anion can regulate
PH in water in about 7.4 alkalescence, meanwhile, the reduction in surface tension of water, infiltration
Power strengthens, and can reduce hardness of water significantly, improves water quality；
In the present invention, described light shale ore deposit has weak current, when using it for
When preparing clean reagent in drinking water: one, the electrolysis of weak current can eliminate water
In abnormal flavour；Its two, weak current can make moment water occur faint electrolysis, become
H+And OH-, and H+Be combined, in water with the anion of native protein stone granule release
H+Fewer and feweri, in water, pH is more and more higher, ultimately forms alkalescent water, with the body of people
The pH value of liquid and blood is close, is more suitable for people and quotes, and prevents human body fluid to be acidified.
In the present invention, far infrared can be launched in described light shale ore deposit, when being used
In time preparing clean reagent in drinking water: one, it is possible to suppression bacteria breed.Its two, energy
Enough produce the water of subset, specifically: under normal circumstances, light water is by many
The big water clusters (hydrogen bond conclusion) that the associated water molecules reached more than ten becomes, and far infrared
Photon energy and hydrone between the energy equivalence of hydrogen bond, produce resonance, so can make
Hydrogen bond rupture, makes the water of the macromolecular mass of intermolecular mutual conclusion become subset
Water, molecular number is about 6～8, and the micel of water is the least, and the energy of water is the biggest, water
Penetration, dissolving power, metabolism power the strongest, because its micel is little, it is easier to turnover
Cell membrane, transports nutrient, gets rid of poisonous and harmful substance, is good cell cleaning agent,
Enhance metabolism, cell activity enhancing, improves human activity, therefore, little molecule
The water of group is the water being best suitable for human body cell.
According to one of the present invention preferred embodiment in, with light shale powder body and viscous
Knot agent weight and be 100% meter, the consumption of described binding agent is 5～25wt%.
In further preferred embodiment, with light shale powder body and binding agent
Weight and be 100% meter, the consumption of described binding agent is 10～20wt%.
In the most preferred embodiment, with light shale powder body and binding agent
Weight and be 100% meter, the consumption of described binding agent is 15wt%.
Wherein, the effect of binding agent is to connect light shale powder body to form it into block or ball,
And improving block or the procedural strength of ball and hot property, its consumption is difficult to too much, can play
Adhesive property, consumption cause the most for a moment unnecessary waste, two can reduce right
The clean-up effect of drinking water, therefore, in the present invention, the consumption of binding agent is the lowest
Consumption in light shale powder body.
According to one of the present invention preferred embodiment, described binding agent is selected from containing oxidation
The aluminosilicate of aluminium component or ore deposit soil.
In further preferred embodiment, described binding agent is selected from bentonite, silicon
One or more in diatomaceous earth, attapulgite, Kaolin and sheep Montmorillonitum.
In the most preferred embodiment, described binding agent is selected from bentonite.
Wherein, described binding agent is natural adhesive, actually natural ore soil, will not produce
Life is inorganic or organically pollutes, and itself also has the strongest adsorption, energy
Drinking water is purified by enough auxiliary, and its raw material is easy to get, with low cost.
In the present invention, described cleanser is prepared by the method comprised the steps of:
Step 1, carry out light shale ore deposit crushing, clean, levigate and screening, obtain gently
Matter shale powder body.
According to one of the present invention preferred embodiment, in step 1, described cleaning is adopted
Carry out with waterpower washing screen, tubular washing screen, cylinder swaging machine or grooved log washer,
Mainly remove earth or other impurity on light shale rubble surface.
According to one of the present invention preferred embodiment, in step 1, described lightweight page
The particle diameter of rock dust body is 50～2000 mesh, preferably 100～1000 mesh, more preferably
200～500 mesh.
Step 2, light shale powder body, binding agent are mixed with water, obtain compound.
According to one of the present invention preferred embodiment, in step 2, based on lightweight page
The weight of rock dust body and binding agent and, the consumption of water is 5～25wt%, preferably 10～20
Wt%, more preferably 15wt%.
Wherein, the interpolation of water is to make light shale powder body preferably mix with binding agent
Close, make binding agent preferably play cementation, if the consumption of water is less than 5wt%,
Then not having effect, light shale powder body mixes bad with binding agent, if the consumption of water
Higher than 25wt%, then make system thinning, be unfavorable for the shaping pelletize in later stage, and,
The grain that water is created too much has fault of construction, and such as quality heterogeneity contains hole,
Meanwhile, too much water also can be on the quality affecting extruder in granulation process, such as
Corrosion or rustization.
Step 3, add mixture into extruder carry out extruding pelletization, then post processing,
Obtain clean reagent in drinking water.
According to one of the present invention preferred embodiment, in step 3, the entering of extruder
Mouth temperature is 200～300 DEG C, preferably 220～280 DEG C, more preferably 250 DEG C.
Wherein, the inlet temperature of extruder cannot be below 200 DEG C, when less than 200 DEG C,
Light shale powder body and binding agent can not reach good molten condition, mixing inequality
Even, can not get homogeneous product；The inlet temperature of extruder can not be higher than 300 DEG C,
When higher than 300 DEG C, owing to temperature is the highest, the grain extruded can the most quick-fried fall, impact
Its quality, and directly influence its clean-up effect to drinking water.
According to one of the present invention preferred embodiment, in step 3, the going out of extruder
Mouth temperature is 60～80 DEG C, preferably 65～75 DEG C, more preferably 70 DEG C.
Wherein, if outlet temperature is less than 60 DEG C, material quenching extrusion when can be made,
Affect its internal performance；If temperature is higher than 80 DEG C, owing to temperature is the highest, extrude
Grain is in class molten condition or viscous state, it is impossible to form the grain significantly separated.
According to one of the present invention preferred embodiment, in step 3, described post processing
Include successively being dried, cool down and sieving.
In further preferred embodiment, described it is dried as naturally drying, baking oven
Dry or lyophilization；The described room temperature that is cooled to cools down or sub-cooled.
In the most preferred embodiment, the temperature of described drying is
40～80 DEG C, preferably 60 DEG C；The described room temperature that is cooled to cools down.
Wherein, described room temperature is 10～30 DEG C, and described low temperature is about 5 DEG C.
According to one of the present invention preferred embodiment, in step 3, described drinking water
The particle diameter of cleanser is 1～5mm, preferably 2～4mm, more preferably 3mm.
Fourth aspect present invention is to provide the drinking water described in second and third aspect clean
Agent is for the purposes of purifying drinking water.
Wherein, second aspect and the clean reagent in drinking water described in the third aspect are by lightweight page
Rock ore deposit prepares, and has drinking water purifying functional.
The present invention is had the advantage that to include:
(1) in the present invention, described clean reagent in drinking water is prepared by light shale ore deposit,
Make chlorine that cleanser can effectively remove in drinking water, silt, Organic substance and thin
Bacterium etc.；
(2) in the present invention, described clean reagent in drinking water can regulate in drinking water
PH so that it is in alkalescence, and reduce hardness of water；
(3) in the present invention, described clean reagent in drinking water can make to divide greatly in drinking water
Hydrogen bond rupture between son group, makes water present with the form of subset, it is easy to by people
Body absorbs.
(4) raw material of clean reagent in drinking water of the present invention is easy to get, with low cost；
(5) the repeatable utilization of clean reagent in drinking water of the present invention, saves the energy；
(6) preparation method of institute of the present invention clean reagent in drinking water is simple, it is easy to extensive
Production application.
Embodiment
The present invention is further described below by way of instantiation.But these examples are only
It is exemplary, protection scope of the present invention is not constituted any restriction.
Wherein, light shale ore deposit used is selected from the domestic egg of Inner Mongol Mo Qi E Er and township
White shale ore.
The preparation of embodiment 1 native protein stone granule
Light shale ore deposit is crushed, cleans in grooved log washer, dry, then
Secondary pulverizing is also sieved, and obtains native protein stone granule, and granularity is 2mm.
The preparation of embodiment 2 native protein stone granule
Light shale ore deposit is crushed, cleans in grooved log washer, dry, then
Secondary pulverizing is also sieved, and obtains native protein stone granule, and granularity is 5mm.
The preparation of embodiment 3 clean reagent in drinking water
Being crushed in light shale ore deposit, obtain light shale rubble, particle diameter is 100mm.
Light shale rubble waterpower washing screen is cleaned, and roasting 110 at 500 DEG C
Min, cools down at 5 DEG C the most successively, sieves, and obtains clean reagent in drinking water, and particle diameter is
8mm。
The preparation of embodiment 4 clean reagent in drinking water
Being crushed in light shale ore deposit, obtain light shale rubble, particle diameter is 80mm.
By light shale rubble roasting 100min at 800 DEG C, the most successively at 5 DEG C
Cooling down, sieve, obtain clean reagent in drinking water, particle diameter is 6mm.
The preparation of embodiment 5 clean reagent in drinking water
Being crushed in light shale ore deposit, obtain light shale rubble, particle diameter is 60mm.
By light shale rubble roasting 90min at 900 DEG C, cold under room temperature the most successively
But, sieving, obtain clean reagent in drinking water, particle diameter is 5mm.
The preparation of embodiment 6 clean reagent in drinking water
Being crushed in light shale ore deposit, obtain light shale rubble, particle diameter is 40mm.
By light shale rubble roasting 80min at 1000 DEG C, the most successively in room temperature
Lower cooling, sieving, obtain clean reagent in drinking water, particle diameter is 2mm.
The preparation of embodiment 7 clean reagent in drinking water
Being crushed in light shale ore deposit, obtain light shale rubble, particle diameter is 20mm.
By light shale rubble roasting 70min at 1200 DEG C, the most successively in room temperature
Lower cooling, sieving, obtain clean reagent in drinking water, particle diameter is 2mm.
The preparation of embodiment 8 clean reagent in drinking water
Carry out light shale ore deposit crushing, clean in waterpower washing screen, levigate and sieve
Point, obtain light shale powder body.
By the mixing of 750kg light shale powder body, 250kg Kaolin and 250kg water all
Even, obtain compound.
Above-mentioned compound addition extruder is carried out extruding pelletization, the most successively in 40 DEG C
It is dried, cools down at 5 DEG C, sieves, obtain clean reagent in drinking water, wherein, extruder
Inlet temperature is 200 DEG C, and outlet temperature is 60 DEG C.
The preparation of embodiment 9 clean reagent in drinking water
Carry out light shale ore deposit crushing, clean in waterpower washing screen, levigate and sieve
Point, obtain light shale powder body.
By the mixing of 800kg light shale powder body, 200kg kieselguhr and 200kg water all
Even, obtain compound.
Above-mentioned compound addition extruder is carried out extruding pelletization, the most successively in 50 DEG C
It is dried, cools down at 5 DEG C, sieves, obtain clean reagent in drinking water, wherein, extruder
Inlet temperature is 220 DEG C, and outlet temperature is 65 DEG C.
The preparation of embodiment 10 clean reagent in drinking water
Carry out light shale ore deposit crushing, clean in waterpower washing screen, levigate and sieve
Point, obtain light shale powder body.
By the mixing of 850kg light shale powder body, 150kg bentonite and 150kg water all
Even, obtain compound.
Above-mentioned compound addition extruder is carried out extruding pelletization, the most successively in 60 DEG C
It is dried, cools down at room temperature, sieves, obtain clean reagent in drinking water, wherein, extruder
Inlet temperature be 250 DEG C, outlet temperature is 70 DEG C.
The preparation of embodiment 11 clean reagent in drinking water
Carry out light shale ore deposit crushing, clean in waterpower washing screen, levigate and sieve
Point, obtain light shale powder body.
By the mixing of 900kg light shale powder body, 100kg sheep Montmorillonitum and 100kg water all
Even, obtain compound.
Above-mentioned compound addition extruder is carried out extruding pelletization, the most successively in 70 DEG C
Being dried, cool down at room temperature, sieve, wherein, the inlet temperature of extruder is 280 DEG C,
Outlet temperature is 75 DEG C.
The preparation of embodiment 12 clean reagent in drinking water
Carry out light shale ore deposit crushing, clean in waterpower washing screen, levigate and sieve
Point, obtain light shale powder body.
By 950kg light shale powder body, 50kg kieselguhr and 50kg water mix homogeneously,
Obtain compound.
Above-mentioned compound addition extruder is carried out extruding pelletization, the most successively in 80 DEG C
Being dried, cool down at room temperature, sieve, wherein, the inlet temperature of extruder is 300 DEG C,
Outlet temperature is 80 DEG C.
Test example
Water sample used by this test example takes from Qiqihar Vehicle Factory well water.
Take four buckets and divide into No. A, No. B, No. C and No. D respectively, toward No. A, No. B,
The above-mentioned drinking water of 10kg is added respectively in No. C and No. D, and, add in A bucket
The native protein stone that about 1kg is prepared by embodiment 1, add in B bucket about 1kg by
The clean reagent in drinking water that embodiment 5 prepares, adds about 1kg by embodiment in C bucket
10 clean reagent in drinking waters prepared, are not added with any material as comparison in D bucket.
Wherein, due to the impact of surrounding working environment, the drinking water (well in carshop
Water) in heavy metal severe overweight, the content of heavy metal in its former water source i.e. D bucket
Exceed 500 times of content of beary metal defined in " drinking water sanitary standard ".
But, after cleanser provided by the present invention purifies, the huge sum of money in A, B and C bucket
Belong to and removing the most completely, reach standard for drinking.
The present invention has been carried out specifically by upper combination detailed description of the invention and exemplary example
Bright, but these explanations can not be interpreted as limitation of the present invention.Art technology
Personnel understand, without departing from the spirit and scope of the invention, and can be to this
Bright technical scheme and embodiment thereof carry out multiple equivalencing, modify or improve, this
It is within the scope of the present invention.Protection scope of the present invention is with claims
It is as the criterion.
Claims (10)
1. a native protein stone granule is for the purposes of purifying drinking water.
Purposes the most according to claim 1, wherein,
The particle diameter of described native protein stone granule is 0.5～8mm, preferably 1～6mm,
More preferably 2～5mm.
3. a clean reagent in drinking water, it is characterised in that
Described cleanser by light shale ore deposit through broken, clean, roasting and post processing system
?；And/or
The particle diameter of described cleanser is 0.5～8mm, preferably 1～6mm, more preferably
2～5mm.
Cleanser the most according to claim 3, it is characterised in that described lightweight
The inside of shale ore has poriform micropore gap, and the aperture of described micropore is 5～20
nm。
5. according to the cleanser described in claim 3 or 4, it is characterised in that
Obtaining light shale rubble after Po Sui, the particle diameter of described light shale rubble is
10～100mm, preferably 20～80mm, more preferably 40～60mm；
Described roasting is carried out as follows: carry out 70～110min at 500～1200 DEG C, excellent
Selection of land, carries out 80～100min at 800～1000 DEG C, it is highly preferred that at 900 DEG C
Carry out 90min；And/or
Described post processing includes cooling and screening successively.
6. a clean reagent in drinking water, it is characterised in that described cleanser by include with
The raw material of lower weight percentage component is made:
Light shale powder body 75～95wt%,
Binding agent 5～25wt%；
Preferably:
Light shale powder body 80～90wt%,
Binding agent 10～20wt%；
More preferably:
Light shale powder body 85wt%,
Binding agent 15wt%.
Cleanser the most according to claim 6, it is characterised in that
Described light shale powder body carries out crushing by light shale ore deposit, cleans, levigate and
Screening prepares；And/or
The inside of described light shale powder body has poriform micropore gap, described micropore
Aperture be 5～20nm；And/or
The particle diameter of described light shale powder body is 50～2000 mesh, preferably 100～1000
Mesh, more preferably 200～500 mesh；And/or
Described binding agent is native selected from aluminosilicate or the ore deposit of salic composition, preferably selects
One or several in bentonite, kieselguhr, attapulgite, Kaolin and sheep Montmorillonitum
Kind, more preferably bentonite.
8. according to the cleanser described in claim 6 or 7, it is characterised in that described only
Agent is prepared by the method comprised the steps of:
Step 1, carry out light shale ore deposit crushing, clean, levigate and screening, obtain gently
Matter shale powder body；
Step 2, light shale powder body, binding agent are mixed with water, obtain compound；
Step 3, add mixture into extruder carry out extruding pelletization, then post processing,
Obtain clean reagent in drinking water.
9. according to the cleanser one of claim 6 to 8 Suo Shu, it is characterised in that
In step 2, weight based on light shale powder body and binding agent and, the use of water
Amount is 5～25wt%, preferably 10～20wt%, more preferably 15wt%；And/or
In step 3, the inlet temperature of extruder is 200～300 DEG C, is preferably
220～280 DEG C, more preferably 250 DEG C；And/or
In step 3, the outlet temperature of extruder is 60～80 DEG C, is preferably
65～75 DEG C, more preferably 70 DEG C；And/or
In step 3, described post processing includes being dried, cool down and sieving successively.
10. want according to the clean reagent in drinking water one of claim 3 to 5 Suo Shu or right
Ask one of 6 to 9 described clean reagent in drinking waters for the purposes of purifying drinking water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610269133.8A CN105923683A (en) | 2016-04-27 | 2016-04-27 | Drinking water purifier |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610269133.8A CN105923683A (en) | 2016-04-27 | 2016-04-27 | Drinking water purifier |
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Family
ID=56836389
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107126762A (en) * | 2017-05-22 | 2017-09-05 | 杭州铭族科技有限公司 | One kind removes medicine and personal care articles in drinking water（PPCPs）Filter medium, filter core and preparation method |
| CN110921727A (en) * | 2018-09-19 | 2020-03-27 | 南京卡邦科技有限公司 | Organic nano water treatment agent and preparation method thereof |
| CN110921729A (en) * | 2018-09-19 | 2020-03-27 | 南京卡邦科技有限公司 | Water treatment agent containing isothiazolinone and preparation method thereof |
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Application publication date: 20160907 |