CN105921913A - Flux core cutting wire for underwater cutting - Google Patents

Flux core cutting wire for underwater cutting Download PDF

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Publication number
CN105921913A
CN105921913A CN201610483436.XA CN201610483436A CN105921913A CN 105921913 A CN105921913 A CN 105921913A CN 201610483436 A CN201610483436 A CN 201610483436A CN 105921913 A CN105921913 A CN 105921913A
Authority
CN
China
Prior art keywords
cutting
powder
thermite
micron
cutting wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610483436.XA
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Chinese (zh)
Inventor
冯吉才
李洪亮
刘多
郭宁
段如东
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Harbin Institute of Technology Weihai
Original Assignee
Harbin Institute of Technology Weihai
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harbin Institute of Technology Weihai filed Critical Harbin Institute of Technology Weihai
Priority to CN201610483436.XA priority Critical patent/CN105921913A/en
Publication of CN105921913A publication Critical patent/CN105921913A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0211Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in cutting
    • B23K35/0216Rods, electrodes, wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3601Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/368Selection of non-metallic compositions of core materials either alone or conjoint with selection of soldering or welding materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/0061Underwater arc welding

Abstract

The invention discloses a flux core cutting wire for underwater cutting. The flux core cutting wire comprises external metal skin and a powdery flux core, wherein the external metal skin is a low-carbon steel strip; the internal flux core comprises 40%-60% of thermite, 30%-50% of dolomite, 5%-10% of potassium carbonate, 0%-2% of rare-earth elements, 0%-5% of potassium feldspar and 0%-5% of lithium fluoride in percentage by mass. The flux core cutting wire has the beneficial effects that underwater metal structures can be cut by virtue of the heat production effect of exothermic components added to the flux core under the action of electric arc heating without additional oxygen supply and gas protection; and the flux core cutting wire has the characteristics of simple manufacturing and high cutting efficiency.

Description

A kind of imderwater cutting flux-cored cutting wire
Technical field
The invention belongs to welding and cutting material technical field, the specifically one wet method electric arc under water of metal material Cutting flux-cored cutting wire.
Background technology
Along with the development of national economy, marine resources development is also into new developing stage, and ocean platform is removed, shipwreck Salvage and the development of other underwater steel construction engineerings urgent need subsea cutting technology.Although China these several years cutting material under water and New technology aspect obtains large development, but cutting technique there is also gap with developed country in economy and applicability.At present, Hot-cut underwater cuts in technology, and the most frequently used in engineering is exactly electric arc-oxygen cutting (cutting bar), but electric arc-oxygen cutting oxygen demand amount is big, Cutting efficiency is low, limits its application, so needing to develop the imderwater cutting material that novel automatic degree is high.
Patent application CN 102699556 A discloses a kind of imderwater cutting material, uses steel pipe to wrap up many aluminium medicine core welderings The structure of silk, principle is consistent with electric arc-oxygen cutting, needs oxygen, and frequently change cutting material in cutting process, and efficiency is relatively Low.
Former Soviet Union patent SU 1358254A1 and domestic patent CN 102554520 B individually discloses a kind of self-shield water Lower wet type melt pole electrical arc cutting method, develops the most special flux-cored cutting wire, all contains more making in both cutting wire medicine cores Gas component, can cut carbon steel and low alloy steel effectively.But, this cutting wire needs technological parameter very big, uncomfortable Cut under deep water conditions;And aoxidize stainless steel inoperative, can only carbon steel and low-alloy steel, limit such and cut The actual application of silk.
Summary of the invention
The technical problem to be solved is to overcome the deficiencies in the prior art, it is provided that a kind of composition is reasonable, Make simple, it is possible to by the calorigenic action of the exothermicity component added in medicine core, it is not necessary to extra oxygen supply and the water of gas shield Lower cutting medication core cutting wire.
The present invention solves above-mentioned technical problem and be the technical scheme is that a kind of imderwater cutting flux-cored cutting wire, including Outer layer metal skin and internal medicine core, it is characterised in that: described outer layer metal skin is mild-carbon steel strip, and described internal medicine core is by aluminothermy Agent, dolomite, potassium carbonate, rare earth element, potassium feldspar and lithium fluoride composition, the mass percent of each constituent is: thermite 40-60%, dolomite 30-50%, potassium carbonate 5-10%, rare earth element 0-2%, potassium feldspar 0-5%, lithium fluoride 0-5%.
Thermite of the present invention is made up of micron order thermite and nanometer aluminum thermit powder, the two quality in medicine core Percentage is respectively micron order thermite 20-60%, nanometer aluminum thermit powder 0-30%.Nano aluminum thermit powder is nanometer aluminium powder and nano oxygen Changing the composition of copper powder, 1:2.5 carries out proportioning by mass percentage;Micron thermite is micron aluminium powder and micron cupric oxide powder Constituent, carries out proportioning according to mass percent 1:2.5.
Mild-carbon steel strip used by the present invention is the SPCC steel band of soft state, bandwidth 8mm, and thickness is 0.5mm.This steel band processability Can be good, the filling rate of medicinal powder is high.
Dolomite of the present invention and potassium feldspar particle diameter are 150-180 μm, and lithium fluoride and potassium carbonate particle diameter are 38-45 μ M, rare earth element particle diameter is 40 μm, and micron aluminium powder particle diameter is 100-150 μm, and micron cupric oxide particle diameter is 45 μm, nano aluminum powder Footpath is 50nm, and nano oxidized copper powder size is 40nm.
Advantage and the feature of the present invention are: the flux-cored cutting wire of the present invention, use SPCC mild steel metal sheath.In medicine core Containing a large amount of heat production components, in medicine core in addition to containing micron order thermite, medicinal powder adds more nano aluminum thermit powder, rely on The carrying out of the feature aggravation reaction that nano particle specific surface area is big, promotes electric arc cutting process further.Cutting process of the present invention Carry out under chemical heat and arc heat act on jointly, can effectively reduce cutting current size, reduce cutting power supply special The requirement of property.Additionally, the potassium feldspar added in medicinal powder and potassium carbonate etc. can make cutting process stable, it is achieved metal under water is tied The stable cutting of structure.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
One imderwater cutting flux-cored cutting wire of the present invention, including outer layer metal skin and internal medicine core, described outer layer metal skin For mild-carbon steel strip, described internal medicine core is made up of thermite, dolomite, potassium carbonate, rare earth element, potassium feldspar and lithium fluoride, respectively The mass percent of constituent is: thermite 40-60%, dolomite 30-50%, potassium carbonate 5-10%, rare earth element 0-2%, potassium Feldspar 0-5%, lithium fluoride 0-5%.Thermite of the present invention is made up of micron order thermite and nanometer aluminum thermit powder, the two Mass percent in medicine core is respectively micron order thermite 20-60%, nanometer aluminum thermit powder 0-30%.Nano aluminum thermit powder is nanometer Aluminium powder and the composition of nano oxidized copper powder, 1:2.5 carries out proportioning by mass percentage;Micron thermite is micron aluminium powder and micro- The constituent of rice cupric oxide powder, carries out proportioning according to mass percent 1:2.5.
Mild-carbon steel strip used by the present invention is the SPCC steel band of soft state, bandwidth 8mm, and thickness is 0.5mm.This steel band processability Can be good, the filling rate of medicinal powder is high.
Dolomite of the present invention and potassium feldspar particle diameter are 150-180 μm, and lithium fluoride and potassium carbonate particle diameter are 38-45 μ M, rare earth element particle diameter is 40 μm, and micron aluminium powder particle diameter is 100-150 μm, and micron cupric oxide particle diameter is 45 μm, nano aluminum powder Footpath is 50nm, and nano oxidized copper powder size is 40nm.
The preparation method of the flux-cored cutting wire of the present invention is, selects soft state SPCC mild-carbon steel strip, bandwidth 8mm, and thickness is 0.5mm.Be made by drawing machine, flux-cored cutting wire cross section in ' O ' shape, cutting wire diameter 2.0mm.
In the chemical composition of above-mentioned internal medicine core, content and the mechanism of action of each composition are as follows:
In the present invention, thermite is the composition that content is more, is made up of micron order thermite and nanometer aluminum thermit powder, and they are at electricity Reacting under the hot high temperature action of arc, release more heat, assistant electric arc is by metal molten to be cut;Nanometer aluminum thermit powder is Utilizing nanometer aluminium powder and nano oxidized copper powder, the method compound by ultrasonic disperse prepares, and relies on nano aluminum thermit reaction speed Hurry up, the feature that energy release rate is high, promote cutting process, but nano aluminum thermit powder content can not be the highest, otherwise can make medicine core stream Dynamic property is deteriorated, and affects flux-cored wire manufacture craft.In the present invention, micron order thermite addition is 20-60%, nanoscale aluminothermy Addition 0-30% of agent.
The dolomite added in the present invention acts primarily as gas making effect, and during imderwater cutting, the gas of dolomite release plays guarantor Protect scarfing, reduce the effect of dross amount, and increase electric arc under water and endure power and penetration power.In the present invention, the addition of dolomite is 30-50%。
Rare earth element, potassium carbonate, lithium fluoride and the potassium feldspar added in the present invention, Main Function stablizes electric arc, and increase is cut Cutting the long arc stbility of electric arc, making imderwater cutting easy arc striking, rare earth elements addition of the present invention is 0-2%, and potassium carbonate adds Amount is 5-10%, and lithium fluoride addition is 0-5%, and potassium feldspar addition is 0-5%.
Table 1 is chemical composition and the composition content of internal medicine core in various embodiments of the present invention.
The medicine core component of embodiment 1 prepares flux-cored cutting wire, under the conditions of cutting current 350-380A, voltage about 40V, right 12mm thickness Q235 steel plate carries out imderwater cutting, can obtain the preferable scarfing of quality.
The medicine core component of embodiment 2 prepares flux-cored cutting wire, under the conditions of cutting current 300-320A, voltage about 40, right 12mm thickness Q235 steel plate carries out imderwater cutting, obtains the preferable scarfing of quality.
The medicine core component of embodiment 3 prepares flux-cored cutting wire, under the conditions of cutting current 400-430A, voltage about 45V, right 16mm thickness Q235 steel carries out imderwater cutting, can obtain scarfing.
The medicine core component of embodiment 4 prepares flux-cored cutting wire, under the conditions of cutting current 300-340A, voltage about 30V, right 8mm thickness Q235 steel carries out imderwater cutting, obtains the preferable scarfing of quality.
The medicine core component of embodiment 5 prepares flux-cored cutting wire, under the conditions of cutting current 380-410A, voltage about 40V, right 12mm thickness Q235 steel carries out imderwater cutting, obtains the preferable scarfing of quality.

Claims (4)

1. an imderwater cutting flux-cored cutting wire, including outer layer metal skin and internal medicine core, it is characterised in that: described outer layer metal Skin is mild-carbon steel strip, and described internal medicine core is made up of thermite, dolomite, potassium carbonate, rare earth element, potassium feldspar, lithium fluoride, respectively The mass percent of constituent is: thermite 40-60%, dolomite 30-50%, potassium carbonate 5-10%, rare earth element 0-2%, potassium Feldspar 0-5%, lithium fluoride 0-5%.
Imderwater cutting flux-cored cutting wire the most according to claim 1, it is characterised in that: described outer layer metal skin is soft state SPCC mild-carbon steel strip, its bandwidth 8mm, thickness is 0.5mm.
Imderwater cutting flux-cored cutting wire the most according to claim 1, it is characterised in that: described thermite is by micron order aluminium Thermit powder and nanometer aluminum thermit powder composition, micron order thermite mass percent in internal medicine core is 20-60%, nanometer aluminum Thermit powder mass percent in internal medicine core is 0-30%;Nano aluminum thermit powder is made up of nanometer aluminium powder and nano oxidized copper powder, presses Mass percent 1:2.5 carries out proportioning;Micron thermite is made up of, according to mass percent micron aluminium powder and micron cupric oxide powder 1:2.5 carries out proportioning.
Imderwater cutting flux-cored cutting wire the most according to claim 3, it is characterised in that: described dolomite and potassium feldspar particle diameter Being 38-45 μm for 150-180 μm, lithium fluoride and potassium carbonate particle diameter, rare earth element particle diameter is 40 μm, and micron aluminium powder particle diameter is 100-150 μm, micron cupric oxide particle diameter is 45 μm, and nanometer aluminium powder particle diameter is 50nm, and nano oxidized copper powder size is 40nm.
CN201610483436.XA 2016-06-28 2016-06-28 Flux core cutting wire for underwater cutting Pending CN105921913A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108213760A (en) * 2018-01-23 2018-06-29 刘希福 Oxygen imderwater cutting item is exempted from a kind of manual metal-arc welding
CN108326466A (en) * 2018-02-07 2018-07-27 郑州机械研究所有限公司 A kind of highly conductive aluminothermy welding powder

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069407A (en) * 1975-12-10 1978-01-17 Brower Jerome S Underwater cutting rod
SU1358254A1 (en) * 1986-03-28 1995-02-09 Институт Электросварки Им.Е.О.Патона Flux-cored wire for underwater cutting
CN101444876A (en) * 2008-11-20 2009-06-03 清华大学 Manual thermit welding electrode and preparation and using methods thereof
CN102049630A (en) * 2010-11-09 2011-05-11 衣衍亮 Material for fast hand cutting and application thereof
CN201848628U (en) * 2010-11-09 2011-06-01 衣衍亮 Manual quick cutting system
CN102699544A (en) * 2012-01-12 2012-10-03 柳吉兰 Cutting system accomplishing cutting by using underwater manual rapid cutting material
CN104722960A (en) * 2015-03-24 2015-06-24 江苏科技大学 High-efficiency heat production flux-cored cutting wire for underwater wet-type arc cutting and preparation method thereof
CN104858565A (en) * 2015-06-03 2015-08-26 哈尔滨工业大学(威海) Chemical core cutting wire for underwater wet method electric arc cutting

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069407A (en) * 1975-12-10 1978-01-17 Brower Jerome S Underwater cutting rod
SU1358254A1 (en) * 1986-03-28 1995-02-09 Институт Электросварки Им.Е.О.Патона Flux-cored wire for underwater cutting
CN101444876A (en) * 2008-11-20 2009-06-03 清华大学 Manual thermit welding electrode and preparation and using methods thereof
CN102049630A (en) * 2010-11-09 2011-05-11 衣衍亮 Material for fast hand cutting and application thereof
CN201848628U (en) * 2010-11-09 2011-06-01 衣衍亮 Manual quick cutting system
CN102699544A (en) * 2012-01-12 2012-10-03 柳吉兰 Cutting system accomplishing cutting by using underwater manual rapid cutting material
CN104722960A (en) * 2015-03-24 2015-06-24 江苏科技大学 High-efficiency heat production flux-cored cutting wire for underwater wet-type arc cutting and preparation method thereof
CN104858565A (en) * 2015-06-03 2015-08-26 哈尔滨工业大学(威海) Chemical core cutting wire for underwater wet method electric arc cutting

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108213760A (en) * 2018-01-23 2018-06-29 刘希福 Oxygen imderwater cutting item is exempted from a kind of manual metal-arc welding
CN108326466A (en) * 2018-02-07 2018-07-27 郑州机械研究所有限公司 A kind of highly conductive aluminothermy welding powder
CN108326466B (en) * 2018-02-07 2020-02-14 郑州机械研究所有限公司 High-conductivity aluminum hot welding powder

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Application publication date: 20160907

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