CN1059136A - The manufacture method and the device of the glass wool that forms thermally-insulated body are used to jet - Google Patents

The manufacture method and the device of the glass wool that forms thermally-insulated body are used to jet Download PDF

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Publication number
CN1059136A
CN1059136A CN91105583A CN91105583A CN1059136A CN 1059136 A CN1059136 A CN 1059136A CN 91105583 A CN91105583 A CN 91105583A CN 91105583 A CN91105583 A CN 91105583A CN 1059136 A CN1059136 A CN 1059136A
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China
Prior art keywords
roller
glass wool
glass
machine
guide plate
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CN91105583A
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Chinese (zh)
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CN1037959C (en
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大泷庆二
依田光司
筱生幸义
半泽忠
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Nitto Boseki Co Ltd
Paramount Glass Manufacturing Co Ltd
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Nitto Boseki Co Ltd
Paramount Glass Manufacturing Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/06Manufacture of glass fibres or filaments by blasting or blowing molten glass, e.g. for making staple fibres

Abstract

A kind of be used to prepare with wet blow the method that method forms the out-of-shape small glass wool piece of thermally-insulated body, it comprises makes fiber with fused glass, on transfer roller, compile glass fibre and form glass wool, simultaneously a kind of treatment agent is sprayed onto on the glass fibre, this treatment agent does not have cementability but has drainage and dirt resistance, moisture content on the evaporation glass wool in the treatment agent, with the Garnett cutter this glass wool is prescinded or fritter in irregular shape, and the step of this small glass wool piece being sent into packaging station.Mixture and water with silicone and whiteruss combine as treatment agent, and the deposition of heating and dried whiteruss and silicone is regulated, and make it to be between the 0.5%-3.0% of glass fibre weight.

Description

The manufacture method and the device of the glass wool that forms thermally-insulated body are used to jet
The present invention relates to the manufacture method and the device of small glass wool piece in irregular shape, these glass wool pieces blow with wetting to reach in the buildings top ceiling in the space of method between the interior exterior wall of buildings and form thermally-insulated body.
This class is used to jet, and the glass wool that forms thermally-insulated body normally makes with a kind of like this method, this method comprises utilizes centrifugal force that melten glass is made fiber, on transfer roller, compile this glass fibre and form glass wool, simultaneously spray a kind of caking agent to them, solidify this caking agent to form glass fiber blanket, smash this glass fiber blanket to pieces forming shape irregular small glass wool piece.
Fig. 3 is the schematic cross-section of traditional stamp mill, as shown in the figure, the machine of being represented by A comprises housing B, wherein is furnished with a rotary hammer C, it is broken into fine grained chippings with glass fiber blanket D, these fine grained chippings are by the hole E of sieve among the F, thereby make small glass wool piece in irregular shape, their formation thermally-insulated bodys of can jetting.
Yet there is following point when forming thermally-insulated body in this glass wool wet blowing.At first, by hit the pieces of glass cotton that broken this glass fiber blanket forms with rotary hammer C, its density is too big, so that when then needing to carry out more stuffing operation than low density product when reaching predetermined insulation value, this will make the rising of equipment work cost.
Blow in the journey wet, pieces of glass is cotton carries by the flexible pipe pneumatically, in the exit of this flexible pipe, sprays a kind of setting aqueous solution when glass wool being jetted in space that will be heat insulation on this glass wool, wherein contains cooling curing type caking agent.Caking agent in the small glass wool piece that forms with stamp mill A does not have higher drainage, so the aqueous solution of used cold solid type caking agent will be full of glass wool, and increases its weight.The cotton piece of these heavy glass will can not fly over sufficiently long distance when jetting in requisite space.Therefore, if the cotton piece of these heavy glass is blown into (for example in the space in the top ceiling) in the horizontal space, it is just very difficult then to want to form predetermined insulating thickness in whole horizontal space.On the other hand, if the space of filling is vertical, and the glass wool that then blows solid deadweight before caking agent solidifies is sunk, thereby causes not filling glass cotton of this spatial top.
People require to be blowed the glass wool that forms thermally-insulated body and can prevent dust, and the method that is used for satisfying this requirement at present is to spray a kind of dust-proofing agent at once when compiling glass fibre become glass wool on transfer roller or at small glass wool piece after the opening part of the sieve F of stamp mill A comes out.If but do not adopt in the time of effectively producing the dust-proofing agent of drainage simultaneously yet, then only can produce low drainage with dust-proofing agent.
In addition, be not unsuitable for being subjected to the effect of repeatedly beaing of rotary hammer C as yet, and easier " playing dirt " or size become littler by the glass wool piece of sieve F mesopore E.The scheme that a kind of usefulness solves this " playing dirt " problem has been described in the U.S. Pat 4296164.But this scheme still can not solve owing to the not enough problem that causes of drainage, and the improvement on output and operation efficiency still is not enough to bear the increase of cost of investment.
Another problem of traditional this class glass wool of forming thermally-insulated body of being used to jet is owing to use mineral oil to reach required performance such as drainage, water resisting property and dustproof that cause and owing to use resol causes as caking agent.If this class glass wool is blown in the space or top ceiling between the interior and exterior wall, then mineral oil or uncured resol may be on wall or top ceiling surface seepage, and in blowing operating process dirt can take place measure greatly.
The present invention finishes under these environment, and an one purpose is to provide a kind of effective ways of glass wool piece of manufacturing, this glass wool piece has gratifying low density, high drainage and dustproof, and its formation thermally-insulated body of jetting effectively, and can not cause any actual dirt.
Another object of the present invention is to provide a kind of device that this is improved one's methods of implementing.
First purpose of the present invention can realize by following this method, it comprises makes fiber with fused glass, on transfer roller, compile this glass fibre to form glass wool, spray a kind of treatment agent simultaneously, this treatment agent does not have adhesive property but has drainage and dirt resistance, evaporation joins the moisture of treatment agent in the glass wool, with the Garnett cutter this glass wool is chopped into fritter in irregular shape, and this fritter is transported to packaging station.
In preferred embodiments, adopt the mixture of whiteruss and silicone to be combined in one and made to be treatment agent with water, through heating and drying after, the deposition of whiteruss and silicone be adjusted at glass fibre weight 0, in the 5-3,0% scope.
Second purpose of the present invention obtains by a kind of cutter, and this cutter comprises:
A housing;
The short roller of cutting of Garnett;
One is positioned at the short roller that is used for feeding glass wool on roller opposite of cutting of this Garnett;
A plate that is used to guide this glass wool, it extends to the delivery end of the transfer roller that is used for carrying glass wool, this guide plate has a delivery end in the gap between two rollers, this guide plate is installed on the housing, but its position can be adjusted along machine direction, so that in the gap of adjustment between its delivery end and feeding roller garden perimeter surface, the bearing of this Gar-nett cutter is installed on the housing, its position can be adjusted along machine direction, thus the spacing of adjusting and guide plate delivery end;
One of feeding roller drives unit, and its speed of rotation is adjustable;
Garnett is short, and of cutting roller drives unit, and its speed of rotation is also adjustable.
The method according to this invention, the glass wool that collects on the transfer roller is only handled with a kind of treatment agent, and this treatment agent has drainage and dirt resistance, but it does not have adhesive property.Therefore, even through heating and drying process, this glass wool can not produce owing to the integrated structure that produces with caking agent yet.When this glass wool was admitted to the Garnett cutter, it can be cut into the even substantially but fritter in irregular shape of size by direct action.Because this glass wool also can not be subjected to repeatedly shortly not cut effect, therefore, the density when its density of the small glass wool piece that is produced can not be higher than this integral body glass wool, and the chance that dirt taken place is reduced to minimum.To guarantee higher productivity.
As the small glass wool piece of the finished product owing to when melten glass forms fiber, having used drainge treating agent to have gratifying drainage.Even thereby sprays on glass wool in the exit that forms the flexible pipe of thermally-insulated body of being used for jetting and to contain the cold aqueous solution of consolidating the type caking agent, this solution can not be full of these small glass wool pieces yet, thereby has just guaranteed its effective application yet.
According to device of the present invention, form the size and the density of the final product of thermally-insulated body according to the specific dimensions of small glass wool piece and density and winding-up, suitablely be used for realizing that the top condition of prescinding the glass wool that does not contain caking agent of high-efficiency and continuous operation can more easily determine
Fig. 1 is the vertical section synoptic diagram of the cutter of second purpose according to the present invention.
Fig. 2 utilizes machine shown in Figure 1 to make the schematic flow sheet of glass wool by method of the present invention.
Fig. 3 is the vertical section synoptic diagram of traditional stamp mill.
As shown in Figure 2, the glass of fusing is admitted to feeder channel 2 in stove 1, sends into rotary glass fiberizer 4 by nozzle 3 then, thereby forms glass fibre 5 in from the flame of fibroblast burner. Simultaneously, spray a kind of inorganic agent on this glass fibre, this inorganic agent does not have adhesive property but has drainage and dust tightness. This inorganic agent is supplied with by nozzle 6. Collect on the conveyer 8 at treated glass fibre under the effect of vacuum tank 7, form mineral wool 9.
Mineral wool 9 is transported on the conveyer 10, makes its moisture evaporation by heating and drying in drier 11. Do not have bonding agent, resulting dried mineral wool 12 just can not make glass fibre be sticked together. Then this mineral wool 12 is delivered to chopping machine 13, and prescind into each fritter 14, fritter 14 enters packing machine 18 by carrier pipe 16 and 17 under the ordering about of air blast 15. Here these fritters are pressed into packaging bag 19.
Fig. 1 has described chopping machine 13 in more detail, it comprises housing 20, the chopped roller 22 of the Garnett of axial support on bearing 21, the axial support feeding roller 24 relative with chopped roller 22 on bearing 23, guide plate 26 has a delivery end 27 in the gap 25 between two rollers 22 and 24.
The bearing 21 of chopped roller 22 is installed on the housing 20 by a kind of known position adjusting mechanism (end illustrates), and its position can be adjusted along machine direction (namely perpendicular to roll shaft) by the slip mouth 28 in the housing 20. The rotary speed of roller 22 can freely be adjusted, this be because it by the adjustable driver element of transmission circuit 30 and rotating speed (shown in situation under, this driver element is a dc motor 29) be coupled.
Spring 32 is between the bearing 23 and housing 20 top inner surfaces 31 of feeding roller 24, by the length with bolt 33 regulating springs 32, bearing 23 can be along on the housing, lower movement, thus freely regulating action is at the pressure of the lower-glass cotton 12 between the upper surface of feeding roller 24 and guide plate 26.
The rotary speed of feeding roller 24 also is can be freely regulated because it by the adjustable driver element of transmission circuit 35 and rotating speed be coupled (shown in situation under, this driver element is a dc motor 34).
Guide plate 26 is having the upper surface of a bending near the end of chopped roller 22, thereby the gap 36 between guide plate 26 and the feeding roller 25 is reduced gradually towards the direction of the delivery end 27 of plate 26.
Guide plate 26 is fixed to by bolt 39 on the carriage 38 of housing 20, and bolt 39 can screw or revolve bolt, to regulate the gap X between delivery end 27 and feeding roller 24 garden perimeter surface.
Bearing 21 by regulating this chopped roller 22 is along the position of machine direction (perpendicular to this roll shaft), and the gap Y on delivery end 27 and the chopped roller 22 between each tooth 40 is also adjustable.
Chopped roller 22 is furnished with device 41, to remove the fiber that adheres on the roller tooth, also is furnished with bolt 42 with the position of adjusting device 41.
In order to reach the purpose of chopped glass cotton 12, preferably its periphery of Gar-nett line on roller 22 has to high-density bigger tooth. If the gap Y on guide plate 26 delivery ends 27 and the roller 22 between each tooth is littler, the size of the mineral wool piece that then obtains will reduce, if Y is bigger, then size will increase. Suitable Y value will be selected to determine in the degree of the effect lower convexity of centrifugal force and according to the size of the mineral wool piece that will obtain in rotary course according to the Gar-nett line.
Can send into continuously and do not interrupt for the mineral wool 12 that guarantees to be formed by crisp glass fibre, this feeding roller 24 is preferably made by hard rubber, and on its garden perimeter surface in axial direction with groove. Should guarantee that mineral wool (wherein being sticked together between each filament) is clamped between the delivery end 27 of roller 24 and guide plate 26 effectively when selecting the value of the gap X of garden between week of the delivery end 27 of guide plate 26 and roller 24 very weakly, and guarantee that this mineral wool integral body 12 can send into continuously lastingly without interruption. Can regulate gap X by move forward and backward nut 39 along machine direction.
The upper surface of guide plate 26 contacts with the glass fibre that hard some slided. Therefore, guide plate 26 is preferably made by full genus, and its upper surface has one deck ceramic coating. The more little effect of then prescinding of the thickness Z of guide plate 26 delivery ends 27 is more good. But in order to guarantee necessary mechanical strength, the Z value is usually in about 1 millimeter.
The following example only is used for further describing the present invention, and does not limit it.
Embodiment
Output with 225 kilograms/hour prepares glass fibre, sprays treatment agent with 130 liters/hour on glass fibre, and this treatment agent is by 0.93% silicone, and 7.60% whiteruss and 91.47% water (surplus) are formed, and with their heating and dry, obtains glass wool 12 then.The content of silicone and whiteruss (weight ratio) between 0.5-3.0% in the glass wool
Under the conditions shown in Table 1 these glass wools are prescinded.These products that prescind are blown in the space.The density that thermally-insulated body had that obtains also is shown in Table 1.
Table 1
X gap, test piece number (Test pc No.) gap Y feeding roller speed V 1Short cutting mixed speed V 2V 1/ V 2Winding-up glass
(rice/minute) cotton density
(kg/m 3)
1 1.5 1.5 4.5 21.6 1∶4.8 39.6
2 1.0 2.0 7.5 25.2 1∶3.36?35.7
3 1.0 2.0 7.5 33.8 1∶4.51?32.4
4 1.0 2.0 7.5 36.0 1∶4.8 32.0
The comparative example
Output with 225 kilograms/hour prepares glass fibre, sprays mineral oil, resol or the like on this glass fibre, subsequently it is solidify to form glass wool.With machine as shown in Figure 3 this glass wool integral body is smashed to pieces.This stamp product is blown in the space, and its density of the thermally-insulated body that obtains is 37.1 kilograms/meter 3
The comparison of a heat-proof quality and a dirt performance:
In the average test temperature is that 30 ℃ and sample density are 35 kilograms/meter 3Condition under measure heat conductivility, sample No.4(sees Table 1) thermal conductivity be 0.0314 kilocalorie/mph ℃, and the heat conductivility of Comparative Examples is 0.0364 a kilocalorie/mph ℃. carry out the vibratory screening apparatus test according to JISA9523-1990, sample No.4 throughput is 0.24% as a result.And the throughput of Comparative Examples is 1.8%.
The comparison of drainage performance:
Pack into 2 gram glass wools that prescind or that smash to pieces (sample No.4 or control sample) and 1 liter of tap water in the mixing tank and with 1500 rev/mins of speed stirrings 30 seconds.Move into this mixture in graduated cylinder (1000 milliliters) and placed 15 minutes.The glass wool that sample No.4 prescinds swims in the water, at the bottom of control sample then absorbs water and is sunken to tin.
These test results are described as follows.Sample 2-4 can be blown into the space and form low-density thermally-insulated body.They not only have good drainage tool " rise dirt " trend less.Also can obtain similar result when satisfying following condition: the gap X between the delivery end 27 of guide plate 26 and the feeding roller 24 garden perimeter surface is between the 0.5-1.5 millimeter; The delivery end 27 of guide plate 26 and short cut on the roller 22 the gap Y between each tooth 40 between the 1-3 millimeter; Feeding roller 24 and weak point are cut the garden roll surface speed ratio of roller 22 1: 4-1: between 6, and short garden roll surface speed rotation of cutting roller 22 with the 25-35 meter per second; And after drying 0.5-3.0% by the content of treatment agent in glass wool that silicone and whiteruss are formed.
As gap X during less than 0.5 millimeter, not only prescinded too little piece by glass wool, nor may with uniform amount and adhesion send into this glass wool integral body.Another problem that is taken place is the glass fibre fracture.When gap X surpassed 1.5 millimeters, glass wool is whole just can not to remain between guide plate 26 and the feeding roller 24 fully effectively, to prevent that this glass wool integral body is prescinded into inappropriate bulk.
As gap Y during less than 1 millimeter, this glass wool integral body is prescinded too little piece.And the short Garnett line of cutting on the roller 22 will radially outward protrude by action of centrifugal force in the high speed rotating process, and this might make the tooth 40 and the delivery end 27 of guide plate 26 come in contact.When gap Y surpassed 3 millimeters, this glass wool is whole might to be prescinded into inappropriate bulk.
When short circumferential speed of cutting roller 22 during less than 25 meter per seconds, its behavior of prescinding will descend, even and adjust feeding roller 24 also can not the less glass wool piece of acquisition size with the feeding speed that reduces glass wool integral body 12.On the other hand, the garden roll surface speed of cutting roller 22 when weak point surpasses 35 meter per seconds, and it prescinds behavior with excessive, and the glass fibre in this glass wool integral body will rupture.
When feeding roller 24 and the short rim vdocity ratio of cutting roller 22 are in 1: 4-1: in the time of outside 6, will produce and lack the garden roll surface speed of cutting roller 22 and exceed the similar problem of 25-35 meter per second scope.
The residual volume of the treatment agent of forming when silicone and whiteruss in the glass wool integral body after the drying is less than 0.5% the time, and it just can not obtain essential drainage and dirt resistance effectively.Even when the residual volume of this treatment agent surpasses 3.0%, can not obtain to improve accordingly therewith as the performance of the glass wool of the finished product.
The method according to this invention collects in glass wool on the transfer roller and does not have stick to each other together structure of glass fibre, and this point is different with situation with caking agent.Therefore, when sending into this glass wool in the Garnett cutter, just can direct action it be prescinded the irregular fritter of forming shape, its size is even substantially, and unwanted influence can not take place, for example, a dirt of glass fibre, or the unwanted increase of dead small density.In brief, method of the present invention can make effectively be used for being blown between the interior and exterior wall or in the top ceiling to form the glass wool of high quality thermofin, they have good drainage and dirt resistance, and can not pollute wall or top ceiling surface or cause that fine particle plays dirt.
According to device of the present invention, can adopt a kind of glass wool that does not contain caking agent, and the top condition of cutting this glass wool integral body determines that easily these conditions are suitable to be used for realizing the efficient production small glass wool piece, these glass wool pieces have predetermined size and density.

Claims (11)

1, the preparation method of the glass wool that forms thermally-insulated body that is used to jet, this method comprises makes fiber with melten glass, on transfer roller, compile glass fibre to form glass wool, while sprays no adhesion performance but has drainage and the treatment agent of dirt resistance on glass fibre, moisture on the evaporation glass wool in the treatment agent, with the Garnett cutter this glass wool is prescinded the irregular fritter of forming shape, and the step of this fritter being sent into packaging station.
2, according to the method for claim 1, wherein the mixture of silicone and whiteruss and water combine and are used as treatment agent, deposition to heating and dried whiteruss and silicone is regulated, and makes it to be in the 0.5-3.0% scope of glass fibre weight.
3, be used to make and be used for jetting the cutter of the glass wool that forms thermally-insulated body, this machine comprises:
A housing
The short roller of cutting of Garnett
One is positioned at described Garnett weak point and cuts the roller that the roller opposite is used for feeding glass wool;
One is used for the glass-guiding cotton and is transported to the guide plate of conveyor delivery end continuously, this guide plate has a delivery end in the gap between this two roller, and so that the mode that its position can be adjusted along machine direction is installed, so that adjust the gap between its delivery end and feeding roller garden perimeter surface, Garnett is short cut roller bearing so that its position can install along the mode of machine direction adjustment so as to adjust and the guide plate delivery end between the gap;
A driver element that is used for feeding roller, its rotating speed is adjustable; And
One is used for the short driver element of cutting roller of Garnett, and its rotating speed is adjustable equally.
4,3 machine as requested, it also comprises: be used for regulating the device that promotes feeding roller, so that regulating effect is being in the pressure on the glass wool between feeding roller and the guide plate upper surface.
5, according to the machine of claim 3, it also comprises being used for removing and adheres to the short device of cutting fiber on the roller tooth of Gar-nett, and the described device of removing is removed the short setting device of cutting the position of roller of the relative Garnett of device and is installed on the housing by regulating this.
6, according to the machine of claim 3, wherein said feeding roller is made by vulcanite, in axial direction has groove on its garden perimeter surface.
7, according to the machine of claim 3, wherein said guide plate is made of metal, and its upper surface has one deck ceramic coating.
8, according to the machine of claim 3, the delivery end thickness of wherein said guide plate is 1 millimeter.
9, according to the machine of claim 3, the value that wherein is in the gap between guide plate delivery end and the feeding roller garden perimeter surface is between the 0.5-1.5 millimeter.
10,, wherein be in guide plate delivery end and Gar-nett weak point and cut the value in the gap between each tooth of roller between the 1-3 millimeter according to the machine of claim 3.
11, according to the machine of claim 3, wherein the short ratio of cutting the garden roll surface speed between the roller of feeding roller and Garnett is 1: 4-1: in 6 scopes, cut the garden roll surface speed of roller in 25-35 meter per second scope and Garnett is short.
CN91105583A 1990-07-17 1991-07-17 Process and apparatus for producing glass wool that is to be blown to form thermal insulation Expired - Fee Related CN1037959C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP189187/90 1990-07-17
JP2189187A JP2753888B2 (en) 1990-07-17 1990-07-17 Method and apparatus for producing glass wool insulation for blowing

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CN1059136A true CN1059136A (en) 1992-03-04
CN1037959C CN1037959C (en) 1998-04-08

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KR (1) KR0171898B1 (en)
CN (1) CN1037959C (en)
HU (1) HU214038B (en)
IT (1) IT1249681B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050587C (en) * 1996-04-12 2000-03-22 北京欣景装饰保温材料有限公司 Process for manufacturing super-thin and high volume weight glass fiber products
CN106128793A (en) * 2016-06-24 2016-11-16 安徽江威精密制造有限公司 The hybrid supercapacitor diaphragm material that a kind of isolation performance is good

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US6562257B1 (en) 2000-04-25 2003-05-13 Owens Corning Fiberglas Technology, Inc. Loose-fill insulation with improved recoverability
JP6175342B2 (en) * 2013-10-09 2017-08-02 株式会社 エスジー Slurry-like coating material and slurry-like coating material preparation apparatus method and apparatus
GB201412350D0 (en) * 2014-07-11 2014-08-27 Knauf Insulation Insulating package
WO2016052950A1 (en) * 2014-09-29 2016-04-07 주식회사 해나라 Filament manufacturing system using waste rope and method therefor
KR101653625B1 (en) * 2014-09-29 2016-09-02 주식회사 해나라 Filament manufacturing apparatus using wasted-rope
KR101659843B1 (en) * 2015-11-05 2016-09-26 주식회사 해나라 Filament manufacturing method using wasted-rope
EP3971149A4 (en) * 2019-10-29 2023-07-19 Nitto Boseki Co., Ltd. Glass multiple-ply roving, random mat for forming thermoplastic composite material, and glass-fiber-reinforced thermoplastic resin sheet
CN110746090B (en) * 2019-11-28 2022-02-22 内蒙古世环新材料股份有限公司 Production system and production method of microfiber glass wool

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US4296614A (en) * 1977-08-27 1981-10-27 Usm Corporation Leather press
CA1116994A (en) * 1979-08-03 1982-01-26 Robert B. Simpson Manufacture of glass fibre blowing wool
US4476185A (en) * 1982-08-30 1984-10-09 Spittle Industries, Inc. Blowable glass fiber thermal insulation product
US4682523A (en) * 1985-02-04 1987-07-28 Owens-Corning Fiberglas Corporation Methods of making glass wool blowing insulation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050587C (en) * 1996-04-12 2000-03-22 北京欣景装饰保温材料有限公司 Process for manufacturing super-thin and high volume weight glass fiber products
CN106128793A (en) * 2016-06-24 2016-11-16 安徽江威精密制造有限公司 The hybrid supercapacitor diaphragm material that a kind of isolation performance is good

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JP2753888B2 (en) 1998-05-20
ITRM910532A0 (en) 1991-07-16
CN1037959C (en) 1998-04-08
JPH0477329A (en) 1992-03-11
KR920002480A (en) 1992-02-28
KR0171898B1 (en) 1999-02-18
ITRM910532A1 (en) 1993-01-16
HU214038B (en) 1997-12-29
HU912360D0 (en) 1991-12-30
HUT66380A (en) 1994-11-28
IT1249681B (en) 1995-03-09

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