CN105908106A - High-strength and wear-resistant oxide-based metal ceramic bearing and preparation method thereof - Google Patents

High-strength and wear-resistant oxide-based metal ceramic bearing and preparation method thereof Download PDF

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Publication number
CN105908106A
CN105908106A CN201610485579.4A CN201610485579A CN105908106A CN 105908106 A CN105908106 A CN 105908106A CN 201610485579 A CN201610485579 A CN 201610485579A CN 105908106 A CN105908106 A CN 105908106A
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China
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parts
powder
oxide
bearing
base cermet
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CN201610485579.4A
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Chinese (zh)
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王莹
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Individual
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Individual
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/10Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
    • B22F5/106Tube or ring forms
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/14Making alloys containing metallic or non-metallic fibres or filaments by powder metallurgy, i.e. by processing mixtures of metal powder and fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/14Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments

Abstract

The invention discloses a high-strength and wear-resistant oxide-based metal ceramic bearing and a preparation method thereof. The high-strength and wear-resistant oxide-based metal ceramic bearing is prepared from the following raw materials in parts by weight: 60-70 parts of aluminum oxide, 45-55 parts of zirconium oxide, 14-20 parts of iron powder, 2-9 parts of realgar powder, 10-20 parts of dickite powder, 3-11 parts of pyrrhotite powder, 3-8 parts of graphene, 2-6 parts of iron citrate, 10-15 parts of glass fibers and 12-16 parts of synthetic wax. Compared with the traditional metal ceramic bearing, the high-strength and wear-resistant oxide-based metal ceramic bearing prepared by using the method disclosed by the invention has higher strength, wear resistance and heat resistance so that the bearing is not deformed at high temperature and is not easily worn; in addition, the preparation method is simple in process, low in processing cost and suitable for large-scale industrial production, parameters are easily controlled, and the production process is safe and environment-friendly.

Description

A kind of high-strength wearable oxide base cermet bearing and preparation method thereof
Technical field
Present invention relates particularly to a kind of high-strength wearable oxide base cermet bearing and preparation thereof Method.
Background technology
Ceramic metal English word cermet or ceramet be by ceramic (ceramic) and Metal (metal) is bonded.Ceramic metal refers to the gold prepared with powder metallurgy process Belonging to and the composite of pottery, ceramic metal has metal and the advantage of pottery concurrently, its density is little, Hardness is high, wear-resisting, heat conductivity is good, will not be because of quenching or shock heating and embrittlement.Ceramic metal was both There is the toughness of metal, high-termal conductivity and good heat stability, there is again the resistance to height of pottery The characteristic such as warm, corrosion-resistant and wear-resistant.Ceramic metal is in Aero-Space, defence and military, essence The fields such as close manufacture are gathered around and are had broad application prospects.Oxide base cermet be with aluminium oxide, Zirconium oxide, magnesium oxide, beryllium oxide etc. are matrix, are composited with tungsten, chromium or cobalt, tool Have high temperature resistant, resist chemical, heat conductivity are good, mechanical strength high.
Along with economical and the fast development of science and technology, the performance requirement to manufacturing mechanical components material More and more higher.Such as bearing will be in operation under high temperature and high pressure environment, and bearing material performance Quality is the Fundamentals of service life and the work efficiency affecting bearing.In recent years, along with work The development of industry technology, people it is also proposed the highest wanting to the performance of bearing material Ask.Ceramic metal bearing has a premium properties that common metal bearing is incomparable, high temperature resistance, Intensity high abrasion, corrosion-resistant, every field has obtained increasingly extensive application.City at present The most all increase for having high-strength wearable oxide base cermet bearing demand on Chang, but do not have There is corresponding product the most corresponding.Rare high-strength wearable oxide base cermet on domestic market Bearing, sells on a small quantity and public praise is preferably substantially imported product, and the market of home products accounts for There is rate less.To this end, we set about from formula and the technique of product, develop new high-performance material Material, it is provided that a kind of high-strength wearable oxide base cermet bearing and preparation method thereof.
Summary of the invention
To achieve these goals, the invention provides a kind of high-strength wearable oxide base pottery Porcelain bearing and preparation method thereof.
It is an object of the invention to be achieved through the following technical solutions:
A kind of high-strength wearable oxide base cermet bearing, by the raw material system of following weight portion Become: aluminium oxide 60-70 part, zirconium oxide 45-55 part, iron powder 14-20 part, Realgar powder 2-9 Part, dickite powder 10-20 part, magnetic iron ore powder 3-11 part, Graphene 3-8 part, Fructus Citri Limoniae Acid ferrum 2-6 part, glass fibre 10-15 part, synthetic wax 12-16 part.
Described high-strength wearable oxide base cermet bearing is prepared by the raw materials in: Aluminium oxide 60 parts, zirconium oxide 45 parts, iron powder 14 parts, Realgar powder 2 parts, dickite powder 10 Part, 3 parts of magnetic iron ore powder, Graphene 3 parts, ferric citrate 2 parts, glass fibre 10 parts, Synthetic wax 12 parts.
Described high-strength wearable oxide base cermet bearing is prepared by the raw materials in: Aluminium oxide 70 parts, zirconium oxide 55 parts, iron powder 20 parts, Realgar powder 9 parts, dickite powder 20 Part, 11 parts of magnetic iron ore powder, Graphene 8 parts, ferric citrate 6 parts, glass fibre 15 parts, Synthetic wax 16 parts.
Described high-strength wearable oxide base cermet bearing is prepared by the raw materials in: Aluminium oxide 65 parts, zirconium oxide 48 parts, iron powder 18 parts, Realgar powder 5 parts, dickite powder 15 Part, 7 parts of magnetic iron ore powder, Graphene 6 parts, ferric citrate 4 parts, glass fibre 13 parts, Synthetic wax 14 parts.
The preparation method of described high-strength wearable oxide base cermet bearing, the method preparation step Rapid as follows: first each raw material to be put in high-speed mixer, it is carried out mix and blend, then will The batch mixing of mix homogeneously is placed in mould and carries out being pressed into prefabricated component, and compacting pressure is 40-50MPa, then by prefabricated component high temperature sintering, sintering temperature is 900-1200 DEG C, during sintering Between be 3-6h, after being cooled to room temperature.
Beneficial effect: the inventive method prepare high-strength wearable oxide base cermet bearing with Traditional ceramic metal bearing is compared, and has more preferable intensity, wear resistence and thermostability so that axle Hold the most indeformable, the most easy to wear, and preparation technology is simple, processing cost is low, Parameter is easily-controllable, production process safety and environmental protection, is suitable for large-scale industrial production.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of high-strength wearable oxide base cermet bearing, by the raw material system of following weight portion Become: aluminium oxide 60 parts, zirconium oxide 45 parts, iron powder 14 parts, Realgar powder 2 parts, dickite 10 parts of powder, 3 parts of magnetic iron ore powder, Graphene 3 parts, ferric citrate 2 parts, glass fibre 10 parts, synthetic wax 12 parts.
Its preparation methods steps is as follows: is first put in high-speed mixer by each raw material, carries out it Mix and blend, is then placed in the batch mixing of mix homogeneously in mould and carries out being pressed into prefabricated component, pressure Pressure processed is 40-50MPa, then by prefabricated component high temperature sintering, sintering temperature is 900-1200 DEG C, Sintering time is 3-6h, after being cooled to room temperature.
Embodiment 2
A kind of high-strength wearable oxide base cermet bearing, by the raw material system of following weight portion Become: aluminium oxide 70 parts, zirconium oxide 55 parts, iron powder 20 parts, Realgar powder 9 parts, dickite 20 parts of powder, 11 parts of magnetic iron ore powder, Graphene 8 parts, ferric citrate 6 parts, glass fibre 15 parts, synthetic wax 16 parts.
Its preparation methods steps is as follows: is first put in high-speed mixer by each raw material, carries out it Mix and blend, is then placed in the batch mixing of mix homogeneously in mould and carries out being pressed into prefabricated component, pressure Pressure processed is 40-50MPa, then by prefabricated component high temperature sintering, sintering temperature is 900-1200 DEG C, Sintering time is 3-6h, after being cooled to room temperature.
Embodiment 3
A kind of high-strength wearable oxide base cermet bearing, by the raw material system of following weight portion Become: aluminium oxide 65 parts, zirconium oxide 48 parts, iron powder 18 parts, Realgar powder 5 parts, dickite 15 parts of powder, 7 parts of magnetic iron ore powder, Graphene 6 parts, ferric citrate 4 parts, glass fibre 13 parts, synthetic wax 14 parts.
Its preparation methods steps is as follows: is first put in high-speed mixer by each raw material, carries out it Mix and blend, is then placed in the batch mixing of mix homogeneously in mould and carries out being pressed into prefabricated component, pressure Pressure processed is 40-50MPa, then by prefabricated component high temperature sintering, sintering temperature is 900-1200 DEG C, Sintering time is 3-6h, after being cooled to room temperature.

Claims (5)

1. a high-strength wearable oxide base cermet bearing, it is characterised in that described height Strong wear-resisting oxide base cermet bearing is prepared by the raw materials in: aluminium oxide 60-70 part, zirconium oxide 45-55 part, iron powder 14-20 part, Realgar powder 2-9 part, dickite Powder 10-20 part, magnetic iron ore powder 3-11 part, Graphene 3-8 part, ferric citrate 2-6 part, Glass fibre 10-15 part, synthetic wax 12-16 part.
A kind of high-strength wearable oxide base cermet bearing, It is characterized in that, former by following weight portion of described high-strength wearable oxide base cermet bearing Material is made: aluminium oxide 60 parts, zirconium oxide 45 parts, iron powder 14 parts, Realgar powder 2 parts, Open stone powder 10 parts, 3 parts of magnetic iron ore powder, Graphene 3 parts, ferric citrate 2 parts, glass Fiber 10 parts, synthetic wax 12 parts.
A kind of high-strength wearable oxide base cermet bearing, It is characterized in that, former by following weight portion of described high-strength wearable oxide base cermet bearing Material is made: aluminium oxide 70 parts, zirconium oxide 55 parts, iron powder 20 parts, Realgar powder 9 parts, Open stone powder 20 parts, 11 parts of magnetic iron ore powder, Graphene 8 parts, ferric citrate 6 parts, glass Fiber 15 parts, synthetic wax 16 parts.
A kind of high-strength wearable oxide base cermet bearing, It is characterized in that, former by following weight portion of described high-strength wearable oxide base cermet bearing Material is made: aluminium oxide 65 parts, zirconium oxide 48 parts, iron powder 18 parts, Realgar powder 5 parts, Open stone powder 15 parts, 7 parts of magnetic iron ore powder, Graphene 6 parts, ferric citrate 4 parts, glass Fiber 13 parts, synthetic wax 14 parts.
5. the preparation of the high-strength wearable oxide base cermet bearing described in claim 1-4 Method, it is characterised in that the method preparation process is as follows: first each raw material is put into mixed at high speed In machine, it is carried out mix and blend, then the batch mixing of mix homogeneously is placed in mould and presses Making prefabricated component, compacting pressure is 40-50MPa, then by prefabricated component high temperature sintering, sintering temperature Degree is for 900-1200 DEG C, and sintering time is 3-6h, after being cooled to room temperature.
CN201610485579.4A 2016-06-23 2016-06-23 High-strength and wear-resistant oxide-based metal ceramic bearing and preparation method thereof Pending CN105908106A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108453262A (en) * 2018-03-23 2018-08-28 南通强生石墨烯科技有限公司 A kind of graphene powder metallurgy oiliness bearing and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102318179A (en) * 2008-08-28 2012-01-11 兰达实验室有限公司 Be used to produce the device and method of electric power
JP2014185769A (en) * 2013-02-20 2014-10-02 Nsk Ltd Thrust ball bearing
CN104190161A (en) * 2014-09-12 2014-12-10 济南圣泉倍进陶瓷过滤器有限公司 Ceramic filter containing graphene for molten metal
JP2015105434A (en) * 2013-12-03 2015-06-08 日本精工株式会社 Rolling bearing
CN105420602A (en) * 2015-11-05 2016-03-23 安徽银球轴承有限公司 Self-lubrication sintered metal powder bearing with good abrasion resistance and preparation method of self-lubrication sintered metal powder bearing
CN105541341A (en) * 2016-01-12 2016-05-04 河北高富氮化硅材料有限公司 Method for preparing high-compactness silicon nitride ceramic by adding composite additives

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102318179A (en) * 2008-08-28 2012-01-11 兰达实验室有限公司 Be used to produce the device and method of electric power
JP2014185769A (en) * 2013-02-20 2014-10-02 Nsk Ltd Thrust ball bearing
JP2015105434A (en) * 2013-12-03 2015-06-08 日本精工株式会社 Rolling bearing
CN104190161A (en) * 2014-09-12 2014-12-10 济南圣泉倍进陶瓷过滤器有限公司 Ceramic filter containing graphene for molten metal
CN105420602A (en) * 2015-11-05 2016-03-23 安徽银球轴承有限公司 Self-lubrication sintered metal powder bearing with good abrasion resistance and preparation method of self-lubrication sintered metal powder bearing
CN105541341A (en) * 2016-01-12 2016-05-04 河北高富氮化硅材料有限公司 Method for preparing high-compactness silicon nitride ceramic by adding composite additives

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108453262A (en) * 2018-03-23 2018-08-28 南通强生石墨烯科技有限公司 A kind of graphene powder metallurgy oiliness bearing and preparation method thereof

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