CN105907347A - Epoxy adhesive for building materials - Google Patents
Epoxy adhesive for building materials Download PDFInfo
- Publication number
- CN105907347A CN105907347A CN201610369464.9A CN201610369464A CN105907347A CN 105907347 A CN105907347 A CN 105907347A CN 201610369464 A CN201610369464 A CN 201610369464A CN 105907347 A CN105907347 A CN 105907347A
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- epoxy resin
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses an epoxy adhesive for building materials. The epoxy adhesive comprises a component A and a component B in a weight ratio of 10:(2-6). The component A is prepared from the following raw materials in parts by weight: 20-40 parts of 6101 epoxy resin, 20-50 parts of glyceryl ester epoxy resin, 15-25 parts of modified compound protein fiber, 1-5 parts of active calcium oxide, 1-5 parts of clay, 1-6 parts of aluminum hydroxide, 1-3 parts of 3-(phenylamino)propyltrimethoxysilane, 1-3 parts of anti-aging agent, 5-20 parts of ethanediol diglycidyl ether, 1-3 parts of dispersing agent and 1-3 parts of 304 unsaturated resin. The component B is prepared from the following raw materials in parts by weight: 10-20 parts of phenolic resin, 1-5 parts of polyphenylpolymethylene polyisocyanate and 5-15 parts of ethanediol diglycidyl ether. The epoxy adhesive for building materials has the advantages of excellent heat stability, high binding strength, favorable toughness, low price and wide raw material sources.
Description
Technical field
The present invention relates to adhesive technical field, particularly relate to a kind of construction material epoxy adhesive.
Background technology
Along with socioeconomic development, require the most bonding various Building wood in construction project field
Material, but the epoxyn kind that at present high temperature can use is seldom, and exist heat stability poor,
The shortcomings such as adhesive strength is the highest, poor water resistance.
Summary of the invention
A kind of construction material epoxy adhesive, goods thermal stability is excellent, and adhesion strength is high, good toughness,
And cheap, raw material sources are wide.
A kind of construction material epoxy adhesive that the present invention proposes, its raw material includes component A, B component, its
Middle component A, the weight ratio of B component are 10:2-6；
The raw material of component A includes by weight: 6101 epoxy resin 20-40 parts, glyceride epoxy resin 20-50
Part, modified compound protein fiber 15-25 part, active calcium oxide 1-5 part, clay 1-5 part, aluminium hydroxide
1-6 part, 3-(phenyl amino) propyl trimethoxy silicane 1-3 part, age resistor 1-3 part, ethylene glycol bisthioglycolate contracts
Water glycerin ether 5-20 part, dispersant 1-3 part, 304 unsaturated-resin 1-3 parts；
The raw material of B component includes by weight: phenolic resin 10-20 part, polyphenyl polymethylene polyisocyanic acid
Ester 1-5 part, Ethylene glycol diglycidyl ether 5-15 part.
Preferably, modified compound protein fiber uses following technique to prepare: by weight by 20-50 part angle egg
White fiber, 1-2 part trim,ethylchlorosilane mix and blend 60-100min, mixing speed is 200-400r/min,
Whipping temp is 40-48 DEG C, adds 60-100 part polylactic acid, 1-2 part ethylene bis stearamide, 1-2 part oil
Acid amide, 1-5 part polyvinyl alcohol vacuum stirring 1-2min, whipping temp 160-170 DEG C, vacuum is
0.5-0.9MPa, cooling, pulverize, add 5-15 part collagen protein, 10-20 part soybean protein, 50-100
Part water, 2-6 part sodium hydroxide mix homogeneously, be heated to 50-60 DEG C of stirring 20-40min, add 20-60 part
Polyvinyl alcohol, 1-3 part potassium peroxydisulfate mix homogeneously, regulation system pH value to 6.2-6.8, in temperature 40-60 DEG C
Stirring 20-40min, cooling, obtain modified compound protein fiber.
Preferably, modified compound protein fiber, active calcium oxide, clay, the weight ratio of aluminium hydroxide are 16-22:
2-4:2-3.5:2-4.
Preferably, 304 unsaturated-resins, the weight ratio of modified compound protein fiber are 1.8-2.2:16-22.
Preferably, modified compound protein fiber, 6101 epoxy resin, epoxy resin E-12, ethylene glycol bisthioglycolate contracting
The weight ratio of water glycerin ether is 16-22:30-34:30-40:10-14.
Preferably, modified compound protein fiber, 6101 epoxy resin, the weight ratio of epoxy resin E-12 are
16-22:30-34:30-40.
Preferably, 6101 epoxy resin, the weight ratio of epoxy resin E-12 are 30-34:30-40.
Preferably, described construction material epoxy adhesive, it is characterised in that its raw material include component A,
B component, wherein component A, the weight ratio of B component are 10:2-5；
The raw material of component A includes by weight: 6101 epoxy resin 30-34 parts, glyceride epoxy resin 30-40
Part, modified compound protein fiber 16-22 part, active calcium oxide 2-4 part, clay 2-3.5 part, hydroxide
Aluminum 2-4 part, 3-(phenyl amino) propyl trimethoxy silicane 1.5-2 part, age resistor 1.5-2 part, second
Hexanediol diglycidyl ether 10-14 part, dispersant 1.5-2 part, 304 unsaturated-resin 1.8-2.2 parts；
The raw material of B component includes by weight: phenolic resin 14-16 part, polyphenyl polymethylene polyisocyanic acid
Ester 2-4 part, Ethylene glycol diglycidyl ether 6-10 part.
In the present invention, 6101 epoxy resin and epoxy resin E-12 with the use of, can supplement mutual not
Foot, both molecular structures determine its solidfied material the highest intensity and adhesive strength, and decay resistance
Excellence, in modified compound protein fiber, keratin fiber after trim,ethylchlorosilane modification, quilt
Polylactic acid introduces and carries out surface modification, and goods not only toughness is fabulous and thermal stability is excellent, further with glue
Former albumen, soybean protein effect, under certain condition after polyvinyl alcohol modification, goods toughness increases further
By force, and spreading property is fabulous, and modified compound protein fiber is joined with 6101 epoxy resin, epoxy resin E-12
Cooperation use, the most cheap, raw material sources are wide, and goods are heat-resisting further enhances with toughness, and bonding is by force
Degree increases further, and the Ethylene glycol diglycidyl ether that it is possible to additionally incorporate is little on the impact of curing system thermal distorsion temperature,
Glue mobility can be effectively improved, improve 6101 epoxy resin, epoxy resin E-12, modified compound protein fibre
Dimension wetting capacity and wetting power, improve adhesive shock resistance, bending resistance and heat resistance, addition
Toughener and 6101 epoxy resin, epoxy resin E-12, modified compound protein fiber mating reaction, adhesive
Fragility is little, and toughening effect is obvious, and active calcium oxide, clay, aluminium hydroxide not only can reduce the use of resin
Amount, reduces cost, can significantly improve adhesive physical property with modified compound protein fiber mating reaction, increase
Adding toughness, glued membrane shock-absorbing effect is good, and waterproof effect is the most excellent, and active calcium oxide can be with glue
The water reaction on glutinous agent surface, improves interface conditions, the interfacial activity that dispersant is special, and adhesive stores stable
Property is good, and can improve the activity of active calcium oxide, clay, aluminium hydroxide, and goods combination property increases further
By force.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of construction material epoxy adhesive, its raw material includes component A, B component, wherein component A, B
The weight ratio of component is 10:2；
The raw material of component A includes by weight: 6101 epoxy resin 40 parts, glyceride epoxy resin 20 parts,
Modified compound protein fiber 25 parts, active calcium oxide 1 part, clay 5 parts, aluminium hydroxide 1 part, 3-(benzene
Base amino) propyl trimethoxy silicane 3 parts, 1 part of age resistor, Ethylene glycol diglycidyl ether 20 parts, point
Powder 1 part, 304 unsaturated-resins 3 parts；
The raw material of B component includes by weight: 10 parts of phenolic resin, polyphenyl polymethylene polyisocyanates
5 parts, Ethylene glycol diglycidyl ether 5 parts.
Embodiment 2
A kind of construction material epoxy adhesive, its raw material includes component A, B component, wherein component A, B
The weight ratio of component is 10:6；
The raw material of component A includes by weight: 6101 epoxy resin 20 parts, glyceride epoxy resin 50 parts,
Modified compound protein fiber 15 parts, active calcium oxide 5 parts, clay 1 part, aluminium hydroxide 6 parts, 3-(benzene
Base amino) propyl trimethoxy silicane 1 part, 3 parts of age resistor, Ethylene glycol diglycidyl ether 5 parts, point
Powder 3 parts, 304 unsaturated-resins 1 part；
The raw material of B component includes by weight: 20 parts of phenolic resin, polyphenyl polymethylene polyisocyanates
1 part, Ethylene glycol diglycidyl ether 15 parts.
Embodiment 3
A kind of construction material epoxy adhesive, its raw material includes component A, B component, wherein component A, B
The weight ratio of component is 10:5；
The raw material of component A includes by weight: 6101 epoxy resin 30 parts, glyceride epoxy resin 40 parts,
Modified compound protein fiber 16 parts, active calcium oxide 4 parts, clay 2 parts, aluminium hydroxide 4 parts, 3-(benzene
Base amino) propyl trimethoxy silicane 1.5 parts, 2 parts of age resistor, Ethylene glycol diglycidyl ether 10 parts,
Dispersant 2 parts, 304 unsaturated-resins 1.8 parts；
The raw material of B component includes by weight: 16 parts of phenolic resin, polyphenyl polymethylene polyisocyanates
2 parts, Ethylene glycol diglycidyl ether 10 parts.
Modified compound protein fiber uses following technique to prepare: by weight by 20 parts of keratin fibers, 2 parts
Trim,ethylchlorosilane mix and blend 60min, mixing speed is 400r/min, and whipping temp is 40 DEG C, adds
100 parts of polylactic acid, 1 part of ethylene bis stearamide, 2 parts of oleamides, 1 part of polyvinyl alcohol vacuum are stirred
Mixing 2min, whipping temp 160 DEG C, vacuum is 0.9MPa, cooling, pulverize, add 5 parts of collagen protein,
20 parts of soybean proteins, 50 parts of water, 6 parts of sodium hydroxide mix homogeneously, be heated to 50 DEG C of stirring 40min, add
Entering 20 parts of polyvinyl alcohol, 3 parts of potassium peroxydisulfate mix homogeneously, regulation system pH value to 6.2, at temperature 60 C
Stirring 20min, cooling, obtain modified compound protein fiber.
Embodiment 4
A kind of construction material epoxy adhesive, its raw material includes component A, B component, wherein component A, B
The weight ratio of component is 10:2；
The raw material of component A includes by weight: 6101 epoxy resin 34 parts, glyceride epoxy resin 30 parts,
Modified compound protein fiber 22 parts, active calcium oxide 2 parts, clay 3.5 parts, aluminium hydroxide 2 parts, 3-(benzene
Base amino) propyl trimethoxy silicane 2 parts, 1.5 parts of age resistor, Ethylene glycol diglycidyl ether 14 parts,
Dispersant 1.5 parts, 304 unsaturated-resins 2.2 parts；
The raw material of B component includes by weight: 14 parts of phenolic resin, polyphenyl polymethylene polyisocyanates
4 parts, Ethylene glycol diglycidyl ether 6 parts.
Modified compound protein fiber uses following technique to prepare: by weight by 50 parts of keratin fibers, 1 part
Trim,ethylchlorosilane mix and blend 100min, mixing speed is 200r/min, and whipping temp is 48 DEG C, adds
60 parts of polylactic acid, 2 parts of ethylene bis stearamides, 1 part of oleamide, 5 parts of polyvinyl alcohol vacuum stirring
1min, whipping temp 170 DEG C, vacuum is 0.5MPa, cooling, pulverize, add 15 parts of collagen protein,
10 parts of soybean proteins, 100 parts of water, 2 parts of sodium hydroxide mix homogeneously, be heated to 60 DEG C of stirring 20min, add
Entering 60 parts of polyvinyl alcohol, 1 part of potassium peroxydisulfate mix homogeneously, regulation system pH value to 6.8, temperature 40 DEG C
Stirring 40min, cooling, obtain modified compound protein fiber.
Embodiment 5
A kind of construction material epoxy adhesive, its raw material includes component A, B component, wherein component A, B
The weight ratio of component is 10:3.5；
The raw material of component A includes by weight: 6101 epoxy resin 32 parts, glyceride epoxy resin 35 parts,
Modified compound protein fiber 20 parts, active calcium oxide 3 parts, clay 2.8 parts, aluminium hydroxide 3.2 parts, 3-
(phenyl amino) propyl trimethoxy silicane 1.8 parts, 1.8 parts of age resistor, Ethylene glycol diglycidyl ether
12 parts, dispersant 1.8 parts, 304 unsaturated-resins 1.92 parts；
The raw material of B component includes by weight: 15 parts of phenolic resin, polyphenyl polymethylene polyisocyanates
3 parts, Ethylene glycol diglycidyl ether 8 parts.
Modified compound protein fiber uses following technique to prepare: by weight by 32 parts of keratin fibers, 1.4
Part trim,ethylchlorosilane mix and blend 80min, mixing speed is 320r/min, and whipping temp is 43 DEG C, adds
Enter 80 parts of polylactic acid, 1.2 parts of ethylene bis stearamides, 1.6 parts of oleamides, 3 parts of polyvinyl alcohol true
Empty stirring 1.5min, whipping temp 164 DEG C, vacuum is 0.7MPa, cooling, pulverizes, adds 8 parts of glue
Former albumen, 14 parts of soybean proteins, 80 parts of water, 4 parts of sodium hydroxide mix homogeneously, be heated to 56 DEG C of stirring 32min,
Adding 35 parts of polyvinyl alcohol, 2.2 parts of potassium peroxydisulfate mix homogeneously, regulation system pH value to 6.4, in temperature
52 DEG C of stirring 20-40min, cooling, obtain modified compound protein fiber.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office
Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this
The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention
Within the scope of.
Claims (8)
1. a construction material epoxy adhesive, it is characterised in that its raw material includes component A, B component,
Wherein component A, the weight ratio of B component are 10:2-6；
The raw material of component A includes by weight: 6101 epoxy resin 20-40 parts, glyceride epoxy resin 20-50
Part, modified compound protein fiber 15-25 part, active calcium oxide 1-5 part, clay 1-5 part, aluminium hydroxide
1-6 part, 3-(phenyl amino) propyl trimethoxy silicane 1-3 part, age resistor 1-3 part, ethylene glycol bisthioglycolate
Glycidyl ether 5-20 part, dispersant 1-3 part, 304 unsaturated-resin 1-3 parts；
The raw material of B component includes by weight: phenolic resin 10-20 part, the many isocyanides of polyphenyl polymethylene
Acid esters 1-5 part, Ethylene glycol diglycidyl ether 5-15 part.
Construction material epoxy adhesive the most according to claim 1, it is characterised in that modified compound
Azelon uses following technique to prepare: by weight by 20-50 part keratin fiber, 1-2 part trimethyl
Chlorosilane mix and blend 60-100min, mixing speed is 200-400r/min, and whipping temp is 40-48 DEG C,
Add 60-100 part polylactic acid, 1-2 part ethylene bis stearamide, 1-2 part oleamide, the poly-second of 1-5 part
Enol mixing vacuum stirring 1-2min, whipping temp 160-170 DEG C, vacuum is 0.5-0.9MPa, cooling,
Pulverize, add 5-15 part collagen protein, 10-20 part soybean protein, 50-100 part water, 2-6 part hydroxide
Sodium mix homogeneously, is heated to 50-60 DEG C of stirring 20-40min, adds 20-60 part polyvinyl alcohol, 1-3 part
Potassium peroxydisulfate mix homogeneously, regulation system pH value to 6.2-6.8, stir 20-40min in temperature 40-60 DEG C,
Cooling, obtains modified compound protein fiber.
Construction material epoxy adhesive the most according to claim 1 and 2, it is characterised in that modified
Compound protein fiber, active calcium oxide, clay, the weight ratio of aluminium hydroxide are 16-22:2-4:2-3.5:
2-4。
4. according to the construction material epoxy adhesive described in any one of claim 1-3, it is characterised in that
304 unsaturated-resins, the weight ratio of modified compound protein fiber are 1.8-2.2:16-22.
5. according to the construction material epoxy adhesive described in any one of claim 1-4, it is characterised in that
Modified compound protein fiber, 6101 epoxy resin, epoxy resin E-12, the weight of Ethylene glycol diglycidyl ether
Amount ratio is 16-22:30-34:30-40:10-14.
6. according to the construction material epoxy adhesive described in any one of claim 1-5, it is characterised in that
Modified compound protein fiber, 6101 epoxy resin, the weight ratio of epoxy resin E-12 are 16-22:30-34:
30-40。
7. according to the construction material epoxy adhesive described in any one of claim 1-6, it is characterised in that
6101 epoxy resin, the weight ratio of epoxy resin E-12 are 30-34:30-40.
8. according to the construction material epoxy adhesive described in any one of claim 1-7, it is characterised in that
Its raw material includes component A, B component, and wherein component A, the weight ratio of B component are 10:2-5；
The raw material of component A includes by weight: 6101 epoxy resin 30-34 parts, glyceride epoxy resin 30-40
Part, modified compound protein fiber 16-22 part, active calcium oxide 2-4 part, clay 2-3.5 part, hydroxide
Aluminum 2-4 part, 3-(phenyl amino) propyl trimethoxy silicane 1.5-2 part, age resistor 1.5-2 part, second
Hexanediol diglycidyl ether 10-14 part, dispersant 1.5-2 part, 304 unsaturated-resin 1.8-2.2 parts；
The raw material of B component includes by weight: phenolic resin 14-16 part, the many isocyanides of polyphenyl polymethylene
Acid esters 2-4 part, Ethylene glycol diglycidyl ether 6-10 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610369464.9A CN105907347A (en) | 2016-05-25 | 2016-05-25 | Epoxy adhesive for building materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610369464.9A CN105907347A (en) | 2016-05-25 | 2016-05-25 | Epoxy adhesive for building materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105907347A true CN105907347A (en) | 2016-08-31 |
Family
ID=56742703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610369464.9A Pending CN105907347A (en) | 2016-05-25 | 2016-05-25 | Epoxy adhesive for building materials |
Country Status (1)
| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833472A (en) * | 2017-02-28 | 2017-06-13 | 湖北慧盾新型材料科技有限公司 | A kind of construction material epoxy adhesive of novel environment friendly |
| CN109181607A (en) * | 2018-11-23 | 2019-01-11 | 深圳市欧科力科技有限公司 | A kind of construction material epoxy adhesive and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619201A (en) * | 2009-07-16 | 2010-01-06 | 青岛红树林投资有限公司 | Underwater epoxy adhesive and preparation method thereof |
| CN102504503A (en) * | 2011-09-29 | 2012-06-20 | 广州卓扬新材料科技有限公司 | Full-biodegradation ceratin fiber reinforced and fireproof modified polylactic acid material and preparation method thereof |
| CN104194699A (en) * | 2014-08-26 | 2014-12-10 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of epoxy resin-soybean protein glue environment-friendly copolymer adhesive |
-
2016
- 2016-05-25 CN CN201610369464.9A patent/CN105907347A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101619201A (en) * | 2009-07-16 | 2010-01-06 | 青岛红树林投资有限公司 | Underwater epoxy adhesive and preparation method thereof |
| CN102504503A (en) * | 2011-09-29 | 2012-06-20 | 广州卓扬新材料科技有限公司 | Full-biodegradation ceratin fiber reinforced and fireproof modified polylactic acid material and preparation method thereof |
| CN104194699A (en) * | 2014-08-26 | 2014-12-10 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of epoxy resin-soybean protein glue environment-friendly copolymer adhesive |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833472A (en) * | 2017-02-28 | 2017-06-13 | 湖北慧盾新型材料科技有限公司 | A kind of construction material epoxy adhesive of novel environment friendly |
| CN109181607A (en) * | 2018-11-23 | 2019-01-11 | 深圳市欧科力科技有限公司 | A kind of construction material epoxy adhesive and preparation method thereof |
| CN109181607B (en) * | 2018-11-23 | 2021-05-14 | 佛山市雅伦高科石业有限公司 | Epoxy adhesive for building materials and preparation method thereof |
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Application publication date: 20160831 |