CN105907116A - High-performance hybrid modified asphalt emulsion and preparation technique thereof - Google Patents
High-performance hybrid modified asphalt emulsion and preparation technique thereof Download PDFInfo
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- CN105907116A CN105907116A CN201610503584.3A CN201610503584A CN105907116A CN 105907116 A CN105907116 A CN 105907116A CN 201610503584 A CN201610503584 A CN 201610503584A CN 105907116 A CN105907116 A CN 105907116A
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- modified pitch
- emulsion
- performance
- emulsifying agent
- modified asphalt
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Colloid Chemistry (AREA)
Abstract
The invention discloses a high-performance hybrid modified asphalt emulsion which comprises 60-75% of modified asphalt, 1-5% of composite emulsifier, 0.05-0.2% of emulsifying aid and 25-40% of water. The preparation method comprises the following steps: preparing the high-performance modified asphalt, and adding 4-8% of the modifier; compounding the specific modified asphalt emulsifier; and heating the high-performance modified asphalt to 70-200 DEG C, heating the water-soluble temperature of the emulsifier to 60-90 DEG C and the like. The crosslinking agent is a special crosslinking agent capable of crosslinking the modifier in the dewatered state at room temperature, and the addition amount is 4%. The properties of the film formed by the dewatered modified asphalt emulsion are greatly enhanced, i.e. the softening point reaches at least 80 DEG C, the low-temperature ductility is at least 40cm when the temperature is 5 DEG C, the elastic recovery rate is up to 92% or above, the average binding force is 1.01 MPa, and the organic matter-inorganic matter composite stabilizer accounts for 0.05-0.2%, thereby effectively solving the problem of room-temperature stability in the modified asphalt emulsion; and thus, the modified asphalt emulsion has favorable long-term storability.
Description
Technical field
This practicality invention relates to Colophonium, particularly relates to a kind of High-performance hybrid modified pitch emulsion and system thereof
Standby technique.
Background technology
The pitchy that Colophonium is made up of Hydrocarbon and the nonmetal derivant thereof of different molecular weight is multiple
Hybrid compound, is the one of high viscosity organic liquid, is in a liquid state, surface is black, dissolves in curing
Carbon, Colophonium is a kind of waterproof and dampproof and antiseptical organic gel gel material, and Colophonium can be largely classified into coal tar drip
Green grass or young crops, asphalt and bitumen three kinds: wherein, coal tar pitch is the side-product of coking.Asphalt
It it is the residue after crude distillation.Bitumen is then to be stored at underground, some formation ore beds or at earth's crust table
Face is piled up, and Colophonium is mainly used in industry and the surfacings etc. such as coating, plastics, rubber.
Existing technique be Colophonium and emulsifying agent under certain process acts, generate oil-in-water or Water-In-Oil (tool
Who wraps the kind of whose emulsifying agent to be seen to body) liquid bitumen, emulsified asphalt is by usual applied at elevated temperature
Road asphalt, grinds and chemically stable method (emulsifying) through mechanical shearing, is diffused into liquid in water
Under chemical conversion room temperature, viscosity is the lowest, mobility well a kind of pavement construction material.Can use with room temperature, also
Can be used together with cold, moist building stones.
Now road surface etc. are built and are repaired, micro-surface area and super viscous wearing course, mist sealing, cold mixing cold-application,
Patch repair, pavement seam filling, house toilet warterproof, bridge deck water-proof and sticking layer oil etc., be required for
Colophonium, but existing asphalt softening point is relatively low, low-temperature ductility poor performance, and storage stability is general, and elastic
Amount of recovery is little.
Practical summary of the invention
For the problems referred to above, this practicality invention provides a kind of High-performance hybrid modified pitch emulsion and system thereof
Standby technique, solves softening point relatively low, and low-temperature ductility poor performance, adhesiveness, cohesive force is undesirable；Storage
Deposit stability general, and the shortcoming that elastic return amount is little.
For solving above-mentioned technical problem, this practicality invention be the technical scheme is that a kind of high-performance is miscellaneous
Changing modified pitch emulsion, described High-performance hybrid modified pitch emulsion includes by the modified drip of 60%-75%
Green grass or young crops, the compound emulsifying agent of 1%-5%, the emulsion adjuvant of 0.5%-2%, the water composition of 25%-40%, preparation height
The modified pitch of performance, adds 4%-8% modifying agent；The modified pitch emulsifying agent of compounding specially good effect；By high property
Modified pitch temperature can be raised to 170-200 DEG C, the water-soluble temperature of emulsifying agent is increased to 60-90 DEG C, breast
The modified pitch emulsion temperature dissolved controls between 50-70 DEG C；Complex stabilizer component 0.5%-2%；
Additional is 3%-6% with modified pitch emulsion SBR emulsion, addition；Additional a kind of cross-linking agent, addition
For 0.5%-1%.
Further, described emulsifying agent compound includes many amines emulsifying agent of 1%-2%, 0.5%-3%
Acetyl many amines emulsifying agent, the nonionic emulsifier of 0.1%-1%, for High-performance hybrid modified pitch emulsion
Prepare material.
Further, described emulsifying agent compound includes many amines emulsifying agent of 1.5%, and 2% acetyl is many
Amine emulsifying agent, the nonionic emulsifier of 0.5%, suitably measures so that High-performance hybrid modification drips
Blue or green emulsion excellent effect.
Further, described prepares high performance modified pitch, and adding modifying agent is that 5%SBS is modified
Agent, makes SBS be uniformly dispersed mutually by methods such as shearing, stirrings and is dissolved in Colophonium, adds meanwhile
A certain proportion of exclusive stabilizer, forms SBS intermingling material, utilizes the physical property pair that SBS is good
Colophonium does modification.
Further, the modified pitch emulsifying agent of described compounding specially good effect, be two polyamine species salts sun from
Sub-emulsion and a kind of non-ionic emulsifier liquid are re-dubbed so that it is possess the spy of emulsifying high performance modified bitumen
Effect function.
Further, described compound be that to use Organic substance, inorganic matter complex stabilizer component be 1.5%,
Efficiently solve the ambient stable sex chromosome mosaicism of modified pitch emulsion, modified pitch emulsion can be made the best
Store.
Further, described additional and modified pitch emulsion is and modified pitch emulsion, intermiscibility pole
Good SBR emulsion, addition is about 5%, greatly improves the cryogenic property of modified pitch emulsion.
Further, described a kind of cross-linking agent is to make modifying agent exist under room temperature, energy under desiccation
The special cross-linking agent of crosslinking, addition is 1%, can make modified pitch emulsion, and after dehydration film forming, performance is big
Width improves, and reaches 80 DEG C including softening point, and low-temperature ductility is 40cm when 5 DEG C, and elastic return reaches 92%
Above, cohesive force meansigma methods is more than 1.01Mpa.
Further, described rises temperature by high performance modified bitumen, and temperature is 180 DEG C, emulsifying agent water
Dissolubility is warming up to 80 DEG C, and emulsifying modified pitch emulsion temperature out controls at about 60 DEG C, suitably
Temperature is conducive to the preparation of High-performance hybrid modified pitch emulsion, pressure superatmospheric in emulsifying mill,
And after emulsifying mill, connect cooler, make emulsifying modified pitch emulsion temperature out from about 130 DEG C
It is rapidly reduced to control at about 60 DEG C, solves when modified pitch emulsion surpasses 100 DEG C moment in the open
A difficult problem for gasification breakdown of emulsion.
From the above-mentioned description to this practicality inventive structure, compared to the prior art, this practicality invention
Have the advantage that
One High-performance hybrid modified pitch emulsion of the present invention, prepares crosslinking dose and can make to change under room temperature
Property agent exists, the special cross-linking agent that can cross-link under water state, and addition is 1%, can make modified pitch emulsion,
After MJPZ, performance is greatly improved, and reaches 80 DEG C including softening point, and low-temperature ductility is 40cm when 5 DEG C,
Elastic return reaches more than 92%, and cohesive force meansigma methods is 1.01Mpa, uses Organic substance, inorganic matter to be combined
Stabilizer component 0.5%-2%, efficiently solves the ambient stable sex chromosome mosaicism of modified pitch emulsion, can make to change
Property asphalt emulsion the most well stores.
Accompanying drawing explanation
The accompanying drawing of the part constituting the application is used for providing being further appreciated by this practicality invention, this
The schematic description and description of practical invention is used for explaining that this practicality is invented, and is not intended that this reality
Improper restriction with invention.In the accompanying drawings:
Fig. 1 is a kind of High-performance hybrid modified pitch emulsion preparation flow structural representation of this practicality invention；
Detailed description of the invention
In order to the purpose making this practicality invent, technical scheme and advantage are clearer, below in conjunction with
Drawings and Examples, are further elaborated to this practicality invention.Should be appreciated that this place is retouched
The specific embodiment stated, only in order to explain that this practicality is invented, is not used to limit this practicality invention.
The pitchy that Colophonium is made up of Hydrocarbon and the nonmetal derivant thereof of different molecular weight is multiple
Hybrid compound, is the one of high viscosity organic liquid, is in a liquid state, surface is black, dissolves in curing
Carbon, Colophonium is a kind of waterproof and dampproof and antiseptical organic gel gel material, and Colophonium can be largely classified into coal tar drip
Green grass or young crops, asphalt and bitumen three kinds: wherein, coal tar pitch is the side-product of coking.Asphalt
It it is the residue after crude distillation.Bitumen is then to be stored at underground, some formation ore beds or at earth's crust table
Face is piled up, and Colophonium is mainly used in industry and the surfacings etc. such as coating, plastics, rubber, and softening point is relatively
Low, low-temperature ductility poor performance, storage stability is general, and elastic return amount is little.
With reference to Fig. 1, a kind of High-performance hybrid modified pitch emulsion, described High-performance hybrid modified pitch
Emulsion includes by the modified pitch of 60%-75%, the compound emulsifying agent of 1%-5%, the emulsion adjuvant of 0.5%-2%,
The water composition of 25%-40%, described emulsifying agent compound includes many amines emulsifying agent of 1%-2%, 0.5%-3%
Acetyl many amines emulsifying agent, the nonionic emulsifier of 0.1%-1%, described emulsifying agent compound includes 1.5%
Many amines emulsifying agent, 2% acetyl many amines emulsifying agent, the nonionic emulsifier of 0.5%, prepare high-performance
Modified pitch, add 4%-8% modifying agent；The modified pitch emulsifying agent of compounding specially good effect；High-performance is changed
Property asphalt temperature is raised to 170-200 DEG C, and the temperature of emulsifying agent is increased to 60-90 DEG C, emulsifying changing out
Property asphalt emulsion temperature controls between 50-70 DEG C；Complex stabilizer component 0.05%-0.2%；Additional with
Modified pitch emulsion SBR emulsion, addition are 3%-6%；Additional a kind of cross-linking agent, addition is
0.5%-1%；Described prepares high performance modified pitch, and adding modifying agent is 5%SBS modifying agent；Institute
The modified pitch emulsifying agent of the compounding specially good effect stated, be two polyamine species salt cationic emulsions and a kind of non-from
Sub-emulsion is re-dubbed；Described compound be that to use Organic substance, inorganic matter complex stabilizer component be 1.5%,
Described additional and modified pitch emulsion is the SBR emulsion that intermiscibility is splendid, and addition is 5%；Described
A kind of cross-linking agent be under room temperature, to make modifying agent exist, the special cross-linking agent that can cross-link under desiccation, add
Dosage is 4%, and described rises temperature by high performance modified bitumen, and temperature is 180 DEG C, and emulsifying agent rises potential temperature
80 DEG C, emulsifying modified pitch emulsion temperature out controls at about 60 DEG C.
One High-performance hybrid modified pitch emulsion of the present invention, prepares crosslinking dose and can make to change under room temperature
Property agent exist, the special cross-linking agent that can cross-link under desiccation, addition is 1%, can make modified pitch breast
Liquid, after dehydration film forming, performance is greatly improved, and reaches 80 DEG C including softening point, and low-temperature ductility is when 5 DEG C
For 40cm, elastic return reaches more than 92%, and cohesive force meansigma methods is 1.01Mpa, uses Organic substance, nothing
Machine thing complex stabilizer component 0.5%-2%, the ordinary temperature stability efficiently solving modified pitch emulsion is asked
Topic, can make modified pitch emulsion the most well store.
A kind of High-performance hybrid modified pitch emulsion, can be used for pavement construction and reparation, such as: micro-surface area
And super viscous wearing course, mist sealing, cold mixing cold-application, patch repair, pavement seam filling, house defend
Waterproof, bridge deck water-proof and sticking layer oil etc. between life, prior art have the advantages that energy-saving and emission-reduction,
Low-carbon environment-friendly, Project Product aqueous, meet environmental requirement.
The foregoing is only the preferred embodiment of this practicality invention, not in order to limit this practicality
Bright, that made within all spirit in this practicality invention and principle any amendment, equivalent and improvement
Deng, within should be included in the protection domain of this practicality invention.
Claims (10)
1. a High-performance hybrid modified pitch emulsion, it is characterised in that: described High-performance hybrid modified pitch emulsion includes by the modified pitch of 60%-75%, the compound emulsifying agent of 1%-5%, the emulsion adjuvant of 0.05%-0.2%, the water composition of 25%-40%.
A kind of High-performance hybrid modified pitch emulsion, it is characterised in that: described emulsifying agent compound includes many amines emulsifying agent of 1%-2%, 0.5%-3% acetyl many amines emulsifying agent, the nonionic emulsifier of 0.1%-1%.
A kind of High-performance hybrid modified pitch emulsion, it is characterised in that: described emulsifying agent compound includes many amines emulsifying agent of 1.5%, 2% acetyl many amines emulsifying agent, the nonionic emulsifier of 0.5%.
4. the preparation technology of a High-performance hybrid modified pitch emulsion, it is characterised in that:
Prepare high performance modified pitch, add 4%-8% modifying agent；
The modified pitch emulsifying agent of compounding specially good effect；
High performance modified bitumen temperature is raised to 170-200 DEG C, and the water-soluble temperature of emulsifying agent is increased to 60-90 DEG C, and emulsifying modified pitch emulsion temperature out controls between 50-70 DEG C；
Complex stabilizer component 0.05%-0.2%；
Additional is 3%-6% with modified pitch emulsion SBR emulsion, addition；
Additional a kind of cross-linking agent, addition is 0.5%-1%.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterised in that: described prepares high performance modified pitch, and adding modifying agent is 5%SBS modifying agent.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterised in that: the modified pitch emulsifying agent of described compounding specially good effect, it is two polyamine species salt cationic emulsions and a kind of non-ionic emulsifier liquid is re-dubbed.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterised in that: described compound be that to use Organic substance, inorganic matter complex stabilizer deal be 0.15%.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterised in that: described additional and modified pitch emulsion is the SBR emulsion that intermiscibility is splendid, and addition is 5%.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterised in that: described a kind of cross-linking agent is to make modifying agent exist under room temperature, the special cross-linking agent that can cross-link under desiccation, and addition is 1%.
A kind of preparation technology of High-performance hybrid modified pitch emulsion, it is characterized in that: described is increased to 180 DEG C by high performance modified bitumen, emulsifying agent soap lye is warming up to 80 DEG C, flash cooler installed by colloid mill outlet conduit, makes emulsifying modified pitch emulsion temperature out be reduced to about 60 DEG C from about 120 DEG C rapidly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610503584.3A CN105907116A (en) | 2016-06-30 | 2016-06-30 | High-performance hybrid modified asphalt emulsion and preparation technique thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610503584.3A CN105907116A (en) | 2016-06-30 | 2016-06-30 | High-performance hybrid modified asphalt emulsion and preparation technique thereof |
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| Publication Number | Publication Date |
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| CN105907116A true CN105907116A (en) | 2016-08-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610503584.3A Pending CN105907116A (en) | 2016-06-30 | 2016-06-30 | High-performance hybrid modified asphalt emulsion and preparation technique thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200595A (en) * | 2006-12-12 | 2008-06-18 | 中国石油天然气股份有限公司 | Modified emulsified asphalt |
| CN103059585A (en) * | 2011-10-18 | 2013-04-24 | 中国石油化工股份有限公司 | Modified asphalt emulsion and preparation method thereof |
-
2016
- 2016-06-30 CN CN201610503584.3A patent/CN105907116A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200595A (en) * | 2006-12-12 | 2008-06-18 | 中国石油天然气股份有限公司 | Modified emulsified asphalt |
| CN103059585A (en) * | 2011-10-18 | 2013-04-24 | 中国石油化工股份有限公司 | Modified asphalt emulsion and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘尚乐: "《乳化沥青及其在道路、建筑丁程中的应用》", 31 July 2008, 中国建材工业出版社 * |
| 段利艳等: ""复合改性乳化沥青的制备及其性能分析"", 《湖南工业大学学报》 * |
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