CN105906215B - A kind of high transparency Quantum Dot Glass of silver-containing nanoparticles and preparation method thereof - Google Patents
A kind of high transparency Quantum Dot Glass of silver-containing nanoparticles and preparation method thereof Download PDFInfo
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- CN105906215B CN105906215B CN201610217996.0A CN201610217996A CN105906215B CN 105906215 B CN105906215 B CN 105906215B CN 201610217996 A CN201610217996 A CN 201610217996A CN 105906215 B CN105906215 B CN 105906215B
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- 239000002096 quantum dot Substances 0.000 title claims abstract description 40
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 27
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000004332 silver Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000002105 nanoparticle Substances 0.000 title abstract description 13
- 239000011521 glass Substances 0.000 claims abstract description 58
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 9
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 5
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 13
- IURNOFSIYGTQFC-UHFFFAOYSA-N [Si].[B].[Na] Chemical group [Si].[B].[Na] IURNOFSIYGTQFC-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 claims description 9
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052738 indium Inorganic materials 0.000 claims description 6
- 229910000846 In alloy Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052681 coesite Inorganic materials 0.000 claims description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229910052682 stishovite Inorganic materials 0.000 claims description 4
- 229910052905 tridymite Inorganic materials 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- CFOAUMXQOCBWNJ-UHFFFAOYSA-N [B].[Si] Chemical compound [B].[Si] CFOAUMXQOCBWNJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011159 matrix material Substances 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 238000009423 ventilation Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000009021 linear effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000009022 nonlinear effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/16—Microcrystallites, e.g. of optically or electrically active material
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
High transparency Quantum Dot Glass of the synthesis containing silver nano-grain is controlled by special atmosphere this application discloses a kind of, the technology controlled using sol-gal process combination special atmosphere is prepared for containing such Ag In2O3The high transparency Quantum Dot Glass of structure, by the time of the conversion and the ventilation that adjust atmosphere, it have studied using a variety of means of testing and form the Ag nano particles that particle size is smaller, is evenly distributed under microstructure in glass matrix, and the transparency of glass increases substantially.This special atmosphere is combined by sol-gal process and controls structure Ag In in glass2O3Structure improves the transparency of glass.
Description
Technical field
The present invention relates to a kind of high transparency Quantum Dot Glass of silver-containing nanoparticles, the preparation of the Quantum Dot Glass is further related to
Method.
Background technology
In recent years, silver nano-grain due to its catalysis, optics, biology etc. have important and novel property and
Cause the interest of scientist.Recently, silver nano-grain is successfully doped to transparent solid matrix and this composite
Unique property and potential application optically make it receive much concern.Glass, as a kind of important solid transparent material, no
Stable presence environment can be only provided for silver nano-grain, for itself as a kind of good photoelectric material, what is had is transparent
Property and uniformity, high mechanical performance and heat endurance, the features such as being easily formed desired shapes and sizes.Therefore, by silver
It is to select well that nano particle, which is doped in transparent glass, and the Quantum Dot Glass of silver nano-grain doping is in visible light source
Equipment, optical storage, third-order non-linear etc. possess extensive potential value.
But silver nano-grain is doped in clear glass have one it is extremely important the problem of, be exactly when silver nanoparticle
It is the transparency that can reduce glass that grain, which is successfully doped in glass,.This also implies that this composite answering in photoelectric field
With can be subject to certain restrictions.Therefore, it is very important to solve this problem.
The content of the invention
It is an object of the invention to provide a kind of high transparency Quantum Dot Glass of silver-containing nanoparticles, it is possible to increase is received containing silver
The transparency of the Quantum Dot Glass of rice grain, Ag nano particles and the higher quantum dot glass of transparency are formed in glass matrix
Glass.
It is a further object to provide the preparation method of above-mentioned Quantum Dot Glass, the preparation method can be in glass
A kind of Ag-In is built in matrix2O3Structure improves the transparency of the Quantum Dot Glass containing Ag.
For high transparency Quantum Dot Glass problem, there is provided following technical scheme：A kind of height containing silver nano-grain is thoroughly
Bright Quantum Dot Glass, it is characterised in that：Doped with Ag-In in glass body material2O3Compound, wherein Ag is with crystalline state
Form is present, In2O3To exist as an amorphous form, Ag, In co-doped to glass body material and both account for doping after mole
Than for 0.47%~0.7%, wherein the mol ratio of Ag and In elements is 1: 1.
The present invention is further arranged to, and described glass body is sodium boron silicon-based glass, each component of sodium boron silicon-based glass
Mole composition is：Na2O：5~8mol%, B2O3：21~24mol%, SiO2：70~73mol%.
Sodium boron silicon-based glass in foregoing invention, by doped with Ag-In2O3Compound, form with high transparency
The Quantum Dot Glass of degree, and the silver nano-grain that particle size is smaller, is evenly distributed is formd in glass matrix.
For the preparation method problem of high transparency Quantum Dot Glass, the invention discloses a kind of height containing silver nano-grain
The preparation method of transparent Quantum Dot Glass, it is characterised in that comprise the following steps：
1st, the preparation of xerogel：A, glass colloidal sol is made, b, will be dripped respectively containing the ethanol solution of silver nitrate and indium nitrate
It is added in glass colloidal sol, it is 1%~1.5% to add silver nitrate and indium nitrate and account for the mol ratio of glass body material, is sufficiently stirred,
Formation contains Ag+And In3+Glass, mounted box and place 1 week after, 120 DEG C dry 4 weeks, i.e., formation contain Ag+And In3+Block
Shape xerogel.
2nd, sintering process, xerogel is placed in tube furnace and is sintered：A, first, under oxygen atmosphere, temperature is by room
Temperature rise is to 450 DEG C, it is therefore an objective to which removing organic matter and makes silver nitrate and indium nitrate sufficiently decompose, and b, oxygen atmosphere is converted into hydrogen
Gas atmosphere is simultaneously incubated at 450 DEG C, it is therefore an objective to forms Ag-In alloy under reducing atmosphere, c, insulation terminate, hydrogen atmosphere turned
Change oxygen atmosphere into, and temperature risen to 600 DEG C, by adjust oxidization time to the end it is transparent, completely contain
The Quantum Dot Glass of Ag nano particles.
In this method, wherein obtained glass material is sodium boron silicon-based glass, corresponding sodium boron silicon-based glass sol gel process
Comprise the following steps, tetraethyl orthosilicate is added slowly to be fully hydrolyzed in the mixed solution of absolute ethyl alcohol and nitric acid by (a), is obtained
To SiO2Presoma；(b) boric acid is dissolved into ethylene glycol monomethyl ether, metallic sodium is dissolved into absolute ethyl alcohol and formed respectively
B2O3And Na2O presoma；(c) two kinds of solution in (b) are added drop-wise in (a) in solution according to this, be sufficiently stirred at room temperature
Form transparent, uniform sodium boron silicon-based glass colloidal sol.
The present invention has the advantages of following several respects compared with prior art：
(1) by building a kind of Ag-In in glass2O3Structure improves the saturating of the Quantum Dot Glass of the nano particle containing Ag
Lightness, in sintering process, in a steps, organic matter can be removed and silver nitrate and indium nitrate is sufficiently decomposed, in step b
Ag-In alloy is formd, in step c, during Ag-In alloy state, In has higher activity than Ag, and it is first oxidized
Obtain In2O3And Ag-In is ultimately formed2O3Compound, the Quantum Dot Glass with the high grade of transparency is formd, and in glass matrix
In form the silver nano-grain that particle size is smaller, is evenly distributed.
(2) there is above-mentioned Ag-In2O3The argentiferous Quantum Dot Glass of structure has higher transparency, and this receives solving metal
The Quantum Dot Glass of rice grain doping is low the limitation of photoelectric field the problem of due to translucidus.
(3) controlled using special atmosphere to prepare the high transparency Quantum Dot Glass containing silver nano-grain, in preparation method
It is upper that there is versatility.
Brief description of the drawings
Quantum Dot Glass sample under Fig. 1 differences dopants and control climate：(a)、O2-H2It is lower to sinter the Ag quantum formed
Point glass；(b), (c), (d), different Ag-In2O3O under component2-H2-O2It is lower to sinter the Quantum Dot Glass formed；
Fig. 2 (a) Ag-In2O3Quantum Dot Glass XRD spectrum；(b) different component (pure glass, Ag-In are contained2O3, Ag)
Quantum Dot Glass UV-Vis-NIR transmitted light spectrograms；
Fig. 3 .Ag-In2O3The TEM collection of illustrative plates of Quantum Dot Glass：(a) shape appearance figure；(b)SEAD.
Embodiment
With reference to the accompanying drawings and examples, the embodiment of the present invention is described in further detail.Implement below
Example is used to illustrate the present invention, but is not limited to the scope of the present invention.
In the present embodiment, glass body material selection sodium boron silicon-based glass, each component mole group of sodium boron silicon-based glass
Turn into：Na2O：5~8mol%, B2O3：21~24mol%, SiO2：70~73mol%, glass is made according to said ratio value range
Glass colloidal sol, using silver nitrate and indium nitrate as forming metal Ag+And In3+Precursor doped into glass colloidal sol, the ratio of doping
Example is 1~1.5mol%, and wherein the mol ratio of Ag and In elements is 1: 1, is sufficiently stirred, and formation contains Ag+And In3+Glass,
Mounted box and place 1 week after, 120 DEG C dry 4 weeks, i.e., formation contain Ag+And In3+Block xerogel.
In the process, quantum dot-doped concentration is too low to cause quantum dot to be unfavorable for being formed, and this can cause quantum dot
Many properties (such as photoluminescent property, third-order non-linear property) of glass are too low or lack, and doping concentration is too high, in sintering process
The middle easy fragmentation of Quantum Dot Glass, is not easy to form complete bulk material, and the transparency of excessive concentration Quantum Dot Glass
It can decline.
The building-up process of dry glue is the same as synthesizing the building-up process of sodium boron silicon-based glass in the present embodiment.
Synthetic glass technique is as follows：First, containing Ag+And In3+Xerogel, 450 DEG C are heated in oxygen atmosphere and is removed
Remove organic matter and promote silver nitrate and indium nitrate fully to decompose.Secondly, oxygen atmosphere is converted into hydrogen atmosphere and in 450 DEG C of guarantors
Warm 10 hours, now, aeroge forms Ag-In alloys on this condition.After insulation terminates, hydrogen is converted into oxygen atmosphere
And temperature is risen to 600 DEG C, it is incubated 10 hours.Finally, one complete, the transparent Ag Quantum Dot Glass of light brown is formed.
In order to contrast, it is sintered with the obtained xerogel for comprising only Ag+ of above-mentioned same method with same temperature-rise period, it is different
It is exactly the control of atmosphere, after insulation terminates, hydrogen atmosphere is not converted into oxygen atmosphere, but rises to 600 DEG C at 450 DEG C
When continue to lead to.Eventually form complete, the Ag Quantum Dot Glass of black non transparent.Finally in glass body material doped with
Ag-In2O3Compound, wherein Ag is present with crystalline form, In2O3It is to exist as an amorphous form, according to addition silver nitrate
With the amount of indium nitrate, final Ag, In co-doped to glass body material and both account for doping after mol ratio be 0.47%~
0.7% (theoretical value).
With reference to shown in Fig. 1 to Fig. 3, disclosed by the transmitted spectrum of test sample containing Ag-In2O3The quantum dot of structure
Glass only adulterates Ag with sintering under the reducing conditions+The resulting Quantum Dot Glass for comprising only Ag nano particles is compared, transparent
Degree substantially increases substantially.The present invention discloses the nanocrystalline things of Ag using micro-structural test and mutually formed in glass.Transmission
Electron microscope (TEM) shows, the Ag nano particles that particle size is smaller, is evenly distributed are formd in sodium boron silicon-based glass.
Silver nano-grain is doped in clear glass in optical nano label, visible light source, optical storage, third-order non-linear material etc.
Aspect has very big latent effect, it is often more important that the application on light limitation material, this material can be than dark ring
The eyes of people, optical device are protected not to be injured by laser emission in border.These applications are required for Quantum Dot Glass to have preferably thoroughly
Bright property, from the pictorial diagram in figure to some signs, it can be seen that, we form the nano particle of silver in glass, and have very
The good transparency, has widened application of the Quantum Dot Glass in photoelectric field to a certain extent.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvement and modification can also be made, above-mentioned hypothesis these
Improvement and modification are same to should be regarded as protection scope of the present invention.
Claims (2)
- A kind of 1. preparation method for preparing the high transparency Quantum Dot Glass containing silver nano-grain, it is characterised in that：The high transparency quantum points out glass in glass body material doped with Ag-In2O3Compound, wherein Ag is with crystalline state shape Formula is present, In2O3To exist as an amorphous form, Ag, In co-doped to glass body material and both account for doping after mol ratio For 0.47%~0.7%, wherein the mol ratio of Ag and In elements is 1: 1；The preparation method comprises the following steps：1) preparation of xerogel：A, it is made glass colloidal sol, b, is added drop-wise to the ethanol solution respectively containing silver nitrate and indium nitrate In glass colloidal sol, it is sufficiently stirred, formation contains Ag+And In3+Glass, mounted box and place 1 week after, 120 DEG C dry 4 weeks, i.e., Formation contains Ag+And In3+Block xerogel；2) sintering process, xerogel is placed in tube furnace and is sintered：A, first, under oxygen atmosphere, temperature is by room temperature liter To 450 DEG C, it is therefore an objective to remove organic matter and silver nitrate and indium nitrate is sufficiently decomposed, b, oxygen atmosphere is converted into hydrogen gas Atmosphere is simultaneously incubated at 450 DEG C, it is therefore an objective to forms Ag-In alloy under reducing atmosphere, c, insulation terminate, hydrogen atmosphere are converted into Oxygen atmosphere, and temperature is risen to 600 DEG C, by adjust oxidization time obtain to the end it is transparent, completely contain Ag nanometers The Quantum Dot Glass of particle.
- 2. preparation method according to claim 1, it is characterised in that：Described glass body is sodium boron silicon-based glass, sodium The each component mole of boron silicon-based glass forms：Na2O：5~8mol%, B2O3：21~24 mol%, SiO2：70~ 73mol%.
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| CN106950624A (en) * | 2017-04-24 | 2017-07-14 | 宁波东旭成新材料科技有限公司 | A kind of quantum dot light diffusion barrier |
| CN109437563B (en) * | 2018-12-25 | 2020-06-16 | 浙江大学 | Silver quantum cluster doped blue-green fluorescent glass utilizing zinc-oxygen tetrahedron charge balance and preparation method thereof |
| CN109437557B (en) * | 2018-12-25 | 2020-06-16 | 浙江大学 | Green-white fluorescent silver quantum cluster doped fluorophosphate glass based on non-bridging oxygen coordination and preparation method thereof |
| CN109592899B (en) * | 2018-12-25 | 2020-06-16 | 浙江大学 | Visible waveband adjustable fluorescent silver quantum cluster doped inorganic glass with stable boron-oxygen network and preparation method thereof |
| CN113336436B (en) * | 2021-05-18 | 2022-08-26 | 杭州电子科技大学 | Noble metal sensitized carbon quantum dot glass material for LED and preparation method and application thereof |
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| CN103011589A (en) * | 2012-06-27 | 2013-04-03 | 温州大学 | Sodium borosilicate glass doped with In2S3 quantum dots and preparation method thereof |
| CN103833222A (en) * | 2014-01-14 | 2014-06-04 | 杭州电子科技大学 | Multifunctional quantum dot glass material doped with Fe nano-particles and preparation method thereof |
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| JP3625415B2 (en) * | 2000-04-20 | 2005-03-02 | 株式会社日清製粉グループ本社 | Method for producing oxide-encapsulated glass particles and oxide-encapsulated glass particles produced by this method |
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| CN103011589A (en) * | 2012-06-27 | 2013-04-03 | 温州大学 | Sodium borosilicate glass doped with In2S3 quantum dots and preparation method thereof |
| CN103833222A (en) * | 2014-01-14 | 2014-06-04 | 杭州电子科技大学 | Multifunctional quantum dot glass material doped with Fe nano-particles and preparation method thereof |
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| Title |
|---|
| "氧化铟半导体量子点玻璃材料的制备与性能研究";裴浪;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20160315(第3期);B015-380 * |
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