CN105904584A - Dry-pressing moulding carbon fiber cement-based composite material maintenance method - Google Patents

Dry-pressing moulding carbon fiber cement-based composite material maintenance method Download PDF

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Publication number
CN105904584A
CN105904584A CN201610240366.5A CN201610240366A CN105904584A CN 105904584 A CN105904584 A CN 105904584A CN 201610240366 A CN201610240366 A CN 201610240366A CN 105904584 A CN105904584 A CN 105904584A
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carbon fiber
dry
cement
pressing formed
maintenance
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CN201610240366.5A
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CN105904584B (en
Inventor
魏剑
赵莉莉
张倩
聂证博
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Xi'an Huaqing Science And Education Industry Group Co ltd
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Xian University of Architecture and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)

Abstract

A dry-pressing moulding carbon fiber cement-based composite material maintenance method comprising the following steps: using dry pressing moulding mode to prepare cement-based composite material; using water to fully immerse the sample, exposing the sample in a wet environment for pre-maintenance, and immersing the sample into water for maintenance. The carbon fiber cement-based composite material mainly comprises PAN-based short cut carbon fibers and Portland cement, or comprises PAN-based short cut carbon fibers, Portland cement and aggregate, or comprises PAN-based short cut carbon fibers and sulfur aluminate cement, or comprises PAN-based short cut carbon fibers, sulfur aluminate cement and aggregate; the carbon fiber cement-based composite material is stable in thermoelectric performance, excellent in mechanical properties, and simple in moulding and maintenance technology, thus preventing low composite material intensity problems causing by using expandable graphite, preventing high porosity problem caused by small pressure intensity, preventing micro-crack problem caused by insufficient pre-maintenance, thus providing excellent mechanics and thermoelectricity performances.

Description

A kind of maintenance process of dry-pressing formed Carbon Fiber Cement-based Composites
Technical field
The invention belongs to the maintenance technology field of cement-base composite material, particularly to a kind of dry-pressing formed carbon The maintenance process of fiber cement composites.
Background technology
Carbon Fiber Cement-based Composites is the structural material that field of civil engineering research is wide, not only has There is excellent mechanical property, and there is significant thermoelectricity capability etc..Healthy prison at civil engineering structure Survey, road solar heat converts the aspects such as collection and road snow melt deicing and has important application prospect, It it is one of the important directions of intelligent cement based composites research and development.
The raw material types of Carbon Fiber Cement-based Composites, match ratio, molding and maintaining process, and Use the factors such as environment that its mechanics and thermoelectricity capability are played a crucial role.In raw material types and cooperation On the premise of more consistent than certain, moulding process, use environmental condition, the most effective maintaining process is to carrying The aspects such as high material mechanical performance, minimizing shrinkage cracking and raising thermoelectricity capability are most important, warp Become the crucial governing factor improving Carbon Fiber Cement-based Composites performance.
Carbon Fiber Cement-based Composites is a kind of macro-dense and the material of microcosmic porous.Cement based is combined During hardened material, microscopic void is filled by aqueous solution, when the too fast evaporation from hole of these moisture, Material surface arises that cracking, affects its mechanics and thermoelectricity capability.Practical engineering application is most widely supported Nurse's skill includes sprinkle water (spraying) maintenance, covering (wet cloth, plastic sheeting etc.) maintenance, spraying maintenance Agent etc., but above-mentioned maintaining process is mainly for pouring the cement-based material of molding, and for dry-pressing formed Cement-based material, its maintaining process condition control seem even more important.
Document 1 (" Sivaraja Muthusamy, Shoukai Wang, D.D.L.Chung, Carbon, 2010, 48:1457-1464 ") disclose and a kind of utilize the dry-pressing formed expanded graphite-cement-base composite material prepared Method and maintaining process thereof, not only increase cement-base composite material mechanical property, and improve its electricity Learn performance.The method uses dry-pressing formed, and pressure is 5.6MPa, owing to pressure is less, and sample after molding The porosity is bigger.This maintaining process is to be exposed to by sample in wet environment 2 days, is then immersed in water supporting Protect 26 days.When sample is exposed in wet environment, surface formed one layer of hardening of cement shell, be unfavorable for into One step hydration and hardening, and can not be impregnated with completely, the unhydrated cement raw material in sample centre is at follow-up water During change, easily and between casehardening shell, produce fine cracks, it is impossible to well meet experiment and application requirement. It addition, it is relatively low to mix cement-base composite material intensity prepared by expanded graphite.
Summary of the invention
In order to overcome the shortcoming of above-mentioned prior art, it is an object of the invention to provide a kind of dry-pressing formed carbon The maintenance process of fiber cement composites, can overcome and dry-pressing formed prepare cement-base composite material process Present in the porosity high, easy to crack and mix the problems such as expanded graphite intensity is relatively low.
To achieve these goals, the technical solution used in the present invention is:
The maintenance process of a kind of dry-pressing formed Carbon Fiber Cement-based Composites, prepares cement dry-pressing formed After based composites, with water sample is impregnated with completely and is exposed in wet environment and carry out precuring, with After be immersed in the water maintenance.
Described Carbon Fiber Cement-based Composites, mainly by PAN base chopped carbon fiber and portland cement group Become, or be made up of PAN base chopped carbon fiber, portland cement and aggregate, or by PAN base chopped carbon Fiber and sulphate aluminium cement composition, or by PAN base chopped carbon fiber, sulphate aluminium cement and aggregate group Become.
The described PAN a length of 5-10mm of base chopped carbon fiber, with other raw material after pre-dispersed one-tenth monofilament shape It is dry mixed uniform and the most dry-pressing formed.
Described dry-pressing formed pressure is 20-60MPa.
Sample after dry-pressing formed is placed on the water saturated sponge sheet of suction, utilizes capillarity to make it absorb water To being impregnated with completely, then sample is exposed in wet environment and carries out precuring.
Described wet environment, for the water vapor atmosphere of relative humidity more than 95%.
The time of described precuring is 24h.
The temperature of described precuring and maintenance is 20-25 DEG C.
Described it is immersed in the water maintenance to the most fully hardened.
Compared with prior art, the invention has the beneficial effects as follows: it is multiple that the present invention has gained carbon-fiber cement Condensation material thermoelectricity capability is stable, good mechanical performance, molding and the simple feature of maintaining process.The present invention The PAN base chopped carbon fiber tensile strength used is high, electrical conductivity is high, thermal conductivity is low and stable chemical performance, It is possible not only to increase substantially the mechanics of Carbon Fiber Cement-based Composites and thermoelectricity capability, and avoids The problem that the composite material strength using expanded graphite to bring reduces.The present invention is dry-pressing formed prepares carbon fiber The method of cement-base composite material, owing to typed pressure is bigger, it is to avoid when pressure is less, the porosity is high Problem.The maintaining process of the present invention, is placed on the sample after dry-pressing formed on the water saturated sponge sheet of suction, Utilize capillarity to make it absorb water to completely to be impregnated with, then sample is exposed in wet environment and carries out precuring Protect, the problem that precuring insufficient generation micro-crack can be prevented effectively from, make to prepare mechanics and thermoelectricity capability is excellent Good Carbon Fiber Cement-based Composites is possibly realized.
Accompanying drawing explanation
Fig. 1 is schematic flow sheet of the present invention, labelling in figure:
The sample that 1-is dry-pressing formed;The sample of 2-part water suction;3-inhales water saturated sample;4-water suction is saturated Sponge sheet;5-water;The water vapor atmosphere of 6-relative humidity more than 95%.
Fig. 2 is the abundant maintenance of the present invention dry-pressing formed Carbon Fiber Cement-based Composites gained sample and do not fill The graph of a relation of the porosity dividing the dry-pressing formed sample of maintenance and pour obtained by molding sample.
Fig. 3 is the abundant maintenance of the present invention dry-pressing formed Carbon Fiber Cement-based Composites gained sample and do not fill The graph of a relation of the comprcssive strength dividing the dry-pressing formed sample of maintenance and pour obtained by molding sample.
Fig. 4 is the present invention dry-pressing formed Carbon Fiber Cement-based Composites of abundant maintenance and the examination of striaght cement gained The graph of a relation of sample and the comprcssive strength pouring obtained by molding sample.
Fig. 5 is the abundant maintenance of the present invention dry-pressing formed Carbon Fiber Cement-based Composites gained sample and pour The graph of a relation of obtained by molding sample electrical conductivity at different temperatures.
Detailed description of the invention
Embodiments of the present invention are described in detail below in conjunction with the accompanying drawings with embodiment.
Embodiment 1: as it is shown in figure 1, preparing die cavity is the steel die of cuboid, according to mass ratio be The ratio of 1:100, weighs PAN base chopped carbon fiber and sulphate aluminium cement.
Simpson mill is utilized to make PAN base chopped carbon fiber be dispersed in cement matrix, will mixing Uniform powder steel die is dry-pressing formed, and typed pressure is 20MPa.
First dry-pressing formed sample is placed on the water saturated sponge sheet of suction, utilizes capillarity to make it inhale The sample being impregnated with completely, to being impregnated with completely, is exposed to the steam that relative humidity is more than 95% by water subsequently Carrying out precuring in environment, the time is 24h, finally the sample after precuring is immersed in the water further water Changing hardening, the time is 3 days, and in whole maintenance processes, temperature is 20 DEG C.
Embodiment 2: as it is shown in figure 1, preparing die cavity is the steel die of cuboid, according to mass ratio be The ratio of 1:100, weighs PAN base chopped carbon fiber and portland cement.
Simpson mill is utilized to make PAN base chopped carbon fiber be dispersed in cement matrix, will mixing Uniform powder steel die is dry-pressing formed, and typed pressure is 20MPa.
First dry-pressing formed sample is placed on the water saturated sponge sheet of suction, utilizes capillarity to make it inhale The sample being impregnated with completely, to being impregnated with completely, is exposed to the steam that relative humidity is more than 95% by water subsequently Carrying out precuring in environment, the time is 24h, finally the sample after precuring is immersed in the water further water Changing hardening, the time is 28 days, and in whole maintenance processes, temperature is 20 DEG C.
Embodiment 3: as it is shown in figure 1, preparing die cavity is the steel die of cuboid, according to mass ratio be The ratio of 1.2:100, takes, PAN base chopped carbon fiber and sulphate aluminium cement.
Simpson mill is utilized to make PAN base chopped carbon fiber be dispersed in cement matrix, will mixing Uniform powder steel die is dry-pressing formed, and typed pressure is 60MPa.
First dry-pressing formed sample is placed on the water saturated sponge sheet of suction, utilizes capillarity to make it inhale The sample being impregnated with completely, to being impregnated with completely, is exposed to the steam that relative humidity is more than 95% by water subsequently Carrying out precuring in environment, the time is 24h, finally the sample after precuring is immersed in the water further water Changing hardening, the time is 3 days, and in whole maintenance processes, temperature is 25 DEG C.
Embodiment 4: as it is shown in figure 1, preparing die cavity is the steel die of cuboid, according to mass ratio be The ratio of 1.2:100, takes, PAN base chopped carbon fiber and portland cement.
Simpson mill is utilized to make PAN base chopped carbon fiber be dispersed in cement matrix, will mixing Uniform powder steel die is dry-pressing formed, and typed pressure is 60MPa.
First dry-pressing formed sample is placed on the water saturated sponge sheet of suction, utilizes capillarity to make it inhale The sample being impregnated with completely, to being impregnated with completely, is exposed to the steam that relative humidity is more than 95% by water subsequently Carrying out precuring in environment, the time is 24h, finally the sample after precuring is immersed in the water further water Changing hardening, the time is 28 days, and in whole maintenance processes, temperature is 25 DEG C.
Refering to shown in Fig. 2, the porosity of gained Carbon Fiber Cement-based Composites when maintenance of the present invention is abundant Time more insufficient than maintenance, gained sample is the lowest with the porosity pouring obtained by molding sample.
Refering to shown in Fig. 3, the pressure resistance of gained Carbon Fiber Cement-based Composites when maintenance of the present invention is abundant When spending more insufficient than maintenance, gained sample is the highest with the comprcssive strength pouring obtained by molding sample.
Refering to shown in Fig. 4, Carbon Fiber Cement-based Composites that the present invention obtains and the pressure resistance of striaght cement Spend all high than the comprcssive strength pouring obtained by molding sample.
Refering to shown in Fig. 5, the Conductivity Ratio of the Carbon Fiber Cement-based Composites that the present invention obtains waters and builds up High 4 orders of magnitude of electrical conductivity of type gained sample, and its electrical conductivity increases with the rising of temperature.
The foregoing is only one embodiment of the present invention, be not all of or unique embodiment, this It is any etc. that technical solution of the present invention is taked by field those of ordinary skill by reading description of the invention The conversion of effect, the claim being the present invention is contained.

Claims (9)

1. the maintenance process of a dry-pressing formed Carbon Fiber Cement-based Composites, it is characterised in that dry Molded prepare cement-base composite material after, with water sample be impregnated with completely and be exposed in wet environment Carry out precuring, be subsequently dipped to maintenance in water.
The maintenance process of the most dry-pressing formed Carbon Fiber Cement-based Composites, its It is characterised by, described Carbon Fiber Cement-based Composites, mainly by PAN base chopped carbon fiber and silicate Cement forms, or is made up of PAN base chopped carbon fiber, portland cement and aggregate, or by PAN base Chopped carbon fiber and sulphate aluminium cement composition, or by PAN base chopped carbon fiber, sulphate aluminium cement and Aggregate forms.
The maintenance process of the most dry-pressing formed Carbon Fiber Cement-based Composites, its Being characterised by, the described PAN a length of 5-10mm of base chopped carbon fiber, with it after pre-dispersed one-tenth monofilament shape Its raw material is dry mixed uniform and the most dry-pressing formed.
The maintenance process of the most dry-pressing formed Carbon Fiber Cement-based Composites, its Being characterised by, described dry-pressing formed pressure is 20-60MPa.
The maintenance process of the most dry-pressing formed Carbon Fiber Cement-based Composites, its It is characterised by, the sample after dry-pressing formed is placed on the water saturated sponge sheet of suction, utilizes capillarity to make It absorbs water to be impregnated with completely, is then exposed in wet environment by sample and carries out precuring.
6. according to the maintenance process of Carbon Fiber Cement-based Composites dry-pressing formed described in claim 1 or 5, It is characterized in that, described wet environment, for the water vapor atmosphere of relative humidity more than 95%.
7. according to the maintenance process of Carbon Fiber Cement-based Composites dry-pressing formed described in claim 1 or 5, It is characterized in that, the time of described precuring is 24h.
8. according to the maintenance process of Carbon Fiber Cement-based Composites dry-pressing formed described in claim 1 or 5, It is characterized in that, the temperature of described precuring and maintenance is 20-25 DEG C.
The maintenance process of the most dry-pressing formed Carbon Fiber Cement-based Composites, its Be characterised by, described in be immersed in the water maintenance to the most fully hardened.
CN201610240366.5A 2016-04-18 2016-04-18 A kind of maintenance process of dry-pressing formed Carbon Fiber Cement-based Composites Expired - Fee Related CN105904584B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106747140A (en) * 2016-12-16 2017-05-31 西安建筑科技大学 A kind of method for improving Carbon Fiber Cement-based Composites Seebeck coefficients
CN108656328A (en) * 2017-03-27 2018-10-16 北新集团建材股份有限公司 The steaming pressuring curing process of fiber cement board

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109354A (en) * 1998-10-01 2000-04-18 Nishikawa Shokai:Kk Production of building board
CN101654957A (en) * 2009-08-26 2010-02-24 江苏博特新材料有限公司 Method for maintaining cement-based material in early stages
CN101712183A (en) * 2009-10-20 2010-05-26 武汉理工大学 Method for manufacturing chopped carbon fiber reinforced concrete
CN101747072A (en) * 2008-11-26 2010-06-23 弗劳恩霍弗实用研究促进协会 Method for the manufacture of a ceramic component
CN103072200A (en) * 2013-02-20 2013-05-01 无锡职业技术学院 Water curing equipment and curing method for concrete
CN105036678A (en) * 2015-07-08 2015-11-11 安徽省溜口新型建筑材料有限公司 Light aerated brick containing carbon fibers
CN105067164A (en) * 2015-08-12 2015-11-18 大连理工大学 Conductive cement based composite material, preparation method thereof and application thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000109354A (en) * 1998-10-01 2000-04-18 Nishikawa Shokai:Kk Production of building board
CN101747072A (en) * 2008-11-26 2010-06-23 弗劳恩霍弗实用研究促进协会 Method for the manufacture of a ceramic component
CN101654957A (en) * 2009-08-26 2010-02-24 江苏博特新材料有限公司 Method for maintaining cement-based material in early stages
CN101712183A (en) * 2009-10-20 2010-05-26 武汉理工大学 Method for manufacturing chopped carbon fiber reinforced concrete
CN103072200A (en) * 2013-02-20 2013-05-01 无锡职业技术学院 Water curing equipment and curing method for concrete
CN105036678A (en) * 2015-07-08 2015-11-11 安徽省溜口新型建筑材料有限公司 Light aerated brick containing carbon fibers
CN105067164A (en) * 2015-08-12 2015-11-18 大连理工大学 Conductive cement based composite material, preparation method thereof and application thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106747140A (en) * 2016-12-16 2017-05-31 西安建筑科技大学 A kind of method for improving Carbon Fiber Cement-based Composites Seebeck coefficients
CN106747140B (en) * 2016-12-16 2019-05-10 西安建筑科技大学 A method of improving Carbon Fiber Cement-based Composites Seebeck coefficient
CN108656328A (en) * 2017-03-27 2018-10-16 北新集团建材股份有限公司 The steaming pressuring curing process of fiber cement board
CN108656328B (en) * 2017-03-27 2019-10-11 北新集团建材股份有限公司 The steaming pressuring curing process of fiber cement board

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