CN105903404B - A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents and preparation method thereof - Google Patents

A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents and preparation method thereof Download PDF

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Publication number
CN105903404B
CN105903404B CN201610250890.0A CN201610250890A CN105903404B CN 105903404 B CN105903404 B CN 105903404B CN 201610250890 A CN201610250890 A CN 201610250890A CN 105903404 B CN105903404 B CN 105903404B
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foaming agent
splashproof
gemini quaternary
active agents
surface active
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CN105903404A (en
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张放
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C09K23/018—Mixtures of two or more different organic oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/20—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents

Abstract

The invention discloses a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it includes surfactant, foam stabilizer, thickener, emulsifying agent, propellant, Bactericidal cleaner, deionized water, and the invention also discloses the preparation method of above-mentioned Gemini quaternary ammonium salt surface active agents and splashproof foaming agent.The Gemini quaternary ammonium salt surface active agents of the present invention can stable foam, make foam surface tension force suitable and there is certain intensity, and the dosage of foaming agent in splashproof foaming agent can be reduced and foam yield is not reduced；Splashproof foaming agent based on above-mentioned Gemini quaternary ammonium salt surface active agents can be substantially prevented from it is caused when dirt crashes into collection vessel dabble, and with deodorization, antibacterial effect, be adapted to large-scale promotion application.

Description

It is a kind of based on the splashproof foaming agent of Gemini quaternary ammonium salt surface active agents and its preparation Method
Technical field
The present invention relates to hygiene article sector, more particularly to a kind of splashproof based on Gemini quaternary ammonium salt surface active agents Foaming agent and preparation method thereof.
Background technology
Closestool is that present family of China, a kind of of hotel's generally existing facilitate facility, but currently without a technology energy Enough solves the technology that people does not dabble with deodorization at a convenient time, the water for especially in stool being often closestool splashes people's hip or clothing It is very unhygienic on clothes, very big inconvenience is brought to user.Existing detergent of closet and the articles for use of sterilization are mostly liquid, and one As be in direct or indirect addition water tank, with entering closestool during Water flushing for cistern, so as to have the function that cleaning, but but without Method solves the problems, such as mentioned above to prevent closestool from dabbling.
The patent application of Application No. 201510381166.7 discloses a kind of splashproof foaming agent and its application, disclosed Splashproof foaming agent includes any one or more in following surfactant：Lauryl sodium sulfate, sodium alkyl benzene sulfonate, alkene Base sodium sulfonate, fatty alcohol-ether sodium sulfate, foregoing invention is canned using aerosol, and button can eject foam during use, with human body Contactless, foam can effectively play a part of splash-proof, deodorization, sterilization, sterilization, lubrication.But matching somebody with somebody disclosed in foregoing invention It is only surfactant in side, has no sterilization, disinfection composition, and do not disclose its foam stabilization degree.
The patent application of Application No. 201510097321.2 discloses Spattering-proof for closet foam aerosol and preparation method thereof, It is that raw material adds a kind of filling manufactured foam aerosol of propellant using compositions such as foaming agent mixing thickeners, refills in inhalator jar In, foam is produced by shower nozzle.But also without sterilization, disinfection composition in the formula disclosed in foregoing invention, and it is also not disclosed Foam stabilization degree.
The content of the invention
In order to solve the above problems, the present invention provides a kind of foam stabilization persistently and easily washed away with current, possesses sterilization suppression Taste and cleaning efficacy, added with Gemini quaternary ammonium salt surface active agents so as to being reduced in the case where not influenceing foam yield The splashproof foaming agent of frother dosages.
The technical solution adopted by the present invention is：A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, Characterized in that, consist of the following composition, including surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, Emulsifying agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5- 10%th, surplus is deionized water, and above-mentioned each component content sum is 100%；
Further, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl chlorine Change ammonium, the one or more in cocinic acid di-methylcarbinol acid amides, the thickener is sodium alginate, xanthans, and cellulose spreads out Biology, starch, pectin, dextrin, alginates, carragheen, Arabic gum, konjac glucomannan, polyacrylamide, sodium cellulose glycolate, One or more in methylcellulose, carrageenan, guar gum or dextrin；
Further, described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxyl The one or more of sulfobetaines, lauroylamidopropyl betaine, the emulsifying agent are in Span-40, Tween-80 One or two；
Further, described propellant is propane, butane or dimethyl ether；
Further, described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl two One kind or several in methyl-benzyl ammonium chloride, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide Kind；
Further, described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon；
Further, described surfactant is Gemini quaternary cationic surfactants；
Further, the structural formula of described Gemini quaternary cationic surfactants is as follows：
The invention also discloses the preparation method of the above-mentioned splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, Characterized in that, comprise the following steps that：
1) weigh raw material according to formula as below, surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, Emulsifying agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5- 10%th, surplus is deionized water, and above-mentioned each component content sum is 100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression Taste additive, deionized water are mixed at 20-50 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the shape that pressure is 0.3-1MPa Poured under state in aluminium pot and valve is installed, shower nozzle, that is, obtain splashproof foaming agent；
Further, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl chlorine Change the one or more in ammonium, cocinic acid di-methylcarbinol acid amides；
The thickener is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, OK a karaoke club Glue, Arabic gum, konjac glucomannan, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin In one or more；
Described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxyl sulfobetaines The one or more of alkali, lauroylamidopropyl betaine；
The emulsifying agent is one or both of Span-40, Tween-80；
Described propellant is propane, butane or dimethyl ether；
Described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl dimethyl benzyl chloride Change the one or more in ammonium, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide；
Described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon；
Described surfactant is Gemini quaternary cationic surfactants；
The structural formula of described Gemini quaternary cationic surfactants is as follows：
Above-mentioned Gemini quaternary cationic surfactants have low surface tension, contribute to the stabilization of foam, energy It is enough effectively to reduce pressure difference so that foams drain speed is slower, and thinning of liquid film is also slower.
Beneficial effects of the present invention：
Relative to closestool of the prior art splashproof foaming agent, the Gemini quaternary ammonium salts used in inventive formulation Surfactant is the noval chemical compound that synthesizes first, can stable foam, make foam surface tension force suitable and with certain strong Degree, and the dosage of foaming agent in splashproof foaming agent can be reduced and foam yield is not reduced；Based on above-mentioned Gemini quaternary ammoniums The splashproof foaming agent of type surfactant can be substantially prevented from it is caused when dirt crashes into collection vessel dabble, and with anti- Smelly, antibacterial effect, it is adapted to large-scale promotion application.
Brief description of the drawings
Fig. 1 is the Gemini quaternary ammonium salt surface active agent structural formulas of the present invention.
Embodiment
Embodiment 1：
The preparation method for the Gemini quaternary ammonium salt surface active agents being shown below, is comprised the following steps that：
1) by 0.1mol propionic acid and 0.12mol NC2H5(CH=CHOH)2It is fitted into after well mixed in reflux, adds 50mL hexamethylenes, 0.1g p-methyl benzenesulfonic acids, 0.3g zinc powders, 110 DEG C of back flow reactions 4 hours, after reaction terminates, reaction solution is spent Anhydrous sodium sulfate drying is used after ion water washing, boiling off solvent in Rotary Evaporators obtains residue, and then column chromatography purifies, and obtains To propionic acid-N- ethyl divinyl hydramine monoesters, yield 94%；
2) 0.05mol propionic acid-N- ethyl divinyl hydramine monoesters is mixed with 50mL chloroforms, addition 5mL triethylamines, and with Cooling, the mitigation solution of 0.025mol paraphthaloyl chlorides and 30mL chloroforms is then added dropwise, drips off within about 2 hours, after dripping often Warm stirring reaction 20 hours, after reaction terminates, reaction solution is washed with deionized water to neutrality, and nothing is used after being then washed with deionized Aqueous sodium persulfate is dried, and is boiled off solvent in Rotary Evaporators and is obtained residue, and then column chromatography purifies, and obtains not quaternized target Compound precursor, yield 92%；
3) the not quaternized target compound precursors of 0.01mol are well mixed with 30mL methanol, arrived at a low price at 50 DEG C 0.02mol dithyl sulfates react with the mixed solution of 30mL methanol, dripping off within about 2 hours, back flow reaction 10 hours at 50 DEG C It is evaporated off alcohol after end, and with re-crystallizing in ethyl acetate, obtaining white powder i.e. Gemini quaternary ammonium salt surface active agents, yield is 82%.
Determined through surface tension instrument, the critical micelle concentration of obtained Gemini quaternary ammonium salt surface active agents is 3 × 10- 4Mol/L, surface tension 22.1mN/m.
Embodiment 2：
(1) a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that by below into It is grouped into, including Gemini quaternary ammonium salt surface active agents 5%, the foam stabilizer cocinic acid as shown in the structural formula of embodiment 1 are double Glycollic amide 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80 0.5%, foaming agent coconut oleoyl amine CAB 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl benzyl ammonium bromide 10%, suppression taste Additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is 100%.
(2) preparation method of above-mentioned splashproof foaming agent：
1) raw material is weighed according to formula as below, the Gemini quaternary ammonium salt surface active agents as shown in the structural formula of embodiment 1 5%th, foam stabilizer cocinic acid di-methylcarbinol acid amides 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80 0.5%th, foaming agent Cocoamidopropyl betaine 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl Benzylphosphonium Bromide ammonium 10%, suppression taste additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is 100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression Taste additive, deionized water are mixed at 20 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state that pressure is 0.3MPa Under pour into aluminium pot and valve be installed, shower nozzle, that is, obtain splashproof foaming agent.
(3) application method of above-mentioned splashproof foaming agent：
Before closestool defecation, aluminium pot shower nozzle is directed at the closestool water surface, the propellant for making to squeeze out by movable valve gasifies The gas formed afterwards contacts in material liquid, so as to which the related substances in material liquid be acted on, forms foam and sprays, is laid in horse Effective coating is formed on inner bucket water face, strip analogies 80g is put into apart from coating 50cm, does not produce and dabble, through observing, 20 Foam total amount is 90% just generated after minute, and durable lather is stable, and water punching can be clean, and has the effect of cleaning closestool concurrently, So that dirt is not easy wall built-up.
Embodiment 3：
(1) a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that by below into It is grouped into, including Gemini quaternary ammonium salt surface active agents 5%, the foam stabilizer cocinic acid as shown in the structural formula of embodiment 1 are double Glycollic amide 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80 0.5%, foaming agent coconut oleoyl amine CAB 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl benzyl ammonium bromide 10%, suppression taste Additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is 100%.
(2) preparation method of above-mentioned splashproof foaming agent：
1) raw material is weighed according to formula as below, the Gemini quaternary ammonium salt surface active agents as shown in the structural formula of embodiment 1 10%th, foam stabilizer cocinic acid di-methylcarbinol acid amides 0.1%, thickener polyacrylamide 5%, emulsifying agent Tween-80 0.5%th, foaming agent neopelex 20%, propellant liquefied propane 3%, Bactericidal cleaner hexadecyldimethyl benzyl ammonium benzyl Ammonium chloride 10%, the mixture 5% of suppression taste additive horsewhip grass meal and wrinkled giant hyssop powder, surplus are deionized water, above-mentioned each component Content sum is 100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression Taste additive, deionized water are mixed at 30 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state that pressure is 0.3MPa Under pour into aluminium pot and valve be installed, shower nozzle, that is, obtain splashproof foaming agent.
(3) application method of above-mentioned splashproof foaming agent：
Before closestool defecation, aluminium pot shower nozzle is directed at the closestool water surface, the propellant for making to squeeze out by movable valve gasifies The gas formed afterwards contacts in material liquid, so as to which the related substances in material liquid be acted on, forms foam and sprays, is laid in horse Effective coating is formed on inner bucket water face, strip analogies 80g is put into apart from coating 50cm, does not produce and dabble, through observing, 20 Foam total amount is 90% just generated after minute, and durable lather is stable, and water punching can be clean, and has the effect of cleaning closestool concurrently, So that dirt is not easy wall built-up.
Above-described embodiment is in the art the purpose is to be to allow simply to illustrate that the technical concepts and features of the present invention Those of ordinary skill can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all It is the equivalent change or modification according to made by the essence of present invention, should all covers in protection scope of the present invention.

Claims (8)

  1. A kind of 1. splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that consist of the following composition, Including surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, emulsifying agent 0.01-0.5%, foaming agent 20- 40%th, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-10%, surplus are deionized water, above-mentioned each group It is 100% to divide content sum；
    Described surfactant is Gemini quaternary cationic surfactants；
    The structural formula of described Gemini quaternary cationic surfactants is as follows：
  2. 2. splashproof foaming agent as claimed in claim 1, it is characterised in that described foam stabilizer is glycerine, polyacrylamide, gathered One or more in vinyl alcohol, polyethers, dodecyl dimethyl ammonium chloride, cocinic acid di-methylcarbinol acid amides, the thickening Agent is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, carragheen, Arabic gum, konjaku It is a kind of or more in glue, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin Kind.
  3. 3. splashproof foaming agent as claimed in claim 1, it is characterised in that described foaming agent be neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxy sulfo lycine, the one or more of lauroylamidopropyl betaine, it is described Emulsifying agent is one or both of Span-40, Tween-80.
  4. 4. splashproof foaming agent as claimed in claim 1, it is characterised in that described propellant is propane, butane or dimethyl ether.
  5. 5. splashproof foaming agent as claimed in claim 1, it is characterised in that described Bactericidal cleaner is citric acid, ethylenediamine Tetraacethyl sodium, hydrogen peroxide, dodecyl benzyl dimethyl ammonium chloride, cetalkonium chloride, dodecyl One or more in dimethylbenzyl ammonium bromide.
  6. 6. splashproof foaming agent as claimed in claim 1, it is characterised in that described suppression taste additive is horsewhip grass meal, wrinkled giant hyssop One or more in powder, ground cinnamon.
  7. A kind of 7. preparation side of the splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents as claimed in claim 1 Method, it is characterised in that comprise the following steps that：
    1) raw material, surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, emulsification are weighed according to formula as below It is agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-10%, remaining It is 100% to measure as deionized water, above-mentioned each component content sum；
    Described surfactant is Gemini quaternary cationic surfactants；
    The structural formula of described Gemini quaternary cationic surfactants is as follows：
    2) surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression taste are added Add agent, deionized water to be mixed at 20-50 DEG C, obtain mixed material；
    3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state of pressure is 0.3-1MPa Pour into aluminium pot and valve is installed, shower nozzle, that is, obtain splashproof foaming agent.
  8. 8. the preparation method of the splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents as claimed in claim 7, its It is characterised by, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl ammonium chloride, coconut palm One or more in seed oil acid di-methylcarbinol acid amides；
    The thickener is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, carragheen, Ah Draw in primary glue, konjac glucomannan, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin It is one or more kinds of；
    Described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxy sulfo lycine, the moon The one or more of osmanthus amido propyl betaine；
    The emulsifying agent is one or both of Span-40, Tween-80；
    Described propellant is propane, butane or dimethyl ether；
    Described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl dimethyl Benzylmagnesium chloride One or more in ammonium, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide；
    Described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon.
CN201610250890.0A 2016-04-15 2016-04-15 A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents and preparation method thereof Expired - Fee Related CN105903404B (en)

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CN108707517A (en) * 2018-07-10 2018-10-26 浙江时光信息科技有限公司 A kind of potent degreaser of corrosion-free household and its production technology
CN112056970A (en) * 2019-06-11 2020-12-11 北京摩室科技有限公司 Foam flushing-free toilet and operation method thereof
CN110507944B (en) * 2019-09-29 2021-11-23 应急管理部天津消防研究所 High-concentration environment-friendly fluorine-free compressed air foam extinguishing agent
CN113801028B (en) * 2021-10-15 2023-11-10 成都科宏达科技有限公司 Special surfactant for hydrogen peroxide and compound thereof

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