CN105890346A - Counterflow-heat-exchange manganese dioxide reduction ring kiln - Google Patents

Counterflow-heat-exchange manganese dioxide reduction ring kiln Download PDF

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CN105890346A
CN105890346A CN201510021931.4A CN201510021931A CN105890346A CN 105890346 A CN105890346 A CN 105890346A CN 201510021931 A CN201510021931 A CN 201510021931A CN 105890346 A CN105890346 A CN 105890346A
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manganese dioxide
heat
urceolus
rotary kiln
ring
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CN201510021931.4A
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CN105890346B (en
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张寅�
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Abstract

The invention discloses a counterflow-heat-exchange manganese dioxide reduction ring kiln, and belongs to the field of metallurgical engineering. According to the counterflow-heat-exchange manganese dioxide reduction ring kiln, the process that three procedures of raw material heating, a reduction exothermic reaction and product water cooling are sequentially carried out in a vertical pipe in a vertical type multi-pipe manganese dioxide reduction roasting furnace is changed into the process that counterflow heat exchange is carried out by propelling raw materials upstream through a spiral blade in a sleeve in the raw material heating procedure and rotating the raw materials downstream in the sleeve during the reduction exothermic reaction and the product cooling procedure. The temperature rising procedure of the raw materials and the temperature reducing procedure of products are carried out in the same equipment in an opposite mode, heat exchange is achieved, and therefore consumption of heating fuel and cooling water is lowered. Production equipment which consumes a large amount of resources, pollutes the environment and consumes cooling water is changed into the production equipment which consumes little energy, barely pollutes the environment and consumes little cooling water, and innovation of a manganese dioxide reduction roasting furnace is achieved.

Description

Countercurrent flow manganese dioxide reduction rotary kiln
Technical field
The present invention relates to a kind of Industrial Stoves, belong to metallurgical engineering field.It is particularly used for manganese sand roasting Equipment----countercurrent flow manganese dioxide reduction rotary kiln.
Background technology
Need the MnO in manganese ore to produce electrolytic manganese in manganese field of metallurgy2Roasting reduction becomes MnO, contains MnO2Manganese sand and anchracite duff Hybrid Heating proceed by reduction reaction to 800 DEG C, reduction reaction is to put Thermal response, generates containing the product of MnO, product completely cuts off air and is cooled to 60 DEG C and then completes reduction process.Its In chemical reaction as follows:
2MnO2+ C=2MnO+CO2↑+174.6kJ
The prior art of manganese dioxide roasting apparatus has Muffle furnace, converter, fluidized bed furnace and multitube shaft furnace etc. multiple Stove, common feature is to consume the energy in a large number, pollutes environment, needs a kind of new equipment of exploitation to substitute existing setting Standby.Vertical multi-pipe manganese dioxide reduction roaster is wherein only had to have bigger advantage to put it over than other stoves. But vertical multi-pipe manganese dioxide reduction roaster still suffers from power consumption height, the drawback of cooling effect difference.
Reference paper 1: Tian Zongping, You Xianjun, Peng Shunlian, Li Li. the research of manganese dioxide reduction roaster With application. nation manganese industry, 2009,27 (2): 24-26.
Reference paper 2: Zeng Xiangbo. the technological progress and development direction of China's electrolytic manganese metal. China Metal net: 6 multitube Tecnored Process.
Reference paper 3: Zeng Xiangbo. " manganese dioxide reduction technique ". road visitor's bar bar. meeting paper.
Reference paper 4: vertical multi-pipe manganese dioxide reduction roaster. the patent No.: 202810073937.
Summary of the invention
The present invention is to solve above-mentioned technical problem, by process in vertical multi-pipe manganese dioxide reduction roaster Raw material heating, reduction exothermic reaction, product water cool down three processes in vertical tube order and under flow process, change For raw material heating process in sleeve pipe by helical blade advance adverse grade and on reduction exothermic reaction+product cool down Process in inner tube rotates along slope under carry out the flow process of countercurrent flow.The temperature-rise period of raw material and the fall of product Temperature process is inversely carried out in same equipment, it is achieved heat exchanges, thus reduces heating fuel and cooling water Consumption.
To achieve these goals, the technical scheme that the present invention provides is countercurrent flow manganese dioxide reduction rotary kiln, Its summary of the invention is:
1. the equipment of the present invention is made up of rotary kiln (2) and tripping sleeve (3), and tripping sleeve (3) is enclosed within Rotary kiln (2) outside;The discharging opening (5) of countercurrent flow manganese dioxide reduction rotary kiln and the water-cooled of its lower left But device (1) seals and connects, and the flange port (23) of rotating cylinder (15) axis right connects with burner (4). Cold raw material manganese dioxide enters the revolving plow reclaimer (38) of frequency control from hopper (39), through charging aperture (27) Enter between tripping sleeve and rotary kiln, adverse grade under the promotion of helical blade (16) and upper and rotating cylinder (15) In under rotary action along slope and under hot product manganese dioxide carry out sufficient heat exchange;When raw material manganese dioxide When being preheating to 800 DEG C, proceed by reduction reaction and arrival is turned back in mouth (17) entrance rotating cylinder (15); Reduction reaction is exothermic reaction, rotating cylinder (15) inner edge carry out reduction reaction limit along slope under, terminate reduction Under continuing after reaction to lower the temperature along slope, until the discharging opening (5) of rotary kiln (2), temperature drops to about 250 DEG C Complete the process of cooling heat release.And then it is cooled to 60 DEG C of formation products through water cooler (1) isolation air. Owing on the one hand cold raw material is fully heated with rotating cylinder (15) wall contacts under the agitation of helical blade;Separately On the one hand abundant exothermic heat of reaction under the effect that hot charge overturns in rotating cylinder (15), hot product material and rotating cylinder (15) Inwall is fully contacted conduction heat release, completes reduction reaction and the process that cools under very fare-you-well, As long as reaction heat rises, more than raw material, the difference that warm is subtracted each other with product cooling heat in kiln, equipment once starts Will continuously carry out.Mated burner of the present invention (4) and have the exhaust opening (8) of baffle plate (7), It is that concurrent heating is resumed operation when cold raw material is heated and occurs aborted in the runtime by the equipment starting period , the equipment properly functioning phase then stops the burning of burner, closes the baffle plate of exhaust opening.The present invention is by one Consuming the energy in a large number, pollute environment, the production equipment consuming cooling water becomes a few consumption energy, pole Of low pollution environment, few production equipment consuming cooling water, is the innovation to manganese dioxide roasting oven.
2. the summary of the invention of countercurrent flow manganese dioxide reduction rotary kiln also has: the rotating cylinder (15) of rotary kiln (2) Center outer surface is mounted with helical blade (16) and mouth of turning back (17), constitutes spiral shell with tripping sleeve (3) Rotation propeller, promote raw material adverse grade and on;
3. the summary of the invention of countercurrent flow manganese dioxide reduction rotary kiln also has: the rotating cylinder (15) of rotary kiln (2) And it is dynamic between movable sealing between the left sealing ring (9) that a left side is covered greatly, and the refractory seals ring (20) that covers greatly of the right side Seal;The left side of tripping sleeve (3) sets left sealing ring (25), and right side sets right sealing ring (31).Four close The urceolus (28) of the rotating cylinder (15) of rotary kiln with tripping sleeve (3) is formed jacket space and rotating cylinder (15) by seal ring And left side cover (6) greatly, the right big thorax body space covering (22) form unified closing space, raw material heating process All carry out in this closes space with reduction exothermic reaction+product cooling procedure.What reduction reaction produced lacks Amount CO2Gas forms pressure-fired in space and is possible to prevent air to leak in space, a small amount of CO2Arrange through each gap Amplify gas, greatly reduce the manganese roasting pollution to environment.
4. the summary of the invention of countercurrent flow manganese dioxide reduction rotary kiln also has: refractory seals ring (20) is to cut Face is the annulus of L-shaped, and the internal diameter of ring is slightly larger than the external diameter of rotating cylinder (15), the horizontal ring inner surface of L-shaped annulus Being provided with some annular ditch grooves, groove built-in heat-resistant filler band (26), heat-resistant filler band (26) is rolled up by heat-resistant steel wire The wired hose become, solid alumina silicate fibre rope forms.Refractory seals ring (20) is an entirety Heat-resisting steel loop, is enclosed within the right-hand member of rotating cylinder (15);Right sealing ring (31) is made up of two semicircular ring, two Semicircular ring bolt (35), spring pad (36), nut (37) are fixed into full circle, right sealing ring (31) For heat-resisting steel loop.In order to prevent scraping between that cause and quiet parts due to rotating cylinder (15) thermal deformation rotated Rub, between High Temperature Rotating rotating cylinder (15) and quiet parts, need bigger gap.Refractory seals ring (20) Cover greatly and floating with the quiet parts right side with the rotating cylinder (15) that the right sealing ring (31) of heat resisting steel solves High Temperature Rotating The sealing problem of the larger gap between moving sleeve (3).
5. the summary of the invention of countercurrent flow manganese dioxide reduction rotary kiln also has: at the right part of tripping sleeve (3) If arc electric boiling plate (53) and thermocouple (52), the effect of arc electric boiling plate (53) is by the most pre- The part electrical heating of raw material of heat is brought rapidly up initial reduction reaction temperature 800 DEG C, play ignite and The effect of concurrent heating, thermocouple (52) then monitors the temperature of this part material.
6. the summary of the invention of countercurrent flow manganese dioxide reduction rotary kiln also has: elastic support (30) holds up and floats Sleeve (3), makes tripping sleeve (3) float on the axis of rotary kiln (2), alleviates and produces rotary kiln (2) Breaking force.
The structure of the countercurrent flow manganese dioxide reduction rotary kiln of the present invention and vertical multi-pipe manganese dioxide reduction roasting Stove has difference substantially, thermal procession very goodization in this equipment, entering continuously for chemical process Row provides fully carrying out of the best temperature conditions and stirring condition, beneficially chemical process.Countercurrently Heat exchange manganese dioxide reduction rotary kiln has a following income than prior art:
1. raw material heating process and reduction exothermic reaction+product cooling procedure are all in this closes space Carry out.A small amount of CO that reduction reaction produces2Gas forms pressure-fired in closing space and is possible to prevent air to leak Enter, the CO that only a small amount of chemical reaction generates2Discharge air through each gap, greatly reduce manganese dioxide The roasting pollution to environment;
2. a cold raw material of aspect is fully heated with rotary kiln wall contacts under the agitation of helical blade, and It is stirred visibly homogeneous;On the other hand hot charge abundant exothermic heat of reaction, delivery in hot weather under the effect that rotary kiln overturns Product and rotary kiln inwall are fully contacted heat release, complete reduction reaction and cooled under very fare-you-well Journey, can reduce the ratio mixing excess anchracite duff in the feed, raw material MnO2Conversion ratio be up to 98% Above, reduce production cost and improve the yield rate of product.
3 countercurrent flow manganese dioxide reduction rotary kilns will be passed through in vertical multi-pipe manganese dioxide reduction roaster Raw material heating, reduction exothermic reaction, product water cooling three processes sequence flow, change into raw material heating Process in sleeve pipe by helical blade advance adverse grade and on reduction exothermic reaction+product cooling procedure pipe in The flow process of countercurrent flow is carried out under rotating along slope.Make the temperature-rise period of raw material and the temperature-fall period of product same One equipment is inversely carried out, it is achieved heat exchanges, thus reduce heating fuel and the consumption of cooling water.This Inventing an a large amount of consumption energy, pollute environment, the production equipment of consumption cooling water becomes one and seldom disappears Power consumption source, seldom pollutes environment, few production equipment consuming cooling water, greatly reduces manganese dioxide roasting The production cost burnt.
4 in order to prevent the scratch between that cause and quiet parts due to revolving drum thermal deformation, and High Temperature Rotating turns Need bigger gap between cylinder and quiet parts, the present invention takes refractory seals ring and elastic support two Item technology, solves the sealing problem between the rotating cylinder of High Temperature Rotating and quiet parts.The present invention not only solves The high temperature movable sealing problem of this countercurrent flow manganese dioxide reduction rotary kiln, also provides high temperature for same category of device and moves Potted component.
Accompanying drawing explanation
Fig. 1 countercurrent flow manganese dioxide calciner elevation;
Rotary kiln (2) profilograph of Fig. 2 present invention;
Tripping sleeve (3) profilograph of Fig. 3 present invention;
Fig. 4 B to
Fig. 5 A partial enlargement
Fig. 6 C partial enlargement
Detailed description of the invention
Describe the present invention below in conjunction with specific embodiment.
Embodiment describes: see accompanying drawing 1, and countercurrent flow manganese dioxide reduction rotary kiln by rotary kiln (2) and floats Sleeve (3) forms, and rotating cylinder (15) outer surface of rotary kiln (2) is equipped with helical blade (16) and mouth of turning back (17);Tripping sleeve (3) is enclosed within rotary kiln (2) outside, is sitting on two elastic supports (30);Rotary kiln (2) discharging opening (5) seals with the water cooler (1) of its lower left and connects, under water cooler (1) The discharging opening (40) of side seals with impeller blowdown machine (41) of frequency control and connects;Rotary kiln (2) axis is right The flange port (23) of side connects with burner (4);The charging aperture (27) of tripping sleeve (3) connects frequency conversion The revolving plow reclaimer (38) of speed governing, receiving hopper (39) above it;Water cooler (1), burner (4), The revolving plow reclaimer (38) of frequency control and impeller blowdown machine (41) of frequency control are approved product.
See accompanying drawing 2, rotary kiln by a left side cover greatly (6), rotating cylinder (15), revolver band (10), bull gear (11), Helical blade (16), mouth of turning back (17), right wheel band (19), right big cover (22) composition;Left big cover is one Individual left end is closed, and the cylinder of right-end openings, lower section sets discharging opening (5), and top sets the smoke evacuation of band baffle plate (7) Mouth (8), exhaust opening (8) is a flange short tube;Cylinder right-hand member sets sealing ring (9), sealing ring (9) For carbon steel ring, it is enclosed within the left end of rotating cylinder (15);Left big cover (6) is sitting on bearing (50);Right big cover (22) Being the cylinder of an inner surface set heat resistance concrete layer, right-hand member sets flange port (23), and left end sets refractory seals Ring (20), refractory seals ring (20) be cross section be the annulus of L-shaped, the internal diameter of ring be slightly larger than rotating cylinder (15) External diameter, the horizontal ring inner surface of L-shaped annulus is provided with some annular ditch grooves, groove built-in heat-resistant filler band (26), The wired hose that heat-resistant filler band (26) is rolled into by heat-resistant steel wire, solid alumina silicate fibre rope forms; Refractory seals ring (20) is a heat-resisting steel loop of entirety, is enclosed within the right-hand member of rotating cylinder (15);Right big cover (22) It is sitting on bearing (49);Rotating cylinder (15) is a cylinder, and left side is carbon steel, and right-hand part is heat resisting steel, Rotating cylinder (15) left side dress revolver band (10), revolver band is the carbon steel ring that an outside is smooth, is enclosed within rotating cylinder, The right side of revolver band (10) is bull gear (11), and bull gear is external toothing steel loop, is enclosed within rotating cylinder (15); Rotating cylinder (15) center outer surface sets helical blade (16), and the external diameter of helical blade (16) is slightly less than floating bushing The internal diameter of the urceolus (28) of cylinder (3);The right side of helical blade (16) sets mouth of turning back (17), mouth of turning back (17) rotating cylinder (15) several long square openings around it are around;Turn back the right of mouth (17) sets right wheel band (19), right wheel band is the heat-resisting steel loop of a smooth outer surface, is enclosed within rotating cylinder;Left support roller (13) and the right side Support roller (18) holds up rotating cylinder (15), and the axis of rotating cylinder (15) and horizontal line have suitable angle, and left and right is held in the palm Wheel is approved product;The drive mechanism (14) of variable-frequency governor is arranged on the side-lower of bull gear (11), Gear wheel (12) is arranged on the left side of revolver band (10), the drive mechanism (14) of frequency control and gear wheel (12) Also approved product is had to supply.
See accompanying drawing 3 and accompanying drawing 5, accompanying drawing 6, tripping sleeve by left sealing ring (25), charging aperture (27), Urceolus (28), heat-insulation layer (29), spring fastening (30), arc electric boiling plate (53), thermocouple base (51), right sealing ring (31) composition;Left sealing ring (25) and right sealing ring (31) be cross section be L The annulus of shape, the internal diameter of ring is slightly larger than the external diameter of rotating cylinder (15), if the horizontal ring inner surface of L-shaped annulus is provided with Dry annular ditch groove, groove built-in heat-resistant filler band (26), the steel that heat-resistant filler band (26) is rolled into by heat-resistant steel wire Silk flexible pipe, solid alumina silicate fibre rope forms;The perpendicular ring of L-shaped annulus is flange, with bolt (32), Spring pad (33), nut (34) are fixed on urceolus (28) two ends, and sealing ring is made up of two semicircular ring, Two semicircular ring bolts (35), spring pad (36), nuts (37) are fixed into full circle, left sealing ring (25) For carbon steel ring, right sealing ring (31) is heat-resisting steel loop;Urceolus (28) is a cylinder, and left side is carbon Steel, right-hand part is heat resisting steel, and the upper left quarter of urceolus (28) sets charging aperture (27), and charging aperture is a flange Square short tube;Setting arc electric boiling plate (53) below the right part of urceolus (28), right side sets thermocouple base (51); Arc electric boiling plate (53) is made up of arc shell (54), radial brick (55) and resistance wire (56), arc Brick (55) is the fluted refractory brick of inner surface, is contained in arc shell (54), the ditch of radial brick (55) The built-in resistance wire of groove (56);Thermocouple base (51) is an internal thread short tube, is welded on urceolus (28) On wall, thermocouple (52) is installed;Urceolus (28) outer surface sets rock wool heat-preservation layer (29), urceolus (28) It is sitting on two spring fastenings (30).
See accompanying drawing 5, elastic support (30) by upper spring seat (42), spring (43), lower spring cup (44), Arc pallet (45), upper block (46), lower block (47), base plate (48) form, four springs (43) Being contained between upper spring seat (42) and lower spring cup (44), upper spring seat (42) is the cylinder of falling turriform, Upper end is inclined-plane, is fixed on the corner of arc pallet (45), and lower spring cup is cylindrical, is fixed on length On the corner of square floor (48);Under during on cuboid, block (46) is fixed on arc pallet (45) Portion, under two cuboids, block (47) is fixed on base plate (48) and is in the both sides of block (46); Arc pallet (45) is fixed on the urceolus (28) of tripping sleeve (3).

Claims (4)

1. countercurrent flow manganese dioxide reduction rotary kiln is to be passed through in vertical multitube manganese dioxide reduction roaster Raw material heating, reduction exothermic reaction, product water cool down three processes in vertical tube order and under flow process enter Row improves.Flow characteristics after improvement is: raw material heating process is advanced adverse grade by helical blade in sleeve pipe And upper with reduction exothermic reaction+product cooling procedure in inner tube rotates along slope under carry out the stream of countercurrent flow Journey.The device realizing flow process is made up of rotary kiln (2) and tripping sleeve (3), and tripping sleeve (3) is enclosed within and turns Kiln (2) outside, is sitting on two elastic supports (30);The discharging opening (5) of rotary kiln (2) and its lower-left The water cooler (1) of side seals and connects, the discharging opening (40) of water cooler (1) end opening and frequency control Impeller blowdown machine (41) seal connect;The flange port (23) of rotary kiln (2) axis right and burner (4) Connect;The charging aperture (27) of tripping sleeve (3) connects the revolving plow reclaimer (38) of frequency control, above it Receiving hopper (39);Water cooler (1), burner (4), the revolving plow reclaimer (38) of frequency control and change Impeller blowdown machine (41) of frequency modulation speed is approved product.
Countercurrent flow manganese dioxide the most according to claim 1 reduction rotary kiln, is characterized in that: rotary kiln (2) Rotating cylinder (15) center outer surface be mounted with that helical blade (16), the external diameter of helical blade (16) are slightly less than The internal diameter of the urceolus (28) of tripping sleeve (3);The right side of helical blade (16) sets mouth of turning back (17), Mouth (17) of turning back is placed around rotating cylinder (15) several long square openings around.
Countercurrent flow manganese dioxide the most according to claim 1 reduction rotary kiln, is characterized in that: floating bushing Cylinder (3) is by left sealing ring (25), charging aperture (27), urceolus (28), arc electric boiling plate (53), warm Galvanic couple base (51), heat-insulation layer (29), elastic support (30), right sealing ring (31) form, left sealing Ring (25) and right sealing ring (31) be cross section be the annulus of L-shaped, the internal diameter of ring be slightly larger than rotating cylinder (15) External diameter, the horizontal ring inner surface of L-shaped annulus is provided with some annular ditch grooves, groove built-in heat-resistant filler band (26), The wired hose that heat-resistant filler band (26) is rolled into by heat-resistant steel wire, solid alumina silicate fibre rope forms;L The perpendicular ring of shape annulus is flange, is fixed on urceolus (28) with bolt (32), spring pad (33), nut (34) Two ends, two sealing rings are respectively made up of two semicircular ring, two semicircular ring bolts (35), spring pad (36), Nut (37) is fixed into full circle ring, and left sealing ring (25) is carbon steel ring, and right sealing ring (31) is heat-resisting Steel loop;Urceolus (28) is a cylinder, and left side is carbon steel, and right-hand part is heat resisting steel, urceolus (28) Upper left quarter set charging aperture (27), charging aperture (27) is a square short tube of flange;The right side of urceolus (28) Setting arc electric boiling plate (53) below portion, the right side of arc electric boiling plate sets thermocouple base (51);Arc Electric boiling plate (53) is made up of arc shell (54), radial brick (55) and resistance wire (56), radial brick (55) It is the fluted refractory brick of inner surface, is contained in arc shell (54), the built-in electricity of groove of radial brick (55) Resistance silk (56);Thermocouple base (51) is an internal thread short tube, is welded on the wall of urceolus (28), peace Dress thermocouple (52);Urceolus (28) outer surface sets rock wool heat-preservation layer (29), and urceolus (28) is sitting in two On elastic support (30).
Countercurrent flow manganese dioxide the most according to claim 1 reduction rotary kiln, is characterized in that: elastic Seat (30) by upper spring seat (42), spring (43), lower spring cup (44), arc pallet (45), on Block (46), lower block (47), base plate (48) form, and four springs (43) are contained in upper spring seat (42) And between lower spring cup (44), upper spring seat (42) is the cylinder of falling turriform, and upper end is inclined-plane, is fixed on On the corner of arc pallet (45), lower spring cup is cylindrical, is fixed on the four of rectangle base plate (48) On angle;On cuboid, block (46) is fixed on the middle and lower part of arc pallet (45), two cuboid lower blocks Block (47) is fixed on base plate (48) and is in the both sides of block (46);Arc pallet (45) is solid It is scheduled on the urceolus (28) of tripping sleeve (3).
CN201510021931.4A 2015-01-16 2015-01-16 Countercurrent flow manganese dioxide reduces rotary kiln Expired - Fee Related CN105890346B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108180756A (en) * 2017-12-07 2018-06-19 天长市昭田磁电科技有限公司 A kind of multitube rotary kiln
CN110006247A (en) * 2019-05-10 2019-07-12 黎柴佐 A kind of back-heating type powder annealing device and its method

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CN2869723Y (en) * 2006-02-08 2007-02-14 孙学忠 Novel multi-return-stroke drum heating apparatus
US20080176178A1 (en) * 2007-01-23 2008-07-24 Ffe Mineras Usa Inc. Reduction kiln
CN102040247A (en) * 2010-11-20 2011-05-04 湖北开元化工科技股份有限公司 Method and device for producing chemical manganese dioxide
CN202692618U (en) * 2012-06-06 2013-01-23 王松正 External-heating-type dual-layer drying kiln
CN204461041U (en) * 2015-01-16 2015-07-08 张寅� Countercurrent flow manganese dioxide reduction rotary kiln

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2869723Y (en) * 2006-02-08 2007-02-14 孙学忠 Novel multi-return-stroke drum heating apparatus
US20080176178A1 (en) * 2007-01-23 2008-07-24 Ffe Mineras Usa Inc. Reduction kiln
CN102040247A (en) * 2010-11-20 2011-05-04 湖北开元化工科技股份有限公司 Method and device for producing chemical manganese dioxide
CN202692618U (en) * 2012-06-06 2013-01-23 王松正 External-heating-type dual-layer drying kiln
CN204461041U (en) * 2015-01-16 2015-07-08 张寅� Countercurrent flow manganese dioxide reduction rotary kiln

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108180756A (en) * 2017-12-07 2018-06-19 天长市昭田磁电科技有限公司 A kind of multitube rotary kiln
CN110006247A (en) * 2019-05-10 2019-07-12 黎柴佐 A kind of back-heating type powder annealing device and its method
CN110006247B (en) * 2019-05-10 2024-04-12 黎柴佐 Regenerative powder heat treatment device and method thereof

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Granted publication date: 20180525