CN105887501A - Production method of suede superfine fiber synthetic leather - Google Patents

Production method of suede superfine fiber synthetic leather Download PDF

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Publication number
CN105887501A
CN105887501A CN201610281080.1A CN201610281080A CN105887501A CN 105887501 A CN105887501 A CN 105887501A CN 201610281080 A CN201610281080 A CN 201610281080A CN 105887501 A CN105887501 A CN 105887501A
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CN
China
Prior art keywords
superfine fiber
finished product
strand
suede
synthetic leather
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610281080.1A
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Chinese (zh)
Inventor
顾宇霆
林天送
张鹏
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Anan (China) Co Ltd
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Anan (China) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Priority to CN201610281080.1A priority Critical patent/CN105887501A/en
Publication of CN105887501A publication Critical patent/CN105887501A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/096Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/36Matrix structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C11/00Teasing, napping or otherwise roughening or raising pile of textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/02Setting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention relates to a production method of suede superfine fiber synthetic leather. The production method of the suede superfine fiber synthetic leather includes: introducing a dry-method coating technology; coating high-solid-content suede resin coating on a superfine fiber non-woven fabric surface layer; forming compact and uniform resin bubble holes in the non-woven fabric surface layer by permeation, drying and solvent evaporation; then implementing impregnation, reduction and afterfinish technologies to finally form the suede superfine fiber synthetic leather which is compact in surface, uniform, and relatively low in production cost.

Description

A kind of production method of suede superfine fiber synthetic leather
Technical field
The present invention relates to technical field of synthetic leather, a kind of suede superfine fiber synthetic leather Production method.
Background technology
Suede superfine fiber synthetic leather is that surface has natural suede floss effect, substitutes natural suede It is widely used in for footwear, case and bag, the artificial leather of clothing.
Traditional suede superfine fiber synthetic leather produces, and matte resin is mainly impregnated with by wet method Mode enters superfine fibre nonwoven cloth, then by wet coagulation, in displacement wet method impregnation material DMF, forms abscess, then the sea component in decrement operation dissolves superfine fibre, and it is fixed to dry Type, by mill skin and the combination of dyeing and finishing technology, forms surface and has the synthetic leather of suede nap effect. The pile effects of suede nap depends primarily on the density of wet method resin abscess, fineness, uniformity, Fineness with fiber.
Due to wet method impregnation, solidification the abscess that formed of mode by resin stability, auxiliary agent, The impact of curing condition, and the restriction of solid content, the abscess forming dense uniform has certain tired Difficulty, simultaneously because special matte resin price is significantly higher than ordinary resin, also results in whole product Product are relatively costly.
Summary of the invention
The technical problem to be solved be solve conventional suede leather cell uniformity not, The problem fine and close not, production cost is high, it is provided that one shows densification, uniform, production cost The production method of relatively low suede superfine fiber synthetic leather.
For solving above-mentioned technical problem, this production method introduces dry coating technique, first by Gao Gu The matte resinous coat of content is coated on superfine fibre nonwoven cloth surface layer, by permeating and being dried, Volatilized by solvent again, form densification, uniform resin abscess at non-woven fabrics surface layer, then implement Impregnation, decrement, postfinishing process, ultimately form show densification, uniformly, production cost relatively low Suede superfine fiber synthetic leather.
The production method of a kind of suede superfine fiber synthetic leather of the present invention includes walking as follows Rapid:
1, island superfine fiber processing: first sea component is cut into slices (such as polyethylene, water solublity Polyester, water-soluble cellulose and polypropylene etc. cut into slices) and island component slices (as polyamide cut into slices, Polyester slice) two kinds of raw materials make island superfine fiber by spinning production process;Spinning produces Operation includes being spun or spinning by the way of Compound spinning by mixed melting, and nascent strand is special Air-conditioning ring blowing under the conditions of cooling forming;In order to optimize spinning property and the physical property of strand Can, strand is oiled, and it is poly-to utilize the drawing-off effect of draw roll to improve the height within strand The trend concordance of thing molecule, now strand internal structure basically reaches requirement;Then by folded Silk machine, crimping machine also oil once again, carry out piddler, through relaxation heat setting in course of conveying After the effect of machine, the face shaping of the internal structure of strand, physical property and strand just reaches Production requirement also settles out;Last strand is again through silk guide frame, traction tensioner and cutting machine With the length set, strand being cut off, finished silk enters baling press by air delivery pipe and completes bag Dress;
2, non-weaving cloth produces: utilize bale opener that island superfine fiber is put into loosening mixer Carry out shredding mixing, and add specific oil preparation (palm oil grease, emulsifying agent, antistatic additive) and enter The optimization of the spinnabilitys such as row such as antistatic, carries out fiber combing subsequently into carding machine, combing After fiber enter high-precision lapping machine by feeding unit and be laid to net, thickness and density are high Spend uniform fibre web with constant speed by needing machine or spun-laced machine, at pricker or the work of liquid drugs injection With entangled to each other armful of lower fibre web internal fiber and, form the non-woven of structure and stable physical property Cloth;Non-weaving cloth passes through thermal finalization fixed thickness and shape, is finally made sizing non-weaving cloth;
3, matte polyurethane coating: by matte resin and a certain proportion of solvent of high solids content Mixing, and coat sizing nonwoven fabric surface, coating medium penetrates into sizing non-weaving cloth table Layer, by oven for drying, during drying, solvent volatilization, forms fine and closely woven hole-layer foam, and Solidification prepares semi-finished product after coating;
4, paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity And inject impregnating groove;Then will paint rear semi-finished product to carry out closing padding liquid by impregnating groove;Finally Base fabric containing slurry is implemented curing process, and solidification is replaced by solvent or is dried or salt solidification Hardening of resin is made, by making semi-finished product after impregnation containing soaking technology etc. mode;
5, island superfine fiber Alkali reduction method dissolves sea component: is sent into by semi-finished product after impregnation and subtracts Measuring tank, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, to sea component Dissolve, after multiple-grooved is dissolved, be carried out with boiling water, it is achieved the fibrillation of superfine fibre Prepare fibrillation semi-finished product;
6, the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping, The most again by mill skin and the combination of dyeing and finishing technology, form the colored surface with even compact Suede nap effect, is finally made suede superfine fiber synthetic leather finished product.
The positive effect of the present invention:
The production method of a kind of suede superfine fiber synthetic leather of the present invention, by by large arch dam The matte resin mixture coating of amount is with dry, at super fine non-woven fabrics by the way of solvent volatilizees Top layer forms uniform fine and close hole-layer foam, then implements impregnation, decrement, postfinishing process, Make surface eventually and there is densification, uniform velvet effect, the matte superfine fibre that production cost is low Synthetic leather.
Owing to the process control degree of solvent volatilization is high, the abscess of formation is finer and closely woven, is impregnated with tree simultaneously Fat uses ordinary resin, so final product not only has careful careful pile effects, with Time processing procedure stable, production cost is low.
Detailed description of the invention
Fig. 1 is the schematic flow sheet of island superfine fiber processing
Fig. 2 is the schematic flow sheet that sizing non-weaving cloth produces
Fig. 3 is the schematic flow sheet of matte polyurethane coating
Fig. 4 is to paint the schematic flow sheet that rear semi-finished product impregnation processes
Fig. 5 is the schematic flow sheet that island superfine fiber Alkali reduction method dissolves sea component
Fig. 6 is the schematic flow sheet of the finished product manufacture of suede superfine fiber synthetic leather
The production method of a kind of suede superfine fiber synthetic leather of the present invention includes walking as follows Rapid:
1, island superfine fiber processing: first sea component is cut into slices (such as polyethylene, water solublity Polyester, water-soluble cellulose and polypropylene etc. cut into slices) and island component slices (as polyamide cut into slices, Polyester slice) two kinds of raw materials make island superfine fiber by spinning production process;Spinning produces Operation includes being spun or spinning by the way of Compound spinning by mixed melting, and nascent strand is special Air-conditioning ring blowing under the conditions of cooling forming;In order to optimize spinning property and the physical property of strand Can, strand is oiled, and it is poly-to utilize the drawing-off effect of draw roll to improve the height within strand The trend concordance of thing molecule, now strand internal structure basically reaches requirement;Then by folded Silk machine, crimping machine also oil once again, carry out piddler, through relaxation heat setting in course of conveying After the effect of machine, the face shaping of the internal structure of strand, physical property and strand just reaches Production requirement also settles out;Last strand is again through silk guide frame, traction tensioner and cutting machine With the length set, strand being cut off, finished silk enters baling press by air delivery pipe and completes bag Dress;
2, non-weaving cloth produces: utilize bale opener that island superfine fiber is put into loosening mixer Carry out shredding mixing, and add specific oil preparation (palm oil grease, emulsifying agent, antistatic additive) and enter The optimization of the spinnabilitys such as row such as antistatic, carries out fiber combing subsequently into carding machine, combing After fiber enter high-precision lapping machine by feeding unit and be laid to net, thickness and density are high Spend uniform fibre web with constant speed by needing machine or spun-laced machine, at pricker or the work of liquid drugs injection With entangled to each other armful of lower fibre web internal fiber and, form the non-woven of structure and stable physical property Cloth;Non-weaving cloth passes through thermal finalization fixed thickness and shape, is finally made sizing non-weaving cloth;
3, matte polyurethane coating: by matte resin and a certain proportion of solvent of high solids content Mixing, and coat sizing nonwoven fabric surface, coating medium penetrates into sizing non-weaving cloth table Layer, by oven for drying, during drying, solvent volatilization, forms fine and closely woven hole-layer foam, and Solidification prepares semi-finished product after coating;
4, paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity And inject impregnating groove;Then will paint rear semi-finished product to be carried out containing padding liquid by impregnating groove;Finally Base fabric containing slurry is implemented curing process, and solidification is replaced by solvent or is dried or salt solidification Hardening of resin is made, by making semi-finished product after impregnation containing soaking technology etc. mode;
5, island superfine fiber Alkali reduction method dissolves sea component: is sent into by semi-finished product after impregnation and subtracts Measuring tank, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, to sea component Dissolve, after multiple-grooved is dissolved, be carried out with boiling water, it is achieved the fibrillation of superfine fibre Prepare fibrillation semi-finished product;
6, the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping, The most again by mill skin and the combination of dyeing and finishing technology, form the colored surface with even compact Suede nap effect, is finally made suede superfine fiber synthetic leather finished product.

Claims (1)

1. the production method of a suede superfine fiber synthetic leather, it is characterised in that: include as Lower step:
A) island superfine fiber processing: first by sea component section and two kinds of raw materials of island component slices Island superfine fiber is made by spinning production process;Spinning production process includes leading to Crossing mixed melting to spin or the mode spinning of Compound spinning, nascent strand is special Cooling forming under the conditions of the blowing of air-conditioning ring;In order to optimize spinning property and the thing of strand Rationality energy, oils to strand, and utilizes the drawing-off effect of draw roll to improve silk The trend concordance of the high-polymer molecular within bar, now strand internal structure is basic Reach requirement;Then by folded silk machine, crimping machine and oil once again, course of conveying In carry out piddler, after the effect of loosening heat setting machine, the inside of strand Under the face shaping of structure, physical property and strand just reaches production requirement and stablizes Come;Last strand again through silk guide frame, traction tensioner and cutting machine to set Length cuts off strand, and finished silk enters baling press by air delivery pipe and completes packaging;
B) non-weaving cloth produces: utilizes bale opener that island superfine fiber is put into loosening mixer and enters Row shredding mixes, and add palm oil grease, emulsifying agent, antistatic additive are carried out such as The optimization of the spinnabilitys such as antistatic, carries out fiber combing subsequently into carding machine, comb Fiber after reason enters high-precision lapping machine by feeding unit and is laid to net, thick Degree and the uniform fibre web of density altitude pass through needing machine or spun lacing with constant speed Machine, under the effect of pricker or liquid drugs injection entangled to each other armful of fibre web internal fiber and, shape Become structure and the non-weaving cloth of stable physical property;Non-weaving cloth is solid by thermal finalization Determine thickness and shape, be finally made sizing non-weaving cloth;
C) matte polyurethane coating: matte resin and a certain proportion of solvent of high solids content are mixed Closing, and coat sizing nonwoven fabric surface, coating medium penetrates into non-knitting of shaping Make cloth top layer, by oven for drying, solvent volatilization during drying, formed thin Close hole-layer foam, and solidify semi-finished product after prepared coating;
D) paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity also Inject impregnating groove;Then will paint rear semi-finished product to be carried out containing padding liquid by impregnating groove; Finally the base fabric containing slurry is implemented curing process, solidification replaced by solvent or The modes such as drying or salt solidification make hardening of resin, after making impregnation containing soaking technology Semi-finished product;
E) island superfine fiber Alkali reduction method dissolves sea component: after being impregnated with, semi-finished product send into decrement Groove, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, right Sea component dissolves, and after multiple-grooved is dissolved, is carried out with boiling water, it is achieved The fibrillation of superfine fibre prepares fibrillation semi-finished product;
F) the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping, The most again by mill skin and the combination of dyeing and finishing technology, form colored having and uniformly cause Close surface suede nap effect, is finally made suede superfine fiber synthetic leather finished product.
CN201610281080.1A 2016-05-03 2016-05-03 Production method of suede superfine fiber synthetic leather Pending CN105887501A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108708174A (en) * 2017-04-07 2018-10-26 安安(中国)有限公司 A kind of production method with antistatic and electric conductivity superfine fiber chemical leather
CN108729247A (en) * 2017-04-17 2018-11-02 安安(中国)有限公司 The processing method of superfine fiber chemical leather with high physical property and sanitation performance
CN108894003A (en) * 2018-09-04 2018-11-27 四川大学 A kind of superfine fibre suede and preparation method thereof generating negative oxygen ion
CN108951177A (en) * 2017-05-18 2018-12-07 安安(中国)有限公司 A kind of processing method of the suede superfine fiber synthetic leather with higher scratch resistance wear-resisting property

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Publication number Priority date Publication date Assignee Title
JP3410577B2 (en) * 1995-03-10 2003-05-26 株式会社クラレ Suede-like artificial leather and manufacturing method thereof
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CN1834320A (en) * 2006-04-17 2006-09-20 吴江祥盛纺织染整有限公司 Color insert strip chamois nap fabric and prepn. thereof
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CN103820872A (en) * 2014-03-03 2014-05-28 晋江市闽高纺织科技有限公司 Figured sea-island ultrafine fiber, preparing method and process method of synthetic leather of figured sea-island ultrafine fiber
CN105113273A (en) * 2015-09-02 2015-12-02 安安(中国)有限公司 Production method of superfine fiber synthetic leather with density gradient structure

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CN1834320A (en) * 2006-04-17 2006-09-20 吴江祥盛纺织染整有限公司 Color insert strip chamois nap fabric and prepn. thereof
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108708174A (en) * 2017-04-07 2018-10-26 安安(中国)有限公司 A kind of production method with antistatic and electric conductivity superfine fiber chemical leather
CN108729247A (en) * 2017-04-17 2018-11-02 安安(中国)有限公司 The processing method of superfine fiber chemical leather with high physical property and sanitation performance
CN108951177A (en) * 2017-05-18 2018-12-07 安安(中国)有限公司 A kind of processing method of the suede superfine fiber synthetic leather with higher scratch resistance wear-resisting property
CN108894003A (en) * 2018-09-04 2018-11-27 四川大学 A kind of superfine fibre suede and preparation method thereof generating negative oxygen ion

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Application publication date: 20160824