CN105887501A - Production method of suede superfine fiber synthetic leather - Google Patents
Production method of suede superfine fiber synthetic leather Download PDFInfo
- Publication number
- CN105887501A CN105887501A CN201610281080.1A CN201610281080A CN105887501A CN 105887501 A CN105887501 A CN 105887501A CN 201610281080 A CN201610281080 A CN 201610281080A CN 105887501 A CN105887501 A CN 105887501A
- Authority
- CN
- China
- Prior art keywords
- superfine fiber
- finished product
- strand
- suede
- synthetic leather
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/096—Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/36—Matrix structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C11/00—Teasing, napping or otherwise roughening or raising pile of textile fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention relates to a production method of suede superfine fiber synthetic leather. The production method of the suede superfine fiber synthetic leather includes: introducing a dry-method coating technology; coating high-solid-content suede resin coating on a superfine fiber non-woven fabric surface layer; forming compact and uniform resin bubble holes in the non-woven fabric surface layer by permeation, drying and solvent evaporation; then implementing impregnation, reduction and afterfinish technologies to finally form the suede superfine fiber synthetic leather which is compact in surface, uniform, and relatively low in production cost.
Description
Technical field
The present invention relates to technical field of synthetic leather, a kind of suede superfine fiber synthetic leather
Production method.
Background technology
Suede superfine fiber synthetic leather is that surface has natural suede floss effect, substitutes natural suede
It is widely used in for footwear, case and bag, the artificial leather of clothing.
Traditional suede superfine fiber synthetic leather produces, and matte resin is mainly impregnated with by wet method
Mode enters superfine fibre nonwoven cloth, then by wet coagulation, in displacement wet method impregnation material
DMF, forms abscess, then the sea component in decrement operation dissolves superfine fibre, and it is fixed to dry
Type, by mill skin and the combination of dyeing and finishing technology, forms surface and has the synthetic leather of suede nap effect.
The pile effects of suede nap depends primarily on the density of wet method resin abscess, fineness, uniformity,
Fineness with fiber.
Due to wet method impregnation, solidification the abscess that formed of mode by resin stability, auxiliary agent,
The impact of curing condition, and the restriction of solid content, the abscess forming dense uniform has certain tired
Difficulty, simultaneously because special matte resin price is significantly higher than ordinary resin, also results in whole product
Product are relatively costly.
Summary of the invention
The technical problem to be solved be solve conventional suede leather cell uniformity not,
The problem fine and close not, production cost is high, it is provided that one shows densification, uniform, production cost
The production method of relatively low suede superfine fiber synthetic leather.
For solving above-mentioned technical problem, this production method introduces dry coating technique, first by Gao Gu
The matte resinous coat of content is coated on superfine fibre nonwoven cloth surface layer, by permeating and being dried,
Volatilized by solvent again, form densification, uniform resin abscess at non-woven fabrics surface layer, then implement
Impregnation, decrement, postfinishing process, ultimately form show densification, uniformly, production cost relatively low
Suede superfine fiber synthetic leather.
The production method of a kind of suede superfine fiber synthetic leather of the present invention includes walking as follows
Rapid:
1, island superfine fiber processing: first sea component is cut into slices (such as polyethylene, water solublity
Polyester, water-soluble cellulose and polypropylene etc. cut into slices) and island component slices (as polyamide cut into slices,
Polyester slice) two kinds of raw materials make island superfine fiber by spinning production process;Spinning produces
Operation includes being spun or spinning by the way of Compound spinning by mixed melting, and nascent strand is special
Air-conditioning ring blowing under the conditions of cooling forming;In order to optimize spinning property and the physical property of strand
Can, strand is oiled, and it is poly-to utilize the drawing-off effect of draw roll to improve the height within strand
The trend concordance of thing molecule, now strand internal structure basically reaches requirement;Then by folded
Silk machine, crimping machine also oil once again, carry out piddler, through relaxation heat setting in course of conveying
After the effect of machine, the face shaping of the internal structure of strand, physical property and strand just reaches
Production requirement also settles out;Last strand is again through silk guide frame, traction tensioner and cutting machine
With the length set, strand being cut off, finished silk enters baling press by air delivery pipe and completes bag
Dress;
2, non-weaving cloth produces: utilize bale opener that island superfine fiber is put into loosening mixer
Carry out shredding mixing, and add specific oil preparation (palm oil grease, emulsifying agent, antistatic additive) and enter
The optimization of the spinnabilitys such as row such as antistatic, carries out fiber combing subsequently into carding machine, combing
After fiber enter high-precision lapping machine by feeding unit and be laid to net, thickness and density are high
Spend uniform fibre web with constant speed by needing machine or spun-laced machine, at pricker or the work of liquid drugs injection
With entangled to each other armful of lower fibre web internal fiber and, form the non-woven of structure and stable physical property
Cloth;Non-weaving cloth passes through thermal finalization fixed thickness and shape, is finally made sizing non-weaving cloth;
3, matte polyurethane coating: by matte resin and a certain proportion of solvent of high solids content
Mixing, and coat sizing nonwoven fabric surface, coating medium penetrates into sizing non-weaving cloth table
Layer, by oven for drying, during drying, solvent volatilization, forms fine and closely woven hole-layer foam, and
Solidification prepares semi-finished product after coating;
4, paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity
And inject impregnating groove;Then will paint rear semi-finished product to carry out closing padding liquid by impregnating groove;Finally
Base fabric containing slurry is implemented curing process, and solidification is replaced by solvent or is dried or salt solidification
Hardening of resin is made, by making semi-finished product after impregnation containing soaking technology etc. mode;
5, island superfine fiber Alkali reduction method dissolves sea component: is sent into by semi-finished product after impregnation and subtracts
Measuring tank, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, to sea component
Dissolve, after multiple-grooved is dissolved, be carried out with boiling water, it is achieved the fibrillation of superfine fibre
Prepare fibrillation semi-finished product;
6, the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping,
The most again by mill skin and the combination of dyeing and finishing technology, form the colored surface with even compact
Suede nap effect, is finally made suede superfine fiber synthetic leather finished product.
The positive effect of the present invention:
The production method of a kind of suede superfine fiber synthetic leather of the present invention, by by large arch dam
The matte resin mixture coating of amount is with dry, at super fine non-woven fabrics by the way of solvent volatilizees
Top layer forms uniform fine and close hole-layer foam, then implements impregnation, decrement, postfinishing process,
Make surface eventually and there is densification, uniform velvet effect, the matte superfine fibre that production cost is low
Synthetic leather.
Owing to the process control degree of solvent volatilization is high, the abscess of formation is finer and closely woven, is impregnated with tree simultaneously
Fat uses ordinary resin, so final product not only has careful careful pile effects, with
Time processing procedure stable, production cost is low.
Detailed description of the invention
Fig. 1 is the schematic flow sheet of island superfine fiber processing
Fig. 2 is the schematic flow sheet that sizing non-weaving cloth produces
Fig. 3 is the schematic flow sheet of matte polyurethane coating
Fig. 4 is to paint the schematic flow sheet that rear semi-finished product impregnation processes
Fig. 5 is the schematic flow sheet that island superfine fiber Alkali reduction method dissolves sea component
Fig. 6 is the schematic flow sheet of the finished product manufacture of suede superfine fiber synthetic leather
The production method of a kind of suede superfine fiber synthetic leather of the present invention includes walking as follows
Rapid:
1, island superfine fiber processing: first sea component is cut into slices (such as polyethylene, water solublity
Polyester, water-soluble cellulose and polypropylene etc. cut into slices) and island component slices (as polyamide cut into slices,
Polyester slice) two kinds of raw materials make island superfine fiber by spinning production process;Spinning produces
Operation includes being spun or spinning by the way of Compound spinning by mixed melting, and nascent strand is special
Air-conditioning ring blowing under the conditions of cooling forming;In order to optimize spinning property and the physical property of strand
Can, strand is oiled, and it is poly-to utilize the drawing-off effect of draw roll to improve the height within strand
The trend concordance of thing molecule, now strand internal structure basically reaches requirement;Then by folded
Silk machine, crimping machine also oil once again, carry out piddler, through relaxation heat setting in course of conveying
After the effect of machine, the face shaping of the internal structure of strand, physical property and strand just reaches
Production requirement also settles out;Last strand is again through silk guide frame, traction tensioner and cutting machine
With the length set, strand being cut off, finished silk enters baling press by air delivery pipe and completes bag
Dress;
2, non-weaving cloth produces: utilize bale opener that island superfine fiber is put into loosening mixer
Carry out shredding mixing, and add specific oil preparation (palm oil grease, emulsifying agent, antistatic additive) and enter
The optimization of the spinnabilitys such as row such as antistatic, carries out fiber combing subsequently into carding machine, combing
After fiber enter high-precision lapping machine by feeding unit and be laid to net, thickness and density are high
Spend uniform fibre web with constant speed by needing machine or spun-laced machine, at pricker or the work of liquid drugs injection
With entangled to each other armful of lower fibre web internal fiber and, form the non-woven of structure and stable physical property
Cloth;Non-weaving cloth passes through thermal finalization fixed thickness and shape, is finally made sizing non-weaving cloth;
3, matte polyurethane coating: by matte resin and a certain proportion of solvent of high solids content
Mixing, and coat sizing nonwoven fabric surface, coating medium penetrates into sizing non-weaving cloth table
Layer, by oven for drying, during drying, solvent volatilization, forms fine and closely woven hole-layer foam, and
Solidification prepares semi-finished product after coating;
4, paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity
And inject impregnating groove;Then will paint rear semi-finished product to be carried out containing padding liquid by impregnating groove;Finally
Base fabric containing slurry is implemented curing process, and solidification is replaced by solvent or is dried or salt solidification
Hardening of resin is made, by making semi-finished product after impregnation containing soaking technology etc. mode;
5, island superfine fiber Alkali reduction method dissolves sea component: is sent into by semi-finished product after impregnation and subtracts
Measuring tank, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, to sea component
Dissolve, after multiple-grooved is dissolved, be carried out with boiling water, it is achieved the fibrillation of superfine fibre
Prepare fibrillation semi-finished product;
6, the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping,
The most again by mill skin and the combination of dyeing and finishing technology, form the colored surface with even compact
Suede nap effect, is finally made suede superfine fiber synthetic leather finished product.
Claims (1)
1. the production method of a suede superfine fiber synthetic leather, it is characterised in that: include as
Lower step:
A) island superfine fiber processing: first by sea component section and two kinds of raw materials of island component slices
Island superfine fiber is made by spinning production process;Spinning production process includes leading to
Crossing mixed melting to spin or the mode spinning of Compound spinning, nascent strand is special
Cooling forming under the conditions of the blowing of air-conditioning ring;In order to optimize spinning property and the thing of strand
Rationality energy, oils to strand, and utilizes the drawing-off effect of draw roll to improve silk
The trend concordance of the high-polymer molecular within bar, now strand internal structure is basic
Reach requirement;Then by folded silk machine, crimping machine and oil once again, course of conveying
In carry out piddler, after the effect of loosening heat setting machine, the inside of strand
Under the face shaping of structure, physical property and strand just reaches production requirement and stablizes
Come;Last strand again through silk guide frame, traction tensioner and cutting machine to set
Length cuts off strand, and finished silk enters baling press by air delivery pipe and completes packaging;
B) non-weaving cloth produces: utilizes bale opener that island superfine fiber is put into loosening mixer and enters
Row shredding mixes, and add palm oil grease, emulsifying agent, antistatic additive are carried out such as
The optimization of the spinnabilitys such as antistatic, carries out fiber combing subsequently into carding machine, comb
Fiber after reason enters high-precision lapping machine by feeding unit and is laid to net, thick
Degree and the uniform fibre web of density altitude pass through needing machine or spun lacing with constant speed
Machine, under the effect of pricker or liquid drugs injection entangled to each other armful of fibre web internal fiber and, shape
Become structure and the non-weaving cloth of stable physical property;Non-weaving cloth is solid by thermal finalization
Determine thickness and shape, be finally made sizing non-weaving cloth;
C) matte polyurethane coating: matte resin and a certain proportion of solvent of high solids content are mixed
Closing, and coat sizing nonwoven fabric surface, coating medium penetrates into non-knitting of shaping
Make cloth top layer, by oven for drying, solvent volatilization during drying, formed thin
Close hole-layer foam, and solidify semi-finished product after prepared coating;
D) paint rear semi-finished product impregnation to process: first polyurethane resin is diluted to certain viscosity also
Inject impregnating groove;Then will paint rear semi-finished product to be carried out containing padding liquid by impregnating groove;
Finally the base fabric containing slurry is implemented curing process, solidification replaced by solvent or
The modes such as drying or salt solidification make hardening of resin, after making impregnation containing soaking technology
Semi-finished product;
E) island superfine fiber Alkali reduction method dissolves sea component: after being impregnated with, semi-finished product send into decrement
Groove, groove is built with solvent or aqueous slkali, under the effect of solvent or aqueous slkali, right
Sea component dissolves, and after multiple-grooved is dissolved, is carried out with boiling water, it is achieved
The fibrillation of superfine fibre prepares fibrillation semi-finished product;
F) the finished product manufacture of suede superfine fiber synthetic leather: fibrillation semi-finished product carry out drying and shaping,
The most again by mill skin and the combination of dyeing and finishing technology, form colored having and uniformly cause
Close surface suede nap effect, is finally made suede superfine fiber synthetic leather finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610281080.1A CN105887501A (en) | 2016-05-03 | 2016-05-03 | Production method of suede superfine fiber synthetic leather |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610281080.1A CN105887501A (en) | 2016-05-03 | 2016-05-03 | Production method of suede superfine fiber synthetic leather |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105887501A true CN105887501A (en) | 2016-08-24 |
Family
ID=56703034
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610281080.1A Pending CN105887501A (en) | 2016-05-03 | 2016-05-03 | Production method of suede superfine fiber synthetic leather |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105887501A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108708174A (en) * | 2017-04-07 | 2018-10-26 | 安安(中国)有限公司 | A kind of production method with antistatic and electric conductivity superfine fiber chemical leather |
CN108729247A (en) * | 2017-04-17 | 2018-11-02 | 安安(中国)有限公司 | The processing method of superfine fiber chemical leather with high physical property and sanitation performance |
CN108894003A (en) * | 2018-09-04 | 2018-11-27 | 四川大学 | A kind of superfine fibre suede and preparation method thereof generating negative oxygen ion |
CN108951177A (en) * | 2017-05-18 | 2018-12-07 | 安安(中国)有限公司 | A kind of processing method of the suede superfine fiber synthetic leather with higher scratch resistance wear-resisting property |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3410577B2 (en) * | 1995-03-10 | 2003-05-26 | 株式会社クラレ | Suede-like artificial leather and manufacturing method thereof |
CN1590635A (en) * | 2004-06-17 | 2005-03-09 | 东莞市新纶纤维材料科技有限公司 | Processing method of ultrafine fiber needing non-woven fabric simulated genuine leather |
CN1834320A (en) * | 2006-04-17 | 2006-09-20 | 吴江祥盛纺织染整有限公司 | Color insert strip chamois nap fabric and prepn. thereof |
CN101260619A (en) * | 2007-12-20 | 2008-09-10 | 福建省南平金月合成革有限公司 | Method for processing island ultra-thin fiber high-density needling non-woven fabrics emulation leather |
CN103820872A (en) * | 2014-03-03 | 2014-05-28 | 晋江市闽高纺织科技有限公司 | Figured sea-island ultrafine fiber, preparing method and process method of synthetic leather of figured sea-island ultrafine fiber |
CN105113273A (en) * | 2015-09-02 | 2015-12-02 | 安安(中国)有限公司 | Production method of superfine fiber synthetic leather with density gradient structure |
-
2016
- 2016-05-03 CN CN201610281080.1A patent/CN105887501A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3410577B2 (en) * | 1995-03-10 | 2003-05-26 | 株式会社クラレ | Suede-like artificial leather and manufacturing method thereof |
CN1590635A (en) * | 2004-06-17 | 2005-03-09 | 东莞市新纶纤维材料科技有限公司 | Processing method of ultrafine fiber needing non-woven fabric simulated genuine leather |
CN1834320A (en) * | 2006-04-17 | 2006-09-20 | 吴江祥盛纺织染整有限公司 | Color insert strip chamois nap fabric and prepn. thereof |
CN101260619A (en) * | 2007-12-20 | 2008-09-10 | 福建省南平金月合成革有限公司 | Method for processing island ultra-thin fiber high-density needling non-woven fabrics emulation leather |
CN103820872A (en) * | 2014-03-03 | 2014-05-28 | 晋江市闽高纺织科技有限公司 | Figured sea-island ultrafine fiber, preparing method and process method of synthetic leather of figured sea-island ultrafine fiber |
CN105113273A (en) * | 2015-09-02 | 2015-12-02 | 安安(中国)有限公司 | Production method of superfine fiber synthetic leather with density gradient structure |
Non-Patent Citations (1)
Title |
---|
马兴元 等: "《合成革化学与工艺学》", 30 November 2015 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108708174A (en) * | 2017-04-07 | 2018-10-26 | 安安(中国)有限公司 | A kind of production method with antistatic and electric conductivity superfine fiber chemical leather |
CN108729247A (en) * | 2017-04-17 | 2018-11-02 | 安安(中国)有限公司 | The processing method of superfine fiber chemical leather with high physical property and sanitation performance |
CN108951177A (en) * | 2017-05-18 | 2018-12-07 | 安安(中国)有限公司 | A kind of processing method of the suede superfine fiber synthetic leather with higher scratch resistance wear-resisting property |
CN108894003A (en) * | 2018-09-04 | 2018-11-27 | 四川大学 | A kind of superfine fibre suede and preparation method thereof generating negative oxygen ion |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105113273B (en) | A kind of production method of the superfine fiber chemical leather with density gradient structure | |
CN105401334B (en) | A kind of preparation method of needle punched non-woven fabrics | |
CN102071495B (en) | Figured sea-island super-fine fiber, and preparation method thereof and synthetic leather preparing process method using same | |
CN105970664B (en) | A kind of processing method of the superfine fiber chemical leather with higher sanitation performance quality | |
CN102619095B (en) | Manufacturing method of environmentally-friendly flame-retardant bunched sea-island chamois leather | |
CN102168345B (en) | Method for preparing composite superfine fiber artificial leather base fabric | |
CN105887501A (en) | Production method of suede superfine fiber synthetic leather | |
CN106521956B (en) | A kind of preparation method of tangerine valve type ultrafine fiber simulation leather base fabric | |
CN102776602A (en) | Figured island superfine fiber, figured island superfine fiber synthetic leather base cloth, suede leather for clothes, smooth synthetic leather for clothes and production method of fiber, base cloth, suede leather and smooth synthetic leather | |
CN102774098B (en) | Thin scrimp Super-fine Synthetic Leather of a kind of artificial leather and preparation method thereof | |
CN103820872A (en) | Figured sea-island ultrafine fiber, preparing method and process method of synthetic leather of figured sea-island ultrafine fiber | |
CN104631136B (en) | Production method of superfine fiber high-imitation natural top-layer leather | |
CN108035068A (en) | A kind of preparation method of non-woven fabrics | |
CN107385948B (en) | The method for going back raw hide is prepared based on collagen fabric fabric combination water jet process | |
CN107326536A (en) | Special-shaped polyester fiber and the composite spunlaced wet tissue cloth of wood pulp cellulose and preparation method thereof | |
CN106222884A (en) | A kind of fire retardant nonwoven fabric material and preparation method thereof | |
CN107620158A (en) | Spunlace non-woven cloth mask substrate of 3D D structures and preparation method thereof | |
CN102168321A (en) | Sea-island type composite fiber manufacture method | |
CN101385921A (en) | No-weaving filter composite material of feather fiber and preparation method thereof | |
CN104452326A (en) | Preparation method of moisture-absorbing ventilating superfine fiber polyurethane synthetic leather | |
CN101798714B (en) | Bi-component composite fiber and preparation method thereof | |
CN102587037A (en) | Imitation inner leather non-woven fabric and preparation method thereof | |
CN108729247A (en) | The processing method of superfine fiber chemical leather with high physical property and sanitation performance | |
CN108691095A (en) | A kind of production method of the compound microfiber synthetic leather of corium fabric | |
CN102758263A (en) | Fabricating method of tangerine section shaped composite fiber |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160824 |