CN105887485A - Antimicrobial moldproof finishing agent for rabbit-hair fabric - Google Patents

Antimicrobial moldproof finishing agent for rabbit-hair fabric Download PDF

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Publication number
CN105887485A
CN105887485A CN201610392882.XA CN201610392882A CN105887485A CN 105887485 A CN105887485 A CN 105887485A CN 201610392882 A CN201610392882 A CN 201610392882A CN 105887485 A CN105887485 A CN 105887485A
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Prior art keywords
parts
finishing agent
rabbit
rabbit hair
hair fabric
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CN201610392882.XA
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Chinese (zh)
Inventor
董根琴
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HUZHOU HONGXIN SILK FACTORY
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HUZHOU HONGXIN SILK FACTORY
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Priority to CN201610392882.XA priority Critical patent/CN105887485A/en
Publication of CN105887485A publication Critical patent/CN105887485A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses an antimicrobial moldproof finishing agent for rabbit-hair fabric. The finishing agent is prepared from, by weight, 5-6 parts of sodium polystyrenesulfonate, 3-6 parts of hydroxypropyl xanthan gum, 10-14 parts of emulsifier, 12-16 parts of natural saponins, 5-10 parts of sophorolipid, 3-6 parts of epoxy chloropropane, 5-8 parts of ethyltriethoxysilane, 15-20 parts of 2-methyl-4-isothiazoline-3-ketone, 11-14 parts of dibutyltin dilaurate, 16-22 parts of coupling agent, 1-8 parts of glycerin, 4-8 parts of crosslinking monomers, 8-10 parts of alkylphenol polyoxyethylene and 40-50 parts of deionized water. By means of the antimicrobial moldproof finishing agent for the rabbit-hair fabric, the functions of mold prevention, anti-microbial, deodorization and the like can be given to the rabbit-hair fabric, and the finishing agent is free of irritation to skin, free of allergic reaction and free of toxicity, teratogenicity and potential carcinogenicity and meets the environment-friendly requirement.

Description

A kind of rabbit hair fabric antibacterial and mouldproof finishing agent
Technical field
The present invention relates to a kind of rabbit hair fabric antibacterial and mouldproof finishing agent.
Background technology
The rabbit hair (rabbit hair) family's rabbit hair and the general designation of hare hair.The weaving rabbit hair originates from peace Brother draws rabbit and rabbit, is wherein best with the quality of Angora rabbit hair, the most soft.Rabbit hair feel Soft, light weight is fluffy, novel in style, warmth retention property and good hygroscopicity, is the wool spinning of a kind of preciousness Knit raw material.Rabbit hair yarn fabric quality is slim and graceful, sliding glutinous fluffy, soft, and rabbit hair color Pure white, dyeing, color matching there are is the biggest adaptability.Further, since inflation in rabbit fur fibre Medullary layer is flourishing, and the rabbit hair not only has high hygroscopicity, also has excellent thermal property.Rabbit The warming rate of hair is 68.5%, and the warming rate of Pilus Caprae seu Ovis is 63.5%, and the hygroscopicity of the rabbit hair is also Higher than Pilus Caprae seu Ovis.Therefore to have feel soft, sliding glutinous for rabbit hair fabric, and outward appearance is plentiful, fluffy and wears Cosy feature.The rabbit hair suitably spins stocking yarn, for sweater, scarf, medicated cap With interior clothing trousers etc..Rabbit hair sweater fine hair towers, and does not have style, can keep out the cold, and is again beautiful The ornament seen.In wool spinning product, add a certain proportion of rabbit hair, value-added content of product can be made Significantly improve, at high proportion or even pure rabbit hair yarn fabric has more luxurious rich and honour sense.The most right The people of sweater allergy, will not be to rabbit hair allergy, and the sweater that on market, the rabbit hair makees, is not very Expensive, price is quite reasonable, and the demand of rabbit hair product is progressively expanded, both at home and abroad by society in recent years The rabbit hair product occurred on market is of a great variety, including knitting product, woolen fabrics and spinning product Product etc..But the row such as human sweat glands and the sweat of smegma, metabolism product and sebum Let out thing, thus form the nutrient source of microorganism, contained in plus the natural fiber of rabbit hair fabric Cellulose and protein, if easily causing the growing with numerous of microorganism when cleaning is clean Grow.Not only stimulate human body skin, cause discomfort, even result in pathological changes, but also can make Fabric produces and goes mouldy, and is detrimental to health.For that purpose it is necessary to use antibacterial and mouldproof finishing agent to carry out Arrange.But sealing compound Performance comparision in the market is single, and anti-mold effect is the best.The most such as What overcomes the deficiencies in the prior art to be the problem that current textile technology field needs solution badly.
Summary of the invention
To achieve these goals, the invention provides a kind of rabbit hair fabric antibacterial and mouldproof to arrange Agent.
It is an object of the invention to be achieved through the following technical solutions:
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion: Kayexalate 5-6 part, hydroxypropyl xanthan gum 3-6 part, emulsifying agent 10-14 part, sky So Saponin 12-16 part, sophorolipid 5-10 part, epoxychloropropane 3-6 part, ethyl three ethoxy Base silane 5-8 part, MIT 15-20 part, di lauric dibutyl Stannum 11-14 part, coupling agent 16-22 part, glycerol 1-8 part, cross-linking monomer 4-8 part, alkyl Phenol polyethenoxy ether 8-10 part, deionized water 40-50 part.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602 Mixture.
Beneficial effect: the rabbit hair fabric antibacterial and mouldproof finishing agent of the present invention gives rabbit hair fabric to be prevented The functions such as mould, antibacterial, deodorant, non-stimulated to skin, without anaphylaxis, nontoxic, without teratogenesis Property, without potential carcinogenecity, meet environmental requirement.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, Although the present invention being described in detail with reference to previous embodiment, for the technology of this area For personnel, the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention Within the scope of.
Embodiment 1
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion: Kayexalate 5 parts, hydroxypropyl xanthan gum 3 parts, emulsifying agent 10 parts, natural Saponin 12 parts, sophorolipid 5 parts, epoxychloropropane 3 parts, ethyl triethoxysilane 5 parts, 2- Methyl-4-isothiazoline-3-ketone 15 parts, dibutyl tin laurate 11 parts, coupling agent 16 Part, glycerol 1 part, cross-linking monomer 4 parts, alkylphenol polyoxyethylene 8 parts, deionized water 40 parts.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602 Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes 2-3 time, dewatered drying.
Embodiment 2
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion: Kayexalate 6 parts, hydroxypropyl xanthan gum 6 parts, emulsifying agent 14 parts, natural Saponin 16 parts, sophorolipid 10 parts, epoxychloropropane 6 parts, ethyl triethoxysilane 8 parts, 2- Methyl-4-isothiazoline-3-ketone 20 parts, dibutyl tin laurate 14 parts, coupling agent 22 Part, glycerol 8 parts, cross-linking monomer 8 parts, alkylphenol polyoxyethylene 10 parts, deionized water 50 parts.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602 Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes 2-3 time, dewatered drying.
Embodiment 3
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion: Kayexalate 5.5 parts, hydroxypropyl xanthan gum 5 parts, emulsifying agent 12 parts, natural soap Glycoside 14 parts, sophorolipid 7 parts, epoxychloropropane 4 parts, ethyl triethoxysilane 6 parts, MIT 17 parts, dibutyl tin laurate 13 parts, coupling agent 18 parts, glycerol 5 parts, cross-linking monomer 6 parts, alkylphenol polyoxyethylene 9 parts, deionization 45 parts of water.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602 Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes 2-3 time, dewatered drying.

Claims (4)

1. a rabbit hair fabric antibacterial and mouldproof finishing agent, it is characterised in that by following weight portion Raw material composition: kayexalate 5-6 part, hydroxypropyl xanthan gum 3-6 part, emulsifying agent 10-14 part, natural Saponin 12-16 part, sophorolipid 5-10 part, epoxychloropropane 3-6 part, Ethyl triethoxysilane 5-8 part, MIT 15-20 part, February Dilaurylate 11-14 part, coupling agent 16-22 part, glycerol 1-8 part, cross-linking monomer 4-8 part, alkylphenol polyoxyethylene 8-10 part, deionized water 40-50 part.
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special Levy and be: described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, abienol polyoxy second One in alkene ether monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special Levy and be: described cross-linking monomer be 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide- One or more in Azimethylene..
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special Levy and be: described coupling agent be the one in silane coupler KH560, KH570, DL602 or Multiple mixture.
CN201610392882.XA 2016-06-03 2016-06-03 Antimicrobial moldproof finishing agent for rabbit-hair fabric Withdrawn CN105887485A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904940A (en) * 2017-11-30 2018-04-13 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method of fungus-proof antisepsis fabric
CN107904933A (en) * 2017-11-30 2018-04-13 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method of durable water repellent fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101158114A (en) * 2007-11-22 2008-04-09 大连工业大学 Chitosan durable antibiotic tidying method for Cashmere (wool) fabric
CN101509190A (en) * 2009-03-06 2009-08-19 东华大学 Antimicrobial milled finishing agent, preparation method and uses thereof
CN104894854A (en) * 2015-05-30 2015-09-09 青岛启源振东电气有限公司 Multifunctional textile finishing agent
CN104983107A (en) * 2015-06-24 2015-10-21 张家港市华阳针纺织品有限公司 Warm-keeping antibacterial garment fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101158114A (en) * 2007-11-22 2008-04-09 大连工业大学 Chitosan durable antibiotic tidying method for Cashmere (wool) fabric
CN101509190A (en) * 2009-03-06 2009-08-19 东华大学 Antimicrobial milled finishing agent, preparation method and uses thereof
CN104894854A (en) * 2015-05-30 2015-09-09 青岛启源振东电气有限公司 Multifunctional textile finishing agent
CN104983107A (en) * 2015-06-24 2015-10-21 张家港市华阳针纺织品有限公司 Warm-keeping antibacterial garment fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107904940A (en) * 2017-11-30 2018-04-13 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method of fungus-proof antisepsis fabric
CN107904933A (en) * 2017-11-30 2018-04-13 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method of durable water repellent fabric

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