CN105887485A - Antimicrobial moldproof finishing agent for rabbit-hair fabric - Google Patents
Antimicrobial moldproof finishing agent for rabbit-hair fabric Download PDFInfo
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- CN105887485A CN105887485A CN201610392882.XA CN201610392882A CN105887485A CN 105887485 A CN105887485 A CN 105887485A CN 201610392882 A CN201610392882 A CN 201610392882A CN 105887485 A CN105887485 A CN 105887485A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an antimicrobial moldproof finishing agent for rabbit-hair fabric. The finishing agent is prepared from, by weight, 5-6 parts of sodium polystyrenesulfonate, 3-6 parts of hydroxypropyl xanthan gum, 10-14 parts of emulsifier, 12-16 parts of natural saponins, 5-10 parts of sophorolipid, 3-6 parts of epoxy chloropropane, 5-8 parts of ethyltriethoxysilane, 15-20 parts of 2-methyl-4-isothiazoline-3-ketone, 11-14 parts of dibutyltin dilaurate, 16-22 parts of coupling agent, 1-8 parts of glycerin, 4-8 parts of crosslinking monomers, 8-10 parts of alkylphenol polyoxyethylene and 40-50 parts of deionized water. By means of the antimicrobial moldproof finishing agent for the rabbit-hair fabric, the functions of mold prevention, anti-microbial, deodorization and the like can be given to the rabbit-hair fabric, and the finishing agent is free of irritation to skin, free of allergic reaction and free of toxicity, teratogenicity and potential carcinogenicity and meets the environment-friendly requirement.
Description
Technical field
The present invention relates to a kind of rabbit hair fabric antibacterial and mouldproof finishing agent.
Background technology
The rabbit hair (rabbit hair) family's rabbit hair and the general designation of hare hair.The weaving rabbit hair originates from peace
Brother draws rabbit and rabbit, is wherein best with the quality of Angora rabbit hair, the most soft.Rabbit hair feel
Soft, light weight is fluffy, novel in style, warmth retention property and good hygroscopicity, is the wool spinning of a kind of preciousness
Knit raw material.Rabbit hair yarn fabric quality is slim and graceful, sliding glutinous fluffy, soft, and rabbit hair color
Pure white, dyeing, color matching there are is the biggest adaptability.Further, since inflation in rabbit fur fibre
Medullary layer is flourishing, and the rabbit hair not only has high hygroscopicity, also has excellent thermal property.Rabbit
The warming rate of hair is 68.5%, and the warming rate of Pilus Caprae seu Ovis is 63.5%, and the hygroscopicity of the rabbit hair is also
Higher than Pilus Caprae seu Ovis.Therefore to have feel soft, sliding glutinous for rabbit hair fabric, and outward appearance is plentiful, fluffy and wears
Cosy feature.The rabbit hair suitably spins stocking yarn, for sweater, scarf, medicated cap
With interior clothing trousers etc..Rabbit hair sweater fine hair towers, and does not have style, can keep out the cold, and is again beautiful
The ornament seen.In wool spinning product, add a certain proportion of rabbit hair, value-added content of product can be made
Significantly improve, at high proportion or even pure rabbit hair yarn fabric has more luxurious rich and honour sense.The most right
The people of sweater allergy, will not be to rabbit hair allergy, and the sweater that on market, the rabbit hair makees, is not very
Expensive, price is quite reasonable, and the demand of rabbit hair product is progressively expanded, both at home and abroad by society in recent years
The rabbit hair product occurred on market is of a great variety, including knitting product, woolen fabrics and spinning product
Product etc..But the row such as human sweat glands and the sweat of smegma, metabolism product and sebum
Let out thing, thus form the nutrient source of microorganism, contained in plus the natural fiber of rabbit hair fabric
Cellulose and protein, if easily causing the growing with numerous of microorganism when cleaning is clean
Grow.Not only stimulate human body skin, cause discomfort, even result in pathological changes, but also can make
Fabric produces and goes mouldy, and is detrimental to health.For that purpose it is necessary to use antibacterial and mouldproof finishing agent to carry out
Arrange.But sealing compound Performance comparision in the market is single, and anti-mold effect is the best.The most such as
What overcomes the deficiencies in the prior art to be the problem that current textile technology field needs solution badly.
Summary of the invention
To achieve these goals, the invention provides a kind of rabbit hair fabric antibacterial and mouldproof to arrange
Agent.
It is an object of the invention to be achieved through the following technical solutions:
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion:
Kayexalate 5-6 part, hydroxypropyl xanthan gum 3-6 part, emulsifying agent 10-14 part, sky
So Saponin 12-16 part, sophorolipid 5-10 part, epoxychloropropane 3-6 part, ethyl three ethoxy
Base silane 5-8 part, MIT 15-20 part, di lauric dibutyl
Stannum 11-14 part, coupling agent 16-22 part, glycerol 1-8 part, cross-linking monomer 4-8 part, alkyl
Phenol polyethenoxy ether 8-10 part, deionized water 40-50 part.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry
One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first
One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602
Mixture.
Beneficial effect: the rabbit hair fabric antibacterial and mouldproof finishing agent of the present invention gives rabbit hair fabric to be prevented
The functions such as mould, antibacterial, deodorant, non-stimulated to skin, without anaphylaxis, nontoxic, without teratogenesis
Property, without potential carcinogenecity, meet environmental requirement.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention,
Although the present invention being described in detail with reference to previous embodiment, for the technology of this area
For personnel, the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it
In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention
Within the scope of.
Embodiment 1
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion:
Kayexalate 5 parts, hydroxypropyl xanthan gum 3 parts, emulsifying agent 10 parts, natural Saponin
12 parts, sophorolipid 5 parts, epoxychloropropane 3 parts, ethyl triethoxysilane 5 parts, 2-
Methyl-4-isothiazoline-3-ketone 15 parts, dibutyl tin laurate 11 parts, coupling agent 16
Part, glycerol 1 part, cross-linking monomer 4 parts, alkylphenol polyoxyethylene 8 parts, deionized water
40 parts.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry
One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first
One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602
Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping
Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes
2-3 time, dewatered drying.
Embodiment 2
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion:
Kayexalate 6 parts, hydroxypropyl xanthan gum 6 parts, emulsifying agent 14 parts, natural Saponin
16 parts, sophorolipid 10 parts, epoxychloropropane 6 parts, ethyl triethoxysilane 8 parts, 2-
Methyl-4-isothiazoline-3-ketone 20 parts, dibutyl tin laurate 14 parts, coupling agent 22
Part, glycerol 8 parts, cross-linking monomer 8 parts, alkylphenol polyoxyethylene 10 parts, deionized water
50 parts.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry
One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first
One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602
Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping
Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes
2-3 time, dewatered drying.
Embodiment 3
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent, it is made up of the raw material of following weight portion:
Kayexalate 5.5 parts, hydroxypropyl xanthan gum 5 parts, emulsifying agent 12 parts, natural soap
Glycoside 14 parts, sophorolipid 7 parts, epoxychloropropane 4 parts, ethyl triethoxysilane 6 parts,
MIT 17 parts, dibutyl tin laurate 13 parts, coupling agent
18 parts, glycerol 5 parts, cross-linking monomer 6 parts, alkylphenol polyoxyethylene 9 parts, deionization
45 parts of water.
Described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, rosin industry
One in monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
Described cross-linking monomer is 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-diazonium first
One or more in alkane.
Described coupling agent is one or more in silane coupler KH560, KH570, DL602
Mixture.
Its using method is: rabbit hair fabric antibacterial and mouldproof finishing agent dilute is configured to dipping
Liquid, then puts into rabbit hair fabric in impregnation liquid and pads, and pick-up 70-80% finally washes
2-3 time, dewatered drying.
Claims (4)
1. a rabbit hair fabric antibacterial and mouldproof finishing agent, it is characterised in that by following weight portion
Raw material composition: kayexalate 5-6 part, hydroxypropyl xanthan gum 3-6 part, emulsifying agent
10-14 part, natural Saponin 12-16 part, sophorolipid 5-10 part, epoxychloropropane 3-6 part,
Ethyl triethoxysilane 5-8 part, MIT 15-20 part, February
Dilaurylate 11-14 part, coupling agent 16-22 part, glycerol 1-8 part, cross-linking monomer
4-8 part, alkylphenol polyoxyethylene 8-10 part, deionized water 40-50 part.
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special
Levy and be: described emulsifying agent is polyoxyethylene lauryl ether monomester succinate, abienol polyoxy second
One in alkene ether monomester succinate, sorbitol polyoxyethylene ether monomester succinate.
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special
Levy and be: described cross-linking monomer be 2-Hydroxy ethyl acrylate, N-hydroxy-succinamide-
One or more in Azimethylene..
A kind of rabbit hair fabric antibacterial and mouldproof finishing agent the most according to claim 1, it is special
Levy and be: described coupling agent be the one in silane coupler KH560, KH570, DL602 or
Multiple mixture.
Priority Applications (1)
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CN201610392882.XA CN105887485A (en) | 2016-06-03 | 2016-06-03 | Antimicrobial moldproof finishing agent for rabbit-hair fabric |
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CN201610392882.XA CN105887485A (en) | 2016-06-03 | 2016-06-03 | Antimicrobial moldproof finishing agent for rabbit-hair fabric |
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CN201610392882.XA Withdrawn CN105887485A (en) | 2016-06-03 | 2016-06-03 | Antimicrobial moldproof finishing agent for rabbit-hair fabric |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107904940A (en) * | 2017-11-30 | 2018-04-13 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of fungus-proof antisepsis fabric |
CN107904933A (en) * | 2017-11-30 | 2018-04-13 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of durable water repellent fabric |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101158114A (en) * | 2007-11-22 | 2008-04-09 | 大连工业大学 | Chitosan durable antibiotic tidying method for Cashmere (wool) fabric |
CN101509190A (en) * | 2009-03-06 | 2009-08-19 | 东华大学 | Antimicrobial milled finishing agent, preparation method and uses thereof |
CN104894854A (en) * | 2015-05-30 | 2015-09-09 | 青岛启源振东电气有限公司 | Multifunctional textile finishing agent |
CN104983107A (en) * | 2015-06-24 | 2015-10-21 | 张家港市华阳针纺织品有限公司 | Warm-keeping antibacterial garment fabric |
-
2016
- 2016-06-03 CN CN201610392882.XA patent/CN105887485A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101158114A (en) * | 2007-11-22 | 2008-04-09 | 大连工业大学 | Chitosan durable antibiotic tidying method for Cashmere (wool) fabric |
CN101509190A (en) * | 2009-03-06 | 2009-08-19 | 东华大学 | Antimicrobial milled finishing agent, preparation method and uses thereof |
CN104894854A (en) * | 2015-05-30 | 2015-09-09 | 青岛启源振东电气有限公司 | Multifunctional textile finishing agent |
CN104983107A (en) * | 2015-06-24 | 2015-10-21 | 张家港市华阳针纺织品有限公司 | Warm-keeping antibacterial garment fabric |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107904940A (en) * | 2017-11-30 | 2018-04-13 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of fungus-proof antisepsis fabric |
CN107904933A (en) * | 2017-11-30 | 2018-04-13 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of durable water repellent fabric |
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