CN105886144A - Low-irritating bactericidal cleaning agent and preparation method thereof - Google Patents

Low-irritating bactericidal cleaning agent and preparation method thereof Download PDF

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Publication number
CN105886144A
CN105886144A CN201610308583.3A CN201610308583A CN105886144A CN 105886144 A CN105886144 A CN 105886144A CN 201610308583 A CN201610308583 A CN 201610308583A CN 105886144 A CN105886144 A CN 105886144A
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parts
bactericidal
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ethoxy
cleaning agent
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陈健
张建光
杨文乾
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Suzhou Futong New Material and High Tech Co Ltd
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Suzhou Futong New Material and High Tech Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/26—Sulfonic acids or sulfuric acid esters; Salts thereof derived from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

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  • Oil, Petroleum & Natural Gas (AREA)
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  • Health & Medical Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
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Abstract

The invention discloses a low-irritating bactericidal cleaning agent, which is prepared from the following raw materials in parts by weight: 30-35 parts of 1-ethoxyl-2-oleic acid base-imidazoline sulphate salt, 30-35 parts of fatty acid methyl ester ethoxylate, 25-30 parts of sodium dodecyl benzene sulfonate, 25-30 parts of lauramide propyl dimethylamine ethyl lactone, 20-25 parts of polyvinylpyrrolidone, 20-25 parts of thermosetting phenolic resin, 15-20 parts of benzalkonium bromide, 10-15 parts of polytetrahydrofuran ether, 5-10 parts of alkyl polyoxyethylene methyl ammonium salt, 2-5 parts of diammonium hydrogen phosphate, 25-30 parts of isopropyl alcohol, 2-5 parts of carbonate and 75-90 parts of water. Furthermore, the invention discloses a preparation method of the bactericidal cleaning agent. The bactericidal cleaning agent has excellent cleaning ability and stable bactericidal ability, and is low in irritation, thus being widely used for sterilizing and cleaning floor, kitchen ware, electric appliances and the like.

Description

A kind of Bactericidal cleaner of low irritant and preparation method thereof
Technical field
The present invention relates to cleaning agent field, particularly to a kind of low irritant Bactericidal cleaner and Its preparation method.
Background technology
Along with modern society's growth in the living standard, people for floor in living environment, kitchen tools, The requirement for cleaning of electrical equipment etc. progressively increases.Accordingly, market is produced for above-mentioned article Cleaning agent is also arisen at the historic moment.But most of cleaning agent are only by sodium hypochlorite, surfactant Simply allocate Deng composition and form, while possessing cleaning, bactericidal effect, to human body skin, The zest at the positions such as eyes is relatively strong, is unfavorable for life-time service.Further, the chemistry in cleaning agent Composition equally exists bigger harm for environment, easily causes the pollution of air, water body.Therefore, It is badly in need of one on market and is provided simultaneously with human body low on the basis of possessing excellent sterilization, cleaning effect Stimulation, novel cleaning free from environmental pollution.
Summary of the invention
For solve above-mentioned technical problem, the present invention provide a kind of low irritant Bactericidal cleaner and Its preparation method.
The purpose of the present invention can be achieved through the following technical solutions:
The Bactericidal cleaner of a kind of low irritant, comprises the raw material of following weight portion: 1-ethoxy -2-oleic acid base-imidazoline sulfate salt 30-35 part, fatty acid methyl ester ethoxylate 30-35 Part, dodecylbenzene sodium sulfonate 25-30 part, dodecanamide propyl decil lactone 25-30 Part, polyvinylpyrrolidone 20-25 part, thermosetting phenolic resin 20-25 part, benzalkonium bromide 15-20 part, PTMG 10-15 part, alkyl oxygen ethylene methyl ammonium salt 5-10 part, Diammonium phosphate 2-5 part, isopropanol 25-30 part, carbonate 2-5 part, water 75-90 part.
Preferably, described carbonate is sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate In one or more.
Preferably, in raw material possibly together with diethylene glycol monobutyl ether, 3-hydroxyl piperidine hydrochloric acid salt, One in dicyclohexyl carbodiimide, shared weight portion is 10-15 part.
The preparation method of the Bactericidal cleaner of described low irritant, comprises the following steps:
(1) each raw material is weighed according to above-mentioned formula ratio；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 85-90 DEG C, then by benzalkonium bromide, poly-tetrahydrochysene furan Mutter ether, alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, with the speed of 260 revs/min Degree stirs, and obtains intermediate blend；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 8.5-9.5, add surplus stock, stir with the speed of 200 revs/min Uniformly, it is finished product.
Preferably, in described step (4), regulate intermediate blend pH to 9.0.
Compared with prior art, it has the beneficial effect that the present invention
(1) Bactericidal cleaner of the present invention is with 1-ethoxy-2-oleic acid base-imidazoline sulfate Salt, fatty acid methyl ester ethoxylate, dodecylbenzene sodium sulfonate, dodecanamide propyl diformazan Amine second lactone, polyvinylpyrrolidone, thermosetting phenolic resin, benzalkonium bromide, poly-tetrahydrochysene furan Mutter ether, alkyl oxygen ethylene methyl ammonium salt, diammonium phosphate, isopropanol is primary raw material, passes through Stir the preparation means such as mixing, heat treated, regulation acid-base value stage by stage so that be prepared from Bactericidal cleaner the zest of human body is substantially reduced, health environment-friendly.
(2) Bactericidal cleaner of the present invention, its raw material economics is easy to get, and preparation technology is simple and clear, Manufacturing process industrial discharge pollutant are few, are suitable to large-scale industrial production.
Detailed description of the invention
Below in conjunction with specific embodiment, the technical scheme of invention is described in detail.
Embodiment 1
(1) 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 30 parts, fatty acid are weighed FMEE 30 parts, dodecylbenzene sodium sulfonate 25 parts, dodecanamide propyl diformazan Amine second lactone 25 parts, polyvinylpyrrolidone 20 parts, thermosetting phenolic resin 20 parts, benzene Prick bromine ammonium 15 parts, PTMG 10 parts, alkyl oxygen ethylene methyl ammonium salt 5 parts, phosphoric acid Hydrogen diammonium 2 parts, isopropanol 25 parts, sodium carbonate 2 parts, 75 parts of water, diethylene glycol mono butyl base 10 parts of ether；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 85 DEG C, then by benzalkonium bromide, PTMG, Alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, stirs with the speed of 260 revs/min Uniformly, intermediate blend is obtained；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 8.5, add surplus stock, stir with the speed of 200 revs/min, It is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
Embodiment 2
(1) 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 33 parts, fatty acid are weighed FMEE 33 parts, dodecylbenzene sodium sulfonate 28 parts, dodecanamide propyl diformazan Amine second lactone 28 parts, polyvinylpyrrolidone 23 parts, thermosetting phenolic resin 23 parts, benzene Prick bromine ammonium 18 parts, PTMG 13 parts, alkyl oxygen ethylene methyl ammonium salt 8 parts, phosphoric acid Hydrogen diammonium 3 parts, isopropanol 28 parts, potassium carbonate 3 parts, 85 parts of water；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 88 DEG C, then by benzalkonium bromide, PTMG, Alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, stirs with the speed of 260 revs/min Uniformly, intermediate blend is obtained；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 9.0, add surplus stock, stir with the speed of 200 revs/min, It is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
Embodiment 3
(1) 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 35 parts, fatty acid are weighed FMEE 35 parts, dodecylbenzene sodium sulfonate 30 parts, dodecanamide propyl diformazan Amine second lactone 30 parts, polyvinylpyrrolidone 25 parts, thermosetting phenolic resin 25 parts, benzene Prick bromine ammonium 20 parts, PTMG 15 parts, alkyl oxygen ethylene methyl ammonium salt 10 parts, phosphorus Acid hydrogen diammonium 5 parts, isopropanol 30 parts, sodium bicarbonate 5 parts, 90 parts of water, 3-hydroxyl piperazine Thiamine hydrochloride 15 parts；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 90 DEG C, then by benzalkonium bromide, PTMG, Alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, stirs with the speed of 260 revs/min Uniformly, intermediate blend is obtained；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 9.5, add surplus stock, stir with the speed of 200 revs/min, It is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
Embodiment 4
(1) 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 30 parts, fatty acid are weighed FMEE 35 parts, dodecylbenzene sodium sulfonate 25 parts, dodecanamide propyl diformazan Amine second lactone 30 parts, polyvinylpyrrolidone 20 parts, thermosetting phenolic resin 25 parts, benzene Prick bromine ammonium 15 parts, PTMG 15 parts, alkyl oxygen ethylene methyl ammonium salt 5 parts, phosphoric acid Hydrogen diammonium 5 parts, isopropanol 25 parts, potassium bicarbonate 5 parts, 75 parts of water；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 85 DEG C, then by benzalkonium bromide, PTMG, Alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, stirs with the speed of 260 revs/min Uniformly, intermediate blend is obtained；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 9.5, add surplus stock, stir with the speed of 200 revs/min, It is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
Comparative example 1
(1) fatty acid methyl ester ethoxylate 30 parts, dodecylbenzene sodium sulfonate 25 are weighed Part, dodecanamide propyl decil lactone 25 parts, polyvinylpyrrolidone 20 parts, thermosetting Property 20 parts of phenolic resin, benzalkonium bromide 15 parts, PTMG 10 parts, phosphoric acid hydrogen two Ammonium 2 parts, isopropanol 25 parts, sodium carbonate 2 parts, 75 parts of water, diethylene glycol monobutyl ether 10 parts；
(2) by fatty acid methyl ester ethoxylate, dodecylbenzene sodium sulfonate, lauramide Diemethylamine second lactone, polyvinylpyrrolidone, thermosetting phenolic resin, water add reaction Still stirs with the speed of 320 revs/min, obtains initial mixture；
(3) after being tentatively mixed and heated to 85-90 DEG C, then by benzalkonium bromide, poly-tetrahydrochysene furan Ether of muttering joins in initial mixture, stirs with the speed of 260 revs/min, obtains middle mixed Compound；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 8.5-9.5, add surplus stock, stir with the speed of 200 revs/min Uniformly, it is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
Comparative example 2
(1) 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 35 parts, dodecane are weighed Base benzene sulfonic acid sodium salt 30 parts, dodecanamide propyl decil lactone 30 parts, polyvinylpyrrolidine Ketone 25 parts, thermosetting phenolic resin 25 parts, benzalkonium bromide 20 parts, alkyl oxygen ethylene methyl Ammonium salt 10 parts, diammonium phosphate 5 parts, isopropanol 30 parts, sodium bicarbonate 5 parts, water 90 Part, 3-hydroxyl piperidine hydrochloric acid salt 15 parts；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt dodecylbenzene sodium sulfonate, Dodecanamide propyl decil lactone, polyvinylpyrrolidone, thermosetting phenolic resin, water Add in reactor and stir with the speed of 320 revs/min, obtain initial mixture；
(3) after being tentatively mixed and heated to 85-90 DEG C, then by benzalkonium bromide alkyl oxygen ethylene Methyl ammonium salt joins in initial mixture, stirs with the speed of 260 revs/min, in obtaining Between mixture；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 8.5-9.5, add surplus stock, stir with the speed of 200 revs/min Uniformly, it is finished product.
The zest test of the Bactericidal cleaner prepared and environment affected evaluating result such as table 1 Shown in.
The Bactericidal cleaner of embodiment 1-4 and comparative example 1-2 is carried out zest test and to ring Border affect evaluating result.
Table 1
The Bactericidal cleaner that the present invention obtains is with 1-ethoxy-2-oleic acid base-imidazoline sulfate Salt, fatty acid methyl ester ethoxylate, dodecylbenzene sodium sulfonate, dodecanamide propyl diformazan Amine second lactone, polyvinylpyrrolidone, thermosetting phenolic resin, benzalkonium bromide, poly-tetrahydrochysene furan Mutter ether, alkyl oxygen ethylene methyl ammonium salt, diammonium phosphate, isopropanol is primary raw material, passes through Stir the preparation means such as mixing, heat treated, regulation acid-base value stage by stage so that be prepared from Bactericidal cleaner the zest of human body is substantially reduced, health environment-friendly.Further, this sterilization is clear The raw material economics of clean dose is easy to get, and preparation technology is simple and clear, and manufacturing process industrial discharge pollutant are few, Be suitable to large-scale industrial production.
The foregoing is only embodiments of the invention, not thereby limit the patent model of the present invention Enclose, every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion, or Directly or indirectly it is used in other relevant technical fields, is the most in like manner included in the patent of the present invention In protection domain.

Claims (5)

1. the Bactericidal cleaner of a low irritant, it is characterised in that comprise following weight portion Raw material: 1-ethoxy-2-oleic acid base-imidazoline sulfate salt 30-35 part, fatty acid methyl ester second Epoxide compound 30-35 part, dodecylbenzene sodium sulfonate 25-30 part, dodecanamide propyl diformazan Amine second lactone 25-30 part, polyvinylpyrrolidone 20-25 part, thermosetting phenolic resin 20-25 Part, benzalkonium bromide 15-20 part, PTMG 10-15 part, alkyl oxygen ethylene methyl ammonium Salt 5-10 part, diammonium phosphate 2-5 part, isopropanol 25-30 part, carbonate 2-5 part, Water 75-90 part.
The Bactericidal cleaner of low irritant the most according to claim 1, it is characterised in that: Described carbonate is the one in sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or several Kind.
The Bactericidal cleaner of low irritant the most according to claim 1 and 2, its feature It is: possibly together with diethylene glycol monobutyl ether, 3-hydroxyl piperidine hydrochloric acid salt, bicyclo-in raw material One in hexyl carbodiimides, shared weight portion is 10-15 part.
4. according to the preparation of the Bactericidal cleaner of the arbitrary described low irritant of claims 1 to 3 Method, it is characterised in that comprise the following steps:
(1) each raw material is weighed according to above-mentioned formula ratio；
(2) by 1-ethoxy-2-oleic acid base-imidazoline sulfate salt, fatty acid methyl ester ethoxy Base compound, dodecylbenzene sodium sulfonate, dodecanamide propyl decil lactone, polyethylene pyrrole Pyrrolidone, thermosetting phenolic resin, water add the speed stirring in reactor with 320 revs/min Uniformly, initial mixture is obtained；
(3) after being tentatively mixed and heated to 85-90 DEG C, then by benzalkonium bromide, poly-tetrahydrochysene furan Mutter ether, alkyl oxygen ethylene methyl ammonium salt joins in initial mixture, with the speed of 260 revs/min Degree stirs, and obtains intermediate blend；
(4) adding concentration in intermediate blend is the sodium hydroxide solution of 10%, in regulation Between mixture pH to 8.5-9.5, add surplus stock, stir with the speed of 200 revs/min Uniformly, it is finished product.
The preparation method of the Bactericidal cleaner of low irritant the most according to claim 4, its It is characterised by, in described step (4), regulates intermediate blend pH to 9.0.
CN201610308583.3A 2016-05-11 2016-05-11 Low-irritating bactericidal cleaning agent and preparation method thereof Pending CN105886144A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107410301A (en) * 2017-06-22 2017-12-01 上海久安水质稳定剂厂 A kind of efficiently sticky mud inhibitor and preparation method thereof
CN111575127A (en) * 2020-04-13 2020-08-25 广州市浪奇实业股份有限公司 Liquid detergent composition with washing and softening functions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102947435A (en) * 2010-03-26 2013-02-27 利奎德范尼提公司 Laundry detergent
CN104087431A (en) * 2014-07-08 2014-10-08 谢伟杰 Ceramic tile seam detergent
CN104830555A (en) * 2015-05-16 2015-08-12 青岛德翕拓创高新技术有限公司 Bactericidal towel detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102947435A (en) * 2010-03-26 2013-02-27 利奎德范尼提公司 Laundry detergent
CN104087431A (en) * 2014-07-08 2014-10-08 谢伟杰 Ceramic tile seam detergent
CN104830555A (en) * 2015-05-16 2015-08-12 青岛德翕拓创高新技术有限公司 Bactericidal towel detergent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107410301A (en) * 2017-06-22 2017-12-01 上海久安水质稳定剂厂 A kind of efficiently sticky mud inhibitor and preparation method thereof
CN111575127A (en) * 2020-04-13 2020-08-25 广州市浪奇实业股份有限公司 Liquid detergent composition with washing and softening functions

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