CN1058804A - But can flow and liquid surfactant enriched material that pump extracts - Google Patents

But can flow and liquid surfactant enriched material that pump extracts Download PDF

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Publication number
CN1058804A
CN1058804A CN91105417A CN91105417A CN1058804A CN 1058804 A CN1058804 A CN 1058804A CN 91105417 A CN91105417 A CN 91105417A CN 91105417 A CN91105417 A CN 91105417A CN 1058804 A CN1058804 A CN 1058804A
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Prior art keywords
formula
weight
carbon atom
alkyl
alkylglycoside
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CN91105417A
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Inventor
伯里奇特·基森
安德列·思尔达斯
迪特马·科石客尔
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cosmetics (AREA)
  • Table Devices Or Equipment (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

This concentrated solution is mainly by the water of 50-80% (weight), the formula R of 5-30% (weight) 1-O (G) nAlkylglycoside (the R in the formula of expression 1Represent the alkyl of 8-22 carbon atom, G is the glucose unit, and n is 1-10); The formula R of 3-20% (weight) 2-O-SO 3The surface-active sulfuric acid long-chain alkyl groups (R in the formula that X represents 2Represent the alkyl of 12-22 carbon atom, X is alkalimetal ion or ammonium ion) and the formula R of 1-15% (weight) 3-OSO 3The sulfuric acid short-chain alkyl ester (R in the formula that Y represents 3Represent 6-10 carbon atom, Y represents alkalimetal ion or ammonium ion) form.But this surfactant mixture as shelf-stable, can flow and premixture that pump extracts, be preferably used in preparing washing agent or washing agent.

Description

But can flow and liquid surfactant enriched material that pump extracts
The present invention relates to by alkylglycoside, sulfuric acid long-chain alkyl groups, sulfuric acid short-chain alkyl and also form in case of necessity by fatty alcohol ethoxylate, as can flowing and pumpable, stable liquid surfactant enriched mixture, and relate to used as the washing composition of preparation liquid and the premixture of washing agent.
Alkylglycoside with chain alkyl belongs to the nonionic surface active agent of being known by the people already, expert expert also knows (A.M.Schwartz for example, J.W.Perry is at " tensio-active agent " book Vol.I, Interscience press, 1949, the 372nd page is described), surfactant mixture has synergism usually, and its de-sludging performance is better than the effect of single composition.
European patent EP 070074 has been narrated some washing composition, and these washing composition contain at least the aniorfic surfactant blended alkylglycoside with a kind of conventional usefulness.The also known washing composition that contains alkylglycoside and anion surfactant in European patent EP 092877.Also known in European patent EP 105556 have a liquid washing agent, and it contains alkylglycoside, some other nonionic surface active agent and aniorfic surfactant.By the known conventional anion surfactant and the liquid washing agent of alkylglycoside of containing among the international monopoly WO86/02943.
When preparation liquid washing agent and washing agent, usually each component is added as flowable solution, this solution respectively contains a kind of material or as premixture, promptly so-called mixture is made up of multiple ordinary matter in ready-made preparation.For the composition that is mixed into ready-made preparation defined should have high as far as possible active substance content, should be easy to simultaneously handle, promptly should be can mobile as far as possible, be easy to that pump smokes, and high as far as possible package stability is arranged.Alkylglycoside is full-bodied mashed prod under the normal circumstances.
Basic task of the present invention from the alkylglycoside mashed prod develop a kind of shelf-stable, liquid, can flow and pumpable surfactant mixture.
This task is to solve by the water mixture of being made up of the synthetic anionic tensio-active agent and the sulfuric acid short-chain alkyl ester of a certain amount of alkylglycoside, sulfuric acid chain alkyl ester-formin.
" long-chain " compound of the scope of the invention is meant the aliphatic cpd that contain 12 or more carbon atom, can be straight chain or one or more side chains are arranged, therefore the longest carbon atom chain also may be shorter than 12 carbon." short chain " compound in the scope of the invention is meant the compound that mostly is 10 carbon atoms most, and irrelevant with branch degree.
Mixture of the present invention is a water mixture, mainly is grouped into by following one-tenth:
50-80%(weight) water, preferably 55-70%(weight) water;
5-30%(weight) formula I alkylglycoside, preferably 10-25%(weight) alkylglycoside
R in the formula 1Be the alkyl of 8-22 carbon atom, G is the glucose unit, and n is 1-10;
3-20%(weight) the surfactivity sulfuric acid long-chain alkyl groups of formula II preferably contains 5-15%(weight),
R in the formula 2Be the alkyl of 12-22 carbon atom, X represent alkalimetal ion or ammonium ion and
The sulfuric acid short-chain alkyl ester of formula III 1-15%(weight), preferably 2-10%(weight),
R in the formula 3Be the alkyl of 6-10 carbon atom, Y represents alkalimetal ion or ammonium ion.
Surfactant mixture of the present invention preferably also contains 10-20%(weight), 12-18%(weight particularly) the alcohol of ethoxylation of formula IV.
R represents the alkyl of 10-22 carbon atom in the formula, and p is 1-20, particularly 3-10.
Be suitable for the alkylglycoside of surfactant mixture of the present invention and method for making thereof for example in European patent EP 92355, EP301298 is described in EP357969 and EP362671 or the U.S. Pat 3547828.The glycosides component of this alkylglycoside ((G) n in the formula I) relates to the oligopolymer or the polymkeric substance that are made of naturally occurring aldose monomer or ketose monomer, and belonging to these aldose monomers or ketose monomer especially has glucose, seminose, fructose, semi-lactosi, talose, gulose, altrose, allose, idose, ribose, pectinose, wood sugar and lyxose.The feature of the oligopolymer of being made up of such glycosides banded monomer is that so-called oligomeric degree is determined by its number also except that being determined by its sacchariferous kind.Oligomeric degree (n of formula I) is as analyzing the general fractional value that adopts of the size of determining, scope is 1-10, and the alkylglycoside n value of adding is preferably below 1.5, particularly 1.2-1.4.Glucose is best monomer because obtain easily.
The moieties of the alkylglycoside that in surfactant mixture of the present invention, the contains (R in the formula I 1) preferably also be derivative from the raw material that grows that obtains easily, particularly from aliphatic alcohols, even their branched chain isomer, particularly so-called oxo alcohol also can be used to prepare available alkylglycoside.Therefore, useful especially is the primary alconol and composition thereof of octyl group, decyl, dodecyl, tetradecyl, hexadecyl or octadecyl with straight chain.Shi Yi alkylglycoside contains the Oleum Cocois alkyl especially, that is to say, and mainly be R 1=dodecyl and R 1The mixture of=tetradecyl.
Alkylglycoside can contain under preparation condition on a small quantity for example unreacted free long-chain alcohol of 1-2%, and this character to the surfactant mixture prepared does not have disadvantageous effect.
Be suitable for being added in the sulfuric acid long-chain alkyl groups in the surfactant mixture of the present invention, can consider the sulfating product of straight chain alcohol or branched-chain alcoho.Suitable especially is the fatty alcohol derivative of the fatty alcohol derivative that 12-22 carbon atom arranged, an especially 12-16 carbon atom.Such alkyl sodium sulfate just knows it is effectively aniorfic surfactant for a long time.
Suitable sulfuric acid short-chain alkyl ester is to contain the straight chain alcohol of 6-10 carbon atom or the sulfating product of branched-chain alcoho, and the derivative of the straight chain alcohol of 8-10 carbon atom is preferably arranged.As everyone knows, such alkyl sodium sulfate ester does not have or has only faint Action of Surfactant.
The alkyl sodium sulfate ester can prepare with known method, being about to the alcohol of corresponding long chain or short chain and conventional sulfur acidizing reagent reacts, particularly reacts with sulphur trioxide or chlorsulfonic acid, neutralize then, preferably the amine alkali that replaces with alkali metal base, ammonium alkali or alkyl or hydroxyalkyl neutralizes.
The ethoxy compound that is fit to join in the mixture of the present invention is the derivative with straight or branched alcohol of 10-22 carbon atom, preferably has the straight or branched alcohol derivate of 12 to 16 carbon atoms.The ethoxylation degree (p in the formula IV) of alcohol between 1-20,3-10 preferably.Their available known methods are produced corresponding alcohol with reacting ethylene oxide.
Prepare surfactant mixture of the present invention and have no difficulty.Can obtain by each composition of simple mixing without a doubt, each composition can be used as itself or preferably exists in the aqueous solution.
Mixture of the present invention has low viscosity, easily flows and pumpability and the high feature of package stability.The viscosity of mixture of the present invention is generally between 20-7000mpa.s.Generally, approximately be 9.8-10.5, but can add conventional acid, especially add citric acid, neutralize fully, can not lose its superior performance up to weakly acidic pH value at alkaline ph value.Mixture of the present invention is deposited the long period (at least 30 days) steady quality between about 1 ℃-45 ℃ of temperature.
Being counted as another advantage of not expecting of mixture of the present invention is to have improved the rheological property that surface-active alkyl sodium sulfate ester-alkylglycoside is stuck with paste by adding some compounds, although their surfactivity of these compounds is very little, but join in the final product the critical nature of alkylglycoside mashed prod, all have no adverse effect as detergent power and lathering power.
Mixture of the present invention can directly use or dilute with water after be used for industrial production, for example do flotation aid or bore flushing agent.Yet preferably as the premixture for preparing liquid detergent and washing agent.Belong to liquid detergent and washing agent, light effect washing composition, hair detergent and vessel irrigation especially arranged, also have shampoo.These preparations can make the concentration that this mixture is diluted with water to desirable effective constituent with short-cut method.The composition commonly used, particularly synergistic agent that can add other in these preparations are as zeolite, layered silicate (Schichtsilikate), corrosion inhibitor, SYNTHETIC OPTICAL WHITNER, bleach-activating agent, white dyes, enzyme, antiredeposition agent, antibiotic active substance, solvent that can be mixed, abradant with water, suds-stabilizing agent, sanitas.PH conditioning agent, tinting material, spices and other tensio-active agent.
Embodiment
Embodiment 1
By the simple mixing of the composition that exists as the aqueous solution, make in the following table 1 with it and form employed preparation V1 and V2 in the surfactant mixture M1 to M7 of the present invention that characterizes and the controlled trial.
Figure 911054170_IMG1
The A:C12/14-alkyl glucoside, low polymerization degree 1.4
B:Na-C12/14-alkyl sulfuric ester (Texapon
Figure 911054170_IMG2
LS35, Henkel manufactory)
C:Na-C8-alkyl sulfuric ester (Texapon
Figure 911054170_IMG3
842, Henkel manufactory)
D:C1-18-alcohol, 7 times of ethoxylation (Eumulgin
Figure 911054170_IMG4
W07, Henker manufactory)
It is 9.8-10.5 that surfactant mixture M1-M7 of the present invention has pH value, in 10%(weight) its PH is 8.5-9.9 in the aqueous solution.
Table 2: viscosity (20 ℃ are pressed the Hoppler falling-sphere viscometer and measure)
Viscosity (20 ℃) optical phenomena optical phenomena
(mpa.s) (room temperature) (1 ℃)
M1 465 clarified liq clarified liqs
M2??190??″″??″″
M3??1370??″″??″″
M4??570??″″??″″
M5??6380??″″??″″
M6??35??″″??″″
M7??880??″″??″″
V1 161325 " " solid matter
V2??169925??″″??″″
The sample of mixture M 1-M7 of the present invention was respectively deposited under 1 ℃ or 10 ℃ 30 days, and it is constant to measure its denseness.Deposit more than 30 days in 40 ℃, most cases occurs slight muddy, and muddiness disappears again during cool to room temperature.Mixture of the present invention is adjusted to pH value is 6.0-8.8 if add a small amount of citric acid, and its viscosity does not have obvious change, then can deposit under up to 45 ℃ temperature and does not have a consistency change.

Claims (8)

1, contain flowing and pumpable tensio-active agent water mixture of alkylglycoside and synthetic aniorfic surfactant, it is characterized in that, mainly be grouped into by following one-tenth:
50%-80% (weight) water,
The alkylglycoside of the formula I of 5-30% (weight)
R in the formula 1Be the alkyl of 8-22 carbon atom, G is the glucose unit, and n is 1-10,
The surface-active sulfuric acid long-chain alkyl groups that the formula II of 3-20% (weight) represents
R in the formula 2Be the alkyl of 12-22 carbon atom, X be alkalimetal ion or ammonium ion and
The sulfuric acid short-chain alkyl ester that the formula III of 1-15% (weight) is represented
R in the formula 3Represent the alkyl of 6-10 carbon atom, Y represents alkalimetal ion or ammonium ion.
2, press the surfactant mixture of claim 1, it is characterized in that, contain 55-70%(weight) water, 10-25%(weight) the formula I shown in alkylglycoside, 5-15%(weight) the formula II shown in sulfuric acid long-chain alkyl groups and 2-10%(weight) the formula III shown in sulfuric acid short-chain alkyl ester;
3, by claim 1 or 2 surfactant mixture, it is characterized in that, also contain 10-20%(weight), 12-18%(weight particularly) the formula IV shown in the alcohol of ethoxylation
R in the formula 4Be the alkyl of the alkyl of 10-22 carbon atom, a particularly 12-16 carbon atom, P represents 1-20, particularly 3-10;
4, by a described surfactant mixture among the claim 1-3, it is characterized in that the low polymerization degree n of the alkylglycoside of formula I is lower than 1.5, preferably 1.2-1.4;
5, by a described surfactant mixture among the claim 1-4, it is characterized in that the alkylglycoside of formula I is an alkyl glucoside;
6, by a described surfactant mixture among the claim 1-5, it is characterized in that the alkyl R of the sulfuric acid long-chain alkyl groups that the formula II is represented 2Have 12-18 carbon atom;
7, by a described surfactant mixture among the claim 1-6, it is characterized in that the alkyl R of the sulfuric acid short-chain alkyl ester that the formula III is represented 3Have 8-10 carbon atom;
But 8, will by a described surfactant mixture among the claim 1-7 as the preparation liquid detergent and washing agent, that contain is stable, can flow and premixture that pump extracts.
CN91105417A 1990-08-08 1991-08-07 But can flow and liquid surfactant enriched material that pump extracts Pending CN1058804A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4025065A DE4025065A1 (en) 1990-08-08 1990-08-08 LIQUID, POURABLE AND PUMPABLE SURFACTANT CONCENTRATE
DEP4025065.2 1990-08-08

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EP (1) EP0542801B1 (en)
JP (1) JPH05509347A (en)
CN (1) CN1058804A (en)
AT (1) ATE107956T1 (en)
BR (1) BR9106754A (en)
DE (2) DE4025065A1 (en)
ES (1) ES2055994T3 (en)
MX (1) MX9100568A (en)
RU (1) RU2056458C1 (en)
WO (1) WO1992002604A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062705A (en) * 2015-08-14 2015-11-18 浙江赞宇科技股份有限公司 Anhydrous ethoxylated alkyl sulfate concentrate as well as preparation method and device thereof

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FR2667865B1 (en) * 1990-10-12 1992-12-11 Saint Gobain Isover PHENOLIC RESIN, PROCESS FOR PREPARING THE RESIN, AND SIZING COMPOSITION OF MINERAL FIBERS CONTAINING THE SAME.
DE4117689A1 (en) * 1991-05-29 1992-12-03 Henkel Kgaa LIQUID, POURABLE AND PUMPABLE SURFACTANT PREPARATION
TW211595B (en) * 1991-12-07 1993-08-21 Hoechst Ag
DE59305647D1 (en) * 1992-04-21 1997-04-10 Basf Ag METHOD FOR THE PRODUCTION OF ALKYL GLYCOSIDES AND THEIR USE
NZ247676A (en) * 1992-06-08 1995-04-27 Colgate Palmolive Co Anionic surfactant compositions containing alkyl sulphates as viscosity modifiers; hair shampoo
DE4236506A1 (en) * 1992-10-29 1994-05-05 Henkel Kgaa Process for the preparation of aqueous solutions of anionic surfactants with improved low-temperature stability
JPH08503013A (en) * 1992-11-03 1996-04-02 ザ、プロクター、エンド、ギャンブル、カンパニー Cleaning with short-chain surfactant
EP0616027A1 (en) * 1993-03-19 1994-09-21 The Procter & Gamble Company Concentrated cleaning compositions
EP0616026A1 (en) * 1993-03-19 1994-09-21 The Procter & Gamble Company Concentrated cleaning compositions
ES2159304T3 (en) * 1993-09-20 2001-10-01 Procter & Gamble THICKENED WATER DETERGENT COMPOSITIONS, WITH IMPROVED CLEANING BEHAVIOR.
DE4344991A1 (en) * 1993-12-30 1995-07-06 Huels Chemische Werke Ag Process for the conversion of hexagonal liquid-crystalline aqueous surfactant phases
DK0693548T3 (en) * 1994-07-18 2002-02-11 Procter & Gamble Stable concentrated premix and its use in the preparation of aqueous detergent compositions
US5737471A (en) * 1995-05-19 1998-04-07 Bridgestone Corporation Optical waveguide tube
US5866530A (en) * 1995-11-25 1999-02-02 Henkel Kommanditgesellschaft Auf Aktien Non-aqueous liquid mixtures of alkyl polyglycoside and alkyl polyalkylene glycol ether useful in various detergent applications
EP0916718A1 (en) 1997-10-14 1999-05-19 The Procter & Gamble Company Cleaning and disinfecting compositions
DE19908563C2 (en) * 1999-02-27 2002-11-14 Cognis Deutschland Gmbh Detergent for hard surfaces
WO2015000792A1 (en) * 2013-07-03 2015-01-08 Basf Se Mixtures of compounds, their preparation, and uses

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DE3278670D1 (en) * 1981-07-13 1988-07-21 Procter & Gamble Foaming surfactant compositions
US4483787A (en) * 1983-12-28 1984-11-20 The Procter & Gamble Company Concentrated aqueous detergent compositions
DE3838808A1 (en) * 1988-11-17 1990-05-23 Henkel Kgaa DETERGENT AND CLEANING AGENT, CONTAINING A TENSIDE MIXTURE OF ALKYL GLYCOSIDES AND ANIONSIDE

Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN105062705A (en) * 2015-08-14 2015-11-18 浙江赞宇科技股份有限公司 Anhydrous ethoxylated alkyl sulfate concentrate as well as preparation method and device thereof

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MX9100568A (en) 1992-04-01
ATE107956T1 (en) 1994-07-15
EP0542801B1 (en) 1994-06-29
WO1992002604A1 (en) 1992-02-20
DE59102082D1 (en) 1994-08-04
JPH05509347A (en) 1993-12-22
ES2055994T3 (en) 1994-09-01
BR9106754A (en) 1993-06-29
RU2056458C1 (en) 1996-03-20
EP0542801A1 (en) 1993-05-26
DE4025065A1 (en) 1992-02-13

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