CN105866366A - Multi-parameter monitoring system for industrial water quality based on radio frequency identification - Google Patents

Multi-parameter monitoring system for industrial water quality based on radio frequency identification Download PDF

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Publication number
CN105866366A
CN105866366A CN201610274779.5A CN201610274779A CN105866366A CN 105866366 A CN105866366 A CN 105866366A CN 201610274779 A CN201610274779 A CN 201610274779A CN 105866366 A CN105866366 A CN 105866366A
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module
detection
detection module
water quality
circuit
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CN201610274779.5A
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Inventor
胡晓荣
俞娟
胡瑜
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Wuxi Haoyu Energy Saving Environmental Protection Equipment Co Ltd
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Wuxi Haoyu Energy Saving Environmental Protection Equipment Co Ltd
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Priority to CN201610274779.5A priority Critical patent/CN105866366A/en
Publication of CN105866366A publication Critical patent/CN105866366A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01DMEASURING NOT SPECIALLY ADAPTED FOR A SPECIFIC VARIABLE; ARRANGEMENTS FOR MEASURING TWO OR MORE VARIABLES NOT COVERED IN A SINGLE OTHER SUBCLASS; TARIFF METERING APPARATUS; MEASURING OR TESTING NOT OTHERWISE PROVIDED FOR
    • G01D21/00Measuring or testing not otherwise provided for
    • G01D21/02Measuring two or more variables by means not covered by a single other subclass
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/04Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
    • G01N27/06Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a liquid
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/31Half-cells with permeable membranes, e.g. semi-porous or perm-selective membranes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1813Specific cations in water, e.g. heavy metals
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • G01N33/1853Hardness of water
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B19/00Programme-control systems
    • G05B19/02Programme-control systems electric
    • G05B19/04Programme control other than numerical control, i.e. in sequence controllers or logic controllers
    • G05B19/042Programme control other than numerical control, i.e. in sequence controllers or logic controllers using digital processors
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B19/00Programme-control systems
    • G05B19/02Programme-control systems electric
    • G05B19/04Programme control other than numerical control, i.e. in sequence controllers or logic controllers
    • G05B19/042Programme control other than numerical control, i.e. in sequence controllers or logic controllers using digital processors
    • G05B19/0428Safety, monitoring

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
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  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Automation & Control Theory (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

The invention discloses a multi-parameter monitoring system for industrial water quality based on radio frequency identification. The multi-parameter monitoring system comprises a detection terminal and a monitoring terminal connected with the detection terminal, wherein the detection terminal comprises a heavy metal detection module, a PH detection module, an ORP detection module, a conductivity detection module, a dissolved oxygen detection module, a temperature detection module, a microcontroller module, a data transmission module and a power supply module; the heavy metal detection module, the PH detection module, the ORP detection module, the conductivity detection module, the dissolved oxygen detection module and the temperature detection module are respectively connected with the microcontroller module; and the data transmission module and the power supply module are respectively connected with the corresponding ports of the microcontroller module. The multi-parameter monitoring system is integrated with multifunction detection, namely that one instrument can be used for detecting multiple parameters, so that the multi-parameter monitoring system is convenient to apply; the uniform educing treatment for measuring signals can be conveniently performed; and the analytical precision of solution or water quality can be increased, and the cost performance of a sensor can be greatly increased.

Description

A kind of industrial multi-parameter water-quality monitoring system based on RF identification
Technical field
The present invention relates to a kind of multi-parameter water-quality sensor, particularly relate to a kind of industrial many ginsengs of water quality based on RF identification Number monitoring system, belongs to field of water quality detection.
Background technology
Breeding water is owing to being affected by mankind's activity and other factors, and the material causing entry into water body has exceeded water Body self-purification capacity, causes water quality deterioration, has influence on water body purposes.Main pollutant have: heavy metal contaminants, nonmetal Inorganic toxic pollutant, toxic organic compound, oxygen consumption organic, acid, alkali pollution thing, these all can have a strong impact on sending out of aquaculture Exhibition.In consideration of it, industry develops multiple-quality water detection equipment, but the comprehensive detection ability of this kind equipment is the most not enough, detection Parameter
The most single, and data be unfavorable for transmit.
In commercial production or environmental conservation, the detection to solution parameter or water quality is by substantially wanting of Industry Control Ask.Generally solution or the detection of water quality and analysis are related to multiple parameters such as temperature, pH value and electrical conductivity.Current is similar Sensor, is mostly simple function, in the occasion needing multiparameter to detect, it is generally required to be respectively provided with different sensors.This Kind arrange and not only to make that measurement facility is loaded down with trivial details, be not easy to parameter signal is uniformly processed, and due to each sensor mounting location Difference, can cause the error comprehensively analyzed solution or water quality, then be that single the too increasing of sensor function uses and be manufactured into This.
Further, since pH glass electrode is in testing, reference buffer solution needs to be permeated to detected solution by salt bridge, The most inevitably cause following problem: one is that the chlorine ion concentration in reference solution is being changed stepwise, cause measurement knot The slow drift of fruit.In the measurement occasion the highest for pH required precision, the carrying out to electrode is regular is needed to verify, this Sample is the most bothersome, and is unfavorable for measuring continuously very much;Two is when the pressure of reference solution is less than the pressure of solution to be measured, can produce Raw solution to be measured, by the salt bridge inverse osmosis to reference solution, so can cause metering misalignment, even cause sensor failure; Three losses being as reference solution, make certainty of measurement not reach requirement, in turn result in sensor and scrap, and service life is short.
Summary of the invention
It is a kind of based on RF identification that the technical problem to be solved is that the deficiency for background technology provides Industry multi-parameter water-quality monitoring system.
The present invention solves above-mentioned technical problem by the following technical solutions
A kind of industrial multi-parameter water-quality monitoring system based on RF identification, comprises detection terminal and connected monitoring is whole End, described detection terminal comprises heavy metal analysis module, PH detection module, ORP detection module, electrical conductivity detection module, dissolving Oxygen detection module, temperature detecting module, micro controller module, data transmission module and power module;Described heavy metal analysis mould Block, PH detection module, ORP detection module, electrical conductivity detection module, dissolved oxygen detection module and temperature detecting module are respectively with micro- Controller module connects, and described data transmission module and power module are connected on the corresponding port of micro controller module; Described monitor terminal comprises controller module and difference connected display module, data memory module, RF identification mould Block and clock module;
Described radio frequency identification module includes that a regulator rectifier circuit, described regulator rectifier circuit comprise coupling circuit, amplitude limit detection Circuit, amplitude limit bleeder circuit, mu balanced circuit;Described coupling circuit, amplitude limit testing circuit, amplitude limit bleeder circuit are sequentially connected with, institute Stating mu balanced circuit to be connected with amplitude limit bleeder circuit, mu balanced circuit respectively, described coupling circuit is for being coupled to penetrate by input signal Frequently on identification module;Described amplitude limit testing circuit voltage amplitude after detecting rectification;Described amplitude limit bleeder circuit is used for letting out Put unnecessary electric current;Described mu balanced circuit is for carrying out voltage stabilizing process and then exporting stable supply voltage;
Wherein, PH detection module, for detecting the PH value of water quality;
ORP detection module, for detecting the oxidisability of water quality;
Electrical conductivity detection module, for detecting hardenability and the salinity of water quality;
Dissolved oxygen detection module, for detecting the content of the dissolved oxygen of water quality;
Temperature detecting module, for detecting the temperature of water quality;
Micro controller module, for sending detection instruction every detection parameter of water quality treatment;
Display module, for every detection parameter of display water quality in real time;
Data memory module, for storing every detection parameter of water quality;
Clock module, detects the time for real time record.
As the further preferred scheme of a kind of industrial multi-parameter water-quality monitoring system based on RF identification of the present invention, institute Stating dissolved oxygen detection module uses chip model to be the dissolved oxygen sensor of 499ADO.
As the further preferred scheme of a kind of industrial multi-parameter water-quality monitoring system based on RF identification of the present invention, institute State micro controller module and use AVR series monolithic.
As the further preferred scheme of a kind of industrial multi-parameter water-quality monitoring system based on RF identification of the present invention, institute State the ORP analyzer that ORP detection module uses chip model to be ORP-412.
As the further preferred scheme of a kind of industrial multi-parameter water-quality monitoring system based on RF identification of the present invention, institute State the PH analyzer that PH detection module uses chip model to be pH170.
The present invention uses above technical scheme compared with prior art, has following technical effect that
1, the present invention collects multi-functional and is detected on one, and an instrument can detect many kinds of parameters, and application is convenient, and two is to be convenient for measuring letter Number unified extraction process, three is the analysis precision that improve solution or water quality, the most also substantially increases the sexual valence of sensor Ratio;
2, the present invention is additionally provided with clock module and data memory module, by data memory module real-time storage micro controller module Send detection instruction every detection parameter of water quality treatment, store the time by clock module real time record, be effectively prevented from The loss of data brought because of sensor fault.
Accompanying drawing explanation
Fig. 1 is the structured flowchart that the present invention detects terminal.
Detailed description of the invention
Below in conjunction with the accompanying drawings technical scheme is described in further detail:
A kind of industrial multi-parameter water-quality monitoring system based on RF identification, comprises detection terminal and connected monitoring is whole End, described detection terminal comprises heavy metal analysis module, PH detection module, ORP detection module, electrical conductivity detection module, dissolving Oxygen detection module, temperature detecting module, micro controller module, data transmission module and power module;Described heavy metal analysis mould Block, PH detection module, ORP detection module, electrical conductivity detection module, dissolved oxygen detection module and temperature detecting module are respectively with micro- Controller module connects, and described data transmission module and power module are connected on the corresponding port of micro controller module; Described monitor terminal comprises controller module and difference connected display module, data memory module, RF identification mould Block and clock module;
Described radio frequency identification module includes that a regulator rectifier circuit, described regulator rectifier circuit comprise coupling circuit, amplitude limit detection Circuit, amplitude limit bleeder circuit, mu balanced circuit;Described coupling circuit, amplitude limit testing circuit, amplitude limit bleeder circuit are sequentially connected with, institute Stating mu balanced circuit to be connected with amplitude limit bleeder circuit, mu balanced circuit respectively, described coupling circuit is for being coupled to penetrate by input signal Frequently on identification module;Described amplitude limit testing circuit voltage amplitude after detecting rectification;Described amplitude limit bleeder circuit is used for letting out Put unnecessary electric current;Described mu balanced circuit is for carrying out voltage stabilizing process and then exporting stable supply voltage;
Described PH detection module, for detecting the PH value of water quality;
Described ORP detection module, for detecting the oxidisability of water quality;
Described electrical conductivity detection module, for detecting hardenability and the salinity of water quality;
Described dissolved oxygen detection module, for detecting the content of the dissolved oxygen of water quality;
Described temperature detecting module, for detecting the temperature of water quality;
Described micro controller module, for sending detection instruction every detection parameter of water quality treatment;
Described display module, for every detection parameter of display water quality in real time;
Described data memory module, for storing every detection parameter of water quality;
Described clock module, detects the time for real time record;
Described power module, is used for providing working power needed for micro controller module.
Described heavy metal analysis module, PH detection module, ORP detection module, electrical conductivity detection module, dissolved oxygen detection mould Block, temperature detecting module and micro controller module are provided with an analog-digital converter.Described heavy metal analysis module, PH detection module, Collection data are passed through analog digital conversion by ORP detection module, electrical conductivity detection module, dissolved oxygen detection module, temperature detecting module The every detection parameter gathering water quality can preferably be transmitted to micro controller module by device.
Described heavy metal analysis module comprises light source and photoelectric sensor, described light source and power module and connects, described light Electric transducer is connected with micro controller module by analog-digital converter.Light source is irradiated on photoelectric sensor through water quality, light Electric transducer produces analog electrical signal, and then is analyzed through the incoming micro controller module of analog-digital converter by the signal of telecommunication of generation For the content of beary metal utilized in Different lightwave detection water quality;And then exist in data memory module real-time by display module Display.
Described electrical conductivity detection module comprises the first conductance electrode, insulator and the second conductance electrode being sequentially connected with.Electricity Conductance detection module is for detecting hardenability and the salinity of water;First conductance electrode and the second conductance electrode are inserted in water, First conductance electrode and the second conductance electrode the signal detected through the incoming micro controller module of analog-digital converter, described micro- The conductivity data analysis that controller module obtains after signal is transferred to data, calculates draws hardenability and the salinity of water quality; And then exist in data memory module, it is then passed on display screen show.
In the present invention, described dissolved oxygen detection module uses chip model to be the dissolved oxygen sensor of 499ADO, 499ADO dissolved oxygen sensor is the current sensor that a kind of barrier film covers, and it is made up of negative electrode, anelectrode and electrolyte, cloudy One layer of barrier film allowing oxygen infiltration it is covered with on electrode.During working sensor, the oxygen molecule in fluid to be measured passes through barrier film Diffusing in negative electrode, oxygen molecule is reduced into hydroxide ion by the polarizing voltage being applied in negative electrode, and then at yin, yang electricity Producing electric current between pole, this electric current is detected by analytical tool, and its speed reaching negative electrode to oxygen molecule is directly proportional, and It is directly proportional to the concentration of dissolved oxygen in fluid to be measured eventually.Owing to oxygen molecule depends on fluid to be measured by the diffusion rate of barrier film Temperature, so, the response time of sensor must correct temperature impact infiltrative on barrier film.In dissolved oxygen sensor built-in Pt100 temperature probe, therefore, temperature can be revised by analyser automatically.
Wherein, described micro controller module employing AVR series monolithic, described ORP detection module employing chip model is The ORP analyzer of ORP-412, the PH analyzer that described PH detection module uses chip model to be pH170.
In sum, the present invention collects multi-functional and is detected on one, and an instrument can detect many kinds of parameters, and application is convenient, and two Being that the unified extraction being convenient for measuring signal processes, three is the analysis precision that improve solution or water quality, the most also substantially increases The cost performance of sensor;The present invention is additionally provided with clock module and data memory module, micro-by data memory module real-time storage Controller module sends detection instruction every detection parameter of water quality treatment, stores the time by clock module real time record, It is effectively prevented from the loss of data brought because of sensor fault.
It is understood that unless otherwise defined, all terms used herein (include technology art to those skilled in the art of the present technique Language and scientific terminology) have with the those of ordinary skill in art of the present invention be commonly understood by identical meaning.Also should Being understood by, those terms defined in such as general dictionary should be understood that the meaning having with the context of prior art The meaning that justice is consistent, and unless defined as here, will not explain by idealization or the most formal implication.
Above example is only the technological thought that the present invention is described, it is impossible to limit protection scope of the present invention with this, every The technological thought proposed according to the present invention, any change done on the basis of technical scheme, each fall within scope Within.Above embodiments of the present invention are explained in detail, but the present invention is not limited to above-mentioned embodiment, in ability In the ken that territory those of ordinary skill is possessed, it is also possible to make various change on the premise of or else departing from present inventive concept Change.

Claims (5)

1. an industrial multi-parameter water-quality monitoring system based on RF identification, it is characterised in that: comprise detection terminal and with Its monitor terminal connected, described detection terminal comprises heavy metal analysis module, PH detection module, ORP detection module, electrical conductivity Detection module, dissolved oxygen detection module, temperature detecting module, micro controller module, data transmission module and power module;Described Heavy metal analysis module, PH detection module, ORP detection module, electrical conductivity detection module, dissolved oxygen detection module and temperature detection Module is connected with micro controller module respectively, and described data transmission module and power module are connected to micro controller module On corresponding port;Described monitor terminal comprise controller module and respectively connected display module, data memory module, Radio frequency identification module and clock module;
Described radio frequency identification module includes that a regulator rectifier circuit, described regulator rectifier circuit comprise coupling circuit, amplitude limit detection Circuit, amplitude limit bleeder circuit, mu balanced circuit;Described coupling circuit, amplitude limit testing circuit, amplitude limit bleeder circuit are sequentially connected with, institute Stating mu balanced circuit to be connected with amplitude limit bleeder circuit, mu balanced circuit respectively, described coupling circuit is for being coupled to penetrate by input signal Frequently on identification module;Described amplitude limit testing circuit voltage amplitude after detecting rectification;Described amplitude limit bleeder circuit is used for letting out Put unnecessary electric current;Described mu balanced circuit is for carrying out voltage stabilizing process and then exporting stable supply voltage;
Wherein, PH detection module, for detecting the PH value of water quality;
ORP detection module, for detecting the oxidisability of water quality;
Electrical conductivity detection module, for detecting hardenability and the salinity of water quality;
Dissolved oxygen detection module, for detecting the content of the dissolved oxygen of water quality;
Temperature detecting module, for detecting the temperature of water quality;
Micro controller module, for sending detection instruction every detection parameter of water quality treatment;
Display module, for every detection parameter of display water quality in real time;
Data memory module, for storing every detection parameter of water quality;
Clock module, detects the time for real time record.
A kind of industrial multi-parameter water-quality monitoring system based on RF identification the most according to claim 1, it is characterised in that: Described dissolved oxygen detection module uses chip model to be the dissolved oxygen sensor of 499ADO.
A kind of industrial multi-parameter water-quality monitoring system based on RF identification the most according to claim 1, it is characterised in that: Described micro controller module uses AVR series monolithic.
A kind of industrial multi-parameter water-quality monitoring system based on RF identification the most according to claim 1, it is characterised in that: The ORP analyzer that described ORP detection module uses chip model to be ORP-412.
A kind of industrial multi-parameter water-quality monitoring system based on RF identification the most according to claim 1, it is characterised in that: The PH analyzer that described PH detection module uses chip model to be pH170.
CN201610274779.5A 2016-04-28 2016-04-28 Multi-parameter monitoring system for industrial water quality based on radio frequency identification Pending CN105866366A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106556682A (en) * 2016-10-20 2017-04-05 浙江农林大学 Animal farm wastewater treatment effect method of real-time
CN109828092A (en) * 2019-03-28 2019-05-31 商洛学院 A kind of sewage monitoring system

Citations (6)

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CN203259517U (en) * 2013-05-09 2013-10-30 厦门奥林特环保科技有限公司 Online monitoring system for industrial pollution source
CN203376306U (en) * 2013-05-09 2014-01-01 厦门奥林特环保科技有限公司 Automatic water quality monitoring system
CN104515616A (en) * 2013-09-30 2015-04-15 江苏省电力公司常州供电公司 Temperature monitoring and inspecting system of substation primary equipment
CN204666613U (en) * 2014-12-04 2015-09-23 宁波中瑞生物科技有限公司 A kind of water quality testing meter
CN105352193A (en) * 2015-11-10 2016-02-24 苏州美达瑞电子有限公司 Water heater regulating and control system based on radio frequency identification amplitude limiting detection circuit
CN205176542U (en) * 2015-09-30 2016-04-20 苏州富米信息技术有限公司 Thing allies oneself with cloud on -line monitoring data acquisition system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203259517U (en) * 2013-05-09 2013-10-30 厦门奥林特环保科技有限公司 Online monitoring system for industrial pollution source
CN203376306U (en) * 2013-05-09 2014-01-01 厦门奥林特环保科技有限公司 Automatic water quality monitoring system
CN104515616A (en) * 2013-09-30 2015-04-15 江苏省电力公司常州供电公司 Temperature monitoring and inspecting system of substation primary equipment
CN204666613U (en) * 2014-12-04 2015-09-23 宁波中瑞生物科技有限公司 A kind of water quality testing meter
CN205176542U (en) * 2015-09-30 2016-04-20 苏州富米信息技术有限公司 Thing allies oneself with cloud on -line monitoring data acquisition system
CN105352193A (en) * 2015-11-10 2016-02-24 苏州美达瑞电子有限公司 Water heater regulating and control system based on radio frequency identification amplitude limiting detection circuit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106556682A (en) * 2016-10-20 2017-04-05 浙江农林大学 Animal farm wastewater treatment effect method of real-time
CN109828092A (en) * 2019-03-28 2019-05-31 商洛学院 A kind of sewage monitoring system

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