CN105862476A - Formaldehyde-free activated dye color fixing agent and preparation method thereof - Google Patents

Formaldehyde-free activated dye color fixing agent and preparation method thereof Download PDF

Info

Publication number
CN105862476A
CN105862476A CN201610339473.3A CN201610339473A CN105862476A CN 105862476 A CN105862476 A CN 105862476A CN 201610339473 A CN201610339473 A CN 201610339473A CN 105862476 A CN105862476 A CN 105862476A
Authority
CN
China
Prior art keywords
fixing agent
formaldehyde
preparation
free active
dye fixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610339473.3A
Other languages
Chinese (zh)
Other versions
CN105862476B (en
Inventor
傅美缘
彭诗端
刘剑锋
茅勰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Aiwen Biotechnology Co ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610339473.3A priority Critical patent/CN105862476B/en
Publication of CN105862476A publication Critical patent/CN105862476A/en
Application granted granted Critical
Publication of CN105862476B publication Critical patent/CN105862476B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/06—After-treatment with organic compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/08—After-treatment with organic compounds macromolecular
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymerisation Methods In General (AREA)
  • Coloring (AREA)

Abstract

The invention provides a formaldehyde-free activated dye color fixing agent and a preparation method thereof. The preparation method comprises the following steps of 1, sequentially adding oleic acid imidazoline quaternary ammonium salt, trimethylolpropane monoallylether, 1-3-diallylurea, silicon-containing monomer, a chelating agent and deionized water into a reaction kettle provided with a thermometer, a stirrer and a reflux condenser, then starting reflux condensation, conducting stirring, and starting heating for raising the temperature; 2, when the temperature is raised to 85-100 DEG C, starting dropwise adding an initiator solution with the mass percentage concentration ranging from 1% to 10%, wherein the initiator solution is prepared from initiator and part of deionized water, the dropwise adding time is controlled to be 0.5-4 hours, and the temperature in the dropwise-adding process is controlled to be 85-100 DEG C; 3, after the initiator solution is added completely, conducting a reaction for 1-5 hours with the temperature preserved, subsequently adding the balance water, stirring the materials for 0.5 hour, and then discharging the materials, so that the color fixing agent is obtained.

Description

A kind of formaldehyde-free active dye fixing agent and preparation method thereof
Technical field
The invention belongs to field of fine chemical, particularly to a kind of formaldehyde-free active dye fixing agent and preparation method thereof.
Background technology
Reactive dye are cheap, chromatogram is complete, bright in colour, be widely used in cotton fabric dyeing process.Although reactive dye Reactive group in molecule is easily combined with covalent bond with fiber, but color fastness is unsatisfactory.It is in dyeing course, particularly When dye is dark, often there are the reactive dye making to there is a large amount of non-set on dyed fabric because dye strength is too high, these The dyestuff of non-set is difficult to eccysis from dyed fabric, and this some dyes will fade in washing process；Meanwhile, some activity The chemical bond facile hydrolysis formed between base and fiber, causes wet colour fastness relatively low.And color fixing agent such as color fixing agent Y in early days is first The product of the reaction such as aldehyde, dicyandiamide and ammonium chloride, although every fastness of product dyed thereby can be improved, but there is content of formaldehyde relatively Height, the problem such as be detrimental to health, and has not met International Textile requirement.Along with constantly expanding and people of World Textile trade People's living standard, the improving constantly of environmental consciousness, propose higher requirement to indexs such as comfortable, cleaning, the safety of textile.
Since entering 21 century, World Textile Market fastness every to product dyed thereby is had higher requirement, through fixation Agent process after product dyed thereby, not only to have the soaping of certain grade, wash, rub resistance, perspiration resistance, the jail such as sun-resistant, chlorine-resistant drift Degree, but also require without formaldehyde, nontoxic, do not affect fabric feeling and discoloration etc..Therefore, research meets ecological, environmental protective, Wu Jia The new reactive dyes color fixing agent of aldehyde is a significant job.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of formaldehyde-free active dye fixing agent and system thereof Preparation Method, this color fixing agent can more preferably improve fabric fastness to wet rubbing and color fastness to washing and without formaldehyde.
To achieve these goals, the present invention is by the following technical solutions:
A kind of preparation method of formaldehyde-free active dye fixing agent, including the raw material components of following portions by weight proportioning:
Described silicon-containing monomer is vinyl three (2-methoxy ethoxy) silane, 3-(methacryloxypropyl) propyl group trimethoxy In base silane, 3-(methacryloxypropyl) hydroxypropyl methyl dimethoxysilane any one or two or more with any than mixing Mixture.
Described chelating agent be poly-epoxy succinic acid or poly-aspartate or both with any than mixing mixture.
Described initiator be in ammonium persulfate, sodium peroxydisulfate and potassium peroxydisulfate any one or two or more with arbitrarily than The mixture of mixing.
The preparation method of a kind of formaldehyde-free active dye fixing agent, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into described oleic imidazolinone quaternary ammonium Returned cold is opened after salt, trimethyolol propane monoallyl ether, 1,3-diallyl urea, silicon-containing monomer, chelating agent, deionized water Solidifying, stirring, and begin to warm up intensification；
(2) when temperature rises to 85～100 DEG C, then start to drip mass percent concentration be 1～10% initiator molten Liquid, this initiator solution is formulated by the described deionized water of described initiator and part；Time for adding controls in 0.5～4 little Time, during dropping, temperature controls at 85～100 DEG C；
(3) insulation reaction 1～5 hours again after adding, be subsequently added into the water of surplus, and discharging after stirring 0.5 hour obtains institute State color fixing agent.
Compared with prior art, the present invention has a following remarkable result:
1, by introduce amino, ether, containing silicon structure isoreactivity group, make color fixing agent in use, can be with dye Material, the active group (such as hydroxyl, amino etc.) of fiber molecule crosslink combination, thus reduce the dyestuff compatibility to water, carry The wet colour fastnesses such as the soaping of high dyed fabric, staining.Additionally, molecule has quaternary ammonium salt cationic group, pass through cation , there is Coulomb attraction effect, neutralize its electric charge in the anion such as the sulfonic group of base and reactive dye (including its hydrolised dye), reduces The water solubility of dyestuff, and be combined with dye anion, increase the active force between dye molecule and fiber molecule, to improve wet jail Degree.
2, the formaldehydeless pollution of prepared color fixing agent, effectively reduces fabric formaldehyde content, promotes the quality of fabric, meets Environmental requirement and the health demand of the people, have wide market prospects.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further elaborated on.
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Described silicon-containing monomer is vinyl three (2-methoxy ethoxy) silane, 3-(methacryloxypropyl) propyl group trimethoxy Any one or two kinds in base silane, 3-(methacryloxypropyl) hydroxypropyl methyl dimethoxysilane are with any mixed than mixing Compound.
Described chelating agent is in poly-epoxy succinic acid or poly-aspartate or both are with any mixture than mixing.
Described initiator be in ammonium persulfate, sodium peroxydisulfate or potassium peroxydisulfate any one or two or more with arbitrarily than The mixture of mixing.
The preparation method of a kind of formaldehyde-free color fixing agent for reactive dyes of the present invention, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into described oleic imidazolinone quaternary ammonium Returned cold is opened after salt, trimethyolol propane monoallyl ether, 1,3-diallyl urea, silicon-containing monomer, chelating agent, deionized water Solidifying, stirring, and begin to warm up intensification；
(2) when temperature rises to 85～100 DEG C, then start to drip mass percent concentration be 1～10% initiator molten Liquid, this initiator solution is formulated by the described deionized water of described initiator and part；Time for adding controls in 0.5～4 little Time, during dropping, temperature controls at 85～100 DEG C；
(3) insulation reaction 1～5 hours again after adding, be subsequently added into the water of surplus, and discharging after stirring 0.5 hour obtains institute State color fixing agent.
With specific embodiment, the present invention is described in detail below, but the present invention is not limited only to this.
Embodiment one
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 22 parts of oleic imidazolinone quaternary ammoniums Salt, 2 parts of trimethyolol propane monoallyl ether, 18 parts of 1,3-diallyl ureas, 4 parts of vinyl three (2-methoxy ethoxy) silicon Open reflux condensation mode, stirring after alkane, 1 part of poly-aspartate, 20 parts of deionized waters, and begin to warm up intensification；
(2), when temperature rises to 98 DEG C, then start to drip the ammonium persulfate solution that mass percent concentration is 5%, this mistake Ammonium sulfate is formulated by 1 part of ammonium persulfate and 19 parts of deionized waters；Time for adding controls at 2 hours, temperature during dropping Control at 98 DEG C；
(3) insulation reaction 4 hours again after adding, are subsequently added into the water of surplus, discharging after stirring 0.5 hour, obtain described Color fixing agent.
Embodiment two
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 25 parts of oleic imidazolinone quaternary ammoniums Salt, 4 parts of trimethyolol propane monoallyl ether, 16 parts of 1,3-diallyl ureas, 8 parts of 3-(methacryloxypropyl) propyl group trimethoxies Open reflux condensation mode, stirring after base silane, 1 part of poly-aspartate, 10 parts of deionized waters, and begin to warm up intensification；
(2), when temperature rises to 95 DEG C, then start to drip the sodium peroxydisulfate solution that mass percent concentration is 2%, this mistake Metabisulfite solution is formulated by 0.5 part of sodium peroxydisulfate and 24.5 parts of deionized waters；Time for adding controls at 3 hours, during dropping Temperature controls at 97 DEG C；
(3) insulation reaction 4 hours again after adding, are subsequently added into the water of surplus, discharging after stirring 0.5 hour, obtain described Color fixing agent.
Embodiment three
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 25 parts of oleic imidazolinone quaternary ammoniums Salt, 6 parts of trimethyolol propane monoallyl ether, 14 parts of 1,3-diallyl ureas, 6 parts of 3-(methacryloxypropyl) hydroxypropyl methyl two Open reflux condensation mode, stirring after methoxy silane, 2 parts of poly-epoxy succinic acids, 12 parts of deionized waters, and begin to warm up intensification；
(2), when temperature rises to 90 DEG C, then start to drip the sodium peroxydisulfate solution that mass percent concentration is 4%, this mistake Metabisulfite solution is formulated by 1 part of sodium peroxydisulfate and 24 parts of deionized waters；Time for adding controls at 3.5 hours, temperature during dropping Degree controls at 93 DEG C；
(3) insulation reaction 4.5 hours again after adding, are subsequently added into the water of surplus, and discharging after stirring 0.5 hour obtains institute State color fixing agent.
Embodiment four
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 30 parts of oleic imidazolinone quaternary ammoniums Salt, 8 parts of trimethyolol propane monoallyl ether, 12 parts of 1,3-diallyl ureas, 7 parts of 3-(methacryloxypropyl) hydroxypropyl methyl two Open reflux condensation mode, stirring after methoxy silane, 2.5 parts of poly-epoxy succinic acids, 10 parts of deionized waters, and begin to warm up intensification；
(2), when temperature rises to 97 DEG C, then start to drip the potassium persulfate solution that mass percent concentration is 5%, this mistake Potassium sulfate solution is formulated by 1 part of potassium peroxydisulfate and 19 parts of deionized waters；Time for adding controls at 2.5 hours, temperature during dropping Degree controls at 98 DEG C；
(3) insulation reaction 2.5 hours again after adding, are subsequently added into the water of surplus, and discharging after stirring 0.5 hour obtains institute State color fixing agent.
Embodiment five
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Wherein:
Silicon-containing monomer uses vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) propyl group trimethoxy The mixture of base silane, and vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) propyl trimethoxy silicon The amount ratio of alkane is 1:1, i.e. vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) propyl trimethoxy The consumption of silane is respectively 4 parts and 4 parts.
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 35 parts of oleic imidazolinone quaternary ammoniums Salt, 10 parts of trimethyolol propane monoallyl ether, 10 parts of 1,3-diallyl ureas, 4 parts of vinyl three (2-methoxy ethoxy) Open back after silane, 4 parts of 3-(methacryloxypropyl) propyl trimethoxy silicanes, 1.5 parts of poly-aspartates, 8 parts of deionized waters Stream condensation, stirring, and begin to warm up intensification；
(2), when temperature rises to 92 DEG C, then start to drip the ammonium persulfate solution that mass percent concentration is 5%, this mistake Ammonium sulfate is formulated by 1 part of ammonium persulfate and 19 parts of deionized waters；Time for adding controls at 3 hours, temperature during dropping Control at 99 DEG C；
(3) insulation reaction 4 hours again after adding, are subsequently added into the water of surplus, discharging after stirring 0.5 hour, obtain described Color fixing agent.
Embodiment six
A kind of formaldehyde-free active dye fixing agent of the present invention, is made up of the raw material components of following portions by weight proportioning:
Wherein:
Silicon-containing monomer uses vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) hydroxypropyl methyl two The mixture of methoxy silane, and vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) hydroxypropyl methyl two The amount ratio of methoxy silane is 1:2, i.e. vinyl three (2-methoxy ethoxy) silane and 3-(methacryloxypropyl) propyl group The consumption of methyl dimethoxysilane is respectively 3 parts and 6 parts.
Initiator uses sodium peroxydisulfate and the mixture of potassium peroxydisulfate, and the amount ratio of sodium peroxydisulfate and potassium peroxydisulfate is 1: 2, i.e. the consumption of sodium peroxydisulfate and potassium peroxydisulfate is 0.5 part and 1 part.
Its preparation method, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into 38 parts of oleic imidazolinone quaternary ammoniums Salt, 12 parts of trimethyolol propane monoallyl ether, 8 parts of 1,3-diallyl ureas, 3 parts of vinyl three (2-methoxy ethoxy) silicon Open after alkane, 6 parts of 3-(methacryloxypropyl) hydroxypropyl methyl dimethoxysilane, 2 parts of poly-epoxy succinic acids, 3 parts of deionized waters Reflux condensation mode, stirring, and begin to warm up intensification；
(2) when temperature rises to 95 DEG C, then starting to drip the initiator solution that mass percent concentration is 6%, this causes Agent solution is formulated by 0.5 part of sodium peroxydisulfate and 1 part of potassium peroxydisulfate and 23.5 parts of deionized waters；Time for adding controls 3 little Time, during dropping, temperature controls at 97 DEG C；
(3) insulation reaction 3 hours again after adding, are subsequently added into the water of surplus, discharging after stirring 0.5 hour, obtain described Color fixing agent.
The color fixing agent that above-described embodiment one to six directions becomes is processed respectively the bafta after reactive scarlet 3 grams dyeing, uses The solid technique of leaching, color fixing agent consumption is 2% (o.w.f), and pH is 6～7, and temperature is 60 DEG C, and the time is 30min, bath raio 1:12.Cotton is knitted Main performance index after thing fixation is as shown in table 1.
Table 1 bafta main performance index after above-described embodiment one to six fixation treatment
Remarks:
1. crock fastness method of testing presses GB/T3920-2008 " textile color stability test colour fastness to rubbing " method Measure；
2. soaping fastness method of testing presses the survey of GB/T3921-2008 " textile color stability test color fastness to washing " method Fixed；
3. sweat leaching fastness method of testing presses the survey of GB/T5713-2013 " textile color stability test color fastness to water " method Fixed.
4. control sample is the aldehyde-free colour stabilizer that Guangzhou Zhuan Jie Chemical Co., Ltd. produces, and concentration is 30%.
Described above, only utilize the embodiment of this origination techniques content, any those skilled in the art to use this wound Make modification, the change done, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.

Claims (8)

1. a formaldehyde-free active dye fixing agent, it is characterised in that: include the raw material components of following portions by weight proportioning:
A kind of formaldehyde-free active dye fixing agent the most according to claim 1, it is characterised in that: described silicon-containing monomer is second Thiazolinyl three (2-methoxy ethoxy) silane, 3-(methacryloxypropyl) propyl trimethoxy silicane, 3-(methacryloxypropyl) In hydroxypropyl methyl dimethoxysilane any one or two or more with any than mixing mixture.
A kind of formaldehyde-free active dye fixing agent the most according to claim 2, it is characterised in that: described chelating agent is polycyclic Oxydisuccinic acid or poly-aspartate or both are with any mixture than mixing.
A kind of formaldehyde-free active dye fixing agent the most according to claim 3, it is characterised in that: described initiator is over cure In acid ammonium, sodium peroxydisulfate or potassium peroxydisulfate any one or two or more with any mixture than mixing.
5. according to the preparation method of a kind of formaldehyde-free active dye fixing agent described in Claims 1-4 any claim, its It is characterised by, is achieved by the steps of:
(1) equipped with thermometer, agitator, reflux condenser reactor in be sequentially added into described oleic imidazolinone quaternary ammonium salt, Trimethyolol propane monoallyl ether, 1, after 3-diallyl urea, silicon-containing monomer, chelating agent, deionized water open reflux condensation mode, Stirring, and begin to warm up intensification；
(2), when temperature rises to 85～100 DEG C, then start to drip the initiator solution that mass percent concentration is 1～10%, this Initiator solution is formulated by the described deionized water of described initiator and part；Time for adding controls at 0.5～4 hour, drips Added-time temperature controls at 85～100 DEG C；
(3) insulation reaction 1～5 hours again after adding, be subsequently added into the water of surplus, and discharging after stirring 0.5 hour obtains described solid Toner.
The preparation method of a kind of formaldehyde-free active dye fixing agent the most according to claim 5, it is characterised in that: described contain Silicon monomer is vinyl three (2-methoxy ethoxy) silane, 3-(methacryloxypropyl) propyl trimethoxy silicane, 3- In (methacryloxypropyl) hydroxypropyl methyl dimethoxysilane any one or two or more with any than mixing mixture.
The preparation method of a kind of formaldehyde-free active dye fixing agent the most according to claim 5, it is characterised in that: described chela Mixture be poly-epoxy succinic acid or poly-aspartate or both with any than mixing mixture.
The preparation method of a kind of formaldehyde-free active dye fixing agent the most according to claim 5 is characterized in that: described in draw Send out agent be in ammonium persulfate, sodium peroxydisulfate or potassium peroxydisulfate any one or two or more with any than mixing mixture.
CN201610339473.3A 2016-05-20 2016-05-20 A kind of formaldehyde-free active dye fixing agent and preparation method thereof Active CN105862476B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610339473.3A CN105862476B (en) 2016-05-20 2016-05-20 A kind of formaldehyde-free active dye fixing agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610339473.3A CN105862476B (en) 2016-05-20 2016-05-20 A kind of formaldehyde-free active dye fixing agent and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105862476A true CN105862476A (en) 2016-08-17
CN105862476B CN105862476B (en) 2017-12-22

Family

ID=56635575

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610339473.3A Active CN105862476B (en) 2016-05-20 2016-05-20 A kind of formaldehyde-free active dye fixing agent and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105862476B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106544905A (en) * 2016-12-12 2017-03-29 刘海平 A kind of preparation method and obtained color fixing agent of novel seamless underwear acidic color fixing agent
CN106758411A (en) * 2016-12-07 2017-05-31 郑州源冉生物技术有限公司 A kind of alkaline-resisting environmentally friendly color fixing agent of activity and preparation method thereof
CN108660813A (en) * 2018-07-07 2018-10-16 曾文华 A kind of formaldehyde-free color fixing agent and preparation method thereof
CN112813710A (en) * 2020-12-31 2021-05-18 珠海华大浩宏新材料有限公司 Energy-saving and water-saving dyeing post-treatment auxiliary agent and preparation method thereof
CN113043699A (en) * 2021-03-23 2021-06-29 邢台北人印刷有限公司 Novel biodegradable packaging film for chocolate packaging

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103015239A (en) * 2012-12-29 2013-04-03 福建清源科技有限公司 Polydimethyldiallylammonium chloride modified color fixing agent and preparation method thereof
CN103711011A (en) * 2013-12-27 2014-04-09 福建清源科技有限公司 Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof
CN103709326A (en) * 2013-12-27 2014-04-09 福建清源科技有限公司 Preparation method of cationic organic silicon modified poly(diallyldimethylammonium chloride) fixing agent
CN104562803A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Fabric fixing agent
CN105482032A (en) * 2016-01-20 2016-04-13 广东溢达纺织有限公司 Cationic color fixing agent and preparation method and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103015239A (en) * 2012-12-29 2013-04-03 福建清源科技有限公司 Polydimethyldiallylammonium chloride modified color fixing agent and preparation method thereof
CN103711011A (en) * 2013-12-27 2014-04-09 福建清源科技有限公司 Micro-crosslinking type poly(methacryloxyethyltrimethyl ammonium chloride) modified color fixing agent and preparation method thereof
CN103709326A (en) * 2013-12-27 2014-04-09 福建清源科技有限公司 Preparation method of cationic organic silicon modified poly(diallyldimethylammonium chloride) fixing agent
CN104562803A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Fabric fixing agent
CN105482032A (en) * 2016-01-20 2016-04-13 广东溢达纺织有限公司 Cationic color fixing agent and preparation method and application thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758411A (en) * 2016-12-07 2017-05-31 郑州源冉生物技术有限公司 A kind of alkaline-resisting environmentally friendly color fixing agent of activity and preparation method thereof
CN106544905A (en) * 2016-12-12 2017-03-29 刘海平 A kind of preparation method and obtained color fixing agent of novel seamless underwear acidic color fixing agent
CN106544905B (en) * 2016-12-12 2018-11-02 江西德盛精细化学品有限公司 A kind of preparation method of seamless underwear acidic color fixing agent and color fixing agent obtained
CN108660813A (en) * 2018-07-07 2018-10-16 曾文华 A kind of formaldehyde-free color fixing agent and preparation method thereof
CN112813710A (en) * 2020-12-31 2021-05-18 珠海华大浩宏新材料有限公司 Energy-saving and water-saving dyeing post-treatment auxiliary agent and preparation method thereof
CN113043699A (en) * 2021-03-23 2021-06-29 邢台北人印刷有限公司 Novel biodegradable packaging film for chocolate packaging
CN113043699B (en) * 2021-03-23 2023-01-24 邢台北人印刷有限公司 Biodegradable packaging film for chocolate packaging

Also Published As

Publication number Publication date
CN105862476B (en) 2017-12-22

Similar Documents

Publication Publication Date Title
CN105862476B (en) A kind of formaldehyde-free active dye fixing agent and preparation method thereof
CN105131174B (en) It is common to lasting uvioresistant finishing agent of cotton and terylene and preparation method thereof
CN104892832B (en) A kind of preparation method of micro-cross-linked polymethyl acyloxyethyl trimethyl ammonium chloride modification color fixing agent
CN105951483B (en) A kind of color fixing agent for reactive dyeing and preparation method thereof
CN103696296B (en) A kind of REACTIVE DYES cationic formaldehyde-free fixing agent and preparation method thereof
CN108166241A (en) Cotton knitwear short route dyeing and finishing technology method
CN110230216A (en) A kind of Lyocell fibers fabric of natural dye dying and preparation method thereof
CN106049102A (en) Fabric color fixing agent for clothing and preparation method thereof
CN102995472B (en) Preparation method of textile color fixing agent
CN101503514B (en) Synthesizing method of amino / sulfhydryl co-modified organosilicon polysiloxane
CN109098018A (en) A kind of dyeing used additives and preparation method thereof
CN104452368B (en) A kind of formaldehyde-free color fixing agent for reactive dyes and preparation method thereof
CN105622945A (en) Darkening finishing agent and preparation method thereof
CN104610512A (en) Preparation method of super-soft IPN (interpenetrating polymer network) pigment printing binder
CN107287935A (en) A kind of method for improving natural dye dying performance
CN105603791B (en) A kind of preparation method for the aldehyde-free colour stabilizer of resistance to wet friction
CN105421046A (en) Dyeing and finishing process of underwear fabric
CN106758415B (en) A kind of active dye fixing agent and preparation method thereof
CN102086591A (en) Organic germanium-containing home textile fabric and preparation method thereof
CN103724562A (en) Preparation method of cationic hydrophilic modified amino silicone oil
CN106592277A (en) Dry and wet rubbing fastness improving agent and preparation method thereof
CN108755198B (en) Method for improving level-dyeing property of active blue on cotton fabric
CN107604709B (en) Foaming dye solution for improving foam dyeing color depth and dyeing method thereof
CN109096436A (en) A kind of cation formaldehyde-free color fixing agent and preparation method thereof
CN108532329A (en) A kind of one-bath process softening agent and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190709

Address after: 264500 West Dyeing and Finishing Industrial Park, Rushan City, Weihai City, Shandong Province

Patentee after: Shandong Aiwen Biotechnology Co.,Ltd.

Address before: 362700 6, 905, Po Chang garden, 229 Hui Xing Road, Shishi, Quanzhou, Fujian.

Patentee before: Liu Jianfeng

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Formaldehyde free reactive dye fixing agent and its preparation method

Effective date of registration: 20220711

Granted publication date: 20171222

Pledgee: Postal Savings Bank of China Limited Rushan sub branch

Pledgor: Shandong Aiwen Biotechnology Co.,Ltd.

Registration number: Y2022980010233