CN105860789A - Modified alkyd amino insulating paint and preparation method thereof - Google Patents
Modified alkyd amino insulating paint and preparation method thereof Download PDFInfo
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- CN105860789A CN105860789A CN201610373429.4A CN201610373429A CN105860789A CN 105860789 A CN105860789 A CN 105860789A CN 201610373429 A CN201610373429 A CN 201610373429A CN 105860789 A CN105860789 A CN 105860789A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses modified alkyd amino insulating paint and a preparation method thereof. The modified alkyd amino insulating paint is prepared from the following components proportioned in parts by weight: 13-35 parts of tung oil, 12-45 parts of maleic anhydride, 8-3 parts of adipic acid, 9-21 parts of lauric acid, 6-19 parts of trimethylolpropane, 7-22 parts of ethyl orthosilicate, 3-21 parts of nano silica, 3-16 parts of sodium hydroxide and 23-43 parts of isopropanol. Compared with the prior art, the modified alkyd amino insulating paint disclosed by the invention has the following advantages of quick film drying speed, high rigidity, good water resistance, good corrosion resistance and fine weather resistance.
Description
Technical field
The invention belongs to applied chemistry field, relate to a kind of insullac, particularly relate to a kind of acid modified alcoholic amino insullac and system thereof
Preparation Method.
Background technology
Coating has the history of thousand of years, and it is a kind of multifunctional material, is coated in object surface and plays protection, decorates, indicates
And give the effects such as specific function.From the point of view of the history of coating, before more than 4,000 years, China just uses the sky such as Oleum Verniciae fordii and Resina Toxicodendri verniciflui
So material be raw material to make coating products, coating products kind in early days is single, and range of application has certain limitation, along with
Industrial expansion, the mankind start according to self needs, use various synthetic to make coating, and coating products there occurs huge
Big change, not only classification is various, and Various Functions, coating is widely used and develops.At present, coating products is
Through applying the various aspects in productive life, relate to multiple industries such as automobile anticorrosion, electric insulation, house decoration, military science and technology
And field, the research and development of coating increasingly come into one's own, it may be said that coating with the development of national economy, national science and technology
Prosperity, the raising of living standards of the people has close contact, and it is existing that the level of coatings industry even has become as one country of measurement
One of mark of generationization.
Coating in early days, mainly with natural materials as raw material, prepares paint by relatively simple process, and modern coatings raw material
Complexity, is mainly made up of film forming matter, pigment and three components of solvent, and adds a small amount of auxiliary agent according to actual needs, as dry in urged
Agent, defoamer, levelling agent, antisettling agent, corrosion inhibiter etc..
In coating, film forming matter divides mineral-type and organic, and mineral-type film forming matter uses less, and conventional has silicate, and organic becomes
Film thing uses widely, is mostly some low polymers, such as drying oil, lacquer, synthetic polymer etc., these polymer
All possess a feature: be low polymer before film forming, after film forming, then form polymeric film by certain chemical reaction, poly-
Adduct molecule chain is changed into build by line style.Some coating can also thermoplastic polymer be film forming matter, and solvent volatilization gets final product film forming,
There is not chemical change in polymer, such as chlorinated rubber paint.Film forming matter is the most important composition of coating, and its character directly determines to be coated with
The effect of material.Coating by film forming species can be divided into natural resin paint, alkyd resin coating, amino resin coatings, acrylic resin paint,
Epoxy resin coating, polyurethane, elementary organic paint and rubberbase paint etc., wherein alkyd resin be develop the earliest, synthesis that yield is maximum
Lacquer type organic coating, was once up to 90% in Coating Market occupation rate, and according to statistics, within 1997, national coating total output is 135 × 104T, its
Middle alkyd resin accounts for 52.9%, occupies first of synthetic resin.Alkyd resin, since exploitation, has occupied weight in coatings industry always
The status wanted, because of its abundant raw material source, product variety is many, facilitate chemical modification, is still a kind of important coating tree at present
Fat.
In solvent-borne type insullac, volatile organic content is high, and serious environment pollution, along with enhancing and the environmental protection of environmental protection consciousness
Being gradually improved of regulation, the mankind are more and more higher to the performance requirement of insullac, and low volatile organic or non-volatility Organic substance are exhausted
The research and development of edge paint receive significant attention.The dipping that alkyd resin is widely used to middle-size and small-size low voltage motor electrical equipment as insullac is exhausted
Edge processes, and wherein, aqueous alkide resin is lower than the relative molecular mass of corresponding solvent type resin, and dried coating film is slow, hardness
Low, poor water resistance, corrosion-resistant, weatherability are the best.
Summary of the invention
Present invention solves the technical problem that: in order to overcome defect of the prior art, it is thus achieved that a kind of dried coating film is fast, hardness is high,
The insullac that water-tolerant, good corrosion resistance, weatherability are good, the invention provides a kind of acid modified alcoholic amino insullac and system thereof
Preparation Method.
Technical scheme: a kind of acid modified alcoholic amino insullac, is made up of following components proportioning by weight: Oleum Verniciae fordii 13~35 parts,
Maleic anhydride 12~45 parts, adipic acid 8~23 parts, lauric acid 9~21 parts, trimethylolpropane 6~19 parts, positive silicic acid
Ester 7~22 parts, nano silicon 3~21 parts, sodium hydroxide 3~16 parts, isopropanol 23~43 parts.
Preferably, described acid modified alcoholic amino insullac is made up of following components proportioning by weight: Oleum Verniciae fordii 27 parts, maleic
Dicarboxylic anhydride 38 parts, adipic acid 19 parts, lauric acid 17 parts, trimethylolpropane 16 parts, positive esters of silicon acis 18 parts, nano-silica
SiClx 18 parts, sodium hydroxide 13 parts, isopropanol 37 parts.
The preparation method of a kind of acid modified alcoholic amino insullac, comprises the steps of
(1) prepared by modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon is added in reactor, adds wherein
Enter hydrochloric acid as catalyst, then drip isopropanol as medium, react 3.5~6 hours under the conditions of 42~55 DEG C;
(2) prepared by modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, under the protection of helium, by temperature
Degree rises to 195~212 DEG C, reacts 1.2~3.5 hours;It is added thereto to sodium hydroxide after being cooled to 25~30 DEG C, pH value is adjusted
To 8.2~9, modified tung oil can be obtained;
(3) prepared by modified insullac: maleic anhydride, adipic acid and lauric acid are placed in autoclave, modified tung oil
It is placed in head tank;It is little that autoclave intrinsic pressure is 2.6~3.9MPa, temperature reacts 1.2~3 under the conditions of being 212~314 DEG C
Time, to open head tank, in autoclave, drip modified tung oil, after completion of dropwise addition, 246 DEG C of insulations can obtain and change for 2 hours
Property alcohol acid amido insullac.
Preferably, prepared by step (1) modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon are added reactor
In, it is added thereto to hydrochloric acid as catalyst, then drips isopropanol as medium, react 5 hours under the conditions of 51 DEG C.
Preferably, prepared by step (2) modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, at helium
Under protection, temperature is risen to 203 DEG C, react 2.8 hours;It is added thereto to sodium hydroxide after being cooled to 27 DEG C, pH value is adjusted
To 8.8, modified tung oil can be obtained.
Preferably, prepared by the modified insullac of step (3): maleic anhydride, adipic acid and lauric acid are placed in autoclave
In, modified tung oil is placed in head tank;Autoclave intrinsic pressure is 3.4MPa, temperature reacts 2.6 under the conditions of being 298 DEG C
Hour, to open head tank, in autoclave, drip modified tung oil, after completion of dropwise addition, 246 DEG C of insulations can obtain for 2 hours
Acid modified alcoholic amino insullac.
Beneficial effect: acid modified alcoholic amino insullac dried coating film of the present invention is fast, hardness is high, water-tolerant, corrosion-resistant
Property is good, weatherability is good.
Detailed description of the invention
Embodiment 1
A kind of acid modified alcoholic amino insullac, is made up of following components proportioning by weight: Oleum Verniciae fordii 13 parts, maleic anhydride
12 parts, adipic acid 8 parts, lauric acid 9 parts, trimethylolpropane 6 parts, positive esters of silicon acis 7 parts, nano silicon 3 parts,
Sodium hydroxide 3 parts, isopropanol 23 parts.
The preparation method of a kind of acid modified alcoholic amino insullac, comprises the steps of
(1) prepared by modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon is added in reactor, adds wherein
Enter hydrochloric acid as catalyst, then drip isopropanol as medium, react 3.5 hours under the conditions of 42 DEG C;
(2) prepared by modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, under the protection of helium, by temperature
Degree rises to 195 DEG C, reacts 1.2 hours;It is added thereto to sodium hydroxide after being cooled to 25 DEG C, pH value is adjusted to 8.2,
Obtain modified tung oil;
(3) prepared by modified insullac: maleic anhydride, adipic acid and lauric acid are placed in autoclave, modified tung oil
It is placed in head tank;Autoclave intrinsic pressure is 2.6MPa, temperature is reacted 1.2 hours under the conditions of being 212 DEG C, opens height
Position groove, drips modified tung oil in autoclave, and after completion of dropwise addition, 246 DEG C of insulations can obtain acid modified alcoholic amino in 2 hours
Insullac.
Embodiment 2
A kind of acid modified alcoholic amino insullac, is made up of following components proportioning by weight: Oleum Verniciae fordii 27 parts, maleic anhydride
38 parts, adipic acid 19 parts, lauric acid 17 parts, trimethylolpropane 16 parts, positive esters of silicon acis 18 parts, nano silicon 18
Part, sodium hydroxide 13 parts, isopropanol 37 parts.
The preparation method of a kind of acid modified alcoholic amino insullac, comprises the steps of
(1) prepared by modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon is added in reactor, adds wherein
Enter hydrochloric acid as catalyst, then drip isopropanol as medium, react 5 hours under the conditions of 51 DEG C;
(2) prepared by modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, under the protection of helium, by temperature
Degree rises to 203 DEG C, reacts 2.8 hours;It is added thereto to sodium hydroxide after being cooled to 27 DEG C, pH value is adjusted to 8.8,
Obtain modified tung oil;
(3) prepared by modified insullac: maleic anhydride, adipic acid and lauric acid are placed in autoclave, modified tung oil
It is placed in head tank;Autoclave intrinsic pressure is 3.4MPa, temperature is reacted 2.6 hours under the conditions of being 298 DEG C, opens height
Position groove, drips modified tung oil in autoclave, and after completion of dropwise addition, 246 DEG C of insulations can obtain acid modified alcoholic amino in 2 hours
Insullac.
Embodiment 3
A kind of acid modified alcoholic amino insullac, is made up of following components proportioning by weight: Oleum Verniciae fordii 35 parts, maleic anhydride
45 parts, adipic acid 23 parts, lauric acid 21 parts, trimethylolpropane 19 parts, positive esters of silicon acis 22 parts, nano silicon 21
Part, sodium hydroxide 16 parts, isopropanol 43 parts.
The preparation method of a kind of acid modified alcoholic amino insullac, comprises the steps of
(1) prepared by modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon is added in reactor, adds wherein
Enter hydrochloric acid as catalyst, then drip isopropanol as medium, react 6 hours under the conditions of 55 DEG C;
(2) prepared by modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, under the protection of helium, by temperature
Degree rises to 212 DEG C, reacts 3.5 hours;It is added thereto to sodium hydroxide after being cooled to 30 DEG C, pH value is adjusted to 9, can obtain
Obtain modified tung oil;
(3) prepared by modified insullac: maleic anhydride, adipic acid and lauric acid are placed in autoclave, modified tung oil
It is placed in head tank;Autoclave intrinsic pressure is 3.9MPa, temperature is reacted 3 hours under the conditions of being 314 DEG C, opens a high position
Groove, drips modified tung oil in autoclave, and after completion of dropwise addition, within 2 hours, can to obtain acid modified alcoholic amino exhausted in 246 DEG C of insulations
Edge paint.
The acid modified alcoholic amino insullac preparing embodiment 1~3 carries out performance detection, and result is as shown in the table:
Claims (6)
1. an acid modified alcoholic amino insullac, it is characterised in that be made up of following components proportioning by weight: Oleum Verniciae fordii 13~35
Part, maleic anhydride 12~45 parts, adipic acid 8~23 parts, lauric acid 9~21 parts, trimethylolpropane 6~19 parts,
Positive esters of silicon acis 7~22 parts, nano silicon 3~21 parts, sodium hydroxide 3~16 parts, isopropanol 23~43 parts.
A kind of acid modified alcoholic amino insullac the most according to claim 1, it is characterised in that joined by weight by following components
Ratio is made: Oleum Verniciae fordii 27 parts, maleic anhydride 38 parts, adipic acid 19 parts, lauric acid 17 parts, trimethylolpropane
16 parts, positive esters of silicon acis 18 parts, nano silicon 18 parts, sodium hydroxide 13 parts, isopropanol 37 parts.
3. the preparation method of a kind of acid modified alcoholic amino insullac described in claim 1, it is characterised in that comprise the steps of
(1) prepared by modifying agent: trimethylolpropane, positive esters of silicon acis and nano silicon is added in reactor, adds wherein
Enter hydrochloric acid as catalyst, then drip isopropanol as medium, react 3.5~6 hours under the conditions of 42~55 DEG C;
(2) prepared by modified tung oil: mixed with modifying agent by Oleum Verniciae fordii, adds in vacuum response still, under the protection of helium, by temperature
Degree rises to 195~212 DEG C, reacts 1.2~3.5 hours;It is added thereto to sodium hydroxide after being cooled to 25~30 DEG C, pH value is adjusted
To 8.2~9, modified tung oil can be obtained;
(3) prepared by modified insullac: maleic anhydride, adipic acid and lauric acid are placed in autoclave, modified tung oil
It is placed in head tank;It is little that autoclave intrinsic pressure is 2.6~3.9MPa, temperature reacts 1.2~3 under the conditions of being 212~314 DEG C
Time, to open head tank, in autoclave, drip modified tung oil, after completion of dropwise addition, 246 DEG C of insulations can obtain and change for 2 hours
Property alcohol acid amido insullac.
The preparation method of a kind of acid modified alcoholic amino insullac the most according to claim 3, it is characterised in that step (1) changes
Property agent prepare: trimethylolpropane, positive esters of silicon acis and nano silicon are added in reactor, are added thereto to hydrochloric acid and make
For catalyst, then drip isopropanol as medium, react 5 hours under the conditions of 51 DEG C.
The preparation method of a kind of acid modified alcoholic amino insullac the most according to claim 3, it is characterised in that step (2) changes
Property Oleum Verniciae fordii prepare: Oleum Verniciae fordii is mixed with modifying agent, adds in vacuum response still, under the protection of helium, temperature is risen to
203 DEG C, react 2.8 hours;It is added thereto to sodium hydroxide after being cooled to 27 DEG C, pH value is adjusted to 8.8, can obtain
Modified tung oil.
The preparation method of a kind of acid modified alcoholic amino insullac the most according to claim 3, it is characterised in that step (3) changes
Prepared by property insullac: maleic anhydride, adipic acid and lauric acid being placed in autoclave, modified tung oil is placed in a high position
In groove;Autoclave intrinsic pressure is 3.4MPa, temperature is reacted 2.6 hours under the conditions of being 298 DEG C, opens head tank,
Dripping modified tung oil in autoclave, after completion of dropwise addition, 246 DEG C of insulations can obtain the insulation of acid modified alcoholic amino for 2 hours
Paint.
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CN201610373429.4A CN105860789A (en) | 2016-05-31 | 2016-05-31 | Modified alkyd amino insulating paint and preparation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724335A (en) * | 2009-11-30 | 2010-06-09 | 合肥工业大学 | Method for preparing tung oil-modified water-based insulating paint |
CN102432851A (en) * | 2011-09-06 | 2012-05-02 | 天长市开林化工有限公司 | Liquid alkyd resin and preparation method thereof |
CN104086761A (en) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | Aqueous organosilicone-modified alkyd resin and preparing method thereof |
-
2016
- 2016-05-31 CN CN201610373429.4A patent/CN105860789A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724335A (en) * | 2009-11-30 | 2010-06-09 | 合肥工业大学 | Method for preparing tung oil-modified water-based insulating paint |
CN102432851A (en) * | 2011-09-06 | 2012-05-02 | 天长市开林化工有限公司 | Liquid alkyd resin and preparation method thereof |
CN104086761A (en) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | Aqueous organosilicone-modified alkyd resin and preparing method thereof |
Non-Patent Citations (1)
Title |
---|
贺楠男等: "硅树脂改性桐油醇酸树脂水性绝缘漆的研究", 《涂料工业》 * |
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Application publication date: 20160817 |