CN105860734A - Waterproof colorful coating and preparation method thereof - Google Patents
Waterproof colorful coating and preparation method thereof Download PDFInfo
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- CN105860734A CN105860734A CN201610412153.6A CN201610412153A CN105860734A CN 105860734 A CN105860734 A CN 105860734A CN 201610412153 A CN201610412153 A CN 201610412153A CN 105860734 A CN105860734 A CN 105860734A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a waterproof colorful coating and a preparation method thereof. The waterproof colorful coating is mainly prepared from epoxy resin, methacrylic acid, acetoacetoxy ethyl methacrylate and chitosan, resin pre-emulsification and self-crosslinking are performed, and the main raw materials are mixed with additives to prepare the waterproof colorful coating. All pigment microdroplets are uniform in dispersion, clear in boundary, free of mixing when stirred, good in stability, free of bleeding and diffusion, capable of being stored for as long as 18 months and free of agglomeration when stored for a long time. The coating is bright in color, high in stereoscopic sensation and high in strength. The waterproof colorful coating is easy to prepare, the raw materials are easy to obtain, construction is convenient, the contact angle of the coating and water is large, the waterproof effect is good, water drops can easily flow downwards along the surface, the hydrophobic life is long, strength is high, and the waterproof colorful coating is applicable to the fields of surface treatment for common metal (aluminum, copper, steel and the like), building materials, glass and the like and has universality in the field of common industrial and life materials.
Description
Technical field
The invention belongs to external coating technical field, relate to a kind of water-repellent paint, particularly to a kind of waterproof multicolor finish and preparation method thereof.
Background technology
Multicolor finish is that two or more aqueous colored particle is suspended in aqueous interlayer, by once spraying the coating producing multicolour, is used for skin decoration at present, copys stone effect, therefore also known as liquid stone.
The building coatings such as conventional acrylic coating, styrene-acrylic coating are all the coating products of single-phase, a monochromatic even property, product quality is more stable, coating uniform, and multicolor finish is polychrome, heterogeneous mix particles coexists, the stability of product quality, weather-proof water proofing property of coating etc. is it is possible to there are many problems to produce.Coating water-proof weak effect, water droplet is stayed coating surface for a long time, can be had an impact the life-span of coating, and be easy to enter along gap inside, and then destroys internal structure.
Summary of the invention
The present invention is directed to the above-mentioned shortcomings that existing technology exists, have developed a kind of, waterproof multicolor finish that water resistance good big with water contact angle.
Present invention also offers the preparation method of described waterproof multicolor finish.
Technical solution of the present invention is as follows:
A kind of waterproof multicolor finish, raw material weight proportioning is as follows:
Epoxy resin 80 parts,
Methacrylic acid 80 parts,
AAEM 80 parts,
Chitosan 80 parts,
Dimethyl adipate 7-10 part,
Pigment 1-10 part,
Fructus Gleditsia carbohydrate gum 10-12 part,
Dichloromethane 14-18 part,
Xanthan gum 15-20 part,
Ammonium persulfate. 4.0-6.0 part,
Potassium peroxydisulfate 2.0-3.5 part,
Anionic polycarboxylate's dipersant 4.2-6.5 part,
Nanometer zinc ferrite 6.0-8.0 part,
Universal superfine alumina silicate 37.8-39 part,
Nanometer cobalt 0.7-1.0 part,
Silicon dioxide 2.5-3.0 part,
Lecithin 8.9-10 part,
120 parts of water.
Described universal superfine alumina silicate is 3000 mesh.
The preparation method of above-mentioned waterproof multicolor finish, step includes:
1) respectively by epoxy resin, methacrylic acid and 20 parts of water mixing, the most under stirring at room temperature, dropwise drip AAEM, time for adding is 30-40min, continue stirring 1-1.5h, obtain epoxy resin-methacrylic acid-AAEM solution, standby；
2) by dimethyl adipate, Ammonium persulfate., potassium peroxydisulfate mix homogeneously, what 1-2h was added drop-wise to is warming up in the epoxy resin-methacrylic acid-AAEM solution of 80-82 DEG C, 80-82 DEG C of stirring 1.5-2h, the ammonia of dropping 0.1mol/L adjusts PH7-8, is subsequently adding chitosan stirring 1h；
3) to step 2) solution adds anionic polycarboxylate's dipersant, nanometer zinc ferrite, universal superfine alumina silicate, nanometer cobalt, silicon dioxide, lecithin and remaining water, being dispersed to fineness is less than 10 microns, stirs, and obtains dispersion liquid, standby；
4) take various pigments respectively, be dissolved in dichloromethane, be subsequently adding Fructus Gleditsia sugar and xanthan gum, mix homogeneously, obtain colorant, standby；
5) being sprayed respectively by the colorant of step 4) shades of colour with high-pressure injector is fine mist, the dispersion liquid simultaneously step 3) prepared uses swirl injector, spray for fine mist, the microdroplet of above two fine mist uniformly mixes in descent, dispersion liquid is wrapped in colorant droplet surface, form stable granule, after particle aggregation, obtain waterproof multicolor finish.
In step 4), described pigment is two or more water-fast organic or inorganic pigment, the preferred metal of inorganic pigment, metal-oxide, metal hydroxides, sulfate, phosphate etc.；The preferred AZOpigments of organic pigment, phthalocyanine color, anthraquinone etc..
The waterproof multicolor finish coating that the present invention prepares and water contact angle are 155o~165o。
The waterproof multicolor finish of the present invention, with epoxy resin, methacrylic acid, AAEM, chitosan etc. as primary raw material, by resin pre-emulsification, self-crosslinking, and is mixed with auxiliary agent and obtains.Each colorant microdroplet dispersion is uniform, clear-cut, unmixing during stirring, good stability, nonbleeding, indiffusion, and the phase that stores was up to 18 months, and long term storage is without caking.The vivid third dimension of patterns of coating color is strong, and intensity is high.The waterproof multicolor finish preparation of the present invention is simple, raw material is easy to get, easy construction, big with water contact angle, good water-proof effect, the globule is easy to flow down along surface, the hydrophobic life-span is long, intensity is high, it is adaptable to the fields such as the surface process of common metal (aluminum, copper, steel etc.), construction material, glass etc., has the universality of common industry life Material Field.
Detailed description of the invention
Below will by embodiment, the invention will be further described, these descriptions are not to be further limited present invention.It should be understood by those skilled in the art that the equivalent that present invention is made, or be correspondingly improved, within still falling within protection scope of the present invention.
Embodiment 1:
A kind of waterproof multicolor finish, raw material weight proportioning is as follows:
Epoxy resin 80 parts,
Methacrylic acid 80 parts,
AAEM 80 parts,
Chitosan 80 parts,
Dimethyl adipate 8.5 parts,
Pigment 3 parts (titanium white 1 part, iron oxide yellow 1 part, iron oxide red 1 part),
Fructus Gleditsia carbohydrate gum 11 parts,
Dichloromethane 16 parts,
Xanthan gum 18 parts,
Ammonium persulfate. 5.0 parts,
Potassium peroxydisulfate 2.8 parts,
Anionic polycarboxylate's dipersant 5.5 parts,
Nanometer zinc ferrite 7.0 parts,
Universal superfine alumina silicate 38.6 parts,
Nanometer cobalt 0.9 part,
Silicon dioxide 2.7 parts,
9.2 parts of lecithin,
120 parts of water.
Described superfine alumina silicate is 3000 mesh.
Preparation method, step includes:
1) respectively by epoxy resin, methacrylic acid and 20 parts of water mixing, the most under stirring at room temperature, AAEM is dropwise dripped, time for adding is 35min, continue stirring 1h, obtain epoxy resin-methacrylic acid-AAEM solution, standby；
2) by dimethyl adipate, Ammonium persulfate., potassium peroxydisulfate mix homogeneously, what 1-2h was added drop-wise to is warming up in the epoxy resin-methacrylic acid-AAEM solution of 80-82 DEG C, 80-82 DEG C of stirring 1.5h, the ammonia of dropping 0.1mol/L adjusts PH7-8, is subsequently adding chitosan stirring 1h；
3) to step 2) solution adds anionic polycarboxylate's dipersant, nanometer zinc ferrite, universal superfine alumina silicate 37.8-39,
Nanometer cobalt, silicon dioxide, lecithin and remaining water, being dispersed to fineness is less than 10 microns, stirs, and obtains dispersion liquid, standby；
4) taking titanium white, iron oxide yellow, iron oxide red respectively, dichloromethane, Fructus Gleditsia sugar, xanthan gum are divided into three parts, are dissolved separately in dichloromethane by each pigment, are subsequently adding Fructus Gleditsia sugar and xanthan gum, mix homogeneously, obtain colorant, standby；
5) being sprayed respectively by the colorant of step 4) shades of colour with high-pressure injector is fine mist, the dispersion liquid simultaneously step 3) prepared uses swirl injector, spray for fine mist, the microdroplet of above two fine mist uniformly mixes in descent, dispersion liquid is wrapped in colorant droplet surface, form stable granule, after particle aggregation, obtain waterproof multicolor finish.
Waterproof multicolor finish embodiment 1 prepared is applied on aluminium flake, and the vivid third dimension of patterns of coating color is strong.Take 4 μ L water to drip gently on the coating surface, then carry out the measurement of contact angle with contact angle instrument.Coating and water contact angle are 157o, water droplet is present on matrix surface with subglobular, rolls down the most under gravity, reaches waterproof effect.Coating soak in water 60 days unchanged, soak in alkali liquor 40 days unchanged；Storing 18 months, product is without caking, unmixing.
Embodiment 2:
A kind of waterproof multicolor finish, raw material weight proportioning is as follows:
Epoxy resin 80 parts,
Methacrylic acid 80 parts,
AAEM 80 parts,
Chitosan 80 parts,
Dimethyl adipate 7 parts,
Pigment 4 parts (titanium white 1 part, iron oxide yellow 1 part, iron oxide red 1 part, rhodamine 6G 1 part),
Fructus Gleditsia carbohydrate gum 10 parts,
Dichloromethane 14 parts,
Xanthan gum 15 parts,
Ammonium persulfate. 4.0 parts,
Potassium peroxydisulfate 2.0 parts,
Anionic polycarboxylate's dipersant 4.2 parts,
Nanometer zinc ferrite 6.0 parts,
Universal superfine alumina silicate 37.8 parts,
Nanometer cobalt 0.7 part,
Silicon dioxide 2.5 parts,
8.9 parts of lecithin,
120 parts of water.
Described superfine alumina silicate is 3000 mesh.
Preparation method, step is with embodiment 1.
Waterproof multicolor finish embodiment 2 prepared is applied on potsherd, and the vivid third dimension of patterns of coating color is strong.Take 4 μ L water to drip gently on the coating surface, then carry out the measurement of contact angle with contact angle instrument.Coating and water contact angle are 155o, water droplet is present on matrix surface with subglobular, rolls down the most under gravity, reaches waterproof effect.Coating soak in water 60 days unchanged, soak in alkali liquor 40 days unchanged；Storing 18 months, product is without caking, unmixing.
Embodiment 3:
A kind of waterproof multicolor finish, raw material weight proportioning is as follows:
Epoxy resin 80 parts,
Methacrylic acid 80 parts,
AAEM 80 parts,
Chitosan 80 parts,
Dimethyl adipate 10 parts,
Pigment 4 parts (titanium white 1 part, iron oxide yellow 1 part, iron oxide red 1 part, Fast Blue BB base 1 part),
Fructus Gleditsia carbohydrate gum 12 parts,
Dichloromethane 18 parts,
Xanthan gum 20 parts,
Ammonium persulfate. 6.0 parts,
Potassium peroxydisulfate 3.5 parts,
Anionic polycarboxylate's dipersant 6.5 parts,
Nanometer zinc ferrite 8.0 parts,
Universal superfine alumina silicate 39 parts,
Nanometer cobalt 1.0 parts,
Silicon dioxide 3.0 parts,
10 parts of lecithin,
120 parts of water.
Described superfine alumina silicate is 3000 mesh.
Preparation method, step is with embodiment 1.
Waterproof multicolor finish embodiment 3 prepared is applied on sheet glass, and the vivid third dimension of patterns of coating color is strong.Take 4 μ L water to drip gently on the coating surface, then carry out the measurement of contact angle with contact angle instrument.Coating and water contact angle are 165o, water droplet is present on matrix surface with subglobular, rolls down the most under gravity, reaches waterproof effect.Coating soak in water 60 days unchanged, soak in alkali liquor 40 days unchanged；Storing 18 months, product is without caking, unmixing.
Comparative example 1: commercially available common multicolor finish
It is applied on aluminium flake, takes 4 μ L water and drip gently on the coating surface, then carry out the measurement of contact angle with contact angle instrument.Coating and water contact angle are less than 90 o, water droplet is easily attached on matrix surface, without waterproof effect.Coating soak in alkali liquor 16 days unchanged；After storing 18 months, product has caking, and pigment is miscible.
Claims (5)
1. a waterproof multicolor finish, it is characterised in that raw material weight proportioning is as follows:
Epoxy resin 80 parts,
Methacrylic acid 80 parts,
AAEM 80 parts,
Chitosan 80 parts,
Dimethyl adipate 7-10 part,
Pigment 1-10 part,
Fructus Gleditsia carbohydrate gum 10-12 part,
Dichloromethane 14-18 part,
Xanthan gum 15-20 part,
Ammonium persulfate. 4.0-6.0 part,
Potassium peroxydisulfate 2.0-3.5 part,
Anionic polycarboxylate's dipersant 4.2-6.5 part,
Nanometer zinc ferrite 6.0-8.0 part,
Universal superfine alumina silicate 37.8-39 part,
Nanometer cobalt 0.7-1.0 part,
Silicon dioxide 2.5-3.0 part,
Lecithin 8.9-10 part,
120 parts of water；
Described universal superfine alumina silicate is 3000 mesh.
Waterproof multicolor finish the most according to claim 1, it is characterised in that: coating and water contact angle are 155o-165o。
3. the preparation method of the waterproof multicolor finish described in a claim 1, it is characterised in that step includes:
1) respectively by epoxy resin, methacrylic acid and 20 parts of water mixing, the most under stirring at room temperature, dropwise drip AAEM, time for adding is 30-40min, continue stirring 1-1.5h, obtain epoxy resin-methacrylic acid-AAEM solution, standby；
2) by dimethyl adipate, Ammonium persulfate., potassium peroxydisulfate mix homogeneously, what 1-2h was added drop-wise to is warming up in the epoxy resin-methacrylic acid-AAEM solution of 80-82 DEG C, 80-82 DEG C of stirring 1.5-2h, the ammonia of dropping 0.1mol/L adjusts PH7-8, is subsequently adding chitosan stirring 1h；
3) to step 2) solution adds anionic polycarboxylate's dipersant, nanometer zinc ferrite, universal superfine alumina silicate, nanometer cobalt, silicon dioxide, lecithin and remaining water, being dispersed to fineness is less than 10 microns, stirs, and obtains dispersion liquid, standby；
4) take various pigments respectively, be dissolved in dichloromethane, be subsequently adding Fructus Gleditsia sugar and xanthan gum, mix homogeneously, obtain colorant, standby；
5) being sprayed respectively by the colorant of step 4) shades of colour with high-pressure injector is fine mist, the dispersion liquid simultaneously step 3) prepared uses swirl injector, spray for fine mist, the microdroplet of above two fine mist uniformly mixes in descent, dispersion liquid is wrapped in colorant droplet surface, form stable granule, after particle aggregation, obtain waterproof multicolor finish.
Preparation method the most according to claim 3, it is characterised in that: in step 4), described pigment is two or more water-fast organic or inorganic pigment.
Preparation method the most according to claim 4, it is characterised in that: inorganic pigment is metal, metal-oxide, metal hydroxides, sulfate or phosphate；Organic pigment is AZOpigments, phthalocyanine color or anthraquinone.
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| CN201610412153.6A CN105860734A (en) | 2016-06-13 | 2016-06-13 | Waterproof colorful coating and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916328A (en) * | 2017-04-20 | 2017-07-04 | 聪缙电子（昆山）有限公司 | Plastic parts table applies colouring processing method |
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| CN1165168A (en) * | 1995-11-27 | 1997-11-19 | 固特异轮胎和橡胶公司 | Aqueous multicolor paint |
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2016
- 2016-06-13 CN CN201610412153.6A patent/CN105860734A/en active Pending
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| CN1281016A (en) * | 1999-07-20 | 2001-01-24 | 罗姆和哈斯公司 | Polymer-pigment compound |
| CN101328272A (en) * | 2007-06-20 | 2008-12-24 | 关西涂料株式会社 | Granulated gel, preparing method, preparing apparatus and preparing method of multicolor pattern paint |
| CN103649249A (en) * | 2011-04-27 | 2014-03-19 | 关西涂料株式会社 | Aqueous multicolor coating composition |
| CN103184786A (en) * | 2013-03-25 | 2013-07-03 | 新疆红山涂料有限公司 | Method for using waterborne multicolor coating and solvent-free epoxy terrace coating in combination |
| CN104845478A (en) * | 2015-05-27 | 2015-08-19 | 浙江大学自贡创新中心 | Water-based light-emitting multicolor paint and preparation method thereof |
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| Title |
|---|
| 迟玉杰: "《蛋制品加工技术》", 31 January 2009, 中国轻工业出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106916328A (en) * | 2017-04-20 | 2017-07-04 | 聪缙电子（昆山）有限公司 | Plastic parts table applies colouring processing method |
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