CN105860608A - Water-soluble high-temperature-resistant radiation-resistant paint and preparation method thereof - Google Patents

Water-soluble high-temperature-resistant radiation-resistant paint and preparation method thereof Download PDF

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Publication number
CN105860608A
CN105860608A CN201610263487.1A CN201610263487A CN105860608A CN 105860608 A CN105860608 A CN 105860608A CN 201610263487 A CN201610263487 A CN 201610263487A CN 105860608 A CN105860608 A CN 105860608A
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China
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parts
water
powder
high temperature
radiation shielding
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CN201610263487.1A
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Inventor
高德峰
牛彦鹏
李会芹
刘超
刘朝中
赵保强
于旺堂
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Huanghe Science and Technology College
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Huanghe Science and Technology College
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Priority to CN201610263487.1A priority Critical patent/CN105860608A/en
Publication of CN105860608A publication Critical patent/CN105860608A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

Abstract

The invention provides a water-soluble high-temperature-resistant radiation-resistant paint which comprises the following raw materials in parts by weight: 8-12 parts of aluminasol, 10-15 parts of expanded graphite, 5-10 parts of carbon nanotube, 1-5 parts of titanium white, 0.5-3 parts of hydroxypropyl methylcellulose, 8-14 parts of glass powder, 5-10 parts of talcum powder, 10-15 parts of kaolin powder, 10-15 parts of wollastonite powder, 1-5 parts of bicyclopentenyloxyethyl acrylate and 20-30 parts of water. The invention also provides a preparation method of the water-soluble high-temperature-resistant radiation-resistant paint. Various components in the water-soluble high-temperature-resistant radiation-resistant paint interact and complement each other's advantages, so that the paint has the characteristics of excellent corrosion resistance, excellent radiation resistance, excellent mold resistance, excellent flame retardancy, excellent high temperature resistance, excellent crack resistance, excellent rust resistance, excellent cold-heat alternation resistance, high storage stability and the like.

Description

Water solublity is high temperature resistant radiation shielding coating and preparation method thereof
Technical field
The invention belongs to technical field of coatings, particularly relate to a kind of high temperature resistant radiation shielding coating of water solublity and preparation method thereof.
Background technology
Radiation proof material has become a big problem of current material subject, and along with appearance and the extensively application of various high radiation devices, the research of radiation proof material has caused the common concern of people.The Fukushima nuclear power station crisis that the Japanese violent earthquake on March 11st, 2011 is caused, has also caused people's worry to radioprotective;And various radiation sources exist in people's life, also force people's attention to radiation proof material;Radiation is classified as the fourth-largest environomental pollution source after water source, air, noise by World Health Organization (WHO), becomes the stealth " killer " of harm human health, and protection radiation has become the task of top priority.
At present, radiation shielding coating mostly uses and adds heavy metal or rare metal powder and oxide thereof in coating composition, especially containing metallic compounds such as Ba, Pb, U, Lu, or employing composite deposite, but inevitable also bringing constructional difficulties, adhesive force is inadequate, the function defect such as not simultaneously, thus radiation shielding coating is the most only applied at some special industries and special dimension, and apply less in the field such as life of people.
Therefore the radiation shielding coating of the additional properties that exploitation has other concurrently becomes the task of top priority;The radiation shielding coating with other additional properties can meet the basic function of coating, widens again its application, also complies with that coating is multi-functional, the requirement of multi-field development.
Summary of the invention
In view of this, a kind of high temperature resistant radiation shielding coating of water solublity of necessary offer and preparation method thereof, to overcome the problems referred to above.
The present invention provides a kind of high temperature resistant radiation shielding coating of water solublity, and it includes the raw material of following weight portion: Alumina gel 8~12 parts, expanded graphite 10~15 parts, CNT 5~10 parts, titanium dioxide 1~5 parts, hydroxypropyl methyl cellulose 0.5~3 parts, glass dust 8~14 parts, Pulvis Talci 5~10 parts, kaolin powder 10~15 parts, wollastonite in powder 10~15 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 1~5 parts and water 20~30 parts.
Wherein, described Alumina gel be a kind of pH value be 5~7, particle size analysis is at 60 ran, preferable, translucent to the transparent thick gel of the transparency, micelle microstructure in this Alumina gel is featheriness, positively charged, nontoxic, odorless, non-volatile, non-combustible, generate activated alumina or high purity aluminium oxide after high temperature dehydration.Described kaolin powder is preferably calcined kaolin.The granularity of described wollastonite in powder is preferably 325 purposes compared with fine fraction and the fine level of 10 μm.
Based on above-mentioned, it includes the raw material of following weight portion: Alumina gel 9~11 parts, expanded graphite 12~14 parts, CNT 7~9 parts, titanium dioxide 2~4 parts, hydroxypropyl methyl cellulose 1~2 parts, glass dust 10~12 parts, Pulvis Talci 7~9 parts, kaolin powder 12~14 parts, wollastonite in powder 11~14 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2~3 parts and water 23~27 parts.
Based on above-mentioned, it includes the raw material of following weight portion: Alumina gel 10 parts, expanded graphite 17 parts, 11 parts of glass dust, Pulvis Talci 8 parts, kaolin powder 13 parts, wollastonite in powder 13 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2 parts and 25 parts of water.
The present invention also provides for the preparation method of a kind of high temperature resistant radiation shielding coating of above-mentioned water solublity, and it comprises the following steps:
Under conditions of 40~80 DEG C, Alumina gel, expanded graphite and water are uniformly mixed, form the first mixed solution;
Glass dust, Pulvis Talci, wollastonite in powder and kaolin powder are joined in described first mixed solution, and ultrasonic disperse 30~40 minutes, obtain the second mixed solution;
CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and ultrasonic agitation 1~2 hours under conditions of 40~80 DEG C, prepare the high temperature resistant radiation shielding coating of described water solublity.
At the high temperature resistant radiation shielding coating of above-mentioned water solublity, expanded graphite not only remains the advantageous properties such as high temperature resistant, corrosion-resistant, radiation hardness, the electric conductivity of native graphite, but also has the characteristics such as flexibility, resilience, autohension, impermeability, adsorptivity and low-density.CNT is the particle diameter a kind of one-dimensional material at 10~50 nm, has the performances such as excellent heat-conductivity conducting and electronic shield.The diameter of titanium dioxide is below 100 nanometers, and product appearance is fluffy white powder;There is the performance such as anti-line, antibacterial, self-cleaning, aging resistance, weatherability.Expanded graphite, CNT and titanium dioxide interact at dispersant so that described environment-friendly type thermostable radiation shielding coating has fire-retardant, radioprotective and the function such as antibacterial.Hydroxypropyl methyl cellulose primarily serves the effect of dispersant, additionally has the features such as the low ashes of salt tolerance, pH stability, water-retaining property, dimensional stability, excellent film property and the most resistance to enzyme, thickening property and caking property.Acrylic acid double cyclopentenyl oxygen ethyl ester can carry out being polymerized and cross-linking as coalescents in the environment of film forming automatically, becomes a composition part for paint film, it is possible to makes up volume contraction in film forming procedure compared with problem big, that paint film is easy to crack.
Glass dust, Pulvis Talci, wollastonite in powder and kaolin powder are mainly used as the implant of the high temperature resistant radiation shielding coating of above-mentioned water solublity.Glass dust is white powder, has the advantages such as transparency good, hardness is high, even particle size distribution, good dispersion, and paint film is good without blue light, recoatability, improves the anti scuffing performance of paint film, has photoextinction, can improve the weatherability of paint film.Pulvis Talci linear expansion coefficient is the biggest, the coefficient of expansion brushing base material close to the high temperature resistant radiation shielding coating of described water solublity, but its volumetric expansion dilution is the least, the most talcous interpolation can change the linear expansion coefficient of coating, anti-be full of cracks performance under the alternating hot and cold performance of raising coating and high temperature, sedimentation when coating stores can be slowed down simultaneously, and coating flowing hanging can be prevented, improve the resistance to water of film, wearability.Kaolin powder can improve the opacity of coating, the fastness of film, abrasion resistance and resistance to chalking.Wollastonite in powder acts primarily as covering, incremental contribution in coating, can reduce the cost of paint, the most also have anticorrosion, antirust, make white paint keep the functions such as permanent bright tone.
Therefore, cooperate between each component in the high temperature resistant radiation shielding coating of water solublity that the present invention provides, have complementary advantages, on the premise of making this coating keep good adhesion and environmental-protecting performance, there is the characteristics such as the anticorrosion of excellence, anti-radiation and antibacterial, fire-retardant, tolerance high temperature, anti-be full of cracks, cold-hot alternation, storage stability, have a extensive future at special dimensions such as petroleum and petrochemical industry, metallurgy, electric power, national defence.The preparation method of the high temperature resistant radiation shielding coating of above-mentioned water solublity that the present invention provides is easy and simple to handle, easily realizes.
Detailed description of the invention
Below by detailed description of the invention, technical scheme is described in further detail.
Embodiment 1
The embodiment of the present invention 1 provides a kind of high temperature resistant radiation shielding coating of water solublity, it includes the raw material of following weight portion: Alumina gel 8 parts, expanded graphite 10 parts, CNT 5 parts, titanium dioxide 1 part, hydroxypropyl methyl cellulose 0.5 part, 8 parts of glass dust, Pulvis Talci 5 parts, kaolin powder 10 parts, wollastonite in powder 10 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 1 part and 20 parts of water, wherein, each raw material in this embodiment is technical grade.
Preparation method: under conditions of 40 DEG C, uniformly mixes Alumina gel, expanded graphite and water, forms the first mixed solution;Glass dust, Pulvis Talci, wollastonite in powder and kaolin powder are joined in described first mixed solution, and ultrasonic disperse 30 minutes, obtain the second mixed solution;CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and under conditions of 40 DEG C ultrasonic agitation 1 hour, prepare the high temperature resistant radiation shielding coating of water solublity described in the present embodiment.
Embodiment 2
The embodiment of the present invention 2 provides a kind of high temperature resistant radiation shielding coating of water solublity, it includes the raw material of following weight portion: Alumina gel 9 parts, expanded graphite 12 parts, CNT 7 parts, titanium dioxide 2 parts, hydroxypropyl methyl cellulose 1 part, 10 parts of glass dust, Pulvis Talci 7 parts, kaolin powder 12 parts, wollastonite in powder 11 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2 parts and 23 parts of water, wherein, each raw material in this embodiment is technical grade.
Preparation method: under conditions of 50 DEG C, uniformly mixes Alumina gel, expanded graphite and water, forms the first mixed solution;Glass dust, Pulvis Talci, wollastonite in powder and kaolin powder are joined in described first mixed solution, and ultrasonic disperse 30 minutes, obtain the second mixed solution;CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and under conditions of 50 DEG C ultrasonic agitation 1.5 hours, prepare the high temperature resistant radiation shielding coating of water solublity described in the present embodiment.
Embodiment 3
The embodiment of the present invention 3 provides a kind of high temperature resistant radiation shielding coating of water solublity, it includes the raw material of following weight portion: Alumina gel 10 parts, expanded graphite 13 parts, CNT 8 parts, titanium dioxide 3 parts, hydroxypropyl methyl cellulose 1.5 parts, 11 parts of glass dust, Pulvis Talci 8 parts, kaolin powder 13 parts, wollastonite in powder 13 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2 parts and 25 parts of water, wherein, each raw material in this embodiment is technical grade.
Preparation method: under conditions of 60 DEG C, uniformly mixes Alumina gel, expanded graphite and water, forms the first mixed solution;Glass dust, kaolin powder, wollastonite in powder and Pulvis Talci are joined in described first mixed solution, and ultrasonic disperse 35 minutes, obtain the second mixed solution;CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and under conditions of 60 DEG C ultrasonic agitation 1.5 hours, prepare the high temperature resistant radiation shielding coating of water solublity described in the present embodiment.
Embodiment 4
The embodiment of the present invention 4 provides a kind of high temperature resistant radiation shielding coating of water solublity, it includes the raw material of following weight portion: Alumina gel 11 parts, expanded graphite 14 parts, CNT 9 parts, titanium dioxide 4 parts, hydroxypropyl methyl cellulose 2 parts, 12 parts of glass dust, Pulvis Talci 9 parts, kaolin powder 14 parts, wollastonite in powder 14 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 3 parts and 27 parts of water, wherein, each raw material in this embodiment is technical grade.
Preparation method: under conditions of 70 DEG C, uniformly mixes Alumina gel, expanded graphite and water, forms the first mixed solution;Glass dust, wollastonite in powder, kaolin powder and Pulvis Talci are joined in described first mixed solution, and ultrasonic disperse 40 minutes, obtain the second mixed solution;CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and under conditions of 70 DEG C ultrasonic agitation 2 hours, prepare the high temperature resistant radiation shielding coating of water solublity described in the present embodiment.
Embodiment 5
The embodiment of the present invention 5 provides a kind of high temperature resistant radiation shielding coating of water solublity, it includes the raw material of following weight portion: Alumina gel 12 parts, expanded graphite 15 parts, CNT 10 parts, titanium dioxide 5 parts, hydroxypropyl methyl cellulose 3 parts, 14 parts of glass dust, Pulvis Talci 10 parts, kaolin powder 15 parts, wollastonite in powder 15 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 5 parts and 30 parts of water, wherein, each raw material in this embodiment is technical grade.
Preparation method: under conditions of 80 DEG C, uniformly mixes Alumina gel, expanded graphite and water, forms the first mixed solution;Glass dust, wollastonite in powder, kaolin powder and Pulvis Talci are joined in described first mixed solution, and ultrasonic disperse 35 minutes, obtain the second mixed solution;CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and under conditions of 80 DEG C ultrasonic agitation 2 hours, prepare the high temperature resistant radiation shielding coating of water solublity described in the present embodiment.
The high temperature resistant radiation shielding coating of water solublity embodiment 1 to embodiment 5 provided is coated on surface cleaning, dry sheet metal, carries out the test of correlated performance after the most at room temperature placing solidification in 24 hours.Wherein, the sheet metal used in this test be smooth, without the mechanical defect such as impression and pit, a size of 50 × 120 × 1 mm(presses GB GB1735-79), and through oil removing, processing of rust removing, it is ensured that this surface of thin steel sheet cleaning, dry.
Storage stability, adhesive force (by GB GB1720-89), impact strength (by GB GB/T1732-1993), drying time (by GB GB1728-1979) etc. all test according to concerned countries standard.
Heat-resisting quantity is tested: is put in Muffle furnace by model, is warmed up to 800 degree, takes out after placing 10 hours, is cooled to room temperature, observes specimen surface situation, as without pull-away, be full of cracks situation, illustrated that paint film heat resistance is good (by GB GB1735-89).
Cold-hot alternation performance test: be put in Muffle furnace by model, is warmed up to 800 degree, is incubated 10 hours, takes out, and puts in cold water and soaks 1 hour, is 1 cycle.In 5 cycles repeatedly, observe paint film change.As without pull-away, be full of cracks situation, illustrated that paint film cold-hot alternation is functional.
Whether corrosion resistance is tested: model is put into salt fog machine, does spray testing with the sodium chloride solution of 5%, observation model bubbling, get rusty (by GB GB/T1771-91).
By above method of testing, embodiment 1 to embodiment 5 result of the test is as shown in the table:
Test result table
Therefore, the high temperature resistant radiation shielding coating of water solublity corrosion resistance under normal temperature cure, paint film base material adhesive force, anti-be full of cracks, cold-hot alternation, high temperature that the embodiment of the present invention provides, storage property etc. is all had outstanding performance, and is a kind of well fire-resistant anticorrosion paint;Meanwhile, expanded graphite, CNT and titanium dioxide make above-mentioned coating also have radioprotective, the function such as fire-retardant, antibacterial.The production of this coating is relatively easy, saves the energy.It has a extensive future at special dimensions such as petroleum and petrochemical industry, metallurgy, electric power, national defence.
Finally should be noted that: above example is only in order to illustrate that technical scheme is not intended to limit;Although being described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the field are it is understood that still can modify to the detailed description of the invention of the present invention or portion of techniques feature is carried out equivalent;Without deviating from the spirit of technical solution of the present invention, it all should be contained in the middle of the technical scheme scope that the present invention is claimed.

Claims (4)

1. the high temperature resistant radiation shielding coating of water solublity, it is characterized in that, it includes the raw material of following weight portion: Alumina gel 8~12 parts, expanded graphite 10~15 parts, CNT 5~10 parts, titanium dioxide 1~5 parts, hydroxypropyl methyl cellulose 0.5~3 parts, glass dust 8~14 parts, Pulvis Talci 5~10 parts, kaolin powder 10~15 parts, wollastonite in powder 10~15 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 1~5 parts and water 20~30 parts.
Water solublity the most according to claim 1 is high temperature resistant radiation shielding coating, it is characterized in that, it includes the raw material of following weight portion: Alumina gel 9~11 parts, expanded graphite 12~14 parts, CNT 7~9 parts, titanium dioxide 2~4 parts, hydroxypropyl methyl cellulose 1~2 parts, glass dust 10~12 parts, Pulvis Talci 7~9 parts, kaolin powder 12~14 parts, wollastonite in powder 11~14 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2~3 parts and water 23~27 parts.
The described high temperature resistant radiation shielding coating of water solublity the most according to claim 2, it is characterized in that, it includes the raw material of following weight portion: Alumina gel 10 parts, expanded graphite 13 parts, CNT 8 parts, titanium dioxide 3 parts, hydroxypropyl methyl cellulose 1.5 parts, 11 parts of glass dust, Pulvis Talci 8 parts, kaolin powder 13 parts, wollastonite in powder 13 parts, acrylic acid double cyclopentenyl oxygen ethyl ester 2 parts and 25 parts of water.
4. a preparation method for the high temperature resistant radiation shielding coating of water solublity described in any one of claims 1 to 3, it comprises the following steps:
Under conditions of 40~80 DEG C, Alumina gel, expanded graphite and water are uniformly mixed, form the first mixed solution;
Glass dust, Pulvis Talci, kaolin powder and wollastonite in powder are joined in described first mixed solution, and ultrasonic disperse 30~40 minutes, obtain the second mixed solution;
CNT, titanium dioxide, hydroxypropyl methyl cellulose and acrylic acid double cyclopentenyl oxygen ethyl ester are added separately in described second mixed solution, and ultrasonic agitation 1~2 hours under conditions of 40~80 DEG C, prepare the high temperature resistant radiation shielding coating of described water solublity.
CN201610263487.1A 2016-04-26 2016-04-26 Water-soluble high-temperature-resistant radiation-resistant paint and preparation method thereof Pending CN105860608A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610263487.1A CN105860608A (en) 2016-04-26 2016-04-26 Water-soluble high-temperature-resistant radiation-resistant paint and preparation method thereof

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585570A (en) * 2012-01-09 2012-07-18 武汉理工大学 Water-soluble non-combustible ceramic anti-radiation coating and preparation method thereof
CN103113768A (en) * 2013-03-08 2013-05-22 苏州纳迪微电子有限公司 High temperature resistant coating for engine exhaust system
CN103740284A (en) * 2014-01-06 2014-04-23 武汉双虎涂料有限公司 High temperature-resistant composite inorganic binder, as well as preparation method and application thereof
CN104087034A (en) * 2014-07-18 2014-10-08 关锦池 Inorganic high-temperature resistant and anti-electrostatic coating material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585570A (en) * 2012-01-09 2012-07-18 武汉理工大学 Water-soluble non-combustible ceramic anti-radiation coating and preparation method thereof
CN103113768A (en) * 2013-03-08 2013-05-22 苏州纳迪微电子有限公司 High temperature resistant coating for engine exhaust system
CN103740284A (en) * 2014-01-06 2014-04-23 武汉双虎涂料有限公司 High temperature-resistant composite inorganic binder, as well as preparation method and application thereof
CN104087034A (en) * 2014-07-18 2014-10-08 关锦池 Inorganic high-temperature resistant and anti-electrostatic coating material

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Application publication date: 20160817