CN105860551A - Preparation method of rosin emulsion - Google Patents
Preparation method of rosin emulsion Download PDFInfo
- Publication number
- CN105860551A CN105860551A CN201610313829.6A CN201610313829A CN105860551A CN 105860551 A CN105860551 A CN 105860551A CN 201610313829 A CN201610313829 A CN 201610313829A CN 105860551 A CN105860551 A CN 105860551A
- Authority
- CN
- China
- Prior art keywords
- parts
- rosin
- cardanol
- deionized water
- maleic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 29
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 29
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 title abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims abstract description 16
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims abstract description 16
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 16
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 16
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 16
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 16
- 239000011976 maleic acid Substances 0.000 claims abstract description 16
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 28
- 239000008267 milk Substances 0.000 claims description 16
- 210000004080 milk Anatomy 0.000 claims description 16
- 235000013336 milk Nutrition 0.000 claims description 16
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 15
- -1 polytrimethylene Polymers 0.000 claims description 15
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 14
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 abstract 2
- 235000019357 lignosulphonate Nutrition 0.000 abstract 2
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Polymers [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 abstract 2
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
Abstract
The invention discloses a preparation method of rosin emulsion and belongs to the technical field of deep processing of rosin. The rosin emulsion is prepared with the following materials according to parts by weight: 100 parts of rosin, 6-10 parts of maleic acid, 5-8 parts of cardanol, 1-2 parts of polyether-modified trisiloxane, 6-10 parts of ethyl alcohol, 0.1-0.2 part of sulfonated lignin, 15-25 parts of sodium dodecyl sulfate and 10-15 parts of deionized water less than 5 MuS/cm in electric conductivity, wherein the rosin is first heated and dissolved, the deionized water 5 MuS/cm in electric conductivity is then added, and pH is regulated to 9; the maleic acid, the cardanol, the polyether-modified trisiloxane, the ethyl alcohol, the sulfonated lignin and sodium dodecyl sulfate are then added, and reacting is carried using stagewise heating to obtain the rosin emulsion. The rosin emulsion prepared herein has high stability.
Description
Technical field
The invention belongs to Colophonium deep process technology field, particularly relate to the preparation method of a kind of rosin milk.
Background technology
Colophonium, refers to pine resin as raw material, the non-volatile natural resin obtained by different processing modes, and it is important industrial chemicals, is widely used in the industries such as soap, papermaking, paint, rubber.Additionally, Colophonium can also be made the performance in a certain respect of Colophonium be significantly improved by modified or carry out emulsifying and make emulsion, thus expanded the using value of Colophonium.
Wherein, Colophonium, after Over emulsfication makes emulsion, can be used for paper industry, fills between the fibers, reaches " gluing " or the purpose of " applying glue ", thus increase the water repelling property of paper, prevent ink bleed, improve intensity and smoothness, reduces dilatability.
But, the stability of rosin milk that existing market is sold is poor, still have much room for improvement.
Summary of the invention
The technical problem to be solved is to provide the preparation method of a kind of rosin milk, the rosin milk good stability that the method prepares.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
The raw material of its following weight portion of employing:
Colophonium 100 parts, maleic acid 15 parts～20 parts, Cardanol 5 parts～8 parts, polytrimethylene ether change trisiloxanes 1 part～2 parts, ethanol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, sodium lauryl sulphate 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm；
Comprise the following steps:
A, above-mentioned rosin heating is melted, be subsequently adding the electrical conductivity deionized water less than 5 μ S/cm, and regulate its pH value to 9；
B, in the material that step A prepares, add maleic acid, Cardanol, polytrimethylene ether change trisiloxanes, ethanol, lignosulfonate, sodium lauryl sulphate, and heat and react, prepare；Wherein, the detailed process of described heating is: be first heated to 80 DEG C～95 DEG C react 0.5 hour, be then cooled to 55 DEG C～65 DEG C 1 hour, be warming up to the most again 80 DEG C～95 DEG C react 0.5 hour.
In technique scheme, more specifically technical scheme is: Colophonium 100 parts, maleic acid 15 parts, Cardanol 5 parts, polytrimethylene ether change trisiloxanes 2 parts, ethanol 8 parts, lignosulfonate 0.15 part, sodium lauryl sulphate 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, maleic acid 17 parts, Cardanol 8 parts, polytrimethylene ether change trisiloxanes 1 part, ethanol 10 parts, lignosulfonate 0.1 part, sodium lauryl sulphate 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, maleic acid 20 parts, Cardanol 6 parts, polytrimethylene ether change trisiloxanes 1.5 parts, ethanol 6 parts, lignosulfonate 0.2 part, sodium lauryl sulphate 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Owing to using technique scheme, there is advantages that
The present invention is to change trisiloxanes, ethanol, lignosulfonate, sodium lauryl sulphate and the electrical conductivity deionized water less than 5 μ S/cm by addition maleic acid in Colophonium, Cardanol, polytrimethylene ether, and prepare through specific reacting by heating mode, so that the product rosin milk prepared has the advantage that stability is strong.
Detailed description of the invention
Below in conjunction with instantiation, the invention will be further described:
Embodiment 1
The preparation method of this rosin milk comprises the following steps:
A, above-mentioned 100kg rosin heating is melted, be subsequently adding 15kg electrical conductivity less than the deionized water of 5 μ S/cm, and regulate its pH value to 9；
B, in the material that step A prepares, add maleic acid 15kg, 5kg Cardanol, 2kg polytrimethylene ether change trisiloxanes, 8kg ethanol, 0.15kg lignosulfonate, 20kg sodium lauryl sulphate, and heat and react, prepare；Wherein, the detailed process of described heating is: is first heated to 90 DEG C and reacts 0.5 hour, is then cooled to 60 DEG C 1 hour, is warming up to 90 DEG C the most again and reacts 0.5 hour.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 2
The preparation method of this rosin milk comprises the following steps:
A, above-mentioned 100kg rosin heating is melted, be subsequently adding 12kg electrical conductivity less than the deionized water of 5 μ S/cm, and regulate its pH value to 9；
B, in the material that step A prepares, add maleic acid 17kg, 8kg Cardanol, 1kg polytrimethylene ether change trisiloxanes, 10kg ethanol, 0.1kg lignosulfonate, 15kg sodium lauryl sulphate, and heat and react, prepare；Wherein, the detailed process of described heating is: is first heated to 95 DEG C and reacts 0.5 hour, is then cooled to 55 DEG C 1 hour, is warming up to 95 DEG C the most again and reacts 0.5 hour.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 3
The preparation method of this rosin milk comprises the following steps:
A, above-mentioned 100kg rosin heating is melted, be subsequently adding 10kg electrical conductivity less than the deionized water of 5 μ S/cm, and regulate its pH value to 9；
B, in the material that step A prepares, add maleic acid 20kg, 6kg Cardanol, 1.5kg polytrimethylene ether change trisiloxanes, 6kg ethanol, 0.2kg lignosulfonate, 25kg sodium lauryl sulphate, and heat and react, prepare；Wherein, the detailed process of described heating is: is first heated to 80 DEG C and reacts 0.5 hour, is then cooled to 65 DEG C 1 hour, is warming up to 80 DEG C the most again and reacts 0.5 hour.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Claims (4)
1. the preparation method of a rosin milk, it is characterised in that:
Use the raw material of following weight portion:
Colophonium 100 parts, maleic acid 15 parts～20 parts, Cardanol 5 parts～8 parts, polytrimethylene ether change trisiloxanes 1 part～2 parts, ethanol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, sodium lauryl sulphate 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm；
Comprise the following steps:
A, above-mentioned rosin heating is melted, be subsequently adding the electrical conductivity deionized water less than 5 μ S/cm, and regulate its pH value to 9；
B, in the material that step A prepares, add maleic acid, Cardanol, polytrimethylene ether change trisiloxanes, ethanol, lignosulfonate, sodium lauryl sulphate, and heat and react, prepare；Wherein, the detailed process of described heating is: be first heated to 80 DEG C～95 DEG C react 0.5 hour, be then cooled to 55 DEG C～65 DEG C 1 hour, be warming up to the most again 80 DEG C～95 DEG C react 0.5 hour.
The preparation method of rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 15 parts, Cardanol 5 parts, polytrimethylene ether change trisiloxanes 2 parts, ethanol 8 parts, lignosulfonate 0.15 part, sodium lauryl sulphate 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm.
The preparation method of rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 17 parts, Cardanol 8 parts, polytrimethylene ether change trisiloxanes 1 part, ethanol 10 parts, lignosulfonate 0.1 part, sodium lauryl sulphate 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm.
The preparation method of rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 20 parts, Cardanol 6 parts, polytrimethylene ether change trisiloxanes 1.5 parts, ethanol 6 parts, lignosulfonate 0.2 part, sodium lauryl sulphate 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313829.6A CN105860551A (en) | 2016-05-12 | 2016-05-12 | Preparation method of rosin emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313829.6A CN105860551A (en) | 2016-05-12 | 2016-05-12 | Preparation method of rosin emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105860551A true CN105860551A (en) | 2016-08-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313829.6A Pending CN105860551A (en) | 2016-05-12 | 2016-05-12 | Preparation method of rosin emulsion |
Country Status (1)
| Country | Link |
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| CN (1) | CN105860551A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349940A (en) * | 2016-08-29 | 2017-01-25 | 广西梧州通轩林产化学有限公司 | Preparation method of rosin glyceride for tackifier |
| CN106349941A (en) * | 2016-08-29 | 2017-01-25 | 广西梧州通轩林产化学有限公司 | Method for preparing ester gum |
| CN106634615A (en) * | 2016-08-29 | 2017-05-10 | 广西梧州通轩林产化学有限公司 | Preparation method of polymerized rosin pentaerythritol ester for paint |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN104140540A (en) * | 2014-07-25 | 2014-11-12 | 广西众昌树脂有限公司 | Preparation method of rosin tackifying resin emulsion |
-
2016
- 2016-05-12 CN CN201610313829.6A patent/CN105860551A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN104140540A (en) * | 2014-07-25 | 2014-11-12 | 广西众昌树脂有限公司 | Preparation method of rosin tackifying resin emulsion |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106349940A (en) * | 2016-08-29 | 2017-01-25 | 广西梧州通轩林产化学有限公司 | Preparation method of rosin glyceride for tackifier |
| CN106349941A (en) * | 2016-08-29 | 2017-01-25 | 广西梧州通轩林产化学有限公司 | Method for preparing ester gum |
| CN106634615A (en) * | 2016-08-29 | 2017-05-10 | 广西梧州通轩林产化学有限公司 | Preparation method of polymerized rosin pentaerythritol ester for paint |
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| C06 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160817 |
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