CN105860358A - Method for manufacturing PVC (Polyvinyl Chloride) luggage material - Google Patents
Method for manufacturing PVC (Polyvinyl Chloride) luggage material Download PDFInfo
- Publication number
- CN105860358A CN105860358A CN201610327169.7A CN201610327169A CN105860358A CN 105860358 A CN105860358 A CN 105860358A CN 201610327169 A CN201610327169 A CN 201610327169A CN 105860358 A CN105860358 A CN 105860358A
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- CN
- China
- Prior art keywords
- pvc
- parts
- container
- powder
- luggage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of luggage materials, in particular to a method for manufacturing a PVC (Polyvinyl Chloride) luggage material. The method comprises the following steps: weighing an organic phosphine silane coupling agent, putting the organic phosphine silane coupling agent in a container, diluting with glycol so as to obtain a dilute solution, slowly pouring silicon dioxide into the dilute solution, uniformly mixing, and drying so as to remove the solvent; sequentially adding dioctyl terephthalate, sodium stearate and zinc oxide into the container, slowly adding PVC powder when stirring, further adding modified silicon dioxide powder and the PVC powder, and stirring to sufficiently disperse the materials, so as to obtain a pre-prepared PVC material; filling the pre-prepared PVC material into a mold, heating, keeping the temperature for a certain time, naturally cooling, and demolding, so as to obtain the material. The raw materials used in the method comprise not only dioctyl terephthalate, PVC and the like, and but also silicon dioxide modified by the organic phosphine silane coupling agent, so that the tensile property and the wearing resistance of the prepared PVC luggage material are improved, and the service life of a luggage can be greatly prolonged.
Description
Technical field
The present invention relates to box material technical field, be specifically related to the manufacture method of a kind of PVC box material.
Background technology
Polyvinyl chloride, English abbreviation PVC (Polyvinyl chloride), is VCM (vinyl chloride monomer, letter
Claim VCM) at the initiator such as peroxide, azo-compound, or under light, heat effect, press mechanism of free-radical polymerization polymerization
Polymer.At present, the box material of PVC material increasingly receives publicity, and particularly with the addition of part in PVC and changes
After property material, the intensity of the box material made, the performance such as wear-resisting is made to obtain the lifting of certain amplitude.
Summary of the invention
It is an object of the invention to provide the manufacture method of a kind of PVC box material, for achieving the above object, present invention employs
Techniques below scheme:
A kind of manufacture method of PVC box material, step is as follows:
1) modification of silica:
Weighing the organic phosphine silane coupler of 5% silica weight in container, spent glycol is diluted to the weak solution of 10%,
Again silica is poured slowly in weak solution, stirring while adding, after mixing, container is placed directly in baking oven in
Dry to remove solvent at 80～120 DEG C, then solid is taken out, grind stand-by；
2) preparation of PVC pre-feed:
5 parts of dioctyl phthalates, 5 parts of odium stearate and 1 part of zinc oxide are sequentially added into container, under magnetic agitation,
It is slowly added to 25 parts of PVC powder, after stirring 15min, adds 5 parts of improved silica powder and 35 parts of PVC powder
Material, stirs 30min so that it is fully dispersed, obtains PVC pre-feed；
3) shaping:
PVC pre-feed being filled with in mould, be warming up to 160～200 DEG C and keep 10min, cooling, takes out and i.e. obtains PVC naturally
Box material.
As a kind of improvement of above-mentioned manufacture method, the structural formula of described organic phosphine silane coupler is:
The manufacture method of the PVC box material of the present invention, its beneficial effect shows:
The manufacture method of the PVC box material of the present invention, the raw material used not only includes dioctyl phthalate, stearic acid
Sodium, zinc oxide and PVC, also added through the silane coupler modified silica of organic phosphine, so that the PVC made
The tensile property of box material and wear-resisting intensity, and greatly amplitude extends the service life of case and bag.Meanwhile, manufacture method is the simplest
Just, it is easy to industrialized production.
Detailed description of the invention
Below with reference to embodiment, the present invention is described in detail.But, embodiment content is only to institute of the present invention
The citing made and explanation, described specific embodiment is made various amendment or benefit by affiliated those skilled in the art
Fill or use similar mode to substitute, without departing from the design of invention or surmount scope defined in the claims, all
Protection scope of the present invention should be belonged to.
Embodiment 1
A kind of manufacture method of PVC box material, step is as follows:
1) modification of silica:
Weighing the organic phosphine silane coupler of 5% silica weight in container, spent glycol is diluted to the weak solution of 10%,
Again silica is poured slowly in weak solution, stirring while adding, container is placed directly in baking oven in 100 DEG C after mixing
Solid, to remove solvent, is then taken out, grinds stand-by by lower drying.
The structural formula of organic phosphine silane coupler is:
2) preparation of PVC pre-feed:
5 parts of dioctyl phthalates, 5 parts of odium stearate and 1 part of zinc oxide are sequentially added into container, under magnetic agitation,
It is slowly added to 25 parts of PVC powder, after stirring 15min, adds 5 parts of improved silica powder and 35 parts of PVC powder
Material, stirs 30min so that it is fully dispersed, obtains PVC pre-feed.
3) shaping:
PVC pre-feed being filled with in mould, be warming up to 180 DEG C and keep 10min, cooling, takes out and i.e. obtains PVC case and bag naturally
Material.
Claims (2)
1. the manufacture method of a PVC box material, it is characterised in that step is as follows:
1) modification of silica:
Weighing the organic phosphine silane coupler of 5% silica weight in container, spent glycol is diluted to the weak solution of 10%,
Again silica is poured slowly in weak solution, stirring while adding, after mixing, container is placed directly in baking oven in
Dry to remove solvent at 80～120 DEG C, then solid is taken out, grind stand-by；
2) preparation of PVC pre-feed:
5 parts of dioctyl phthalates, 5 parts of odium stearate and 1 part of zinc oxide are sequentially added into container, under magnetic agitation,
It is slowly added to 25 parts of PVC powder, after stirring 15min, adds 5 parts of improved silica powder and 35 parts of PVC powder
Material, stirs 30min so that it is fully dispersed, obtains PVC pre-feed；
3) shaping:
PVC pre-feed being filled with in mould, be warming up to 160～200 DEG C and keep 10min, cooling, takes out and i.e. obtains PVC naturally
Box material.
2. the manufacture method of PVC box material as claimed in claim 1, it is characterised in that: described organic phosphine is silane coupled
The structural formula of agent is:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610327169.7A CN105860358A (en) | 2016-05-16 | 2016-05-16 | Method for manufacturing PVC (Polyvinyl Chloride) luggage material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610327169.7A CN105860358A (en) | 2016-05-16 | 2016-05-16 | Method for manufacturing PVC (Polyvinyl Chloride) luggage material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105860358A true CN105860358A (en) | 2016-08-17 |
Family
ID=56635141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610327169.7A Pending CN105860358A (en) | 2016-05-16 | 2016-05-16 | Method for manufacturing PVC (Polyvinyl Chloride) luggage material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105860358A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106379012A (en) * | 2016-08-31 | 2017-02-08 | 芜湖恒信汽车内饰制造有限公司 | Anti-slip material used for automobile interior foot pad and preparation method thereof |
| CN106393811A (en) * | 2016-08-31 | 2017-02-15 | 芜湖恒信汽车内饰制造有限公司 | Manufacturing method of automobile interior decoration foot pad |
| CN109912901A (en) * | 2019-01-16 | 2019-06-21 | 瑞安市百盛箱包有限公司 | For making the PVC composite material and preparation method of luggage |
| CN112745601A (en) * | 2020-12-30 | 2021-05-04 | 同曦集团有限公司 | Antibacterial, mildewproof and antiviral material and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613370A (en) * | 2009-07-22 | 2009-12-30 | 中国科学技术大学 | Flame retardant modified silane coupler of a kind of phosphorous nitrogen and preparation method thereof |
| CN102070667A (en) * | 2010-12-30 | 2011-05-25 | 上海交通大学 | Organosilicon compound containing phosphorus and nitrogen and preparation method thereof |
| CN104387692A (en) * | 2014-09-17 | 2015-03-04 | 安徽华恒轻工有限公司 | Manufacturing process for PVC bag material |
| CN104829862A (en) * | 2015-05-28 | 2015-08-12 | 合肥学院 | Organic phosphine silane coupling agent and preparing method thereof |
-
2016
- 2016-05-16 CN CN201610327169.7A patent/CN105860358A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613370A (en) * | 2009-07-22 | 2009-12-30 | 中国科学技术大学 | Flame retardant modified silane coupler of a kind of phosphorous nitrogen and preparation method thereof |
| CN102070667A (en) * | 2010-12-30 | 2011-05-25 | 上海交通大学 | Organosilicon compound containing phosphorus and nitrogen and preparation method thereof |
| CN104387692A (en) * | 2014-09-17 | 2015-03-04 | 安徽华恒轻工有限公司 | Manufacturing process for PVC bag material |
| CN104829862A (en) * | 2015-05-28 | 2015-08-12 | 合肥学院 | Organic phosphine silane coupling agent and preparing method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106379012A (en) * | 2016-08-31 | 2017-02-08 | 芜湖恒信汽车内饰制造有限公司 | Anti-slip material used for automobile interior foot pad and preparation method thereof |
| CN106393811A (en) * | 2016-08-31 | 2017-02-15 | 芜湖恒信汽车内饰制造有限公司 | Manufacturing method of automobile interior decoration foot pad |
| CN109912901A (en) * | 2019-01-16 | 2019-06-21 | 瑞安市百盛箱包有限公司 | For making the PVC composite material and preparation method of luggage |
| CN112745601A (en) * | 2020-12-30 | 2021-05-04 | 同曦集团有限公司 | Antibacterial, mildewproof and antiviral material and preparation method and application thereof |
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Application publication date: 20160817 |
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