CN105860164A - Composite latex condom containing graphene oxide/fish glue and preparation method thereof - Google Patents

Composite latex condom containing graphene oxide/fish glue and preparation method thereof Download PDF

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Publication number
CN105860164A
CN105860164A CN201610263696.6A CN201610263696A CN105860164A CN 105860164 A CN105860164 A CN 105860164A CN 201610263696 A CN201610263696 A CN 201610263696A CN 105860164 A CN105860164 A CN 105860164A
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China
Prior art keywords
condom
graphene oxide
air bladder
composite emulsion
pseudosciaenae seu
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CN201610263696.6A
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Chinese (zh)
Inventor
曾新民
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Guangzhou Mei Qiao New Mstar Technology Ltd
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Individual
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Priority to CN201610263696.6A priority Critical patent/CN105860164A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F6/00Contraceptive devices; Pessaries; Applicators therefor
    • A61F6/02Contraceptive devices; Pessaries; Applicators therefor for use by males
    • A61F6/04Condoms, sheaths or the like, e.g. combined with devices protecting against contagion
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Veterinary Medicine (AREA)
  • Reproductive Health (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)

Abstract

The invention provides a composite latex condom containing graphene oxide/fish glue and a preparation method thereof. The composite latex condom has good stretchability, high bursting property and a physical sterilization function. The composite latex condom comprises 0.05-0.1 part of graphene oxide, 0.6-2.0 parts of fish glue and 56 parts of natural latex by weight. The composite latex condom containing graphene oxide/fish glue has the beneficial effects that the tear resistance, elasticity, heat resistance and skin affinity of the condom can be enhanced by adding graphene oxide and fish glue; the composite latex condom with thickness of 0.04mm has been developed and has good stretchability and high bursting property; meanwhile, due to the physical sterilization function of graphene oxide, bacteria can not have drug resistance, so that the bacterial virus isolation capacity of the condom can be improved.

Description

A kind of composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser and preparation method thereof
Technical field
The present invention relates to a kind of condom and preparation method thereof, especially a kind of containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser Composite emulsion condom and preparation method thereof.
Background technology
Condom, as physical isolation contraceptive device simple, effective, obtains wide model and uses in countries in the world. Research report shows: the glued membrane of condom can shield the pathogen of the disease such as sexually transmitted disease (STD), acquired immune deficiency syndrome (AIDS) effectively.Just Really use condom, the infection probability of sexually transmitted disease (STD) can be reduced significantly.It is presently used for condom Material mainly has: natural emulsion, polyurethane, synthetic rubber.
Natural emulsion (raw rubber, natural rubber) is to obtain from the rubber tree of cultivation, has good one-tenth Film properties, wet gel strength is high, good mechanical properties, and mechanical stability is high, and color is pure white, foam stabilization Property is good.Natural emulsion, after processing, has the most excellent combination property, is currently used most widely to keep away Pregnant set.But owing to natural emulsion material is containing phytoprotein, lipoid, saccharide and inorganic matter, first latex exists Under the influence of antibacterial and enzyme, easily solidify;And the condom that individually latex is prepared is because of phytoprotein etc. Material has anaphylaxis to human body, can cause a lot of health problem, adds the condom that independent latex is prepared Tear resistance is not strong, and the substitute products finding high-quality natural emulsion have been compeled as pressing as a fire singeing one's eyebrows in the whole world.
Polyurethane is a kind of synthesis macromolecular material, is a kind of to use safety, comfortable condom.But it Shortcoming be: elastic package not as natural emulsion contraception, relatively costly, easy to fall off and damaged.
Summary of the invention
The invention provides that a kind of draftability is good, explosion big, there is the oxygen-containing fossil of physical sterilization function simultaneously Composite emulsion condom of ink alkene/Air Bladder pseudosciaenae seu Acipenser and preparation method thereof.
Realize the composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser of one of the object of the invention, bag Include by weight proportion: graphene oxide 0.05~0.1 part, Air Bladder pseudosciaenae seu Acipenser 0.6~2.0 parts and natural emulsion 56 parts
Also include dispersion stabilizer 1.0~1.5 parts of part by weight.
Described dispersion stabilizer is dodecylbenzene sodium sulfonate.
Realize the object of the invention two composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser Its preparation method, will by weight proportion: graphene oxide 0.05~0.1 part, Air Bladder pseudosciaenae seu Acipenser 0.6~2.0 parts and Natural emulsion 56 parts is mixed evenly, and makes Composite Milk glue;After ripening, mould impregnation technology is used to become Type, produces the first glued membrane of composite emulsion condom after dry solidification.
Also include dispersion stabilizer 1.0~1.5 parts of part by weight.
Described dispersion stabilizer is dodecylbenzene sodium sulfonate.
Further, by the glued membrane of molding, described just glued membrane is carried out that crimping, stove be dry, swelling, off-type, bubble Wash, be dehydrated, after dried, then carry out processing, quality inspection and the packagings such as follow-up sulfuration, finally prepare compound Latex prophylactic finished product.
Further, suitable condom mould is impregnated in Composite Milk glue, by described after dipping Condom mould takes out and stove is done under 85~90 degrees celsius, and now the first glued membrane of condom is just prepared Come.
Further, described just glued membrane carries out that crimping, stove be dry, swelling, off-type, foam washing, after processed, Be dried at 100~120 degrees Celsius again, just prepared condom, then through upper silicone oil, packaging Composite Milk Glue condom finished product.
Further, dipping optimum temperature is 24~28 degrees Celsius, and must not impregnate less than 2 times, so makes Few for the condom defective work gone out.
Further, each stove time of doing is 7~9 minutes, until the glued membrane on condom mould is translucent.
The composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser of the present invention and preparation method thereof Have the beneficial effect that:
The composite emulsion condom of the present invention, adds graphene oxide and Air Bladder pseudosciaenae seu Acipenser can strengthen the anti-tear of condom Fragility, elasticity, thermostability and skin-friendly, have been developed that the more thinness composite emulsion condom to 0.04mm, Its draftability is good, and explosion is big;Simultaneous oxidation Graphene physical sterilization function, allows antibacterial will not produce drug resistance, Condom isolation bacterial virus can be improved.Simultaneous oxidation Graphene also has good heat conductivity, it means that this Invention can not only make experience truer, moreover it is possible to adapts to rapidly the body temperature of people, makes whole sexual love process more pleased Happy.
The composite emulsion condom preparation method of this invention is simple, economical and efficient, manufacturing cycle are short, natural nothing Polluting, product property is stable, and the technological process of production with present condom such as matches at the advantage again.
Detailed description of the invention
Embodiment 1
The preparation method of the composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser of the present embodiment, Clean mixing tank adds the natural emulsion that weight ratio is divided into 56 parts, is gradually added under agitation 0.05 part of graphene oxide, adds 1 part of dispersion stabilizer (dodecylbenzene sodium sulfonate), continuously stirred; 0.6 part of Air Bladder pseudosciaenae seu Acipenser preheating 50 degrees Celsius processed adds the mixing tank in stirring, during mixture Control total solids content, 59%, makes it uniformly mix in continuously stirred 45 minutes;Compound latex is stood 24 hours, with 2 impregnation technology molding after ripening, after dry solidification and produce composite emulsion condom; Carry out that crimping, stove be dry by the glued membrane of molding again, swelling, off-type, foam washing, dehydration, after dried, then Carry out processing, quality inspection and the packagings such as follow-up sulfuration, finally prepare the composite emulsion of graphene oxide/Air Bladder pseudosciaenae seu Acipenser Condom.
The composite emulsion condom that embodiment 1 prepares and generic latex condom performance comparison table on the market As follows:
Generic latex condom is dry through ripening, dipping, stove by single natural emulsion on the market, swelling, off-type, After foam washing, dehydration, dried, then carry out follow-up sulfuration and be prepared from.
The composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser of the present invention is can be seen that from following table Having more preferable tear resistance and elasticity, its draftability is good, and explosion is big.
Embodiment 2
A kind of composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser and preparation method thereof, it is characterised in that Comprise the following steps:
The natural emulsion that weight ratio is divided into 56 parts is added, the most progressively in clean mixing tank Add 0.08 part of graphene oxide, add 1.5 parts of dispersion stabilizers (dodecylbenzene sodium sulfonate), hold Continuous stirring;The mixing tank in stirring is added, in mixture mistake by preheating 50 degree of 1.5 parts of Air Bladder pseudosciaenae seu Acipenser processed In journey, control total solids content is 59%, within continuously stirred 45 minutes, makes it uniformly mix;By compound latex Stand 24 hours, with 2 impregnation technology molding after ripening, after dry solidification and produce composite emulsion and keep away Pregnant set;Carry out that crimping, stove be dry by the glued membrane of molding again, swelling, off-type, foam washing, dehydration, dried After, then carry out processing, quality inspection and the packagings such as follow-up sulfuration, finally prepare the Composite Milk of Graphene/Air Bladder pseudosciaenae seu Acipenser Glue condom.
Dipping optimum temperature is 24 degrees Celsius, and must not impregnate less than 2 times, the condom being prepared out Defective work is few.
Being taken out by described condom mould after dipping and stove is done under 85 degrees celsius, the time done by each stove Being 7 minutes, until the glued membrane on condom mould is translucent, now the first glued membrane of condom just prepares ?.Described just glued membrane carries out that crimping, stove be dry, swelling, off-type, foam washing, after processed, then 100 Degree Celsius be dried, just prepared condom, then through upper silicone oil, packaging composite emulsion condom finished product.
Embodiment 2 is more higher than embodiment 1 explosion, and draftability is more preferable.
Embodiment 3
A kind of composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser and preparation method thereof, it is characterised in that Comprise the following steps:
The natural emulsion that weight ratio is divided into 56 parts is added, the most progressively in clean mixing tank Add 0.10 part of graphene oxide, add 1.5 parts of dispersion stabilizers (dodecylbenzene sodium sulfonate), hold Continuous stirring;The mixing tank in stirring is added, in mixture process by preheating 50 degree of 2 parts of Air Bladder pseudosciaenae seu Acipenser processed Middle control total solids content, 59%, makes it uniformly mix in continuously stirred 45 minutes;By quiet for compound latex Put 24 hours, with 2 impregnation technology molding after ripening, after dry solidification and produce composite emulsion contraception Set;Carry out that crimping, stove be dry by the glued membrane of molding again, swelling, off-type, foam washing, dehydration, after dried, Carry out processing, quality inspection and the packagings such as follow-up sulfuration again, finally prepare the Composite Milk of graphene oxide/Air Bladder pseudosciaenae seu Acipenser Glue condom.
Dipping optimum temperature is 28 degrees Celsius, and must not impregnate less than 2 times, the condom being prepared out Defective work is few.
Being taken out by described condom mould after dipping and stove is done under 90 degrees celsius, the time done by each stove Being 9 minutes, until the glued membrane on condom mould is translucent, now the first glued membrane of condom just prepares ?.Described just glued membrane carries out that crimping, stove be dry, swelling, off-type, foam washing, after processed, then 120 Degree Celsius be dried, just prepared condom, then through upper silicone oil, packaging composite emulsion condom finished product.
Embodiment 3 is more higher than embodiment 2 explosion, and draftability is very nearly the same.
Graphene is the thinnest material, is also the most tough material, and fracture strength is also wanted than best steel High 200 times, it has again good elasticity simultaneously, and stretch range can reach the 20% of own dimensions;At plastics In mix millesimal Graphene, can make plastics heat resistanceheat resistant performance improve 30 degrees Celsius, on this basis Make thin, light, the good and superpower Graphene composite emulsion of draftability.Graphene after oxidation is except keeping Graphene Performance outside, also add the oxy functional groups that surface is abundant, its higher specific surface area promotes to have with latex Preferably affinity.Simultaneous oxidation Graphene can physics to kill the kind more than 10 such as bacillus pyocyaneus, escherichia coli thin Bacterium, simultaneous oxidation Graphene has physical sterilization function, allows antibacterial will not produce drug resistance, can improve contraception Set isolation bacterial virus.
Air Bladder pseudosciaenae seu Acipenser is the sizing material prepared after Air Bladder pseudosciaenae seu Acipenser passes through processed, and its main component is biological micromolecule glue Matter, viscosity is the highest, and freezing concentration low (0.5%~0.6%);Add weight and be divided into 0.6-2 part Air Bladder pseudosciaenae seu Acipenser, Make condom the most soft more pro-skin sense, just as getting along swimmingly with each other!
Embodiment described above is only to be described the preferred embodiment of the present invention, not to this Bright scope is defined, under design spirit premise without departing from the present invention, and this area ordinary skill technology people Member's various deformation of making technical solution of the present invention and improvement, all should fall into claims of the present invention true In fixed protection domain.

Claims (10)

1. the composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser, including by weight proportion: Graphene oxide 0.05~0.1 part, Air Bladder pseudosciaenae seu Acipenser 0.6~2.0 parts and natural emulsion 56 parts.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 1, It is characterized in that: also include dispersion stabilizer 1.0~1.5 parts of part by weight.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 2, It is characterized in that: described dispersion stabilizer is dodecylbenzene sodium sulfonate.
4. an its preparation method for the composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser, will By weight proportion: graphene oxide 0.05~0.1 part, Air Bladder pseudosciaenae seu Acipenser 0.6~2.0 parts and natural emulsion 56 parts mix Uniformly, Composite Milk glue is made;After ripening, use mould impregnation technology molding, produce after stove is dry The first glued membrane of composite emulsion condom.
5. the composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser stated according to claim 4 Its preparation method, it is characterised in that: also include dispersion stabilizer 1.0~1.5 parts of part by weight.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 5 Its preparation method, it is characterised in that: described dispersion stabilizer is dodecylbenzene sodium sulfonate.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 4 Its preparation method, it is characterised in that: described just glued membrane is carried out crimping, for the second time stove by the glued membrane of molding After dry, swelling, off-type, foam washing, dehydration, dried, then carry out the processing such as follow-up sulfuration, quality inspection and Packaging, finally prepares composite emulsion condom finished product.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 7 Its preparation method, it is characterised in that: suitable condom mould is impregnated in Composite Milk glue, After dipping, described condom mould is taken out and stove is done, now at the beginning of condom under 85~90 degrees celsius Glued membrane just prepares.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 7 Its preparation method, it is characterised in that: described just glued membrane carries out that crimping, stove be dry, swelling, off-type, foam washing, After processed, then it is dried at 100~120 degrees Celsius, has just prepared condom, then through upper silicone oil, bag Dress composite emulsion condom finished product.
Composite emulsion condom containing graphene oxide/Air Bladder pseudosciaenae seu Acipenser the most according to claim 7 Its preparation method, it is characterised in that: dipping optimum temperature is 24~28 degrees Celsius, and must not impregnate and be less than 2 times;The time that described stove is done is 7~9 minutes, until the glued membrane on condom mould is translucent.
CN201610263696.6A 2016-04-26 2016-04-26 Composite latex condom containing graphene oxide/fish glue and preparation method thereof Pending CN105860164A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108992715A (en) * 2018-08-20 2018-12-14 辽宁格莱菲尔健康科技有限公司 It is a kind of to have effects that the preparation method of compound sheath that private parts conserves
CN112807495A (en) * 2021-01-18 2021-05-18 吉安丽姝科技有限公司 Preparation method of condom with antibacterial and anti-inflammatory effects

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102936359A (en) * 2012-12-03 2013-02-20 上海名邦橡胶制品有限公司 Preparation method of environment-friendly condom
CN104231343A (en) * 2014-08-29 2014-12-24 朱其贵 Rubber material with extremely thin rubber flavor
CN105237828A (en) * 2015-11-04 2016-01-13 辽宁兰晶科技有限公司 Method for preparing high-strength and high-isolation condoms from modified graphene/latex composite material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102936359A (en) * 2012-12-03 2013-02-20 上海名邦橡胶制品有限公司 Preparation method of environment-friendly condom
CN104231343A (en) * 2014-08-29 2014-12-24 朱其贵 Rubber material with extremely thin rubber flavor
CN105237828A (en) * 2015-11-04 2016-01-13 辽宁兰晶科技有限公司 Method for preparing high-strength and high-isolation condoms from modified graphene/latex composite material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张殿荣等: "《现代橡胶配方设计》", 31 August 1994, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108992715A (en) * 2018-08-20 2018-12-14 辽宁格莱菲尔健康科技有限公司 It is a kind of to have effects that the preparation method of compound sheath that private parts conserves
CN112807495A (en) * 2021-01-18 2021-05-18 吉安丽姝科技有限公司 Preparation method of condom with antibacterial and anti-inflammatory effects

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