CN105849933B - The portable electric energy memory device slowed down with thermal runaway - Google Patents

The portable electric energy memory device slowed down with thermal runaway Download PDF

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Publication number
CN105849933B
CN105849933B CN201480056352.7A CN201480056352A CN105849933B CN 105849933 B CN105849933 B CN 105849933B CN 201480056352 A CN201480056352 A CN 201480056352A CN 105849933 B CN105849933 B CN 105849933B
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China
Prior art keywords
electric energy
energy storage
storage batteries
batteries unit
barrier
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CN201480056352.7A
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Chinese (zh)
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CN105849933A (en
Inventor
吴宜宋
学深·贺瑞斯·卢克
吴嘉浓
马修·怀廷·泰勒
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Gogoro Inc Hong Kong
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Gogoro Inc Hong Kong
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/658Means for temperature control structurally associated with the cells by thermal insulation or shielding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • H01M50/213Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/289Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
    • H01M50/293Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/342Non-re-sealable arrangements
    • H01M50/3425Non-re-sealable arrangements in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0445Multimode batteries, e.g. containing auxiliary cells or electrodes switchable in parallel or series connections
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/656Means for temperature control structurally associated with the cells characterised by the type of heat-exchange fluid
    • H01M10/6569Fluids undergoing a liquid-gas phase change or transition, e.g. evaporation or condensation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Mounting, Suspending (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Gas Exhaust Devices For Batteries (AREA)
  • Secondary Cells (AREA)

Abstract

A kind of electric energy storing device for the portable device power supply for such as vehicle or consumer electrical product, comprising: barrier, in electric energy storage batteries cell failure, the rare events for bursting and lighting, thermal energy migration and combustion propagation are minimized.Explosion structure is arranged to, and when the pressure in the device is more than maximum value, gas is discharged along desired direction from the device.Offset outlet escapes the gas to shed from the portable electric energy storage batteries unit in electric energy storage module, and other electric energy storage batteries units are isolated with the gas.

Description

The portable electric energy memory device slowed down with thermal runaway
Technical field
Embodiment described herein is related to portable electric energy memory device, such as electrical equipment (such as vehicle) and Portable electric energy memory device in consumption electronic product, and it is related to the thermal runaway for this portable electric energy memory device Relieving system.
Background technique
The battery of known such as lithium ion battery is by more energy in smaller, lighter unit.Lithium ion battery exists It is widely used for portable electronic device power supply aspect, the portable electronic device is such as mobile phone, plate meter Calculation machine, laptop computer, electric power tool and other high current equipment.Light weight and high-energy density also make lithium ion battery For in mixed motor-car and all-electric vehicle using being attractive.
The latent defect of lithium ion battery is its electrolyte solution.In other kinds of battery, electrolyte be by acid or The aqueous solution composition of alkali, different, the electrolyte in lithium ionic cell unit (cell) is typically by organic solvent In lithium salts composition, organic solvent is such as ethylene carbonate and methyl ethyl carbonate (can be inflammable).
Under normal operation, it is charged to lithium ion battery so that the lithium ion in electrolyte solution is worn from cathodic migration It excessively thin porous polymer partition and is inserted into anode.Charge balance electronics is also moved to anode, but it passes through in charger External circuit.Upon discharging, then inverse process occurs, and electronics flows through powered equipment.
In the case where very rare, it may occur however that the internal or external short circuit of lithium ion battery.E.g., including lithium ion The electrical equipment of battery may undergo serious impact or shock, cause cell damage, this can lead to short circuit.Due to polymer every The thin property of plate, the micron-sized metallic particle generated in cutting, compression, grinding or other battery fabrication steps may be present in In battery cell or it can find into the path in battery cell.These small metallic particles can accumulate and most end form At the short circuit between anode and cathode.This short circuit must be avoided, because its caused temperature can make cathode and electrolyte solution It reacts and decomposes electrolyte solution, generate heat and reaction gas, such as hydrocarbon.Typically, in normal operating At a temperature of, lithium ion battery is highly stable;However, lithium ion battery stability then becomes less on specific temperature It is easy prediction, and at raised temperature, the intracorporal chemical reaction of battery case can generate gas, causes battery case intracorporal interior Pressure increases.These gases can discharge more heat and generate in battery or near battery and be enough further with cathode reaction The temperature of electrolyte is lighted in the presence of oxygen.When electrolyte burning, a small amount of oxygen are generated, this can add combustion-supporting burning.? The pressure at a certain moment, battery case cylinder accumulation causes cell casing rupture.The gas to shed can be lighted and be burnt.Some batteries Manufacturer devises battery unit, in the small probability event that battery unit ruptures and lights, supports the gas of burning predetermined Position and direction shed battery unit.For example, the battery cell with common AAA or AA battery unit shape can be designed To be discharged from the terminal ends (terminal end) respectively held positioned at battery unit.
In the application that single lithium ion battery is used only, a possibility that failure and burning of battery, can generate undesirable Situation.When multiple lithium ion batteries are deployed as the form of battery pack or module, the seriousness of such case be will increase.? There may be the offices higher than making the temperature of other lithium ion battery normal tables for the burning occurred when one lithium ion battery failure Portion's temperature causes these other battery failures, rupture and then ignited and burnt gas is discharged.Therefore, lithium-ion electric The rupture of single battery unit may cause the rupture of other battery units in the group in cell stack and discharge is lighted and burnt Gas.Fortunately it has been confirmed that lithium ion battery is very safe, and the failure of lithium ion battery ruptures right and wrong with caused by It is often rare.Nevertheless, people are also directed to reduce rupture and light the gas flowed out from rupture lithium ion battery Risk.For example, the development of the material for cathode has generated the cathode material based on lithium, this is than widely used lithium cobalt oxidation Cathode made by object is more heat-resisting.Although these materials developed recently are more heat-resisting, this has cost.For example, phase Than in lithium and cobalt oxides, lithium manganese oxide cathode has lower charge capacity, and still can decompose at high temperature.Lithium phosphate Iron cathode is especially resistant to heat injury (thermal abuse);However, compared with lithium and cobalt oxides cathode, based on capacity Operating voltage and energy density are lower.
Other work are dedicated in polymeric separator plates and its design.It has been proposed, for example, that using two layers of polypropylene by one layer The polymeric separator plates that polyethylene is clipped in the middle are directed to the degree of protection that slightly overheats to provide.When the temperature of battery unit starts to connect When the temperature of nearly unpredictable battery unit stability, polyethylene is melted and is filled in polyacrylic hole.Work as vinyl stopper When entering polyacrylic hole, lithium diffusion is stopped, to effectively shut down battery unit before the fuel cell that has an opportunity. Other work, which efforts be made so that, is higher than polyacrylic polymeric separator plates with fusing point.It has for instance been proposed that formed by polyimide Partition and the partition formed by the ceramic layer of High molecular weight polyethylene and insertion, to form more robust high-melting-point polymer Partition.Allotment is investigated to use less flammable electrolyte and non-volatile, non-flammable ionic liquid, fluorine ether (fluoroether) and other high fluorated solvents are as cell electrolyte.Researcher has developed without liquid Lithium ion battery.These solid state batteries include inorganic lithium ion conductor, are substantially non-flammable thus highly stable, peaces Entirely, and there is long life cycle and shelf life.However, the manufacturing cost of these solid state batteries is very high, and need high labor Move intensive vacuum deposition method.
Although above-mentioned work has been carried out, there is still a need for a kind of portable electric energy memory device, the device can be effective Ground manages following risk: electric energy storage batteries cell failure and in the deployment of more battery units because of failure caused by gas combustion It burns and the propagation of failure introduces thermal energy to the battery cell adjacent with faulty battery cell, and is this rare in generation Harm is generated to user when seeing event.
Summary of the invention
Embodiments described herein is related to portable electric energy memory device, including electric energy storage batteries unit barrier, It serves as the thermal insulator propagated for the battery failures for introducing thermal energy and thermal boundary (thermal barrier).Electric energy storage batteries Unit barrier further includes elastic material, and elastic material is used to that the terminal of electric energy storage batteries unit is protected to be protected from destruction, fills When electric isolator and it is used as shock absorber to protect electric energy storing device to be protected from the destruction from impact or other power.
In embodiment described herein, a kind of portable electric energy memory device is provided, comprising: the storage of the first electric energy Battery unit;Second electric energy storage batteries unit;And electric energy storage batteries unit barrier, including heat insulator and elastic material Material, electric energy storage batteries unit barrier is between the first electric energy storage batteries unit and the second electric energy storage batteries unit.
In the embodiment in terms of another description, the first electric energy storage batteries unit includes multiple first electric energy storage electricity Pool unit.
In another embodiment, the second electric energy storage batteries unit includes multiple second electric energy storage batteries units.
In another embodiment, the second electric energy storage batteries unit is adjacent with the first electric energy storage batteries unit.
While not limited to following chemical composition, the first electric energy storage batteries unit may include nickel-metal hydrides chemical group At or lithium ion chemical composition and the second electric energy storage batteries unit may include identical with the first electric energy storage batteries unit Chemical composition.
In a particular embodiment, electric energy storage batteries unit barrier includes: heat insulator layer and elastomeric layer, and/ Or the heat insulator layer between two elastomeric layers.
In a particular embodiment, the thermal conductivity coefficient of heat insulator is less than about 0.5BTU/ft2/ hr/inch, and it is excellent Selection of land, the thermal conductivity coefficient of the temperature when breaking down cells burst are 0.5BTU/ft2/hr/inch.Heat insulator can wrap Include ceramic material, vermiculite base material or other known materials that can provide thermal insulation properties.The carrier of ceramic material can be with It is cloth, fibrous glass or the other materials for being formed as the thin slice containing heat insulator of the injection ceramics based on paper.It is hot exhausted The particular example of edge material includes ceramic fibre, such as ceramic fiber paper.Suitable ceramic fiber paper example includes alumina, Mo Lai Stone (mullite), silicon carbide, zirconium oxide (zirconia) or carbon.
The example of elastic material includes rubber, more specifically includes: fluoropolymer rubber, butyl rubber, the poly- second of chlorosulfonation Alkene rubber, epichlorohydrin rubber, ethylene propylene rubber, fluoroelastomer rubber, fluorine silicone rubber, hydrogenated nitrile rubber, natural rubber, nitrile rubber Glue, perfluorinated elastomer body rubber, polypropylene rubber, (co) polychloroprene rubber, polyurethane rubber, silicon rubber and styrene butadiene Rubber.
In the embodiment in terms of another description, a kind of portable electric energy memory device is provided, comprising: the first electric energy Storage batteries unit module, including multiple electric energy storage batteries units;Second electric energy storage batteries unit module, including multiple electricity Energy storage batteries unit, the second electric energy storage batteries unit module are adjacent with the first electric energy storage batteries unit module.It is portable Electric energy storing device further include: the first electric energy storage batteries unit barrier, including it is located at the first electric energy storage batteries unit module With the heat insulator and elastic material between the second electric energy storage batteries unit module;Second electric energy storage batteries unit screen Barrier, including the heat insulator and elastic material adjacent with the second electric energy storage batteries unit module;And third electric energy storage Battery unit barrier, including elastic material, third electric energy storage batteries unit barrier and the first electric energy storage batteries unit module It is adjacent.
In the specific embodiment in terms of this description, the heat insulator position of the first electric energy storage batteries unit barrier Between two elastomeric layers of the first electric energy storage batteries unit barrier.In other embodiments, the second electric energy storage electricity The elastic material of pool unit barrier is located at the heat insulator and the second electric energy storage electricity of the second electric energy storage batteries unit barrier Between pool unit module.
In the other embodiments of present aspect, portable electric energy memory device includes: third electric energy storage batteries unit mould Block is adjacent with the second electric energy storage batteries unit module;And the 4th electric energy storage batteries unit barrier, including with third electric energy Storage batteries unit module adjacent heat insulator and elastic material.In these additional embodiments, the 4th electric energy storage electricity The heat insulator of pool unit barrier is stored by the elastomeric layer and third electric energy of the 4th electric energy storage batteries unit barrier Battery unit barrier is isolated.
In the other embodiments of present aspect, portable electric energy memory device includes: load absorption component, is stored with electric energy At least one electric energy storage batteries unit of at least one of battery cell module contacts.In other embodiments, load is inhaled Receive each electric energy storage batteries unit that component is connected at least one of electric energy storage batteries unit module.
In another embodiment described herein, a kind of portable electric energy memory device is provided, comprising: shell, Including lid and bottom seat.Contain at least one electric energy storage batteries unit mould with multiple electric energy storage batteries units in shell Block, and elastic material and Gai Xianglin, heat insulator are located between lid and elastic material.Elastic material is adjacent with pedestal and position Between electric energy storage batteries unit module and pedestal.
According to the embodiment of various aspects described in this application, a kind of portable electric energy memory device includes explosion structure, Pressure of the structure that bursts in portable electric energy memory device keeps complete when being lower than maximum internal pressure, and in portable electric Pressure in energy memory device bursts when being more than maximum internal pressure.
In the embodiment in terms of another description, a kind of portable electric energy memory device is provided, comprising: shell, packet Include lid and bottom seat.Contain the first electric energy storage batteries unit module and tool with multiple electric energy storage batteries units in shell There are the second electric energy storage batteries unit module of multiple electric energy storage batteries units, the second electric energy storage batteries unit module and One electric energy storage batteries unit module is adjacent.Third electric energy storage batteries unit module containing multiple electric energy storage batteries units Including in the shell, and in the opposite with the first electric energy storage batteries unit module of the second electric energy storage batteries unit module It is adjacent with the second electric energy storage batteries unit module on side.First electric energy storage batteries unit barrier includes being clipped in elastic material Between heat insulator, and be located at the first electric energy storage batteries unit module and the second electric energy storage batteries unit module it Between.Second electric energy storage batteries unit barrier includes the heat insulator being clipped between elastic material, and is located at the second electric energy Between storage batteries unit module and third electric energy storage batteries unit module.Third electric energy storage batteries unit barrier includes bullet Property material, and between the first electric energy storage batteries unit module and pedestal and the 4th electric energy storage batteries unit screen Barrier includes heat insulator and elastic material, and is located between third electric energy storage batteries unit module and lid.
In another embodiment, a kind of portable electric energy memory device includes shell and the storage of the first electric energy with side wall Battery cell module, the first electric energy storage batteries unit module have multiple electric energy storage batteries units and are located in shell. The second electric energy storage batteries unit module including multiple electric energy storage batteries units is similarly positioned in shell, and with first electricity Energy storage batteries unit module is adjacent.Portable electric energy memory device includes the first electric energy storage batteries unit barrier, including folder Dielectric material between the electric energy storage batteries unit contact protection layer of elastic material and the combustion barriers layer of non-combustible materials Electricity isolated layer.First electric energy storage batteries unit barrier is located at the first electric energy storage batteries unit module and the storage of the second electric energy Between battery cell module.The electricity isolated layer of the dielectric material of first electric energy storage batteries unit barrier includes at least one biasing The combustion barriers layer for exporting the non-combustible materials of (biased vent) and the first electric energy storage batteries unit barrier includes extremely A few offset outlet.Portable electric energy memory device further includes the second electric energy storage batteries unit barrier, including is clipped in elasticity The electricity of dielectric material between the electric energy storage batteries unit contact protection layer of material and the combustion barriers layer of non-combustible materials every Absciss layer.The electricity isolated layer of the dielectric material of second electric energy storage batteries unit barrier includes at least one offset outlet, Yi Ji The combustion barriers layer of the non-combustible materials of two electric energy storage batteries unit barriers includes at least one offset outlet.The storage of second electric energy Battery unit barrier is deposited between the second electric energy storage batteries unit module and the first electric energy storage batteries unit barrier.According to Embodiment as described herein, including at least one in the electricity isolated layer of the dielectric material of the first electric energy storage batteries unit barrier At least one of a offset outlet and the combustion barriers layer of non-combustible materials of the first electric energy storage batteries unit barrier are inclined It sets outlet to be biased to detent position and be movable to release position from detent position, detent position prevents gas from flowing through first Electric energy storage batteries unit barrier, and compared with detent position, stop to release position lesser degree gas to flow through One electric energy storage batteries unit barrier.Including in the electricity isolated layer of the dielectric material of the second electric energy storage batteries unit barrier At least one offset outlet and include in the combustion barriers layer of the non-combustible materials of the second electric energy storage batteries unit barrier At least one offset outlet be biased to detent position and be movable to release position from detent position, detent position prevents Gas flows through the second electric energy storage batteries unit barrier, and compared with detent position, stops gas to release position lesser degree Body flows through the second electric energy storage batteries unit barrier.
In portable electric energy storage batteries unit component embodiment as described herein, portable electric energy memory device includes Shell and the first electric energy storage batteries unit module with side wall, the first electric energy storage batteries unit module includes multiple electric energy Storage batteries unit and be located at shell in.The second electric energy storage batteries unit module containing multiple electric energy storage batteries units It is similarly positioned in shell, and adjacent with the first electric energy storage batteries unit module.First electric energy storage batteries unit barrier packet Include the dielectric materials layer being clipped between elastomeric layer and non-combustible materials layer.First electric energy storage batteries unit barrier is located at the Between one electric energy storage batteries unit module and the second electric energy storage batteries unit module, the first electric energy storage batteries unit barrier Dielectric materials layer include at least one offset outlet and the first electric energy storage batteries unit barrier non-combustible materials layer packet Include at least one offset outlet.It is biased including at least one of the dielectric materials layer in the first electric energy storage batteries unit barrier It exports and includes that at least one offset outlet in the non-combustible materials layer of the first electric energy storage batteries unit barrier is inclined Detent position is set, and is movable to release position from detent position, detent position stops gas to flow through the first electric energy Storage batteries unit barrier stops to release position lesser degree gas to flow through the storage of the first electric energy compared with detent position Deposit battery unit barrier.
Detailed description of the invention
In the accompanying drawings, identical appended drawing reference identifies identical element or movement.The size of element in attached drawing and opposite Position is not necessarily drawn to scale.For example, what the shape and angle of different elements were not necessarily drawn to scale, and in these elements Some arbitrarily enlarged can improve the identity of attached drawing with placing.In addition, as shown, the specific shape of element is not used to Any information of the true form about element-specific is conveyed, but is only selected for convenient for identification.
Fig. 1 be according to non-limiting embodiment include the portable of some various elements as described herein or structure Equidistant (isometric), the partially exploded diagram of electric energy storing device.
Fig. 2 is equidistant, the more complete decomposition diagram of the portable electric energy memory device in Fig. 1.
Fig. 3 be according to non-limiting embodiment include the portable of some various elements as described herein or structure Equidistant, the partially exploded diagram of another embodiment of electric energy storing device.
Fig. 4 is equidistant, the partially exploded diagram of two independent electric energy storage batteries units and four load absorption components.
Fig. 5 is the isometric schematic view of the explosion structure formed according to a non-limiting embodiment.
Fig. 6 is to be shown according to the schematic illustration of the electric energy storing device of a non-limiting embodiment from electricity Potential path used by gas and thermal energy that the failure electric energy storing device of energy storage batteries unit module distributes.
Fig. 7 is the electric energy storage including some various elements as described herein or structure according to a non-limiting embodiment The exploded view of the electric energy storage batteries unit module of memory device.
Fig. 8 be include type shown in Fig. 7 two electric energy storage batteries unit modules portable electric energy memory device Side view.
Fig. 9 is the electric energy storage batteries unit module that detent position is according to a non-limiting embodiment offset outlet A part isometric view.
Figure 10 is the isometric view that the offset outlet of Fig. 9 is in the electric energy storage batteries unit module of release position.
Figure 11 is the electric energy storage batteries unit that detent position is according to the offset outlet of a non-limiting embodiment The isometric view of a part of module.
Figure 12 is the isometric view that the offset outlet of Figure 11 is in the electric energy storage batteries unit module of release position.
Figure 13 is the electric energy storage batteries unit that detent position is according to the offset outlet of a non-limiting embodiment The isometric view of a part of module.
Figure 14 is the isometric view that the offset outlet of Figure 13 is in the electric energy storage batteries unit module of release position.
Specific embodiment
It will be appreciated that although the description of the specific embodiment of the application is for illustrative purposes, not depart from In the case where spirit and scope of the invention, it can carry out various modifications.Therefore, the theme of the application simultaneously is limited solely by appended power Benefit requires.
In the following detailed description, some specific detailed contents are used to provide to various disclosed embodiments It well understands.However, it would be recognized by those skilled in the art that can not have one or more of these specific details In the case where or realize using other methods, component, material etc. these embodiments.In other examples, it is not illustrated in detail Or description known structure associated with the portable electric energy storage batteries unit of such as battery, to avoid the embodiment is made Description it is unnecessary fuzzy.
Except non-content requires otherwise, in the description of the present application and claims, one word of " comprising " and its deformation quilt It is interpreted as open, the non-excluded meaning, i.e., " including but not limited to ".
" one embodiment " or " embodiment " described in the description of the present application are referred to retouches in conjunction with the embodiment The a particular feature, structure, or characteristic stated is included at least one embodiment.Therefore, the different positions in the description of the present application " in one embodiment " or " in embodiment " for setting appearance need not refer to identical embodiment.
Sequence has not been implied that the use (such as first, second and third) of ordinal number, has been only used for division operation Or multiple examples of structure.
Refer to store electric energy and release institute to portable electric energy memory device or referring to for electric energy storing device The device of the electric energy of storage, including but not limited to battery, supercapacitor (supercapacitor) or ultra-capacitor (ultracapacitor) and by multiple modules formed therein.To the finger that refers to of portable electric energy storage batteries unit It is one or more chemical storage batteries unit, such as rechargeable battery battery unit or secondary cell battery unit, including But it is not limited to nickel-cadmium alloy cell battery unit or lithium ion battery battery unit.Portable electric energy storage batteries unit Non-limiting example is shown as cylindrical in the accompanying drawings, such as has similarly sized and shape with conventional AAA size cell;So And the present disclosure is not limited to disclosed form factors.
Title provided by the disclosure and abstract are only for for convenience, not being used to explain the range or meaning of embodiment.
In general, this disclosure relates to be suitably for electrical equipment power supply portable electric energy memory device example, it is electronic Equipment is for example electronic or mixed type vehicle, such as motorcycle, scooter and electric bicycle, electric tool, electronic Lawn and garden furniture etc., including one or more electric energy storage batteries unit barriers, they are used to prevent from making electric energy storage electricity The unstable thermal energy of pool unit is from an electric energy storage batteries unit or module migration or propagates to another electric energy storage batteries Unit or module.To according to the portable electric energy memory device of embodiment described herein further describe be with it is electronic It is carried out in the context for the portable electric energy memory device that scooter is used together;However, it should be understood that according to the application The embodiment described, portable electric energy memory device are not limited to the application in Segway Human Transporter.In addition, described below portable Formula electric energy storing device be related to include multiple electric energy storage batteries units single electric energy storage batteries unit module and respectively A pair of of electric energy storage batteries unit module containing multiple electric energy storage batteries units.The application is not limited to only include single electric energy The electric energy storing device of storage batteries unit module or only a pair of electric energy storage batteries unit module, but cover including not The only portable electric energy memory device of a pair of of electric energy storage batteries unit module.
It is used in portable electric energy memory device according to an embodiment of the present application to electric vehicle (such as electric light Vehicle) power supply specific application in, one or more portable electric energy memory devices are contained in the compartment below user, such as sliding Below the seat of wooden handcart.Typically, portable electric energy memory device includes handle, so that user carries portable electric energy reservoir Part and put it into compartment or from compartment remove.
Referring to Fig.1, portable electric energy memory device 10 includes electric energy storage batteries unit module 12, electric energy storage batteries list Element module 12 includes multiple individual electric energy storage batteries units 14.Electric energy storage batteries unit module 12 is located in shell 16, Shell 16 includes shell 18, lid 20 and pedestal 22.Shell 18, lid 20 and pedestal 22 are by identical or different rigid non-combustible materials system At, such as metal or such as plastics is nonmetallic.The exemplary non-restrictive example of metal is aluminium.Although it is not shown, lid 20 It may include handle, in order to carry electric energy storing device.Similarly, although it is not shown, pedestal 22 includes the conductance across shell 18 Element, and with the conductance element cooperation in shell 18, with from the external position of portable electric energy memory device 10 to electric energy store electricity Pool unit module 12 provides electrical connection.In addition, conductance element is associated with each electric energy storage batteries unit module, and it is electrically connected Connect individual electric energy storage batteries unit and electrical connection electric energy storage batteries unit module.Shell 18 is sealed to lid in a gastight manner 20 and pedestal 22, and form air-tight casing.Conductance element across pedestal 22 is equally sealed to pedestal 22 in a gastight manner.Cause This, shell 18, lid 20 and pedestal 22 form the level Hermetic Package comprising electric energy storage batteries unit module 12.Due to shell 18, lid 20 with Pedestal 22 forms level Hermetic Package, therefore can be evacuated encapsulation, to remove combustion-supporting oxygen.Removal combustion oxygen, which reduces, to be sealed Generable quantity combusted in encapsulating.Alternatively, it can be removed by the way that oxygen is substituted for gas (such as nitrogen) that can not be combustion-supporting Combustion oxygen in encapsulation.It can be by only using conventional material (such as parent part and bull of matching) or combining jointing material, it will Shell 18 is sealed to lid 20 and pedestal 22.Alternately or supplement, it is possible to provide liner (gasket), by the sealing of shell 18 to 20 He of lid Pedestal 22.Similarly, conventional material (such as adhesion material) can be used and/or pad, the conductance element for passing through pedestal 22 is close It is sealed to pedestal 22.
It potential can store hot thermal energy absorbing material and occupy the adjacent electric energy to form electric energy storage batteries unit module 12 The void space between gap and electric energy storage batteries unit 14 and shell 16 between storage batteries unit 14.Suitable heat Energy absorbing material is for example absorbed by phase transformation or discharges thermal energy, without the temperature of material change's material.Thermal energy absorbing material Example includes the material that can be absorbed via phase transformation with store big energy.These materials are often referred to phase-change material.Phase-change material is logical It is often considered limiting in the material for carrying out phase transformation between solid phase and liquid phase;However, phase-change material be not limited to solid phase with The material changed between liquid phase.Phase-change material can be organic material, such as paraffin and fatty acid.Phase-change material can also be nothing Machine, such as salt hydrate.Phase-change material can also be congruent melting material (eutectic material) or hygroscopic material.
As described in the background art, although seldom occur, lithium-ion electric energy storage batteries unit it is internal or external short The temperature that road can lead to independent electric energy storage batteries unit increases to cathode and can react with electrolyte solution and decompose electrolysis The degree of matter solution.In case of this phenomenon, additional thermal energy can be generated, the gas for decomposing electrolyte solution and generating can be with yin Pole reacts and discharges more thermal energy.Gas in electric energy storage batteries unit generates the pressure caused in sealed cell unit Increase.If the pressure in battery unit increases to designed battery unit explosion pressure or more, battery unit can rupture And release gas.In these reaction process, limited amount oxygen is generated, can support further to burn.If released Gas out is exposed to the temperature higher than gas ignition, then gas can be lighted and be burnt.In addition, if from a short circuit battery list The thermal energy and other electric energy storage batteries units can be caused from the burning of rupture battery unit institute escaping gas that member is released Temperature be higher than these battery units and be in the temperature of stable state, then the cathode of these other electric energy storage batteries units can be with Electrolyte solution reaction, and generate the gas for causing these battery units to rupture and burn.Although combustion caused by this short circuit Burn it is rarely found, however for user security good design and be concerned about require in the electric energy storage batteries unit being unlikely to occur User is protected under fault condition.
With continued reference to Fig. 1, and additional reference Fig. 2, the one of the one aspect of portable electric energy memory device as described herein A non-limiting embodiment includes single electric energy storage batteries unit module 12, and electric energy storage batteries unit module 12 includes multiple Electric energy storage batteries unit 14.In the embodiment shown in fig. 1, single electric energy storage batteries unit module 12 includes multiple independent Electric energy storage batteries unit 14.It should be understood that greater number or smaller amounts can be used compared to quantity shown in FIG. 1 Independent electric energy storage batteries unit.
Although being not particularly illustrated, in order to avoid obscuring other features of present disclosure, occupied by phase-change material Gap between electric energy storage batteries unit 14.Used specific phase-change material is carried out in the case where considering many factors Selection, these factors include phase-change material absorbable thermal energy degree before it completes phase transformation and temperature is begun to ramp up.One As, it, with regard to the phase-change material of completion status variation, can be inhaled before completion status variation compared to when absorbing less thermal energy The phase-change material for receiving more energy is more preferably.Illustrative phase-change material includes organic material, such as paraffin and fat Acid.Phase-change material can also be inorganic, such as salt hydrate.Phase-change material can also be congruent melting material or hygroscopic material. In Fig. 1 and embodiment shown in Fig. 2, electric energy storage batteries unit barrier 24 is located on electric energy storage batteries unit module 12 Side.Electric energy storage batteries unit barrier 24 includes heat insulator layer 26 and elastomeric layer 28.Heat insulator layer 26 and bullet The size of property material layer 28 can cover the entire upper surface of electric energy storage batteries unit module 12.By the week of heat insulator layer 26 The shape and size of the circumference of boundary and elastomeric layer 28 are adjusted to be adapted to the inner tight of shell 18.26 He of heat insulator layer Close fitting between elastomeric layer 28 is arrived without close tolerance (closely toleranced) so that in these layers and shell It is provided between 18 inner surface gas-tight seal;However, in the inner surface of shell 18 and heat insulator layer 26 and elastomeric layer 28 At least one between adaptation it is closer, then can preferably stop across stop shell 18 inner surface and insulation material layer 26 And/or combustion flame and thermal energy between the circumference of elastomeric layer 28.Insulation material layer 26 and/or elastomeric layer 28 and shell Cooperation between 18 inner surface prevents and more preferably prevents the electric energy in electric energy storage batteries unit module 12 The thermal energy of the burning of storage batteries unit 14 and flame migrate in electric energy storage batteries unit barrier 24 with electric energy storage batteries One position on opposite sides of the adjacent side of unit module 12.
What the burning that heat insulator 26 is used as electric energy storage batteries unit in electric energy storage batteries unit module 12 generated Thermal energy is migrated to the thermal insulation layer and barrier of the side opposite with electric energy storage batteries unit module 12 of heat insulator layer 26. Barrier is provided by migrating from the side of electric energy storage batteries unit barrier 24 to the other side for thermal energy, is reduced or avoided by temperature The electric energy storage batteries cell failure that degree is increased and induced is propagated.Heat insulator 26 is selected from the material with thermal conductance, so that Heat insulator prevents thermal energy from shifting via heat insulator.In other non-limiting examples, heat insulator 26 is by non- Conductive material and formed.The non-conductive mass-energy of heat insulator 26 prevents heat insulator from negatively affecting and is electrically connected to electricity The conduction feature of energy storage batteries unit 14, such as short circuit.The non-limiting example of heat insulator 26 is included in stores up with electric energy Battery unit is deposited to occur to be vented at temperature corresponding with the temperature lighted with thermal conductance below about 0.5BTU/ft2/hr/ The material of inch.In addition, heat insulator is fire proofing material when temperature is greater than about 130 DEG C.Heat insulator may include ceramics Material, (vermiculite-based) material based on vermiculite or the material that can provide thermal insulation properties known to other.Ceramics The carrier of material may be based on cloth (ceramic-impregnated cloth), the fibre of (paper-based) injection ceramics of paper Dimension glass or the other materials for being formed as the thin slice containing heat insulator.The non-limiting example of heat insulator includes Material with ceramic fibre.This ceramic fibre can be formed by aluminium, mullite (mullet), silicon carbide, zirconium oxide or carbon.? In specific embodiment, heat insulator layer 26 includes the carbon fiber using class paper form.Although being not restricted to this, some ceramics Paper material is fire proofing material in 1260 DEG C or higher temperature.According to Fig. 1 and embodiment shown in Fig. 2, heat insulator layer 26 Thickness range from about 0.5 millimeter to about 2 millimeter, however heat insulator can be thicker or thinner, this depends on desired heat The amount of insulation.
By the burning to the electric energy storage batteries unit 14 in electric energy storage batteries unit module 12 migrate to electric energy Opposite 24 side of electric energy storage batteries unit barrier of storage batteries unit module 12 provides the non-combustible barrier of physics, elastic material 28 are used as combustion barriers.The non-limiting example of the material of elastomeric layer 28 is included in about 130 DEG C of temperature or higher Shi Buke The elastic material of combustion.In non-limiting embodiment, by using the material softer than electric energy storage batteries unit terminal material Material forms elastic material 28, to provide the protection of the terminal to electric energy storage batteries unit 14.In other non-limiting examples, Elastic material 28 is formed by non-conductive material.The non-conductive property of elastic material 28 prevents elastic material from negatively affecting It is electrically connected to the conduction feature of electric energy storage batteries unit 14, such as short circuit.The non-limiting example of elastic material 28 includes pressing It is less than about 50 to 100 according to Shore cooler hardness and resistance is greater than about 10 to about 20ohm or higher material.In particular implementation In example, elastic material is fluoropolymer rubber, butyl rubber, chlorosulfonated polyethylene rubber, epichlorohydrin (epichlorohydrin) Rubber, ethylene propylene rubber, fluoroelastomer rubber, fluorine silicon (fluorosilicone) rubber, hydrogenated nitrile (hydrogenated Nitrile) rubber, natural rubber, nitrile rubber, perfluorinated elastomer body rubber, polypropylene (polyacrylic) rubber, polychlorostyrene fourth two Alkene (polychloroprene) rubber, polyurethane (polyurethane) rubber, silicon (silicone) rubber and styrene fourth Diene (styrene butadiene) rubber.According to Fig. 1 and embodiment shown in Fig. 2, the thickness of elastomeric layer 28 is about 0.5 millimeter to 2.0 millimeters, however elastic material can be thicker or thinner, this depends on desired burning inhibition of metastasis and/or hits Hit absorption.
As described in " background technique ", in the application that single electric energy storage batteries unit is used only, the burning of battery unit Undesirable situation can be generated.When multiple electric energy storage batteries units are deployed to the form of battery pack or module, this can be aggravated The seriousness of kind situation.For example, when electric energy storage batteries unit includes lithium ion chemical composition, the combustion of lithium ion chemical composition It burns and can produce the local temperature for being higher than and making unstable, rupture and burning the temperature of lithium ionic cell unit.Therefore, lithium ion battery The burning of single lithium ionic cell unit in group may cause described group of rupture, light and burn.Fortunately it has been confirmed that lithium from Sub- battery unit is very safe, and the rupture of lithium ionic cell unit and burning are very rare.However, for the peace of user Full interests and use electric energy storage batteries unit as the acceptance of electric vehicle power supply, take action to reduction generation lithium from A possibility that rupture and burning of sub- electric energy storage batteries unit and the thing being unlikely to occur lighted in this battery unit Management burning is very important in part.
According to embodiment as described herein, electric energy storage batteries list is managed by the combination of following characteristics as described herein The burning of member or the burning of multiple electric energy storage batteries units.Firstly, using since rupturing battery unit gas ignition with The burning of support level fuel cell unit needs oxygen.Secondly, limitation thermal energy from failure and may fire in the event burnt The battery unit of burning is migrated to other battery units.Third burns gas caused by battery unit failure and this gas Gas control is formed by airtight electric energy storing device, up to specific threshold pressure.4th, control electric energy accumulator To avoid in inexpectancy and the direction that may cause danger uncontrolled rupture occurs for the rupture of part.
Firstly, lithium-ion electric energy storage batteries unit is contained in the air-tight casing of no oxygen, by battery unit and incite somebody to action Oxygen isolation required for being lighted from the combustible gas that cracking battery unit is discharged and it is maintained to burn.Therefore, exist Single battery cell failure causes battery unit to rupture and lights the unlikely scenario of the gas being discharged from battery unit In, oxygen that the reaction occurred between the reactant that can be used for maintaining the oxygen of burning to be limited by faulty battery cell generates Gas.The oxygen that can support burning is limited to the oxygen that (in situ) is generated in situ, so that electric energy storing device burns Time span it is most short, thus reduce that temperature in device is increased to break down and subsequent rupture and burning are from other electricity A possibility that gas of pool unit.In addition, no oxygen can prevent the burning of thermal energy absorbing material in electric energy storing device.For example, Phase-change material as thermal energy absorbing material is flammable when becoming liquid.Contained by limiting oxygen in electric energy storing device Amount, avoids the burning of phase-change material.
Typically, the gas discharge from independent electric energy storage batteries unit and burning only maintain the several seconds.In this time In, local temperature is close to so that adjacent electric energy storage batteries unit becomes unstable temperature.In order to which other are stable Electric energy storage batteries unit is isolated with the thermal energy being discharged from faulty battery cell, occupies adjacent electricity by above-mentioned thermal energy absorbing material Gap between energy storage batteries unit.What thermal energy absorbing material absorption was discharged by battery unit failure and from faulty battery cell Thermal energy caused by gas burns, the temperature without increasing thermal energy absorbing material.Thermal energy absorbing material in electric energy storing device exists The amount of absorbable thermal energy depends on the composition of thermal energy absorbing material and the current volume of material before its temperature is begun to ramp up.Example Such as, the volume of thermal energy absorbing material is enough to absorb the failure by certain amount of battery unit and the complete of the thermal energy generated that burn Portion;However, thermal energy absorbing material can not be absorbed in the case where not increasing temperature if other battery unit failures and burnt Additional thermal energy.
In the event being unlikely to occur, it is more than that thermal energy absorbing material can inhale that failure electric energy storage batteries unit, which generates, The increase of a possibility that thermal energy of the amount of the thermal energy of receipts, other electric energy storage batteries units may break down and burn causes certainly The Potential feasibility of body fault propagation and the burning of other battery units.When not including feature disclosed in the present application, this itself Fault propagation and burning can cause the pressure of electric energy storing device that can run up to and cause the uncontrollable degree of device breakage.This Shen Electric energy storing device that please be disclosed includes explosion structure, and explosion structure is configured as the pressure in device more than threshold quantity When, it bursts in predetermined position and predetermined direction.This explosion structure is described in detail more fully below.This threshold pressure may be set to any Rank, as long as lower than the device in the pressure for being not intended to the position to burst to burst.The electric energy accumulator The pressure of part explosion is it is also possible to consider pressure caused by more than X single battery cell failure and burning, and wherein X is battery unit Quantity, more than the quantity battery unit failure and burning will cause the pressure in device be more than make the electric energy storing device The pressure needed for the explosion of undesirable position.According to the embodiment for including the explosion structure, the device outer case can burst And hot gas and flame are directed to the direction for reducing the risk for the people that injury is located near shell.
Referring to Fig. 5, in Fig. 1 and embodiment shown in Fig. 2, pedestal 22 has explosion structure 30.Explosion structure in Fig. 5 30 include " indentation (scored) " feature in the bottom of pedestal 22.Indentation is carried out to the bottom of pedestal 22 and generates knurled portion, It is thinner than the non-knurled portion of pedestal 22.Indentation or is imprinted indentation by providing the indentation mold into pedestal It provides in the base.Also indentation can be provided by other known technology.It is carved although explosion structure 30 shown in fig. 5 has Trace part, it will be appreciated that, it also can be used as explosion structure different from other features of mark feature.For example, explosion structure can Using the form of release valves, or using other knots that can be vented shell 16 when the pressure in shell is more than predetermined extent Structure or hardware.
Explosion structure 30 is designed to rupture or fragmentation when the pressure in shell 16 reaches predetermined pressure and opens.It can make to burst The predetermined pressure of structure breaking can be any pressure, such as the independent electric energy storage batteries higher than the predetermined quantity in shell 16 The pressure for the pressure of unit 14 lighted and assembled inside the shell after burning.For example, if the electric energy storage electricity lighted and burnt The quantity of pool unit is less than predetermined quantity, then the pressure increase in shell 16, which will not generate, makes shell 16 that uncontrolled explosion occur Significant risk.On the other hand, if the quantity for the electric energy storage batteries unit lighted and burnt is greater than predetermined quantity, shell Interior pressure increase will increase the risk of the uncontrolled explosion of shell.Explosion structure 30 is designed to the pressure in shell 16 and reaches pre- Rupture or fragmentation are opened when level pressure is strong.In the embodiment shown in fig. 5, explosion structure 30 is located at the bottom of pedestal 22.Therefore, when Burst structure 30 burst when, hot combustion gas and flame can be discharged from the bottom of portable electric energy memory device 10, and by Lower guiding.Although explosion structure 30 is located at the bottom of pedestal 22, it may be alternatively located at other positions.For example, explosion structure 30 The side of pedestal 22 can be located at, or in the side of shell 18, or at the top or side of lid 20.Usually explosion structure is specific Position is chosen as so that fuel gas and flame are exported shell 16 in safe direction, for example away from during normal use close to outer The direction of the people of shell 16.In the embodiment that electric energy storing device is located at the under-seat of Segway Human Transporter, explosion structure 30 is excellent Selection of land is located at the bottom of pedestal 22, so that shell 16 is discharged with the direction far from user in hot gas and flame.
Referring to Fig. 2, on the side of electric energy storage batteries unit module 12, adjacent to pedestal 22, elastomeric layer 32 will The electric energy storage batteries unit 14 of electric energy storage batteries unit module 12 is separated with the pedestal 22 for including explosion structure 30.In this position Place is set, insulation material layer is omitted, this is because since other are not present under battery cell module 12 in the embodiment The propagation of the position of electric energy storage batteries unit and pedestal 22 reason farthest from user, thermal energy and burning is less important ?.
Referring to Fig. 3, another embodiment of electric energy storage batteries unit component is shown, the embodiment includes more than one Electric energy storage batteries unit module 12.In the embodiment described in figure 3, including multiple independent electric energy storage batteries units 46 Two electric energy storage batteries unit modules 34 are located at 12 top of the first electric energy storage batteries unit module, and store up including multiple electric energy Deposit battery unit 14.Above the second electric energy storage batteries unit module 34 is the second electric energy storage batteries unit barrier 36, it is identical as electric energy storage batteries unit barrier 24 shown in FIG. 1.The embodiment of Fig. 3 equally with embodiment shown in FIG. 1 The difference is that including the first electric energy storage batteries unit barrier 38, the first electric energy storage batteries unit barrier 38 include folder Heat insulator layer 40 between elastomeric layer 42 and elastomeric layer 44.Elastic material 42 and 44 and heat insulator 40 is substantially identical as elastic material 32 described in Fig. 2 and heat insulator 26 as above-mentioned Fig. 1.First electric energy storage batteries unit The electricity of electric energy storage batteries unit 46 in the second elastomeric layer 42 protection electric energy storage batteries unit module 34 of barrier 38 Terminal.
Unlike reference Fig. 1 and Fig. 2 the embodiment described, the embodiment of electric energy storing device shown in Fig. 3 includes The second electric energy storage batteries unit module 34 above electric energy storage batteries unit module 12.Second electric energy storage electricity is provided Pool unit module 34 makes it desirable to protection electric energy storage batteries unit module 34 and protects against generation in the first electric energy storage batteries Burning in unit module 12, vice versa.This protection is provided by three layers of electric energy storage batteries unit barrier 38.
Although it should be understood that describing above with reference to Fig. 1 to Fig. 3 including single electric energy storage batteries unit module and two The embodiment of electric energy storage batteries unit module, according to content as described herein, it is possible to provide more than two electric energy storage batteries lists Element module.When providing more than two electric energy storage batteries unit modules, according to embodiment as described herein, electricity is stored in electric energy Between pool unit module, three layers of electric energy storage batteries list similar to the unit barrier of electric energy storage batteries shown in Fig. 3 38 are provided First barrier.
In addition, although it have been described that the specific embodiment of electric energy storage batteries unit barrier 24,36 and 38, it should be understood that It is that if necessary to other thermal insulations, then can provide other heat insulator layers.Similarly, if necessary to further protect electric end Son, it is possible to provide other elastomeric layers.
Referring to Fig. 4, two individual portable electric energy storage batteries units 50 are shown.These electric energy storage batteries units It can be identical as electric energy storage batteries unit 14 and 46 described in reference Fig. 1-Fig. 3.As described in " background technique ", in rare situation In, the internal or external short circuit of the electric energy storage batteries unit of such as lithium ionic cell unit can occur.When battery unit by When serious impact or shock, it may occur however that this short circuit.It is entered between anode and cathode in the metallic particles of micron-scale In event, the thin essence of the polymeric separator plates in battery unit makes it be easy short circuit.According to embodiment as described herein, independent On portable electric energy storage batteries unit 50, the load absorption component 52 of absorbable impact and shock is provided, otherwise, these impacts Interior polymer partition or generation little metallic particles may be destroyed with hitting, once these little metallic particles enter electric energy storage It deposits in battery unit, it will cause short circuits.In the embodiment shown in fig. 4, in independent portable electric energy storage batteries unit 50 Each end on be arranged load absorption component 52.It should be understood that disclosure of this application is not limited to include electric energy storage batteries list Load absorption component 52 on the both ends of member 50, and can load absorption only be provided on one end of electric energy storage batteries unit 50 Component 52.
Load elements 52 include centre lugs (central tab) 54, can hang on annular load by arch cantilever 58 Part ontology 56.In the embodiment shown in fig. 4, plane locating for centre lugs 54 is different from putting down locating for load elements ontology 56 Face, such as thereunder.Cantilever 58 extends to centre lugs 54 from annular load part ontology 56.Due to centre lugs 54 and annular Load elements ontology 56 is located at Different Plane, thus cantilever 58 extends between two planes.Therefore, cantilever 58 is used as centre lugs 54 With the class spring part between annular load part ontology 56.On top referring to the electric energy storage batteries unit 50 being located in Fig. 4 Load elements 52, centre lugs 54 are attached to the top of storage batteries unit 50.Thus, annular load part ontology 56 hangs on center The top of 54 place plane of contact pin.When will load be placed on annular load part ontology 56 when, cantilever 58 absorbs some or all of Load, thus by electric energy storage batteries unit 50 and this load isolation.In Fig. 4 the embodiment described, cantilever 58 is shown as arch Component, and centre lugs 54 are shown as central portion.Fig. 4 shows the non-limiting embodiment of these features, and should be understood that Be that centre lugs 54 can have a different shapes, such as square or triangle, and cantilever 58 is not necessarily arch, such as It can be straight.
Fig. 6 shows gas and thermal energy and can store from the electric energy of the failure in the second electric energy storage batteries unit module 100 The different paths of battery unit discharge.In first example indicated by dotted line 102, from formation electric energy storage batteries unit mould The gas and thermal energy that the electric energy storage batteries unit (not shown) of a part of block 100 is discharged hit the second electric energy storage electricity The inner surface of the top cover 104 of pool unit module 100, the inner surface by top cover 104 reflects, and is housed inside the In two electric energy storage batteries unit modules 100.These gases and thermal energy are to the anti-of the second electric energy storage batteries unit module direction It is undesirable for penetrating, and reason is: gas and thermal energy can be to unspoilt electric energy in electric energy storage batteries unit module 100 Storage batteries unit damages.For example, the thermal energy from gas burning will cause unspoilt electric energy storage batteries unit Spontaneous combustion, this can propagate the thermal runaway of electric energy storage batteries unit module 100.In addition, the second electric energy storage batteries unit module 100 Interior gas burning will cause the pressure in the second electric energy storage batteries unit module 100 and increase.If this pressure is more than the The explosion pressure of two electric energy storage batteries unit modules 100, then the second electric energy storage batteries unit module 100 can burst, can There can be explosive force.
In another example indicated by dotted line 106, gas and thermal energy pass through lid 104, and store electricity from the second electric energy Pool unit module 100 escapes.Gas and thermal energy are flowed about in the first electric energy storage batteries unit module 108.Although this example It reduces gas and thermal energy causes electric energy storage batteries cell failure in the second electric energy storage batteries unit module 100, rupture Or a possibility that lighting or a possibility that reduce the explosion of the second electric energy storage batteries unit module 100, however but increase gas Body and thermal energy cause electric energy storage batteries cell failure in the first electric energy storage batteries unit module 108, quick-fried along dotted line 106 The risk split or lighted, this extensive risk for causing portable electric energy memory device 120 to burst increase.When the first electric energy storage batteries Local temperature in unit module rise to temperature that independent portable electric energy storage batteries unit breaks down and/or lights it When upper, it may occur however that electric energy storage batteries unit lights in the first electric energy storage batteries unit module 108.For example, from electric energy Gas and thermal energy that storage batteries unit module 100 is discharged can hit the downside of the first electric energy storage batteries unit module 108, and And the local temperature in the first electric energy storage batteries unit module 108 can be caused to rise to electric energy storage batteries unit module 108 On the temperature that interior independent electric energy storage batteries unit is lighted and/or bursts.Hit the first electric energy storage batteries unit module The gas and thermal energy of 108 downsides can dissipate and be moved to the circumference of the first electric energy storage batteries unit module 108, herein, Gas and thermal energy can be by between the electric energy storage batteries unit modules 108 and shell 110 of shown electric energy storing device 120. It is more than electric energy that the gas and thermal energy for being present in the position, which can cause the local temperature of the first electric energy storage batteries unit module 108, The temperature that independent in storage batteries unit module 108 electric energy storage batteries cell failure, bursts and/or lights.
Referring to Fig. 7, showing and showing electric energy storing device according to non-limiting embodiment includes electric energy storage batteries list The decomposition diagram of element module 200.Schematically show electric energy storage batteries unit module 200;It will be appreciated, however, that Similar to electric energy storage batteries unit described in Fig. 2 and Fig. 3, module 200 includes multiple individual electric energy storage batteries units.This Outside, electric energy storage batteries unit module 200 is illustrated as rectangular module;However, electric energy storage batteries unit module 200 is not limited to Rectangle, and can be other shapes, such as the cylindrical or rectangle with fillet.Although it is not shown, module 200 includes The electrical connection being electrically connected with the electric energy storage batteries unit in module 200, and module 200 includes being electrically connected to module 200 By the connection for the device that module 200 drives.Module 200 includes the outer wall 202 for limiting the circumference of module 200.
The position adjacent with four sides of outer wall 202 is a pair of of sidewalls 204.Each sidewalls 204 include in face of electricity It is outer on the inner surface 205 of energy storage batteries unit module 200 and the side opposite with inner surface 205 of sidewalls 204 Surface 208.In the embodiment shown, outer surface 208 is backwards to (face away) electric energy storage batteries unit module 200.Scheming In 7 non-limiting embodiment, sidewalls 204 are the two parts for being each other mirror image.It should be understood that sidewalls 204 can Including the single part slided in module 200, or may include is more than two parts.Sidewalls 204 include multiple outlets 206, sidewalls 204 are passed through up to outer surface 208 from inner surface 205.In the embodiment shown, outlet 206 is circle And it is arranged in multiple vertical columns.Outlet 206 is not limited to circle, and can be other shapes, such as ellipse or rectangle. In addition, outlet 206 does not need to be arranged as multiple vertical columns, and it can be configured to the other forms different from vertical column.Outlet 206 In sidewalls 204, position corresponds to the void space in electric energy storage batteries unit module 200.This void space position Between the independent electric energy storage batteries unit in battery cell module 200.It is aligned by the way that 206 will be exported with void space, example Such as in course of normal operation, can be easier that fluid flowing occurs, promote convection current between independent electric energy storage batteries unit or The heat transfer of other forms and from the side of sidewalls 204 to the opposite side of sidewalls 204 fluid flow.Although not It shows, however in some embodiments, sidewalls 204 can be shaped to and meet electric energy storage batteries unit module 200 Lateral profile, this is because displacement 200 circumference of electric energy storage batteries unit module independent electric energy storage batteries unit cause 's.The material of side wall 204 can be kept out and the high temperature associated with thermal energy of the gas after electric energy storage batteries cell failure.This temperature Degree can be 1000 DEG C or higher.The examples material of side wall 204 includes metal or plastics, or can keep out this high temperature without burning or The other materials significantly deformed.
Above electric energy storage batteries unit module 200 is electric energy storage batteries unit barrier 210.Electric energy storage electricity Pool unit barrier 210 has several functions, comprising: as being disseminated to another electricity from electric energy storage batteries unit module 200 Can storage batteries unit module burning barrier, for by the electric energy storage batteries in electric energy storage batteries unit module 200 The electrode of unit and the conductance element of electric energy storage batteries unit barrier 210 are electrically isolated, and are provided for coming from or going to electric energy storage Deposit the electric energy storage batteries list in the barrier of the heat of battery cell module 200, and protection electric energy storage batteries unit module 200 The electrode of member protects against injury caused by due to the hard or coarse material of contact electric energy storage batteries unit barrier 210.? In non-limiting embodiment shown in Fig. 7, electric energy storage batteries unit barrier 210 includes the electric energy storage electricity for being clipped in elastic material The electricity isolated layer 212 of dielectric material between pool unit contact protection layer 214 and the combustion barriers layer 216 of non-combustible materials.
Electric energy storage batteries unit contact protection layer 214 is elastic material, and unrestricted example is included in about 130 DEG C Or the higher non-flammable elastic material of temperature." elastic material " word refers to flexible, resilient and substantial after a deformation The material of its original-shape can be returned back to.Elastic material form as described herein is not limited to return back to it completely after a deformation The flexible and recoverable material of original-shape.According to non-limiting example disclosed in the present application, elastic material is included in change The material flexible and recoverable of its original-shape will not be returned back to after shape completely.In non-limiting embodiment, pass through Electric energy storage batteries unit contact protection layer 214 is formed with the material softer than forming electric energy storage batteries unit terminal, pair The terminal for forming the electric energy storage batteries unit of a part of electric energy storage batteries unit module 200 provides physical protection.At it In his unrestricted example, the elastic material of electric energy storage batteries unit contact protection layer 214 does not have electric conductivity.Electric energy storage The non-conductive of battery unit contact protection layer 214 prevents electric energy storage batteries unit contact protection layer 214 from negatively affecting electricity It is connected to the terminal or conduction feature of electric energy storage batteries unit, such as short circuit.Form the unit contact protection of electric energy storage batteries Layer 214 material non-limiting example include according to Shore cooler hardness be less than about 50 to 100 and resistance be greater than about 10 to About 20ohm or higher elastic material.In certain embodiments, elastic material is fluoropolymer rubber, butyl rubber, chlorine sulphur Change polyethylene rubber, epichlorohydrin rubber, ethylene propylene rubber, fluoroelastomer rubber, fluorine silicone rubber, hydrogenated nitrile rubber, natural rubber Glue, nitrile rubber, perfluorinated elastomer body rubber, polypropylene rubber, (co) polychloroprene rubber, polyurethane rubber, silicon rubber and benzene second Alkene butadiene rubber.In other specific embodiments, elastic material is the foam of low molecular weight, integration, such as thermosetting resin envelope Close battery unit polyurethane foam or other closing battery unit thermoset polymers.
Electric energy storage batteries unit contact protection layer 214 is also as from electric energy storage batteries unit contact layer 214 Combustion propagation from one side to the opposite side of electric energy storage batteries unit contact protection layer 214 barrier or barrier.By to from The gas burning of the electric energy storage batteries unit discharge of 200 internal fault of electric energy storage batteries unit module provides non-flammable obstacle Object or flame barrier object, barrier or barrier of the electric energy storage batteries unit contact protection layer 214 as combustion propagation.At it In his embodiment, electric energy storage batteries unit contact protection layer 214 is in electric energy storage batteries unit module 200 and electricity isolated layer Thermal insulation is provided between 212.Electricity isolated layer 212 is transferred to from electric energy storage batteries unit module 200 for thermal energy, this thermal insulation Stop and/or as barrier.Stop the heat transfer screen between electric energy storage batteries unit module 200 and electricity isolated layer 212 Cover the adjacent electric energy for being located at the adjacent electric energy storage batteries unit module (not shown) of 200 top of electric energy storage batteries unit module Storage batteries unit (not shown), which is protected from, causes electric energy storage batteries unit in adjacent electric energy storage batteries unit module The thermal energy of failure.For example, in the rare events of the electric energy storage batteries cell failure of electric energy storage batteries unit module 200, Evolved gas after the burning of storage batteries unit, the burning of gas can generate a large amount of thermal energy.These thermal energy can cause other electric energy to store up It deposits battery unit failure and fuel gas may be released.If lighting gas, electric energy storage batteries unit may occur Thermal runaway.The non-limiting example of material for electric energy storage batteries unit contact protection layer 214 is corresponding to electric energy storage Battery unit discharges fuel gas and occurs at the temperature of the temperature of gas ignition, has and is less than about 0.5BTU/ft2/hr/inch Thermal conductivity value.According to Fig. 7 and Fig. 8 the embodiment described, about 0.1 milli of thickness of electric energy storage batteries unit contact protection layer 214 Rice is to 3.0 millimeters.In other embodiments, about 0.5 millimeter to 2.0 of the thickness of electric energy storage batteries unit contact protection layer 214 Millimeter, and in other embodiments, about 0.75 millimeter of the thickness of electric energy storage batteries unit contact protection layer 214 to 1.25 millis Rice.Electric energy storage batteries unit contact protection layer 214 is thicker or thinner than above-mentioned non-limiting range, this depends on burning Inhibition of metastasis amount, thermal insulation, electric energy storage batteries unit terminal protecting and/or desired shock absorb.
Electricity isolated layer 212 is formed by non-conductive material, and non-limiting example is included in about 130 DEG C or higher temperature Spend material non-combustible and that there is the dielectric constant for becoming the body that is electrically insulated.In non-limiting embodiment, electricity every The Dielectric materials of absciss layer 212 prevent electricity isolated layer 212 from negatively affecting the terminal for being electrically connected to electric energy storage batteries unit Or conduction feature, such as short circuit.The non-conductive material of electricity isolated layer 212 is also by the terminal and shape of electric energy storage batteries unit It is electrically isolated at the circuit and combustion barriers layer 216 of electric energy storage batteries unit module 200.In other non-limiting embodiments In, the non-conductive material for forming electricity isolated layer 212 is non-flammable or fireproof, so that electricity isolated layer 212 hinders Or the opposite side for preventing from burning from the side of electricity isolated layer 212 to electricity isolated layer 212.In other non-limiting embodiments In, the non-electrical conductive material of electricity isolated layer 212 is formed in electric energy storage batteries unit contact protection layer 214 and combustion barriers layer Thermal insulation is provided between 216.For from electric energy storage batteries unit module 200 via electric energy storage batteries unit contact protection layer 214 to electricity isolated layer 212 heat energy transfer, thermal insulation carry out stop and/or as barrier.Stop electric energy storage batteries unit mould Heat transfer between block 200 and electricity isolated layer 212 help to protect adjacent electric energy storage batteries unit module (not shown) from By thermal energy, thermal energy can cause the failure of the electric energy storage batteries unit in adjacent electric energy storage batteries unit module.For example, (it can be generated greatly the electric energy storage batteries cell failure and discharge gas of electric energy storage batteries unit module 200 after being combusted Calorimetric energy) rare events in, this thermal energy can cause other electric energy storage batteries in adjacent electric energy storage batteries unit module Cell failure bursts and lights.The non-limiting example of material for electricity isolated layer 212 is quick-fried with electric energy storage batteries unit It splits at temperature corresponding with the temperature of fuel gas that release can light, has and be less than about 3BTU/ft2/ hr/inch, it is less than About 2BTU/ft2/ hr/inch and be less than about 1BTU/ft2The thermal conductivity value of/hr/inch.In some embodiments, electricity isolated layer 212 non-electrically conducting material is self-gravitation (self-extinguishing).
Non-electrically conducting material may include ceramic material, based on the material of vermiculite or other be known as non-conductance or bad electricity The material of conductor and excellent heat insulator.The carrier of ceramic material can be based on paper, injection ceramics cloth, fibrous glass or It is the other materials for being formed as the thin slice containing heat insulator.The non-limiting example of non-electrically conducting material includes having ceramics The material of fiber, such as compressible fibre is formed by the braiding of tripoli and calcium oxide fiber and non-flammable organic binder Tie up piece.This ceramic fibre can be formed by alumina, mullite, silicon carbide, zirconium oxide or carbon.In a particular embodiment, non-conductance material Material include tripoli/tripoli fiber, aluminium,And calcium-magnesium-silicon silicate fiber.Although not with this It is limited, but some non-electrically conducting material for electricity isolated layer 212 are fireproof at 1260 DEG C or higher.According to Fig. 7 and Fig. 8 Shown in unrestricted example, form about 0.1 millimeter of the thickness range of the non-electrically conducting material layer of electricity isolated layer 212 to about 3 millis Rice.In other embodiments, about 0.25 millimeter to 2.0 millimeters of the thickness of electricity isolated layer 212, and in other embodiments, electricity About 0.35 millimeter to 1.25 millimeters of the thickness of separation layer 212.Electricity isolated layer 212 can be thicker than the unrestricted range Or it is thinner, depend on electric isolution amount, burning inhibition of metastasis with and/or desired thermal insulation.
Combustion barriers layer 216 is non-flammable high-strength material, and unrestricted example is included in about 130 DEG C or higher Temperature at it is non-combustible and can keep out from the electric energy storage batteries unit of the failure of electric energy storage batteries unit module 200 be discharged The material of the type for the power that gas is applied and event occurred.The failure of electric energy storage batteries unit is (such as due to structure Destroy and/or short circuit) can cause failure electric energy storage batteries unit explosion (as in battery unit pressure accumulation knot Fruit).After explosion, the gas high speed in electric energy storage batteries unit sheds and burns.Combustion barriers layer 216 it is non-combustible, High-strength material, which is selected from, can keep out from portable electric energy memory device with power caused by these gases for shedding at a high speed and support Keep off the material for the related high temperature that burns with this gas.Combustion barriers layer 216 stops and ideally prevents electric energy of the hot gas from failure Flame impingement caused by the discharge of storage batteries unit and/or the anti-burning of hot gas here is located at electric energy storage batteries unit module 200 The adjacent electric energy storage batteries unit module of top.Stop and/or prevent gas and/or flame impingement it is adjacent electric energy storage Battery cell module reduces the electric energy storage batteries unit in adjacent electric energy storage batteries unit module because being exposed to failure electricity Can temperature caused by the gas of storage batteries unit burning and a possibility that break down.In non-limiting embodiment, The non-combustible of combustion barriers layer 216, high-strength material are used as burning from electric energy storage batteries unit module 200 to adjacent electricity The obstruction or barrier of energy storage batteries unit module.The non-limiting embodiment packet of material as combustion barriers layer 216 About 130 DEG C or higher temperature can be kept out without molten metal or metal alloy by including.In other unrestricted examples, as The material of combustion barriers layer 216 include about 500 DEG C or higher, 750 DEG C or higher or even more than 1000 DEG C temperature without It can molten metal.In other embodiments, the metal for forming combustion barriers layer 216 is reached being exposed to the temperature more than 1000 DEG C After at least 10 seconds, it can't melt.In other embodiments, the material as burning zone 216 is included in be exposed to and be more than about 1400 DEG C of temperature later can't molten metal up at least 1 second.In specific non-limiting embodiment, combustion barriers Layer 216 is formed by copper, copper alloy, nickel or nickel alloy.Although copper, copper alloy, nickel and nickel alloy, which has been described, can be used as shape At the example of the metal of combustion barriers layer 216, however combustion barriers layer 216 still can be by that can stop or prevent gas and/or gas Burned flame impacts other metals of adjacent electric energy storage batteries unit module or nonmetallic materials are formed.
What it is positioned at 200 lower section of electric energy storage batteries unit module is the second electric energy storage batteries unit barrier 218.Electric energy storage Depositing battery unit barrier 218 includes electric energy storage batteries unit contact protection layer 220, electricity isolated layer 222 and combustion barriers layer 224.Description is equally suitable as described in electric energy storage batteries unit barrier 210 and its electric energy storage batteries unit contact protection layer 214 For the electric energy storage batteries unit contact protection layer 220 of electric energy storage batteries unit barrier 218, electricity isolated layer 222 and combustion Burn-in barrier layer 224.For the sake of clarity, the equal description is not repeated.The difference is that the second electric energy storage batteries unit barrier 218 The direction of electric energy storage batteries unit contact protection layer 220, electricity isolated layer 222 and combustion barriers layer 224.Electric energy storage batteries list Three layers of first barrier 218 are identical three layers of the mirror images of electric energy storage batteries unit barrier 210.In other words, from the electric energy in Fig. 7 Storage batteries unit module 220 is removed so that electric energy storage batteries unit contact protection layer 220 is closest to electric energy storage batteries list Element module 200.It is electrically isolated layer 222 positioned at 220 lower section of electric energy storage batteries unit contact protection layer, and is located at and is electrically isolated 222 lower section of layer is combustion barriers layer 216.
Although being not shown in Fig. 7, electric energy storing device 120 further shown in Fig. 8 includes positioned at shown in Fig. 7 At least one additional electric energy storage batteries unit module 226 of 200 lower section of electric energy storage batteries unit module.Electric energy storage electricity Pool unit module 200 and electric energy storage batteries unit module 226 all include multiple electric energy storage batteries units 232.In other realities It applies in example, electric energy storing device 120 can comprise more than two electric energy storage batteries unit modules.For example, electric energy storing device 120 may include three or more electric energy storage batteries unit modules.In fig. 8, electric energy storage batteries unit module 226 presss from both sides Between electric energy storage batteries unit barrier 228 and electric energy storage batteries unit barrier 230.Electric energy storage batteries unit barrier 228 is identical as electric energy storage batteries unit barrier 210, and electric energy storage batteries unit barrier 230 and electric energy storage batteries list First barrier 218 is identical.Therefore, for the sake of clarity, omit to electric energy storage batteries unit barrier 228 and electric energy storage batteries unit screen The description of barrier 230.
Referring to Fig. 8, electric energy storage batteries unit module 200 and 226 distance D of electric energy storage batteries unit module.? In non-limiting embodiment, about 5 millimeters to about 20 millimeters of the range of distance D, in other non-limiting embodiments, distance About 7 millimeters to about 15 millimeters of the range of D, and in other embodiments, about 8 millimeters to about 11 millimeters of the range of distance D.Scheming 7 with embodiment shown in Fig. 8, and four spacers (spacer) 234 are located at electric energy storage batteries unit module 200 and electric energy storage It deposits between battery cell module 226.Spacer 234 can be cylinder, and respectively include centre bore.Each spacer 234 Centre bore is through each electric energy storage batteries unit contact protection layer 214 and 220, electricity isolated layer 212 and 222 and combustion barriers Layer 216 and 224 and with opening 236 be in fluid communication.The centre bore of spacer 234 and the combination of opening 236 make electric energy storage electricity The inside of pool unit module 200 and the internal fluid communication of electric energy storage batteries unit module 226.It is in fluid communication so that electric energy stores up The pressure deposited in battery cell module 200 and 226 is equal.
In the specific embodiment of subject matter, the carrying of inner surface 205 fire prevention of sidewalls 204 or fireproof meterial, Such as expansion pigment (intumescent paint).Alternatively, this fire prevention or fireproof meterial can by be located at module outer surface with The external outer wall 202 of electric energy storage batteries unit module 200 between the inner surface of sidewalls 204 carries.It is anti-to provide this Fire/fireproof meterial stops the flame on the outside of sidewalls 204 to migrate to the inside of electric energy storage batteries unit module 200.
Referring to Fig. 7, electricity isolated layer 212 includes multiple offset outlets 238.Combustion barriers layer 216 includes multiple offset outlets 240.Electricity isolated layer 222 includes multiple offset outlets 242 and combustion barriers layer 224 includes multiple offset outlets 244.Biasing Outlet 238,240,242 and 244 is substantially the same.In Fig. 7 the embodiment described, offset outlet 238 and 240 is in upward side To opening, and offset outlet 242 and 244 is opened in downwardly direction.Offset outlet 238,240,242 and 244 substantially with formation The independent electric energy storage batteries unit 232 of electric energy storage batteries unit module 200 is aligned.
Offset outlet 238 is equally applicable to the description of offset outlet 240 below.Referring to Fig. 9 and Figure 10, offset outlet 240 include at least one air flap (flap) 248 being formed in combustion barriers layer 216.In the embodiment of Fig. 9 and Figure 10, Vibration piece 248 is square.Air flap 248 is limited by the multiple knurled portions 250,252 and 254 for passing through combustion barriers layer 216 's.Can be used be suitble to cutting metal cutting device (such as blade, coining, laser etc.) formed knurled portion 250,252 with 254.Knurled portion 250,252 and 254 limits three sides of square air flap 248.Remaining side is by hinge portions (hinge Portion it) 256 limits.256 incomplete penetration combustion barriers layer 216 of hinge portions, and it is used as similar hinge structure, air door Piece 248 is bent along the similar hinge structure, thus air flap 248 is movable to open stance from detent position shown in Fig. 10 It sets.It can be used and be capable of the device of compression and combustion barrier layer 216 in the position of hinge portions 256 to form hinge portions 256.Though So hinge portions 256 are described as to crimp (crimped) structure, but embodiment as described herein is not limited to the hinge of curling Part 256 and including can be as the other structures of the hinge of air flap 248.For example, can by aperture (perforation) or It is that other facilitate combustion barriers layer 216 and provide hinge portions 256 along the structure that hinge portions 256 are folding or bending over.Wind Door piece 248 hinge portions 256 can be designed such that when on air flap 248 apply predetermined threshold pressure when, offset outlet 238 are bent along its hinge portions, and mode as shown in Figure 10 is opened.
In addition to the offset outlet 240 being arranged in combustion barriers layer 216, also provided in electricity isolated layer 212 similar inclined Set outlet 238.In the embodiment shown in Fig. 7,9 and 10, offset outlet 240 and offset outlet 238 are essentially identical;However, this Literary the embodiment described be not limited to include essentially identical offset outlet 240 and offset outlet 238 portable electric energy storage Device.Referring to Fig.1 0, the offset outlet 238 being arranged in electricity isolated layer 212 is formed by three knurled portions and hinge portions.? In the embodiment described, three knurled portions of offset outlet 238 are located at the knurled portion 250,252 and 254 of offset outlet 240 Lower section, the hinge portions of offset outlet 238 are located at hinge portions 256 lower sections and the offset outlet 238 of offset outlet 240 Air flap 239 is located at 248 lower section of air flap.In other embodiments, the knurled portion of offset outlet 238 is located at offset outlet 240 256 lower section of hinge portions.In some embodiments, the peripheral dimensions of air flap 239 can be slightly less than air flap 248 Peripheral dimensions.When air flap 248 is opened, the peripheral dimensions official post between air flap 239 and air flap 248 obtains air flap 239 Opening in combustion barriers layer 216.On the contrary, the smaller peripheral dimensions of air flap 239 stop compared to air flap 248 Air flap 248 passes through the opening of offset outlet 238.In addition, the hinge portions of offset outlet 238 can be from the strand of offset outlet 240 The slightly laterally offset of chain part 256 promotes opening of the opening of offset outlet 238 in combustion barriers layer 216.
The upper table of the contacts-side-down electric energy storage batteries unit contact protection layer 214 of the air flap 248 of offset outlet 238 Face.This contact stops the air flap 238 in Fig. 9 and Figure 10 to move down, and then air flap 248 is stopped to move down.On the contrary, Air flap 239 in Figure 10 can be moved up with air flap 248.Therefore, offset outlet 238 and offset outlet 240 are " unidirectional " Outlet can open in the direction far from electric energy storage batteries unit module 200, without towards electric energy storage batteries unit module It opens in 200 direction.Offset outlet 238 and 240 is biased to detent position shown in Fig. 9;However, electric energy storage batteries unit The power of the pressure or the gas issued from the electric energy storage batteries unit of failure that accumulate in module 200 can provide driving force, cause Air flap 239 and 248 is bent and opens up along its individual hinge portions.In addition to making electric energy storage batteries unit module Except gas discharge in 200, the unidirectional characteristic of offset outlet also stops or prevents the gas that may impact offset outlet direct Contact forms the electric energy storage electricity for being located at the electric energy storage batteries unit module of the offset outlet side opposite with gas impact side Pool unit.Since offset outlet opens up inwardly from electric energy storage batteries unit module, offset outlet to be discharged The gas and thermal energy issued from the failure electric energy storage batteries unit in electric energy storage batteries unit module, and prevent impact phase The gas and thermal energy of the offset outlet of adjacent electric energy storage batteries unit module directly contact adjacent electric energy storage batteries unit module Electric energy storage batteries unit.
Electricity isolated layer 222 includes multiple offset outlets 242, and combustion barriers layer 224 includes multiple offset outlets 244. The foregoing description of offset outlet 238 and offset outlet 240 and the feature for forming offset outlet 238 and 240 is distinguished comparably Suitable for offset outlet 242 and offset outlet 244, only referring to offset outlet 242 in certain non-limiting examples embodiment shown in Fig. 7 It is opened downwards with 244.
1 and Figure 12 referring to Fig.1 shows the other embodiments of the shape of offset outlet 238,240,242 and 244.Figure 11 Periphery shape with the offset outlet in Figure 12 is triangle.Offset outlet in combustion barriers layer 216 includes air flap 260, Air flap 260 is limited by two knurled portions 262 and 264 and hinge portions 266.Electricity isolated layer 212 includes offset outlet, packet Air flap 261 is included, air flap 261 is similar to the air flap 260 of the offset outlet in combustion barriers layer 216.About offset outlet 238,240, the 242 and 244, above description of air flap 239 and 248, knurled portion 250,252 and 254 and hinge portions 256 It is applied equally to the air flap 260 of combustion barriers layer 16 and the offset outlet in electricity isolated layer 212 described in Figure 11 and Figure 12 With 261, knurled portion 262 and 264 and hinge portions 266.
3 and Figure 14 referring to Fig.1 shows the other embodiments of the shape of offset outlet 238,240,242 and 244.Figure 13 Each offset outlet with Figure 14 includes four air flaps 268,270,272 and 274, and respective periphery shape is triangle. Each air flap 268,270,272 and 274 is limited by the knurled portion 276 and 278 and hinge portions 280 of a pair of of square crossing It is fixed.About offset outlet 238 and 240, air flap 239 and 248, knurled portion 250,252 and 254 and hinge portions 256 Above description be applied equally to the burning zone 216 of Figure 13 and Figure 14 and the offset outlet in electricity isolated layer 212 and its individually Air flap, knurled portion and hinge portions.
Referring to Fig. 8, when the pressure in the second electric energy storage batteries unit module 226 is more than the (figure of offset outlet 238 and 240 7) when the pressure opened, offset outlet 238 and 240 is opened, so that gas is escaped via offset outlet.Gas is allowed to escape second Electric energy storage batteries unit module 226 reduces the risk that module 226 can burst.The evolution path of gas can follow similar Fig. 6 In dotted line 106.The gas and thermal energy issued from the second electric energy storage batteries unit module 226 impacts the first electric energy storage batteries The downside of unit module 200 is escaped along the downside of the first electric energy storage batteries unit module 200, enters the storage of the first electric energy Deposit the gap between the circumference and the first electric energy storage batteries unit module 200 and shell 282 of battery cell module 200.Work as gas When gap across the first electric energy storage batteries unit module 200 and shell 282 of body and thermal energy, dissipation gas or combustion gas The thermal energy of body.In fig. 8, the second electric energy storage batteries unit module 226 and the first electric energy storage batteries unit module 200 be apart Distance D.The distance between second electric energy storage batteries unit module 226 and the first electric energy storage batteries unit module 200 D pass through So that gas and thermal energy sideways diffusion by biggish surface area, promote to issue from the second electric energy storage batteries unit module 226 Gas and thermal dissipation.The thermal energy for the gas for promoting the second electric energy storage module to issue dissipates on large surface area and reduces It is gathered in the amplitude of the thermal energy in the small area of electric energy storage batteries unit module 200, thus reduces assembled thermal energy and makes A possibility that breaking down or explode at the electric energy storage batteries unit 232 in the first electric energy storage batteries unit module 200.Partially The opening for setting outlet 238 and 240 reduces the electric energy storage batteries list of the failure in the second electric energy storage batteries unit module 226 The gas and thermal energy that member 232 issues are interior along the dotted line 102 of Fig. 6 directly in the second electric energy storage batteries unit module 226 A possibility that portion guides.
When gas thermal energy flows between the first electric energy storage batteries unit module 200 and shell 282, pass through module side Wall 204 at least completely or partially separates the first electric energy storage batteries unit module 200 and gas and thermal energy.Pass through module side Outlet 206 in wall 204 mitigates the pressure difference of sidewalls 204.The pressure and module on side by making sidewalls 204 Pressure equilibrium on the other side of side wall 204, outlet 206 also promote the pressure equilibrium in portable electric energy memory device 120.Electricity Opening 236 in energy storage batteries unit barrier 210 and electric energy storage batteries unit barrier 218 also promotes portable electric energy storage Pressure equilibrium in memory device 120.Gas in 236 the second electric energy storage batteries unit module 200 of permission of opening passes through electric energy The inside that storage batteries unit barrier 210 or electric energy storage batteries unit barrier 218 reach portable electric energy memory device 120 is empty Between in or adjacent electric energy storage batteries unit module 226 in.Gas is stored up by electric energy storage batteries unit barrier 210 and electric energy Battery unit barrier 218 is deposited to be used for the electric energy storage batteries in the pressure and shell 282 in electric energy storage batteries unit module 200 Pressure equilibrium outside unit module 200, or with the pressure equilibrium in electric energy storage batteries unit module 226.In some implementations In example, pipe or conduit can be in the openings 236 and electric energy storage batteries unit module above electric energy storage batteries unit module Extend between the opening 236 of lower section.
The non-limiting embodiment of present disclosure has been described inclined in electric energy storage batteries unit barrier 210 Set the operation and advantage of outlet, offset outlet 242 and 244 and electric energy storage batteries unit barrier 218 have same operation with Advantage.Although the non-limiting embodiment of Fig. 6 and Fig. 8 only describes two electric energy storage batteries unit modules 200 and 226, so And according to embodiment as described herein, portable electric energy memory device includes that there is the electric energy of more than two type described herein to store up Deposit the portable electric energy memory device of battery cell module.
It provides above by using the various embodiments schematically illustrated with exemplary device.This schematically illustrate with Example includes one or more functions and/or operation, it is understood to one skilled in the art that can pass through extensive hardware and its group It closes, separately or collectively implements the various functions and/or operation in this structure and example.Group can be carried out to the various embodiments described above It closes, to provide more embodiments.This specification is cited and/or all United States Patent (USP)s for being listed in application data form, the U.S. are special Benefit application disclosure, U.S. Patent application, other country's patent, other country's patent application case and non-patent publication all pass through reference It is incorporated by herein.If necessary to use different patents, application and disclosed concept, the various aspects of embodiment can be repaired Change to provide more embodiments.
Although the environment of the electric system usually discussed and content are for personal transporter (such as all-electric scooter And/or motorcycle), but teachings of the present application can be used for various other environment, including other vehicles and non-vehicle environment.This Outside, although describing specific shape and direction, the explanation is not used to for embodiment being limited to description shown Form.For example, electric energy storage batteries unit is not necessarily cylinder, and it can be different shape, such as positive square cylindrical, positive square box Shape or rectangle box-like.Similarly, the embodiment of multiple electric energy storage batteries unit modules will be used to be described as overlieing one another Module;However, this explanation is not used to embodiment described herein being limited to this clear structure.For example, electric energy stores Battery cell module can be arranged side by side, and by the electric energy storage batteries unit barrier containing heat insulator layer and elastomeric layer Separation.In addition, electric energy storage batteries unit barrier is illustrated as the combination of elastomeric layer Yu heat insulator layer, and it is clipped in Heat insulator layer between two layers of elastic material.Similarly, these explanations are with description not embodiment is limited to institute The clear form stated.For example, electric energy storage batteries unit barrier may include more than the heat insulator of shown and specific description The number of plies of layer and elastomeric layer.
Above the description in the description of embodiment and abstract of description is not used to for embodiment to be limited to disclosed Specify form.Although specific examples described herein and example are those skilled in the art for illustrative purposes Understand, without departing from the spirit and scope of the disclosure, various equivalent modifications can be carried out.
According to above-mentioned specific embodiment, various changes can be carried out to embodiment.In general, in claim below In, used term is understood not to for claim to be limited to the particular implementation disclosed in specification and claim Example, and should be read to include all possible embodiment of the equivalent full scope of claim.Therefore, claims It is not limited by the disclosure.

Claims (39)

1. a kind of portable electric energy memory device characterized by comprising
First electric energy storage batteries unit module, the first electric energy storage batteries unit module include multiple first electric energy storages Battery unit, the multiple first electric energy storage batteries unit in the first electric energy storage batteries unit module is along first Longitudinal elongation is done in direction, and the multiple first electric energy storage batteries unit, adjacent to a plane, the plane is perpendicular to described First direction, wherein each of the multiple first electric energy storage batteries unit includes first longitudinal direction end and second longitudinal direction End is separated along the first direction to each other, wherein the multiple first electric energy in the first electric energy storage batteries unit The first longitudinal direction end and the second longitudinal direction end in storage batteries unit is respectively as electric terminal;
Second electric energy storage batteries unit module, the second electric energy storage batteries unit module include multiple second electric energy storages Battery unit, the multiple second electric energy storage batteries unit in the second electric energy storage batteries unit module is along described First direction does longitudinal elongation, and the multiple second electric energy storage batteries unit is adjacent to the plane, wherein the multiple Each of second electric energy storage batteries unit includes first longitudinal direction end and second longitudinal direction end to each other along described first Direction separates, wherein in the multiple second electric energy storage batteries unit in the second electric energy storage batteries unit module The first longitudinal direction end and the second longitudinal direction end are respectively as electric terminal, wherein the second electric energy storage batteries unit It is adjacent along the first direction with the first electric energy storage batteries unit;And
Electric energy storage batteries unit barrier, the electricity isolated layer including dielectric material are clipped in the electric energy storage batteries unit of elastic material Between contact protection layer and the combustion barriers layer of non-combustible materials, the electric energy storage batteries unit barrier is located at first electricity It can be between storage batteries unit and the second electric energy storage batteries unit, wherein the electric energy storage batteries unit barrier is located at The second longitudinal direction in the multiple first electric energy storage batteries unit in the first electric energy storage batteries unit module End as the electric terminal and the second electric energy storage batteries unit module in the multiple second electric energy store The first longitudinal direction end in battery unit as the electric terminal between.
2. portable electric energy memory device according to claim 1, wherein the first electric energy storage batteries unit includes Nickel-metal hydrides chemical composition or lithium ion chemical composition and the second electric energy storage batteries unit include with it is described The identical chemical composition of first electric energy storage batteries unit.
3. portable electric energy memory device according to claim 1, wherein the hardness of the elastic material is according to Shore etc. Grade is from 50 to 100.
4. portable electric energy memory device according to claim 3, wherein the elastic material is rubber.
5. portable electric energy memory device according to claim 4, wherein the elastic material is selected from the following terms: fluorine is poly- Close object rubber, butyl rubber, chlorosulfonated polyethylene rubber, epichlorohydrin rubber, ethylene propylene rubber, fluoroelastomer rubber, fluorine silicon Rubber, hydrogenated nitrile rubber, natural rubber, nitrile rubber, perfluorinated elastomer body rubber, polypropylene rubber, (co) polychloroprene rubber, poly- ammonia Ester rubber, silicon rubber and styrene butadiene ribber.
6. a kind of portable electric energy memory device characterized by comprising
First electric energy storage batteries unit module, including multiple first electric energy storage batteries units, the first electric energy storage electricity The multiple first electric energy storage batteries unit in pool unit module does longitudinal elongation, and the multiple along a first direction One electric energy storage batteries unit is adjacent to a plane, and the plane is perpendicular to the first direction, wherein the multiple first electricity Can each of storage batteries unit include first longitudinal direction end and second longitudinal direction end to each other along the first direction every It opens, wherein described first in the multiple first electric energy storage batteries unit in the first electric energy storage batteries unit is vertical Terminad and the second longitudinal direction end are respectively as electric terminal;
Second electric energy storage batteries unit module, including multiple second electric energy storage batteries units, the second electric energy storage electricity The multiple second electric energy storage batteries unit in pool unit module does longitudinal elongation along the first direction, and described more A second electric energy storage batteries unit is adjacent to the plane, wherein each in the multiple second electric energy storage batteries unit Person includes that first longitudinal direction end is separated along the first direction to each other with second longitudinal direction end, wherein second electric energy stores It is indulged with described second the first longitudinal direction end in the multiple second electric energy storage batteries unit in battery cell module Terminad is respectively as electric terminal, wherein the second electric energy storage batteries unit module and the first electric energy storage batteries list Element module is adjacent along the first direction;
First electric energy storage batteries unit barrier, is located at the first electric energy storage batteries unit module and second electric energy stores up It deposits between battery cell module, wherein the electricity isolated layer that the first electric energy storage batteries unit barrier includes dielectric material is clipped in Between the electric energy storage batteries unit contact protection layer of elastic material and the combustion barriers layer of non-combustible materials, wherein the electric energy Storage batteries unit barrier is located at the multiple first electric energy storage batteries in the first electric energy storage batteries unit module The second longitudinal direction end in unit as the electric terminal and the second electric energy storage batteries unit module in The first longitudinal direction end in the multiple second electric energy storage batteries unit as the electric terminal between;
Second electric energy storage batteries unit barrier, including the thermal insulation material adjacent with the second electric energy storage batteries unit module Material and elastic material;And
Third electric energy storage batteries unit barrier, including elastic material, the third electric energy storage batteries unit barrier with it is described First electric energy storage batteries unit module is adjacent.
7. portable electric energy memory device according to claim 6, wherein the second electric energy storage batteries unit barrier The elastic material be located at the heat insulator and second electric energy of the second electric energy storage batteries unit barrier Between storage batteries unit module.
8. portable electric energy memory device according to claim 6, further includes: third electric energy storage batteries unit module, It is adjacent with the second electric energy storage batteries unit module;And the 4th electric energy storage batteries unit barrier, including with described Three electric energy storage batteries unit modules adjacent heat insulator and elastic material.
9. portable electric energy memory device according to claim 8, wherein the 4th electric energy storage batteries unit barrier The heat insulator and the third electric energy storage batteries unit barrier pass through the 4th electric energy storage batteries unit screen The elastomeric layer of barrier is separately.
10. portable electric energy memory device according to claim 6, further includes: load absorption component is stored up with the electric energy At least one electric energy storage batteries unit contact of at least one of battery cell module is deposited, the load absorption component is one The load absorption component for absorbing impact and hitting.
11. portable electric energy memory device according to claim 10, wherein the load absorption component be connected to it is described Each electric energy storage batteries unit of at least one of electric energy storage batteries unit module.
12. a kind of portable electric energy memory device characterized by comprising
Shell, including lid and bottom seat;
At least one electric energy storage batteries unit module, including multiple electric energy storage batteries units, the electric energy storage batteries list The multiple electric energy storage batteries unit of module does longitudinal elongation, and the multiple electric energy storage electricity along a first direction in member Pool unit is adjacent to a plane, and the plane is perpendicular to the first direction, wherein in the multiple electric energy storage batteries unit Each include that first longitudinal direction end is separated along the first direction to each other with second longitudinal direction end, wherein the electric energy stores up Deposit the first longitudinal direction end in the multiple electric energy storage batteries unit in battery cell module and the second longitudinal direction End is respectively as electric terminal;
Electric energy storage batteries unit barrier, the electricity isolated layer including dielectric material are clipped in the electric energy storage batteries unit of elastic material Between contact protection layer and the combustion barriers layer of non-combustible materials, the electric energy storage batteries unit barrier is adjacent with the lid; And
Elastic material, adjacent with the pedestal, the elastic material is located at the electric energy storage batteries unit module and the bottom Between seat.
13. portable electric energy memory device according to claim 12, wherein the hardness of the elastic material is according to Shore Unit is from 50 to 100.
14. portable electric energy memory device according to claim 13, wherein the elastic material is rubber.
15. portable electric energy memory device according to claim 14, wherein the elastic material is selected from the following terms: fluorine Polymer rubber, butyl rubber, chlorosulfonated polyethylene rubber, epichlorohydrin rubber, ethylene propylene rubber, fluoroelastomer rubber, fluorine Silicon rubber, natural rubber, nitrile rubber, perfluorinated elastomer body rubber, polypropylene rubber, (co) polychloroprene rubber, gathers hydrogenated nitrile rubber Urethane rubber, silicon rubber and styrene butadiene ribber.
16. portable electric energy memory device according to claim 13, further includes: load absorption component, at least one The contact of electric energy storage batteries unit, the load absorption component are a load absorption component for absorbing impact and hitting.
17. portable electric energy memory device according to claim 16, wherein the load absorption component be connected to it is each Electric energy storage batteries unit.
18. portable electric energy memory device according to claim 12, further includes: explosion structure, the explosion structure exist Pressure in the portable electric energy memory device keeps complete when being lower than maximum internal pressure, and in the portable electric energy Pressure in memory device bursts when being more than the maximum internal pressure.
19. portable electric energy memory device according to claim 18, wherein the maximum internal pressure is that 50psi is arrived 300psi。
20. portable electric energy memory device according to claim 18, wherein the explosion structure is adjacent with the pedestal.
21. portable electric energy memory device according to claim 12, further includes: explosion structure, the explosion structure exist Pressure in the portable electric energy memory device keeps complete when being lower than maximum internal pressure, and in the portable electric energy Pressure in memory device bursts when being more than the maximum internal pressure.
22. portable electric energy memory device according to claim 21, wherein the maximum internal pressure is that 50psi is arrived 300psi。
23. portable electric energy memory device according to claim 12, further includes: explosion structure, the explosion structure exist Pressure in the portable electric energy memory device keeps complete when being lower than maximum internal pressure, and in the portable electric energy Pressure in memory device bursts when being more than the maximum internal pressure.
24. portable electric energy memory device according to claim 23, wherein the maximum internal pressure is that 50psi is arrived 300psi。
25. a kind of portable electric energy memory device, comprising:
Shell, including lid and bottom seat;
First electric energy storage batteries unit module, including multiple first electric energy storage batteries units, the first electric energy storage electricity The multiple first electric energy storage batteries unit in pool unit module does longitudinal elongation, and the multiple along a first direction One electric energy storage batteries unit is adjacent to a plane, and the plane is perpendicular to the first direction, wherein the multiple first electricity Can each of storage batteries unit include first longitudinal direction end and second longitudinal direction end to each other along the first direction every It opens, wherein described first in the multiple first electric energy storage batteries unit in the first electric energy storage batteries unit is vertical Terminad and the second longitudinal direction end are respectively as electric terminal;
Second electric energy storage batteries unit module, including multiple second electric energy storage batteries units, the second electric energy storage electricity The multiple second electric energy storage batteries unit in pool unit module does longitudinal elongation along the first direction, and described more A second electric energy storage batteries unit is adjacent to the plane, wherein each in the multiple first electric energy storage batteries unit Person includes that first longitudinal direction end is separated along the first direction to each other with second longitudinal direction end, wherein second electric energy stores The first longitudinal direction end and second longitudinal direction end in the multiple first electric energy storage batteries unit in battery unit End is respectively as electric terminal, wherein the second electric energy storage batteries unit module and the first electric energy storage batteries unit mould Block is adjacent along the first direction;
Third electric energy storage batteries unit module, including multiple electric energy storage batteries units, the third electric energy storage batteries list With the first electric energy storage batteries unit module opposite one of the element module in the second electric energy storage batteries unit module It is adjacent with the second electric energy storage batteries unit module on side;
First electric energy storage batteries unit barrier, the electricity isolated layer including dielectric material are clipped in the electric energy storage batteries of elastic material Between unit contact protection layer and the combustion barriers layer of non-combustible materials, the first electric energy storage batteries unit barrier is located at institute It states between the first electric energy storage batteries unit module and the second electric energy storage batteries unit module, wherein first electric energy Storage batteries unit barrier is located at the multiple first electric energy storage batteries in the first electric energy storage batteries unit module The second longitudinal direction end in unit as the electric terminal and the second electric energy storage batteries unit module in The first longitudinal direction end in the multiple second electric energy storage batteries unit as the electric terminal between;
Second electric energy storage batteries unit barrier, including the heat insulator being clipped between elastic material, the second electric energy storage It deposits battery unit barrier and is located at the second electric energy storage batteries unit module and the third electric energy storage batteries unit module Between;
Third electric energy storage batteries unit barrier, including elastic material, the third electric energy storage batteries unit barrier are located at institute It states between the first electric energy storage batteries unit module and the pedestal;And
4th electric energy storage batteries unit barrier, including between the third electric energy storage batteries unit module and the lid Heat insulator and elastic material.
26. a kind of portable electric energy memory device, comprising:
Shell, including side wall;
First electric energy storage batteries unit module, including multiple first electric energy storage batteries units, the first electric energy storage electricity Pool unit module is located in the shell, the multiple first electric energy storage in the first electric energy storage batteries unit module Battery unit does longitudinal elongation along a first direction, and the multiple first electric energy storage batteries unit is adjacent to a plane, institute Plane is stated perpendicular to the first direction, wherein each of the multiple first electric energy storage batteries unit includes first vertical Terminad is separated along the first direction to each other with second longitudinal direction end, wherein in the first electric energy storage batteries unit The first longitudinal direction end and the second longitudinal direction end in the multiple first electric energy storage batteries unit is respectively as electricity Terminal;
Second electric energy storage batteries unit module, including multiple second electric energy storage batteries units, the second electric energy storage electricity Pool unit module is located in the shell, and with the first electric energy storage batteries unit module along the first direction phase Neighbour, wherein the multiple second electric energy storage batteries unit in the second electric energy storage batteries unit module is along described Longitudinal elongation is done in one direction, and the multiple second electric energy storage batteries unit is adjacent to the plane, wherein the multiple Each of two electric energy storage batteries units include first longitudinal direction end and second longitudinal direction end to each other along the first party To separating, wherein the institute in the multiple second electric energy storage batteries unit in the second electric energy storage batteries unit module First longitudinal direction end and the second longitudinal direction end are stated respectively as electric terminal;
First electric energy storage batteries unit barrier, the electricity isolated layer including dielectric material are clipped in the electric energy storage batteries of elastic material Between unit contact protection layer and the combustion barriers layer of non-combustible materials, the first electric energy storage batteries unit barrier is located at institute It states between the first electric energy storage batteries unit module and the second electric energy storage batteries unit module, the first electric energy storage The electricity isolated layer of the dielectric material of battery unit barrier includes at least one offset outlet and first electric energy storage The combustion barriers layer of the non-combustible materials of battery unit barrier includes at least one offset outlet, wherein the electric energy stores Battery unit barrier is located at the multiple first electric energy storage batteries unit in the first electric energy storage batteries unit module In the second longitudinal direction end as the electric terminal and the second electric energy storage batteries unit module in described in The first longitudinal direction end in multiple second electric energy storage batteries units as the electric terminal between;And
Second electric energy storage batteries unit barrier, the electricity isolated layer including dielectric material, the electricity isolated layer are located at elastic material Electric energy storage batteries unit contact protection layer and non-combustible materials combustion barriers layer between, the second electric energy storage batteries The electricity isolated layer of the dielectric material of unit barrier includes at least one offset outlet and the second electric energy storage batteries The combustion barriers layer of the non-combustible materials of unit barrier includes at least one offset outlet, the second electric energy storage batteries Unit barrier is between the second electric energy storage batteries unit module and the first electric energy storage batteries unit barrier;
Including described in the electricity isolated layer of the dielectric material of the first electric energy storage batteries unit barrier at least one A offset outlet and include the combustion barriers layer in the non-combustible materials of the first electric energy storage batteries unit barrier In at least one described offset outlet be biased to detent position, and be movable to release position from the detent position, The detent position stops gas to flow through the first electric energy storage batteries unit barrier, compared with the detent position, Gas is stopped to the release position lesser degree to flow through the first electric energy storage batteries unit barrier;And
Including described in the electricity isolated layer of the dielectric material in the second electric energy storage batteries unit barrier at least One offset outlet and include the non-combustible materials in the second electric energy storage batteries unit barrier the burning screen At least one described offset outlet in barrier layer is biased to detent position, and is movable to open stance from the detent position It sets, the detent position stops gas to flow through the second electric energy storage batteries unit barrier, with the detent position phase Than stopping to the release position lesser degree gas to flow through the second electric energy storage batteries unit barrier.
27. portable electric energy memory device according to claim 26, wherein the first electric energy storage batteries unit screen Barrier and the second electric energy storage batteries unit barrier are separately.
28. portable electric energy memory device according to claim 26, further includes: at least one spacer is located at described Between first electric energy storage batteries unit barrier and the second electric energy storage batteries unit barrier.
29. portable electric energy memory device according to claim 26, wherein the first electric energy storage batteries unit screen At least 2 millimeters of barrier and the second electric energy storage batteries unit barrier interval.
30. portable electric energy memory device according to claim 29, wherein the first electric energy storage batteries unit screen At least 5 millimeters of barrier and the second electric energy storage batteries unit barrier interval.
31. portable electric energy memory device according to claim 30, wherein the first electric energy storage batteries unit screen At least 8 millimeters of barrier and the second electric energy storage batteries unit barrier interval.
32. portable electric energy memory device according to claim 26, wherein the first electric energy storage batteries unit screen 5 millimeters to 15 millimeters of barrier and the second electric energy storage batteries unit barrier interval.
33. portable electric energy memory device according to claim 26, wherein the first electric energy storage batteries unit screen The electric energy storage batteries list of the electricity isolated layer of the dielectric material of barrier and the first electric energy storage batteries unit barrier First contact protection layer contact.
34. portable electric energy memory device according to claim 26, wherein the second electric energy storage batteries unit screen The electric energy of the electricity isolated layer of the dielectric material of barrier and the elastic material of the second electric energy storage batteries unit barrier The contact of storage batteries unit contact protection layer.
35. portable electric energy memory device according to claim 26, further includes: electric energy storage batteries unit module side Wall is adjacent with the first electric energy storage batteries unit module and be located at the first electric energy storage batteries unit module and described Between the side wall of shell, the electric energy storage batteries unit module side wall includes facing the first electric energy storage batteries unit mould The inside of the multiple electric energy storage batteries unit of block and the outside of the side wall in face of the shell, the electric energy storage Depositing battery cell module side wall includes storing from the inside of the electric energy storage batteries unit module side wall to the electric energy The opening in the outside of battery cell module side wall.
36. portable electric energy memory device according to claim 35, further includes: fire proofing material is located at the electric energy and stores up Deposit battery cell module side wall and the first electric energy storage batteries unit module the multiple electric energy storage batteries unit it Between.
37. portable electric energy memory device according to claim 26, in addition to the first electric energy storage batteries unit screen At least one described offset outlet and the first electric energy storage batteries list in the electricity isolated layer of the dielectric material of barrier Except at least one described offset outlet in the combustion barriers layer of the non-combustible materials of first barrier, the portable electric energy Memory device further include: across at least one opening of the first electric energy storage batteries unit barrier.
38. portable electric energy memory device according to claim 26, wherein the second electric energy storage batteries unit mould Block is located at the lower section of the first electric energy storage batteries unit module.
39. a kind of portable electric energy memory device, comprising:
Shell, including side wall;
First electric energy storage batteries unit module, including multiple first electric energy storage batteries units, the first electric energy storage electricity Pool unit module is located in the shell, the multiple first electric energy storage in the first electric energy storage batteries unit module Battery unit does longitudinal elongation along a first direction, and the multiple first electric energy storage batteries unit is adjacent to a plane, institute Plane is stated perpendicular to the first direction, wherein each of the multiple first electric energy storage batteries unit includes first vertical Terminad is separated along the first direction to each other with second longitudinal direction end, wherein in the first electric energy storage batteries unit The first longitudinal direction end and the second longitudinal direction end in the multiple first electric energy storage batteries unit is respectively as electricity Terminal;
Second electric energy storage batteries unit module, including multiple second electric energy storage batteries units, the second electric energy storage electricity Pool unit module is located in the shell, and with the first electric energy storage batteries unit module along the first direction phase Neighbour, wherein the multiple second electric energy storage batteries unit in the second electric energy storage batteries unit module is along described Longitudinal elongation is done in one direction, and the multiple first electric energy storage batteries unit is adjacent to the plane, wherein the multiple Each of one electric energy storage batteries unit includes first longitudinal direction end and second longitudinal direction end to each other along the first party To separating, wherein described in the multiple first electric energy storage batteries unit in the second electric energy storage batteries unit One longitudinal end and the second longitudinal direction end are respectively as electric terminal;
First electric energy storage batteries unit barrier, including the dielectric material being clipped between elastomeric layer and non-combustible materials layer Layer, the first electric energy storage batteries unit barrier are located at the first electric energy storage batteries unit module and second electric energy Between storage batteries unit module, the dielectric materials layer of the first electric energy storage batteries unit barrier includes at least one Offset outlet and the non-combustible materials layer of the first electric energy storage batteries unit barrier include that at least one is biased out Mouthful, wherein the first electric energy storage batteries unit barrier be located at it is described more in the first electric energy storage batteries unit module The second longitudinal direction end in a first electric energy storage batteries unit as the electric terminal and second electric energy store up Deposit the first longitudinal direction end in the multiple second electric energy storage batteries unit in battery cell module as institute It states between electric terminal;And
Including at least one is partially described in the dielectric materials layer of the first electric energy storage batteries unit barrier Set outlet and include in the non-combustible materials layer of the first electric energy storage batteries unit barrier described at least one A offset outlet is biased to detent position, and is movable to release position, the detent position resistance from the detent position Gear gas flow through the first electric energy storage batteries unit barrier, compared with the detent position, the release position compared with Few degree gas is stopped to flow through the first electric energy storage batteries unit barrier.
CN201480056352.7A 2013-08-30 2014-08-29 The portable electric energy memory device slowed down with thermal runaway Active CN105849933B (en)

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