CN105845458B - A kind of graphene activated metal organic backbone electrode material and its preparation and application - Google Patents
A kind of graphene activated metal organic backbone electrode material and its preparation and application Download PDFInfo
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- CN105845458B CN105845458B CN201610297027.0A CN201610297027A CN105845458B CN 105845458 B CN105845458 B CN 105845458B CN 201610297027 A CN201610297027 A CN 201610297027A CN 105845458 B CN105845458 B CN 105845458B
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- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 239000007772 electrode material Substances 0.000 title claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 13
- 239000002184 metal Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 38
- 239000012621 metal-organic framework Substances 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 239000013110 organic ligand Substances 0.000 claims abstract description 11
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 230000004913 activation Effects 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 11
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 9
- 238000001994 activation Methods 0.000 claims description 9
- 239000012921 cobalt-based metal-organic framework Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000011267 electrode slurry Substances 0.000 claims description 6
- 239000003792 electrolyte Substances 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 238000011056 performance test Methods 0.000 claims description 6
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical class [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 239000011883 electrode binding agent Substances 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims 1
- 239000003990 capacitor Substances 0.000 abstract description 5
- 239000013099 nickel-based metal-organic framework Substances 0.000 description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000013239 manganese-based metal-organic framework Substances 0.000 description 5
- 239000013084 copper-based metal-organic framework Substances 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- 229940011182 cobalt acetate Drugs 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 229940078494 nickel acetate Drugs 0.000 description 2
- AIYYMMQIMJOTBM-UHFFFAOYSA-L nickel(ii) acetate Chemical class [Ni+2].CC([O-])=O.CC([O-])=O AIYYMMQIMJOTBM-UHFFFAOYSA-L 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000006181 electrochemical material Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical class [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- -1 metals ion Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/50—Electrodes characterised by their material specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
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CN201610297027.0A CN105845458B (en) | 2016-05-06 | 2016-05-06 | A kind of graphene activated metal organic backbone electrode material and its preparation and application |
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CN201610297027.0A CN105845458B (en) | 2016-05-06 | 2016-05-06 | A kind of graphene activated metal organic backbone electrode material and its preparation and application |
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CN105845458A CN105845458A (en) | 2016-08-10 |
CN105845458B true CN105845458B (en) | 2018-06-26 |
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CN201610297027.0A Active CN105845458B (en) | 2016-05-06 | 2016-05-06 | A kind of graphene activated metal organic backbone electrode material and its preparation and application |
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106935825A (en) * | 2017-03-21 | 2017-07-07 | 桂林电子科技大学 | A kind of graphene oxide/metal organic frame composite and its preparation method and application |
CN108080034B (en) * | 2017-12-29 | 2020-10-09 | 济南大学 | Preparation method and application of nickel-based three-dimensional metal organic framework catalyst |
CN108441982B (en) * | 2018-02-13 | 2020-09-18 | 浙江工业大学 | Preparation method of graphene/metal organic framework composite fiber |
CN110767464B (en) * | 2018-07-25 | 2022-07-08 | 东莞东阳光科研发有限公司 | Super capacitor containing MOFs material and preparation method thereof |
CN109364995B (en) * | 2018-11-01 | 2021-03-16 | 安阳师范学院 | Preparation method and application of high-dispersion graphene/Fe-based metal organic framework composite material electrochemical sensor |
CN113330608A (en) * | 2019-02-11 | 2021-08-31 | 福特切尔国际有限公司 | Electrode with electrode additive for high performance batteries and use thereof |
CN110183679A (en) * | 2019-06-25 | 2019-08-30 | 淮阴师范学院 | A kind of accessory of metal organic frame and preparation |
CN110350184B (en) * | 2019-06-26 | 2022-07-19 | 五邑大学 | Preparation method of high-capacity NiMoO4 energy storage material for battery positive electrode material |
CN110335762A (en) * | 2019-07-09 | 2019-10-15 | 南京邮电大学 | A kind of preparation of GO/Cu-HHTP composite material and its application in electrochemical energy storage |
CN110358235A (en) * | 2019-07-18 | 2019-10-22 | 华南理工大学 | A kind of passion fruit shell graphene-CeMOF-PVB composite material and preparation method and application |
CN110387099A (en) * | 2019-07-18 | 2019-10-29 | 华南理工大学 | A kind of tealeaf residue graphene-CuCeMOF-PVB composite material and preparation method and application |
CN110420661B (en) * | 2019-08-15 | 2021-01-12 | 山东大学 | MIL-101(Fe) composite catalytic material generated in situ on 3D-rGO and preparation method and application thereof |
CN111085275A (en) * | 2019-12-31 | 2020-05-01 | 华南理工大学 | Reductive graphene oxide/metal organic framework composite material and preparation method and application thereof |
CN111477471A (en) * | 2020-04-25 | 2020-07-31 | 榆林学院 | Preparation method of coal tar-based electrode material |
CN111710529B (en) * | 2020-05-20 | 2022-04-05 | 上海应用技术大学 | Co/Mn-MOF/nitrogen-doped carbon-based composite material and preparation method and application thereof |
CN111704732B (en) * | 2020-06-28 | 2021-11-05 | 南京工业大学 | Metal organic framework loaded graphene microspheres and preparation method and application thereof |
CN112403440B (en) * | 2020-11-18 | 2022-03-18 | 山西大学 | Magnetic recyclable CoNi-MOFs @ GR adsorbent, preparation method and application to adsorption of organic dye |
CN114023960B (en) * | 2021-10-20 | 2023-04-11 | 上海大学(浙江·嘉兴)新兴产业研究院 | Metal coordination polymer organic positive electrode material and preparation method thereof |
CN114188523B (en) * | 2021-12-13 | 2024-02-02 | 中南大学 | Graphene-supported vanadium pentoxide composite material, preparation method thereof and application thereof in water-based zinc ion battery |
Citations (6)
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CN103236542A (en) * | 2013-04-17 | 2013-08-07 | 浙江大学 | Preparation method for lithium-sulfur battery positive electrode material adopting metal-organic framework material as sulfur carrier |
JP5272810B2 (en) * | 2009-03-06 | 2013-08-28 | 株式会社豊田中央研究所 | Capacitors |
CN104538200A (en) * | 2014-12-12 | 2015-04-22 | 上海应用技术学院 | Graphene / Fe-MOFs composite material and preparation method thereof |
CN104979104A (en) * | 2015-07-02 | 2015-10-14 | 上海应用技术学院 | Preparation method of Ni-MOF electrode material |
CN104992848A (en) * | 2015-06-30 | 2015-10-21 | 中国地质大学(武汉) | Binary metal organic framework material applied to super capacitor and preparation method for binary metal organic framework material |
CN105047435A (en) * | 2015-08-14 | 2015-11-11 | 上海工程技术大学 | Manganese-metal-organic-framework electrode material, and preparation method and application thereof |
-
2016
- 2016-05-06 CN CN201610297027.0A patent/CN105845458B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5272810B2 (en) * | 2009-03-06 | 2013-08-28 | 株式会社豊田中央研究所 | Capacitors |
CN103236542A (en) * | 2013-04-17 | 2013-08-07 | 浙江大学 | Preparation method for lithium-sulfur battery positive electrode material adopting metal-organic framework material as sulfur carrier |
CN104538200A (en) * | 2014-12-12 | 2015-04-22 | 上海应用技术学院 | Graphene / Fe-MOFs composite material and preparation method thereof |
CN104992848A (en) * | 2015-06-30 | 2015-10-21 | 中国地质大学(武汉) | Binary metal organic framework material applied to super capacitor and preparation method for binary metal organic framework material |
CN104979104A (en) * | 2015-07-02 | 2015-10-14 | 上海应用技术学院 | Preparation method of Ni-MOF electrode material |
CN105047435A (en) * | 2015-08-14 | 2015-11-11 | 上海工程技术大学 | Manganese-metal-organic-framework electrode material, and preparation method and application thereof |
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Application publication date: 20160810 Assignee: SHANGHAI LEVSONG NANO TECHNOLOGY CO.,LTD. Assignor: SHANGHAI LIWUSHENG ENTERPRISE GROUP Co.,Ltd. Contract record no.: X2019310000015 Denomination of invention: Graphene activated metal organic framework electrode material and preparation and applications thereof Granted publication date: 20180626 License type: Common License Record date: 20191014 |
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Effective date of registration: 20210610 Address after: Room 310, 3rd floor, building 2, 511 Shanlian Road, Baoshan District, Shanghai 200444 Patentee after: Shanghai Shufu New Material Technology Co.,Ltd. Address before: 200444 block a, 4th floor, building 2, 511 Shanlian Road, Baoshan District, Shanghai Patentee before: SHANGHAI LIWUSHENG ENTERPRISE GROUP Co.,Ltd. |
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Address after: Room 310, 3rd Floor, Building 2, No. 511 Shanlian Road, Baoshan District, Shanghai, 2019 Patentee after: Shanghai Shufei Equipment Manufacturing Co.,Ltd. Country or region after: China Address before: Room 310, 3rd floor, building 2, 511 Shanlian Road, Baoshan District, Shanghai 200444 Patentee before: Shanghai Shufu New Material Technology Co.,Ltd. Country or region before: China |
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Effective date of registration: 20240513 Address after: 226600, Group 9, Guanghua Village, Hai'an High tech Zone (formerly Hai'an Town), Nantong City, Jiangsu Province Patentee after: Jiangsu Hezixing Intelligent Equipment Manufacturing Co.,Ltd. Country or region after: China Address before: Room 310, 3rd Floor, Building 2, No. 511 Shanlian Road, Baoshan District, Shanghai, 2019 Patentee before: Shanghai Shufei Equipment Manufacturing Co.,Ltd. Country or region before: China |