CN110335762A - A kind of preparation of GO/Cu-HHTP composite material and its application in electrochemical energy storage - Google Patents
A kind of preparation of GO/Cu-HHTP composite material and its application in electrochemical energy storage Download PDFInfo
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- CN110335762A CN110335762A CN201910614206.6A CN201910614206A CN110335762A CN 110335762 A CN110335762 A CN 110335762A CN 201910614206 A CN201910614206 A CN 201910614206A CN 110335762 A CN110335762 A CN 110335762A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Abstract
The invention discloses a kind of preparation of GO/Cu-HHTP composite material and its applications in electrochemical energy storage.GO/Cu-HHTP composite material is under the conditions of constant pressure hydro-thermal, by GO, Cu (NO3)2·3H2O, HHTP is dispersed in DMF and H2What the in the mixed solvent reaction of O was prepared.The present invention constructs GO/Cu-HHTP composite material for the first time, and prepares the easy to operate of the material, can be completed under hydrothermal condition；Meanwhile the present invention is for the first time using the means preparation GO/Cu-HHTP composite material work electrode for not adding any conductive agent；Composite material specific surface area with higher, more active site and higher electric conductivity, energy-storage property are better than single Cu-HHTP and GO material.
Description
Technical field
The present invention relates to capacitance technology field, it is specifically related to a kind of preparation of GO/Cu-HHTP composite material and its in electricity
Application in chemical energy storage.
Background technique
In recent years, supercapacitor is due to having the characteristics that fast charging and discharging, high specific capacitance, safety and environmental protection, part
Replace existing rechargeable battery, is used in the fields such as mobile electronic product and electric car.Supercapacitor is considered as
It is most suitable for the energy system for making gap between low energy densities capacitor and low power density lithium ion battery up, still,
Compared with battery, it need to be improved in energy output facet.
Metal organic framework (Metal-Organic Frameworks, MOFs) material is a kind of using organic ligand and golden
Belong to interionic coordination and pass through the porous material with periodical mesh skeleton structure being self-assembly of, it is considered to be is super
The potential electrode of grade capacitor.But the electric conductivity of most of original MOFs is very poor, limits its answering in electrochemical field
With.In order to improve their electric conductivity, MOFs is usually pyrolyzed into carbon (being no longer MOF) or multiple with conductive material (carbon black)
It closes, however, the use of conductive additive can reduce the effective ratio area of MOF.Then, if there is researcher to propose huge ratio
The MOF of surface area can in conjunction with conductive characteristic, then MOF material the application of electrochemical field will obtain it is ground-breaking into
Exhibition, the appearance of π-d conjugated conductive MOF just solve the problems, such as this, and transition metal ions provides empty d track, and ligand provides one
The big pi bond of a delocalization, forms π-d conjugation, and this structure is conducive to the transmission of ion-electron, therefore conductive energy.
Recently, Dinca seminar reports a kind of conductive Ni3(HITP)2(six amino three of HITP=2,3,6,7,10,11-
Phenylene) MOFs, it is the coplanar structure of a conjugation by the Ni that four amino is coordinated that the aperture of the MOF material, which is 1.5nm,
Ligand has the big pi bond of a delocalization.Powdered product is compressed into tablet form structure, can be used as the electrode of supercapacitor.But
Intergranular crystal boundary reduces ion/electronics efficiency of transmission, and then limits the further promotion of performance.And there will be conduction
Property π-d conjugation MOFs and other two-dimension nano materials with electro-chemical activity it is compound, be expected to overcome this disadvantage, realize more
High capacitor.Meanwhile using the effect of composite material synergy, it can prevent conductive MOFs from heap occurring in charge and discharge process
It is folded, and then improve the stability of MOFs.Up to now, the research of π-d conjugated conductive MOFs and 2D Material cladding has not yet to see
All reports.
Graphene oxide (Graphene Oxide, GO) is the oxidized derivatives of graphene, have biggish specific surface area,
Ultra-thin two-dimensional structure and good mechanical strength.Meanwhile the oxygen-containing functional group of GO provides a large amount of functionalization site.
Konstantinov seminar is compound by GO and multi-walled carbon nanotube (MWCNT) progress, constructs GO/MWCNT composite material.It is logical
The synergistic function for playing the two is crossed, GO/MWCNT composite material is made to show the energy storage property better than homogenous material.By
Currently, it is compound by carrying out GO and MOFs, GO/MOFs composite material is constructed, MOFs electrochemical energy storage Quality Research is enhanced
Still it is rarely reported.Based on this, in the present invention, 2DGO is introduced into π-d conjugated conductive Cu-HHTPMOFs by we for the first time, structure
GO/Cu-HHTP composite material is built, by playing the synergistic function of the two, realizes that charge and discharge process intermediate ion/electronics has
Effect transmission, and then improve the energy storage property of system.
Summary of the invention
It is an object of the invention to solve deficiency in the prior art, develop a kind of low cost, low energy consumption, simple process
Solvent-thermal method prepares a kind of GO/Cu-HHTP composite material and probes into it in the application of energy storage field.
The technical solution of the present invention is as follows: a kind of preparation method of GO/Cu-HHTP composite material, concrete operation step are as follows:
(1) single-layer graphene oxide (GO) nanometer sheet is dissolved in N,N-dimethylformamide (DMF) and H2The mixed solvent of O
In, it is uniformly mixed；
(2) Gerhardite (Cu (NO is added3)2·3H2O), hexahydroxy triphenylene (HHTP), under the conditions of 70-90 DEG C
React 12h；
(3) it after product is cooled to room temperature, by products therefrom under the conditions of 12000rpm, 10min, is centrifuged 3 times with ethyl alcohol,
Obtained solid is GO/Cu-HHTP composite material.
Further, DMF and H2The volume ratio of both in the mixed solvents of O is 1:2.
Further, GO:Cu2+: the mass ratio of HHTP is 1:1.38:4.67.
A kind of electrode of GO/Cu-HHTP composite material preparation
It uses NMP as solvent, GO/Cu-HHTP composite material and Nafion that mass ratio is 4:1 is mixed and made into paste,
It is uniformly coated on the carbon fiber paper of 1cm × 1cm, 60 DEG C of vacuum drying 12h, as working electrode.Through electrochemical property test
After find there is the chemical property better than single Cu-HHTP, GO, GO/Cu-HHTP composite material can be applicable to electrochemistry
In energy storage.
The invention has the benefit that
(1) preparation method disclosed by the invention, it is easy to operate, it can be completed under hydrothermal condition；
(2) GO/Cu-HHTP composite material prepared by the present invention is with graphene oxide and π-d conjugated conductive Cu-HHTP
MOFs is raw material, specific surface area, more active site and higher electric conductivity with higher；
(3) GO/Cu-HHTP working electrode prepared by the present invention does not add any conductive agent；
(4) GO/Cu-HHTP composite material prepared by the present invention with excellent energy-storage property and has better than single Cu-
The chemical property of HHTP, GO material.
Detailed description of the invention
Fig. 1 is the SEM figure for the GO/Cu-HHTP composite material that embodiment 1 obtains；
Fig. 2 is the XRD diagram of GO/Cu-HHTP composite material, Cu-HHTP and GO that embodiment 3 obtains；
Fig. 3 is the three electrode test CV figure of GO/Cu-HHTP composite material, Cu-HHTP and GO that embodiment 5 obtains；
The three electrode test GCD figure of GO/Cu-HHTP composite material, Cu-HHTP that Fig. 4 obtains for embodiment 6；
Fig. 5 is CV figure of the GO/Cu-HHTP composite material under different scanning rates；
Fig. 6 is GCD figure of the GO/Cu-HHTP composite material under different charge-discharge velocities.
Specific embodiment
Following embodiment further illustrates the contents of the present invention, but should not be construed as limiting the invention.Without departing substantially from
In the case where essence of the present invention, to modification made by the method for the present invention, step or condition and replaces, belong to model of the invention
It encloses.
The preparation of embodiment 1, GO/Cu-HHTP composite material
(1) take 3.5mL single-layer graphene oxide dispersion liquid (4mg/mL) that 20mL vial is added；
(2) Cu (NO is added3)2·3H2O (72.48mg, 0.3mmol)；
(3) HHTP (64.8mg, 0.2mmol) is added, 5mL DMF, 6.5mL H is added2O is stirred evenly；
(4) reactant is transferred to air dry oven and rises to 80 DEG C by room temperature, react 12h；
(5) after product is cooled to room temperature, product is centrifuged 3 times under the conditions of 12000rpm, 10min with ethyl alcohol, gained
Solid is GO/Cu-HHTP composite material.
The preparation of embodiment 2, Cu-HHTP
(1) by Cu (NO3)2·3H2O (72.48mg, 0.3mmol), HHTP (64.8mg, 0.2mmol), are dissolved in 15mL DMF
And H2In the mixed solution of O (V:V=1:2), it is transferred to air dry oven after stirring, rises to 80 DEG C by room temperature,
12h is reacted, after product is cooled to room temperature, product is centrifuged 3 times under conditions of 12000rpm, 10min with ethyl alcohol, gained is solid
Body is Cu-HHTP.
The XRD test of embodiment 3, GO, Cu-HHTP and GO/Cu-HHTP composite material
As seen from Figure 2, the characteristic peak of GO/Cu-HHTP composite material is corresponding with Cu-HHTP, GO characteristic peak,
4.6 °, 12.5 °, 26.9 ° of peaks corresponding to Cu-HHTP, at the peak of 4.6 ° of corresponding GO, it can thus be concluded that GO/Cu-HHTP composite wood out
Expect successfully to prepare.
The preparation of embodiment 4, three-electrode system working electrode
The GO/Cu-HHTP composite material and Nafion for being 4:1 by mass ratio, utilize n-methyl-2-pyrrolidone (NMP)
It is mixed and made into paste as solvent, is uniformly coated on the carbon fiber paper of 1cm × 1cm, 60 DEG C of vacuum drying 12h, as work
Electrode.
The cyclic voltammetry of embodiment 5, GO, Cu-HHTP, GO/Cu-HHTP composite material
GO, Cu-HHTP, GO/Cu-HHTP compound substance are supported on carbon fiber paper as working electrode, electrolysis respectively
Matter: 3M KCl, to electrode: platinized platinum；Reference electrode: Ag/AgCl；Voltage window: 0~0.5V；Sweep speed: 5mVs-1。
Test results are shown in figure 3, in 5mVs-1Sweep under speed, GO/Cu-HHTP composite material quality specific capacitance reaches
81.4F·g-1, Cu-HHTP mass specific capacitance is 34.57Fg-1, GO mass specific capacitance is 0.1Fg-1, composite material has
Better than the excellent electrochemical performance of single Cu-HHTP, GO.
The constant current charge-discharge test of embodiment 6, Cu-HHTP, GO/Cu-HHTP composite material
Cu-HHTP, GO/Cu-HHTP compound substance are supported on carbon fiber paper as working electrode, electrolyte respectively:
3M KCl, to electrode: platinized platinum；Reference electrode: Ag/AgCl；Voltage window: 0V~0.5V；Current density is 0.5Ag-1。
Test results are shown in figure 4, in 0.5Ag-1Current density under, the mass ratio of GO/Cu-HHTP composite material electricity
Appearance reaches 91.9Fg-1, Cu-HHTP mass specific capacitance is 40.1Fg-1, composite material is with the excellent electricity better than Cu-HHTP
Chemical property.
Fig. 5 is GO/Cu-HHTP composite material in the different cyclic voltammetry curves swept under speed, sweeps fast 5mVs-1、10mV·
s-1、20mV·s-1、30mV·s-1、50mV·s-1、100mV·s-1, corresponding specific capacitance is followed successively by 81.4Fg-1、73.9F·
g-1、63.8F·g-1、56.8F·g-1、46.8F·g-1、31.9F·g-1、18.9F·g-1、13.3F·g-1、8.5F·g-1, sweep
Speed is from 5mVs-1Increase to 100mVs-1, capacity retention is 10.4%.
Fig. 6 is constant current charge-discharge curve of the GO/Cu-HHTP composite material under different current densities, and current density exists
0.1A·g-1、0.25A·g-1、0.5A·g-1、1A·g-1、1.5A·g-1, corresponding specific capacitance is followed successively by 103.3Fg-1、
97.5F·g-1、91.9F·g-1、79.8F·g-1Current density is from 0.1Ag-1Increase to 1.5Ag-1Capacity retention exists
77.3%, therefore GO/Cu-HHTP composite material has excellent energy-storage property.
Basic principles and main features and advantage of the invention have been shown and described above.But the foregoing is merely this hairs
Bright specific embodiment, technical characteristic of the invention are not limited thereto, and any those skilled in the art is not departing from this hair
The other embodiments obtained under bright technical solution should all cover within the scope of the patent of the present invention.
Claims (5)
1. a kind of preparation method of GO/Cu-HHTP composite material, which is characterized in that concrete operation step are as follows:
(1) GO nanometer sheet is dissolved in DMF and H2In the mixed solution of O, it is uniformly mixed；
(2) Cu (NO is added3)2·3H2O and HHTP, in 70-90 DEG C of reaction 12h；
(3) after product is cooled to room temperature, products therefrom is centrifuged 3 times under conditions of 12000rpm, 10min with ethyl alcohol, institute
Obtaining solid is GO/Cu-HHTP composite material.
2. a kind of preparation method of GO/Cu-HHTP composite material as described in claim 1, which is characterized in that used in step 1
The DMF and H arrived2The volume ratio of both in the mixed solvents of O is 1:2.
3. a kind of preparation method of GO/Cu-HHTP composite material as described in claim 1, which is characterized in that GO:Cu2+:
The mass ratio of HHTP is 1:1.38:4.67.
4. a kind of electrode of GO/Cu-HHTP composite material preparation as described in claim 1, which is characterized in that specific preparation
Method are as follows:
It uses NMP as solvent, GO/Cu-HHTP composite material and Nafion that mass ratio is 4:1 is mixed and made into paste, uniformly
Be coated on the carbon fiber paper of 1cm × 1cm, 60 DEG C of vacuum drying 12h, as working electrode.
5. a kind of application of the GO/Cu-HHTP composite material as claimed in any one of claims 1-3 in electrochemical energy storage,
It is characterized in that, the composite material has the chemical property better than single Cu-HHTP or GO.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111084975A (en) * | 2019-12-25 | 2020-05-01 | 陕西科技大学 | Leather-based pressure sensor for recording walking track, preparation method and application |
| CN111155143A (en) * | 2020-01-07 | 2020-05-15 | 中国科学院化学研究所 | Preparation method of two-dimensional layered metal organic framework nano material |
| CN111253759A (en) * | 2020-03-27 | 2020-06-09 | 西安交通大学 | Preparation method of composite material based on metal organic framework and carbon nano tube and preparation method of device |
| CN113235118A (en) * | 2021-05-17 | 2021-08-10 | 苏州大学 | Electrochemical synthesis method of conductive metal organic framework anode |
| CN113244961A (en) * | 2021-05-24 | 2021-08-13 | 上海师范大学 | Bimetallic CoCu-MOF visible light catalyst and preparation method and application thereof |
| CN113410461A (en) * | 2021-02-20 | 2021-09-17 | 西安理工大学 | Preparation method and application of self-supporting electrode MOFs/carbon paper composite material of lithium-sulfur battery |
| CN114976015A (en) * | 2022-06-27 | 2022-08-30 | 巢湖学院 | Two-dimensional metal organic framework based composite electrode material, and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103432997A (en) * | 2013-08-30 | 2013-12-11 | 华南理工大学 | Cu-based organic skeleton-graphene oxide composite porous material and preparation method thereof |
| CN105344327A (en) * | 2015-11-26 | 2016-02-24 | 中国科学院生态环境研究中心 | Preparation method of MOFs graphene composite material |
| CN105845458A (en) * | 2016-05-06 | 2016-08-10 | 上海利物盛企业集团有限公司 | Graphene activated metal organic framework electrode material and preparation and applications thereof |
| CN106064052A (en) * | 2016-05-20 | 2016-11-02 | 南京邮电大学 | A kind of preparation method of MOFs/ Graphene adsorbing material |
-
2019
- 2019-07-09 CN CN201910614206.6A patent/CN110335762A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103432997A (en) * | 2013-08-30 | 2013-12-11 | 华南理工大学 | Cu-based organic skeleton-graphene oxide composite porous material and preparation method thereof |
| CN105344327A (en) * | 2015-11-26 | 2016-02-24 | 中国科学院生态环境研究中心 | Preparation method of MOFs graphene composite material |
| CN105845458A (en) * | 2016-05-06 | 2016-08-10 | 上海利物盛企业集团有限公司 | Graphene activated metal organic framework electrode material and preparation and applications thereof |
| CN106064052A (en) * | 2016-05-20 | 2016-11-02 | 南京邮电大学 | A kind of preparation method of MOFs/ Graphene adsorbing material |
Non-Patent Citations (1)
| Title |
|---|
| WEN-HUA LI等: ""Conductive Metal–Organic Framework Nanowire Array Electrodes for High-Performance Solid-State Supercapacitors"", 《ADVANCED FUNCTIONAL MATERIALS》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111084975A (en) * | 2019-12-25 | 2020-05-01 | 陕西科技大学 | Leather-based pressure sensor for recording walking track, preparation method and application |
| CN111084975B (en) * | 2019-12-25 | 2021-11-02 | 陕西科技大学 | Leather-based pressure sensor for recording walking track, preparation method and application |
| CN111155143A (en) * | 2020-01-07 | 2020-05-15 | 中国科学院化学研究所 | Preparation method of two-dimensional layered metal organic framework nano material |
| CN111155143B (en) * | 2020-01-07 | 2021-06-01 | 中国科学院化学研究所 | Preparation method of two-dimensional layered metal organic framework nano material |
| CN111253759A (en) * | 2020-03-27 | 2020-06-09 | 西安交通大学 | Preparation method of composite material based on metal organic framework and carbon nano tube and preparation method of device |
| CN113410461A (en) * | 2021-02-20 | 2021-09-17 | 西安理工大学 | Preparation method and application of self-supporting electrode MOFs/carbon paper composite material of lithium-sulfur battery |
| CN113235118A (en) * | 2021-05-17 | 2021-08-10 | 苏州大学 | Electrochemical synthesis method of conductive metal organic framework anode |
| CN113244961A (en) * | 2021-05-24 | 2021-08-13 | 上海师范大学 | Bimetallic CoCu-MOF visible light catalyst and preparation method and application thereof |
| CN114976015A (en) * | 2022-06-27 | 2022-08-30 | 巢湖学院 | Two-dimensional metal organic framework based composite electrode material, and preparation method and application thereof |
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Application publication date: 20191015 |