CN105839399A - Catalysis carbonization intumescent flame-retardant system and application thereof - Google Patents

Catalysis carbonization intumescent flame-retardant system and application thereof Download PDF

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Publication number
CN105839399A
CN105839399A CN201610196568.4A CN201610196568A CN105839399A CN 105839399 A CN105839399 A CN 105839399A CN 201610196568 A CN201610196568 A CN 201610196568A CN 105839399 A CN105839399 A CN 105839399A
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retardant system
flame
source
intumescent
carbonization
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吴亚容
周翔
马江涛
邢志奇
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Donghua University
National Dong Hwa University
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Donghua University
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention relates to a catalysis carbonization intumescent flame-retardant system and application thereof. The system comprises an acid source, a carbon source, a gas source and a char formation catalyst, wherein in the flame-retardant system, the mass percentage of the acid source is 15 to 30%, a mass ratio of the acid source to the gas source is 2-10: 1, a mass ratio of the acid source to the carbon source is 2-10: 1, and a mass ratio of the acid source to the char formation catalyst is 10-20: 1. The catalysis carbonization intumescent flame-retardant system is applied to flame-retardant after-finishing of a terylene fabric. The system does not contain halogen, accords with the development trend of low smoke and low toxicity of fire retardants and belongs to an environment-friendly flame-retardant system; and a finished product has better flame resistance, and a finished fabric has better flame resistance and molten drop resistance.

Description

A kind of catalysis carbonization Intumescent Retardant System and application thereof
Technical field
The invention belongs to finishing functions of textile fabrics field, particularly to one catalysis carbonization Intumescent Retardant System and application thereof.
Background technology
Terylene is the one that in synthetic fibers, consumption is maximum, is widely used in national defence, industrial cloth and each side of people's life. Terylene belongs to inflammability fiber, it is impossible to meet the requirement to fire resistance of some field, it need to be carried out flame treatment.Built The method of vertical endowing terylene anti-flammability be mostly by increase molten drop make simultaneously molten drop quickly drip with self-extinguishment and reach fire-retardant Effect, but the drippage of high-temperature molten, be easily caused secondary injury.If surface forms tight layer of charcoal when making fiber burn, Reduce fused mass drippage, be then to confer to the more preferable approach of terylene anti-flammability.
Intumescent Retardant System, with phosphorus, nitrogen for mainly comprising element, main plays a role by condensed phase is fire-retardant, can be when being heated Formed by fire proofing surface and expand carbon-coating.Intumescent Retardant System is used for the polymer of some charcoals that can not be heated, has obtained very Good flame retardant effect.
For reaching high flame resistance, the consumption of Intumescent Retardant System is the biggest.For improving Intumescent Retardant System flame retarding efficiency, By the catalysis carbonization by Nano filling or metallic compound, promote that Intumescent Retardant System is cross-linked into charcoal or catalytic polymerization Thing dehydrogenation-crosslinking-one-tenth charcoal is a new research direction.As there are some researches show, employing is made up of APP and tetramethylolmethane Intumescent Retardant System to polypropylene (PP) fire-retardant time, add in flame-retardant system a small amount of manganese, zinc, magnesium, aluminum etc. oxide, During the compound such as sulfate or borate, can further improve the oxygen index (OI) of fire-retardant PP, flame-retardant polymer can shape when burning Become more stable layer of charcoal；Metal halide such as FeCl3、NiCl2And CoCl2Etc. dramatically increasing acrylonitrile-butadiene-benzene second Neat coal amout after the burning of alkene/organo montmorillonite (ABS/OMT) nano composite material；Zinc compound and nanoclay add to Styrene-acrylonitrile (SAN) makes nano composite material, also dramatically increases material neat coal amout after combustion.
Summary of the invention
The technical problem to be solved is to provide a kind of catalysis carbonization Intumescent Retardant System and application, this expandable flame retardant System does not contains halogen, and meets fire retardant few cigarette, the development trend of low toxicity, belongs to environmental protection flame retardant system；Arrangement product fire resistance More preferably, the dacron after arrangement has good flame-retardant and anti-dripping.
A kind of catalysis carbonization Intumescent Retardant System of the present invention, described system includes: acid source, carbon source, source of the gas with become charcoal and be catalyzed Agent；Wherein, in flame-retardant system, the mass percent of acid source is 15-30%；Acid source is 2～10:1 with the mass ratio of source of the gas；Acid Source is 2～10:1 with the mass ratio of carbon source；Acid source is 10～20:1 with the mass ratio of char forming catalyst；System also has water.
Described acid source is ammonium phosphate, with the APP of silane, tripolycyanamide, polyurethane or epoxy resin modification, melamine Amine pyrophosphate or melamine polyphosphate.
Described carbon source is polyalcohols, the water polyacrylic acid of hydroxyl, the aqueous polyurethane of hydroxyl, having of hydroxyl Machine silicon modified polyurethane, the silicone-modified polyacrylate of hydroxyl, polyacrylate modified polyurethane, polyurethane-modified Polyacrylate, Polystyrene polyacrylate or triazines oligomer etc..
Described polyalcohols is tetramethylolmethane, Bis(pentaerythritol), tripentaerythritol, starch or sorbitol.
Described source of the gas is tripolycyanamide or melamine salt, dicyandiamide, guanidine, guanidinesalt or urea.
Described melamine salt is melamine cyanurate or boric acid tripolycyanamide；Described guanidinesalt is guanidine carbonate or sulfamic acid Guanidine.
Described char forming catalyst is the metallic compound of bivalence or multivalence, the silicon dioxide of micro-or nano size, titanium dioxide or 4A Molecular sieve.
The metallic compound of described bivalence or multivalence is Zn, Mg, Fe, Al, Ca, Ni, Mn, Zr, Cu, Ba, V, The oxide of Co, Mo and Cr, chloride, acetate, borate or sulfate.
A kind of application being catalyzed carbonization Intumescent Retardant System of the present invention, is applied to dacron flame-retardant after-finishing.
The method of described dacron flame-retardant after-finishing includes: each component in this flame-retardant system mixed by the way of grinding After Jun Yun, use hot melt, high temperature and high pressure method or support methods for dacron flame-retardant after-finishing.
Described lapping mode is ball milling, colloid mill or sand milling etc..
The present invention is raw materials used the most commercially.
Beneficial effect
(1) Intumescent Retardant System used by the present invention does not contains halogen, and meets fire retardant few cigarette, the development trend of low toxicity, belongs to ring Environment friendly flame-retardant system；
(2) present invention is to acid source, carbon source and the optimization of source of the gas proportioning in Intumescent Retardant System, more efficiently plays this system Fire retardation；
(3) present invention addition by char forming catalyst, improves arrangement product carbon left, reduces arrangement product HRR with total Heat release, arranges product fire resistance more preferable, and flame-proof treatment product burn without molten drop.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments be merely to illustrate the present invention and It is not used in restriction the scope of the present invention.In addition, it is to be understood that after having read the content that the present invention lectures, people in the art The present invention can be made various changes or modifications by member, and these equivalent form of values fall within the application appended claims equally and limited Scope.
Embodiment 1～12
In the ratio shown in table 1 by composition catalysis the acid source of carbonization Intumescent Retardant System, carbon source, source of the gas, char forming catalyst and Water joins grinding 4h in colloid mill, obtains the catalysis carbonization Intumescent Retardant System that milky is thick.
Table 1 is catalyzed carbonization Intumescent Retardant System proportioning
APP APP in table, PER tetramethylolmethane, MEL tripolycyanamide, MPP melamine pyrophosphate, The silane-modified APP of Si-APP, lower same.(what embodiment 12 tested is that melamine pyrophosphate is by sodium pyrophosphate With tripolycyanamide reaction preparation, source of the gas is included in.)
Comparative example 1～6
In the ratio shown in table 2, component acid source, carbon source, source of the gas and the water of composition Intumescent Retardant System is joined in colloid mill Grind 4h, obtain the Intumescent Retardant System that milky is thick.
Table 2 comparative example Intumescent Retardant System proportioning
Utilize embodiment 1～12 and comparative example 1～6 in Intumescent Retardant System carry out dacron flame-proof treatment.
1, dacron flame-proof treatment
Fabric: pure polyester knitting thing (grammes per square metre 110g/m2)
Flame-proof finishing process:
Hot melt: dacron pads the ground flame-retardant system (two leachings two are rolled, liquid carrying rate about 120%) → pre-made Baking (80 DEG C × 3min) → bake (180 DEG C × 3min).
2, the test of product fire resistance is arranged
2.1 limited oxygen index values (LOI)
Measure by " GB/T 5454-1997 textile combustion performance test oxygen index method ".
2.2 vertical combustion performances
Measure by " GB/T 5455-1997 textile combustion performance test normal beam technique ".
2.3 miniature calorimetric tests
Using miniature calorimeter, weigh sample about 5mg and be measured, mensuration atmosphere is air, temperature elevating range 75～750 DEG C, 1 DEG C/s of heating rate, gas flow rate 20mL/min.
Concrete measurement result
Table 3 uses hot melt that dacron carries out flame-proof treatment for comparative example 1～6 flame-retardant system, arranges product vertical burn flammability Energy and oxygen index (OI).
Table 3 comparative example arranges product vertical combustion performance and oxygen index (OI)
In table 3, the result of the test of 6 comparative examples understands, and by the optimization to constituent mass ratio each in system, can make these not Intumescent Retardant System containing catalyst more efficiently plays fire retardation.When total consumption is 25%, comparative example 6 effect is optimum.
Table 4 uses hot melt that dacron carries out flame-proof treatment for embodiment 2 and embodiment 9 flame-retardant system, and the product that arrange hang down Straight combustibility and oxygen index (OI).
Table 4 embodiment arranges product vertical combustion performance and oxygen index (OI)
As shown in Table 4, the flame-retardant system prepared by the inventive method in the way of Final finishing for dacron is fire-retardant can be effective Improve its anti-flammability, can well suppress molten drop.
Table 5 for embodiment 1～12 and comparative example 6 flame-retardant system use hot melt that dacron is carried out flame-proof treatment, arrange Product miniature calorimetry result.
Table 5 arranges product miniature calorimetric test result
From table 5 comparative example 6, Intumescent Retardant System is used for dacron flame-proof treatment can reduce fabric HRC, PHRR and THR, effectively reduces fire risk；Embodiment 1～12 is compared with comparative example 6 and understands, add into charcoal and urge After agent, HRC, PHRR and THR of arranging product reduce further, and carbon left significantly increases, and illustrate that being catalyzed carbonization makees With significantly.

Claims (10)

1. a catalysis carbonization Intumescent Retardant System, described system includes: acid source, carbon source, source of the gas and char forming catalyst；Wherein, In flame-retardant system, the mass percent of acid source is 15-30%；Acid source is 2～10:1 with the mass ratio of source of the gas；Acid source and carbon source Mass ratio is 2～10:1；Acid source is 10～20:1 with the mass ratio of char forming catalyst.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 1, it is characterised in that described acid source is ammonium phosphate Or APP, melamine pyrophosphate or the tripolycyanamide with silane, tripolycyanamide, polyurethane or epoxy resin modification Quadrafos.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 1, it is characterised in that described carbon source is polyhydric alcohol Class, the water polyacrylic acid of hydroxyl, the aqueous polyurethane of hydroxyl, the organic silicon modified polyurethane of hydroxyl, containing hydroxyl The silicone-modified polyacrylate of base, polyacrylate modified polyurethane, polyurethane-modified polyacrylate, polystyrene Modified polyacrylate or triazines oligomer.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 3, it is characterised in that described polyalcohols is season Penta tetrol, Bis(pentaerythritol), tripentaerythritol, starch or sorbitol.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 1, it is characterised in that described source of the gas is melamine Amine or melamine salt, dicyandiamide, guanidine, guanidinesalt or urea.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 5, it is characterised in that described melamine salt is Melamine cyanurate or boric acid tripolycyanamide；Described guanidinesalt is guanidine carbonate or Guanidine Sulfamate 99.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 1, it is characterised in that described char forming catalyst is Bivalence or the metallic compound of multivalence, silicon dioxide, titanium dioxide or 4A molecular sieve.
A kind of catalysis carbonization Intumescent Retardant System the most according to claim 7, it is characterised in that described bivalence or multivalence Metallic compound is the oxidation of Zn, Mg, Fe, Al, Ca, Ni, Mn, Zr, Cu, Ba, V, Co, Mo and Cr Thing, chloride, acetate, borate or sulfate.
9. the application of a catalysis carbonization Intumescent Retardant System as claimed in claim 1, it is characterised in that be applied to terylene and knit Thing flame-retardant after-finishing.
A kind of application being catalyzed carbonization Intumescent Retardant System the most according to claim 9, it is characterised in that described terylene is knitted The method of thing flame-retardant after-finishing includes: by grinding by the way of by each component mix homogeneously in flame-retardant system after, use hot melt Method, high temperature and high pressure method or support methods are used for dacron flame-retardant after-finishing.
CN201610196568.4A 2016-03-31 2016-03-31 Catalysis carbonization intumescent flame-retardant system and application thereof Pending CN105839399A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106626656A (en) * 2017-01-09 2017-05-10 杭州湘隽纺织阻燃科技有限公司 Flame-retardant automobile trim fabric composite and application thereof
CN106930093A (en) * 2016-12-16 2017-07-07 中山康诺德新材料有限公司 A kind of fabric coating efficient halogen-free environmental protection fire retarding agent and preparation method thereof
CN109097981A (en) * 2018-08-07 2018-12-28 浙江彩蝶实业有限公司 A kind of production technology of reaction-type flame-retarding dacron
CN110130092A (en) * 2019-05-25 2019-08-16 北京化工大学 A kind of method of expanding fire retardant flame-retardant after-finishing improved polypropylene non-woven fabrics
CN112981976A (en) * 2021-02-06 2021-06-18 李金赛 Fireproof tent fabric and preparation method thereof
CN115613353A (en) * 2022-09-22 2023-01-17 江苏嘉通能源有限公司 Preparation method of self-extinguishing flame-retardant polyester-nylon fabric

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102392356A (en) * 2011-07-07 2012-03-28 公安部四川消防研究所 Manufacturing technique of wash-resistant and flame-retardant blended fabric
CN104532588A (en) * 2014-12-24 2015-04-22 什邡市太丰新型阻燃剂有限责任公司 Composite intumescent flame retardant and preparation method thereof
CN105256531A (en) * 2015-11-05 2016-01-20 辽宁石油化工大学 Polyester fabric processing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102392356A (en) * 2011-07-07 2012-03-28 公安部四川消防研究所 Manufacturing technique of wash-resistant and flame-retardant blended fabric
CN104532588A (en) * 2014-12-24 2015-04-22 什邡市太丰新型阻燃剂有限责任公司 Composite intumescent flame retardant and preparation method thereof
CN105256531A (en) * 2015-11-05 2016-01-20 辽宁石油化工大学 Polyester fabric processing method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
冯庆立: ""涤纶织物的阻燃及抗熔滴研究"", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *
曾军等: "增效剂在涤纶膨胀型阻燃涂层中的应用", 《印染》 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106930093A (en) * 2016-12-16 2017-07-07 中山康诺德新材料有限公司 A kind of fabric coating efficient halogen-free environmental protection fire retarding agent and preparation method thereof
CN106626656A (en) * 2017-01-09 2017-05-10 杭州湘隽纺织阻燃科技有限公司 Flame-retardant automobile trim fabric composite and application thereof
CN106626656B (en) * 2017-01-09 2019-03-01 杭州湘隽阻燃科技有限公司 A kind of flame retardant automotive inner decoration facing compound and its application
CN109097981A (en) * 2018-08-07 2018-12-28 浙江彩蝶实业有限公司 A kind of production technology of reaction-type flame-retarding dacron
CN110130092A (en) * 2019-05-25 2019-08-16 北京化工大学 A kind of method of expanding fire retardant flame-retardant after-finishing improved polypropylene non-woven fabrics
CN112981976A (en) * 2021-02-06 2021-06-18 李金赛 Fireproof tent fabric and preparation method thereof
CN115613353A (en) * 2022-09-22 2023-01-17 江苏嘉通能源有限公司 Preparation method of self-extinguishing flame-retardant polyester-nylon fabric
CN115613353B (en) * 2022-09-22 2024-03-19 江苏嘉通能源有限公司 Preparation method of self-extinguishing flame-retardant polyester-nylon fabric

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Application publication date: 20160810