CN105838444A - Fluidized bed gasification furnace bottom slag cooling conveying system - Google Patents

Fluidized bed gasification furnace bottom slag cooling conveying system Download PDF

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Publication number
CN105838444A
CN105838444A CN201610258956.0A CN201610258956A CN105838444A CN 105838444 A CN105838444 A CN 105838444A CN 201610258956 A CN201610258956 A CN 201610258956A CN 105838444 A CN105838444 A CN 105838444A
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Prior art keywords
slag
cooling
lock hopper
water
cooled
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CN201610258956.0A
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CN105838444B (en
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邱玉坤
张磊
岳公强
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Qingdao Songling Power Environmental Equipment Co Ltd
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Qingdao Songling Power Environmental Equipment Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56Apparatus; Plants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

The invention relates to a fluidized bed gasification furnace bottom slag cooling conveying system which comprises a primary water-cooling lock hopper, wherein a slag outlet of the primary water-cooling lock hopper is connected with a slag inlet of a secondary water-cooling lock hopper through a first high-temperature cut-off valve; a slag outlet of the secondary water-cooling lock bucket is provided with a first feeding machine; a slag inlet channel connected between the first feeding machine and a slag inlet of a roller slag cooling machine is sequentially provided with a second high-temperature cut-off valve and a corrugated expansion joint; a negative-pressure air port on the secondary water-cooling lock bucket is connected with an air box through a first induced air pipe; a negative-pressure air pipe connected between a slag inlet end and a slag outlet end of the roller slag cooling machine is connected with the air box through a second induced air pipe; the air box is connected with a bag-type dust collector through a dust extraction pipe; and a dust discharge port of the bag-type dust collector is provided with a second feeding machine and connected to a conveyer through an ash discharge pipe. The system has the advantages of simple and practical structure, higher reliability, favorable slag cooling and sealing effects, energy saving and environment friendliness, and can well solve the problems in the existing fluidized bed gasification furnace slag discharge system.

Description

A kind of fluidized gasification bottom slag cooling conveying system
Technical field
The invention belongs to boiler bottom slag processing technology field, be specifically related to a kind of fluidized gasification bottom slag cooling conveying system.
Background technology
Through semicentennial development, the production of energy system that China defines based on coal, provides multiple forms of energy to complement each other, the consumption of coal accounts for about 70% that total energy consumes, traditional direct combustion method is mainly continued to use in the utilization of coal for a long time, not only efficiency is low, and gives off substantial amounts of flue dust, sulfur dioxide and nitrogen oxides.And natural gas is not only clean relative to coal and utilizes conveniently, additionally the carbon dioxide of gas utilization discharge is the half of coal utilization.Along with the environmental Kuznets Curves of increasingly stringent discharges global restriction, the yield of natural gas is far from meeting the demand of people, and therefore, potentiality and the competitiveness of Coal Gasification display, modern Coal Gasification Technology develops quickly, and technical advance and maturity are all beyond example.
Gasification furnace is the abbreviation of gas generator, is the production equipment that coal is converted into coal gas, can be divided into several forms such as fixed-bed gasification furnace, fluidized-bed gasification furnace, airflow bed gasification furnace according to gasification furnace type.Wherein, fluidized gasification technology is more advanced, compared to other gasification technologies, its main advantage is bigger fuel flexibility, can be gasified all types of coal and cinder product, including cheaper, it is more easy to the low-quality obtained, high ash, hydrogenous coal, and reproducible biomass etc., but for a long time, because the characteristic of fluidized-bed gasification furnace, its furnace pressure is high, and the grey quantity of slag produced after Coal Gasification is big, temperature is high and is difficult to seal, therefore deslagging problem fails to be well solved all the time.
Existing fluidized-bed gasification furnace major part uses wet slag removal system, submerged slag conveyor is i.e. used to carry out bottom ash cooling and be delivered to slag storehouse, in this course, lime-ash falls directly in the tank of submerged slag conveyor and cools down, not only wasting substantial amounts of water resource, lime-ash heat is wasted simultaneously, it is impossible to obtain efficient recovery, and the lime-ash after directly contacting with water loses activity, it is impossible to comprehensively utilize again;Sub-fraction fluidized-bed gasification furnace is separately had to have employed dry bottom ash handling system, water-cooled auger is used to carry out lime-ash cooling and conveying, but owing to slag from gasifying furnace amount is compared with big and water-cooled flood dragon heat exchange area is limited, structural stability is poor, heat exchange is exerted oneself little, therefore its heat transfer effect does not reaches on-the-spot service requirement, using effect is the most not fully up to expectations.Therefore, the lime-ash processing mode of fluidized-bed gasification furnace is this skilled person's problem demanding prompt solution.
Summary of the invention
It is an object of the invention to solve above-mentioned technical problem and a kind of fluidized gasification bottom slag cooling conveying system is provided.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of fluidized gasification bottom slag cooling conveying system, the slag notch including one-level water-cooled lock hopper, one-level water-cooled lock hopper connects through the slag inlet of the first high temperature cut-off valve with two-stage water-cooling lock hopper;The slag notch of two-stage water-cooling lock hopper sets the first batcher, and the slag input passage that the first batcher connects with barrel slag cooler slag inlet sets the second high temperature cut-off valve, expansion bellow successively;Negative pressure air port the first induced duct in two-stage water-cooling lock hopper connects bellows, the negative-pressure air duct that the slag input end of barrel slag cooler is connected with slag output end is connected with bellows through the second induced duct, bellows connect sack cleaner by taking out dirt pipe, and the ash discharging hole of sack cleaner sets the second batcher and is connected to conveyer by ash releasing tube.
One-level water-cooled lock hopper, two-stage water-cooling lock hopper are jacket type can-like structure, chuck internal circulation cooling water, tank interior circulation lime-ash.
It is additionally provided with at least one middle water-cooled lock hopper between one-level water-cooled lock hopper and two-stage water-cooling lock hopper, middle water-cooled lock hopper sets negative pressure air port and is connected to bellows through an induced duct.
First high temperature cut-off valve is Pneumatic high temperature gate valve, and the second high temperature cut-off valve is electric high-temperature gate valve;First batcher is that water-cooled locks gas batcher, and the second batcher is electric lock pneumatic batcher.
The dust-exhausting port of sack cleaner connects downtake pipe, and downtake pipe connects air-introduced machine, and air-introduced machine connects second exhaust pipe.
Conveyer is the one of belt conveyor, drag conveyor, bucket chain conveyor.
Barrel slag cooler is jacket type barrel slag cooler, film-type wall-type barrel slag cooler, the one of multitube barrel slag cooler.
Present system features simple structure is practical, and reliability is higher, cold slag, good sealing effect, energy-conserving and environment-protective, can solve the problem that current fluidized-bed gasification furnace dreg removing system exists, and has great practice and produces meaning.
Accompanying drawing explanation
The structural representation of the fluidized gasification bottom slag cooling conveying system that Fig. 1 provides for the embodiment of the present invention:
In figure: 1 is one-level water-cooled lock hopper, and 2 is the first high temperature cut-off valve, and 3 is two-stage water-cooling lock hopper, and 4 is the first batcher, 5 is the second high temperature cut-off valve, and 6 is expansion bellow, and 7 is barrel slag cooler, 8 is the second induced duct, and 9 is bellows, and 10 is the second induced duct, 11 for taking out dirt pipe, and 12 is sack cleaner, and 13 is downtake pipe, 14 is air-introduced machine, and 15 is second exhaust pipe, and 16 is the second batcher, 17 is ash releasing tube, and 18 is negative-pressure air duct, and 19 is conveyer.
Detailed description of the invention
Below, in conjunction with example, substantive distinguishing features and the advantage of the present invention are further described, but the invention is not limited in listed embodiment.
Shown in Figure 1, a kind of fluidized gasification bottom slag cooling conveying system, the two-stage water-cooling lock hopper 3, the slag notch of two-stage water-cooling lock hopper that connect through the slag notch of the first high temperature cut-off valve 2 with one-level water-cooled lock hopper 1 including one-level water-cooled lock hopper 1, slag inlet set and set the second high temperature cut-off valve 5, expansion bellow 6 successively on the slag input passage that first batcher the 4, first batcher 4 connects with barrel slag cooler 7 slag inlet;Negative pressure air port the first induced duct 8 in two-stage water-cooling lock hopper connects bellows 9, the negative-pressure air duct 18 that the slag input end of barrel slag cooler is connected with slag output end is connected with bellows 9 through the second induced duct 10, bellows 9 connect sack cleaner 12 by taking out dirt pipe 11, and the ash discharging hole of sack cleaner sets the second batcher 16 and is connected to conveyer 19 by ash releasing tube 17.
Wherein, one-level water-cooled lock hopper, two-stage water-cooling lock hopper are jacket type can-like structure, chuck internal circulation cooling water, tank interior circulation lime-ash.
Wherein, the first high temperature cut-off valve is Pneumatic high temperature gate valve, and the second high temperature cut-off valve is electric high-temperature gate valve;First batcher is that water-cooled locks gas batcher, and the second batcher is electric lock pneumatic batcher.
Wherein, the dust-exhausting port of sack cleaner connects downtake pipe, and downtake pipe connects air-introduced machine, and air-introduced machine connects second exhaust pipe.
Below, it is as follows that the present invention is described in detail:
The top of one-level water-cooled lock hopper is connected with fluidized-bed gasification furnace burner hearth by Pneumatic high temperature gate valve, its closing primarily serving the purpose of lime-ash and precooling, and bottom is connected with Pneumatic high temperature gate valve by flange and bolt and is switched to two-stage water-cooling lock hopper.
Because gasification furnace gasification does not allow contact with outside air, so it is unaffected for ensureing the gasification of gasification furnace, during system work, upper and lower two the Pneumatic high temperature gate valves of one-level water-cooled lock hopper can not be opened simultaneously, the effect one that two-stage water-cooling lock hopper plays is to precool lime-ash, two is to play sealing process, two-stage water-cooling lock hopper bottom is attached with water-cooled lock gas batcher and electric high-temperature gate valve by flange and bolt, and electric high-temperature gate valve is in order to close down the slag input of barrel slag cooler.
Water-cooled lock gas batcher itself has water cooling function, can be high temperature resistant, the even feeding of lime-ash can be realized, and play certain every pressure effect, make the lime-ash pressure in secondary latch bucket will not be passed directly into barrel slag cooler, therefore lime-ash lag cooler will not coking or blocking, barrel slag cooler also will not produce Lou slag phenomenon.
Electric high-temperature gate valve bottom arranges expansion bellow, and in order to absorb the thermal expansion amount of two-stage water-cooled lock hopper, expansion bellow lower end is connected with barrel slag cooler;nullRed-hot lime-ash is cooled down by barrel slag cooler by the form of indirect water-cooling,And lime-ash is carried to slag notch from slag inlet,Lime-ash is after supercooling,Drain into the belt conveyor being connected with barrel slag cooler and transport boiler room,Enter at barrel slag cooler、Slag output end is respectively equipped with a negative-pressure air duct,And be connected with the second induced duct after converging into a road,Air port at one is had above secondary latch bucket,And be connected with the second induced duct,Second induced duct and the second induced duct are all connected to bellows top,Bellows use rustless steel to make,Can tolerate higher temperature,Effect is to be mixed by two-way dusty gas,And from bellows bottom, mixed dusty gas is caused sack cleaner by taking out dirt pipe,Because high-temperature gas density is little,And bellows use the arrangement form of top air intake bottom air-out,Therefore be easy to high-temperature dusty gas and the most sufficiently mix,Sack cleaner effect is to filter gas,Dusty gas is made to be purified,Electric lock pneumatic batcher it is connected to below the ash bucket of sack cleaner,The dust etc. that can be collected by sack cleaner uniformly discharges ash bucket,Electric lock pneumatic batcher is connected with ash releasing tube,The ash that ash releasing tube is discharged is connected to belt conveyor and transports boiler room.And the gas after sack cleaner filters passes sequentially through downtake pipe, air-introduced machine, second exhaust pipe etc. and drains into air, air-introduced machine provides the kinetic energy in whole gas flow.
During system work, one-level water-cooled lock hopper, two-stage water-cooling lock hopper, water-cooled and electric lock pneumatic batcher, barrel slag cooler are all passed through cooling water, water source is retrieved from steam generator system and condenses water, can introduce from low-temperature level low-pressure heater, returns high-temperature level low-pressure heater or oxygen-eliminating device.
nullDuring gasification furnace burner hearth deslagging,Above one-level water-cooled lock hopper, Pneumatic high temperature gate valve is opened,And lower section Pneumatic high temperature gate valve is closed,900 DEG C of red-hot lime-ash enter one-level water-cooled lock hopper and store and precool,About 800 DEG C can be cooled the temperature to,When in one-level water-cooled lock hopper, lime-ash is full of,The Pneumatic high temperature gate valve on its top is closed,Bottom Pneumatic high temperature gate valve is then opened,Lime-ash enters to two-stage water-cooling lock hopper from one-level water-cooled lock hopper,And carried out the second time precooling of lime-ash by two-stage water-cooling lock hopper simultaneously,About 700 DEG C can be cooled the temperature to,The electric high-temperature gate valve now arranged below two-stage water-cooling lock hopper is opened,Lime-ash feeds into barrel slag cooler equably by water-cooled lock gas batcher,Lime-ash can be cooled to less than 80 DEG C by barrel slag cooler,And it is expelled to belt conveyor by its slag-drip opening,Work and so forth,Just the continuous discharging slag of gasification furnace can be realized.
Because the lime-ash in one-level water-cooled lock hopper, two-stage water-cooling lock hopper exists higher malleation, therefore in order to make lime-ash be unlikely to present spray regime to cause lag cooler that leakage slag phenomenon occurs, the present invention is provided above negative pressure air port in two-stage water-cooling lock hopper, this negative pressure air port is connected by the second induced duct with bellows top, lock hopper internal pressure can be greatly reduced by negative pressure wind, thus alleviating the seal pressure of barrel slag cooler, negative pressure wind also functions to certain cooling effect simultaneously.
The slag input end of barrel slag cooler and slag output end are provided with negative-pressure air duct and converge into a road, in order to cold slag machine drum body is internally formed negative pressure state, thus lime-ash will not produce leakage slag phenomenon at the place of being association of activity and inertia of barrel slag cooler, slag input end negative pressure wind temperature is higher, and slag output end negative pressure wind temperature is relatively low.
Preferably, two sections of negative-pressure air ducts are respectively provided with manually or electrically air door, the negative pressure wind flow in scalable every section negative-pressure air duct, reach to adjust the effect of whole negative pressure wind temperature.
The tolerable temperature of bags in bag-type dust remover is 250 DEG C, but the dusty gas temperature about 300 DEG C got rid of in secondary latch bucket, already more than the tolerance of sack cleaner, and lime-ash can be cooled to 80 DEG C because of itself by barrel slag cooler, the negative pressure wind of its slag input end and slag output end is all from surrounding, therefore the dusty gas temperature after barrel slag cooler two ends negative pressure wind converges is about 100-120 DEG C, therefore when dusty gas herein also causes bellows top with the dusty gas in secondary latch bucket after inner bellows mixes, dusty gas temperature can be down to less than 200 DEG C, fully meet the service requirement of sack cleaner, so that the reliability of this system is substantially improved, life-span significantly extends.
When the mixed gas in bellows is directed to sack cleaner from bellows bottom, granule dust big, heavy, owing to the effect of gravity settles down, fall into ash bucket, gas containing relatively fine dust is when by cloth bag, dust also can be by by detention, gas is made to be purified, purified gas passes sequentially through downtake pipe, air-introduced machine, second exhaust pipe etc. and drains in atmospheric environment, the dust being filtered then electric lock pneumatic batcher and ash releasing tube by ash bucket bottom drains into belt conveyor, and environment will not be caused any pollution by whole process.In lime-ash cooling procedure, the heat of the lime-ash water that is cooled fully absorbs, and by heat recovery to steam generator system, thus can improve the thermal efficiency of boiler, reduces boiler coal consumption, energy-conserving and environment-protective.
It should be noted that in the present invention, the form of described barrel slag cooler can be multiple, according to the difference of exerting oneself of system requirements, can use the forms such as jacket type, film-type wall-type, multitube;
In the present invention, described belt conveyor is only a kind of embodiment, it is possible to be modified to embedded scraper transporter, bucket chain conveyor or other conveying equipments according to practical situation.
In the present invention, described two-stage water-cooled lock hopper is only a kind of preferred embodiment, three grades are arranged also dependent on on-site actual situations, as being connected with at least one middle water-cooled lock hopper also by the Pneumatic high temperature gate valve being connected between one-level water-cooled lock hopper and two-stage water-cooling lock hopper, water-cooled lock hopper in the middle of one-level is coupled together with two-stage water-cooling lock hopper, form the cold lock hopper of tertiary effluent, wherein, set negative pressure air port and be connected to bellows through an induced duct in middle water-cooled lock hopper, thus realize multistage layout water-cooled lock hopper and carry out multistage cooling, thus reach preferably to cool down the effect of slag.
Compared with existing gasification furnace slag removing system, the present invention has an advantage highlighted below:
1, the present invention not only saves substantial amounts of water resource, can be fully absorbed by lime-ash heat simultaneously, improves boiler thermal output, reduces coal consumption;
2, in work process of the present invention lime-ash all the time with cooling water indirect heat exchange, maintain the comprehensive utilization of the activity of lime-ash, beneficially lime-ash;
3, the present invention configures water-cooled lock gas batcher, therefore can will not produce the accidents such as stifled slag, coking by lime-ash uniform discharge to barrel slag cooler;
4, the present invention uses barrel slag cooler to substitute water-cooled auger, and heat exchange area increases, and cold slag is exerted oneself increases, can meet scene actual motion requirement;
5, by the common effect of the parts such as negative-pressure air duct, bellows, sack cleaner so that on-the-spot airborne dust, barrel slag cooler leakage slag phenomenon no longer occur, and have reached the requirement carried out production strictly in line with rules and regulations;
6, by adding bellows in whole system, significantly extend the service life of sack cleaner, improve the reliability of whole dreg removing system;
7, by the filtration of sack cleaner, dusty gas can be filtered to the gas reaching environmental protection standard, will not be to environment.
The above is only the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (7)

1. a fluidized gasification bottom slag cooling conveying system, it is characterised in that include one-level water-cooled lock hopper, the slag notch of one-level water-cooled lock hopper connects through the slag inlet of the first high temperature cut-off valve with two-stage water-cooling lock hopper;The slag notch of two-stage water-cooling lock hopper sets the first batcher, and the slag input passage that the first batcher connects with barrel slag cooler slag inlet sets the second high temperature cut-off valve, expansion bellow successively;Negative pressure air port the first induced duct in two-stage water-cooling lock hopper connects bellows, the negative-pressure air duct that the slag input end of barrel slag cooler is connected with slag output end is connected with bellows through the second induced duct, bellows connect sack cleaner by taking out dirt pipe, and the ash discharging hole of sack cleaner sets the second batcher and is connected to conveyer by ash releasing tube.
Fluidized gasification bottom slag cooling conveying system the most according to claim 1, it is characterised in that one-level water-cooled lock hopper, two-stage water-cooling lock hopper are jacket type can-like structure, chuck internal circulation cooling water, tank interior circulation lime-ash.
Fluidized gasification bottom slag cooling conveying system the most according to claim 1 or claim 2, it is characterized in that, it is additionally provided with at least one middle water-cooled lock hopper between one-level water-cooled lock hopper and two-stage water-cooling lock hopper, middle water-cooled lock hopper sets negative pressure air port and is connected to bellows through an induced duct.
Fluidized gasification bottom slag cooling conveying system the most according to claim 1 or claim 2, it is characterised in that the first high temperature cut-off valve is Pneumatic high temperature gate valve, the second high temperature cut-off valve is electric high-temperature gate valve;First batcher is that water-cooled locks gas batcher, and the second batcher is electric lock pneumatic batcher.
The most according to claim 4, fluidized gasification bottom slag cooling conveying system, it is characterised in that the dust-exhausting port of sack cleaner connects downtake pipe, downtake pipe connects air-introduced machine, and air-introduced machine connects second exhaust pipe.
6. according to fluidized gasification bottom slag cooling conveying system described in claim 1 or 5, it is characterised in that conveyer is the one of belt conveyor, drag conveyor, bucket chain conveyor.
Fluidized gasification bottom slag cooling conveying system the most according to claim 6, it is characterised in that barrel slag cooler is jacket type barrel slag cooler, film-type wall-type barrel slag cooler, the one of multitube barrel slag cooler.
CN201610258956.0A 2016-04-25 2016-04-25 A kind of fluidized gasification bottom slag cooling conveying system Active CN105838444B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110562934A (en) * 2019-09-29 2019-12-13 武汉青江化工黄冈有限公司 Dry-process slag-discharging cleaning device and method for pyrite-based sulfuric acid production

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Publication number Priority date Publication date Assignee Title
JPH09125076A (en) * 1995-11-01 1997-05-13 Mitsubishi Heavy Ind Ltd Slag discharger
CN202369557U (en) * 2011-12-22 2012-08-08 太原重工股份有限公司 Deslagging device for ash agglomeration gasification furnace
CN205710608U (en) * 2016-04-25 2016-11-23 青岛松灵电力环保设备有限公司 A kind of fluidized gasification bottom slag cooling conveying system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09125076A (en) * 1995-11-01 1997-05-13 Mitsubishi Heavy Ind Ltd Slag discharger
CN202369557U (en) * 2011-12-22 2012-08-08 太原重工股份有限公司 Deslagging device for ash agglomeration gasification furnace
CN205710608U (en) * 2016-04-25 2016-11-23 青岛松灵电力环保设备有限公司 A kind of fluidized gasification bottom slag cooling conveying system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110562934A (en) * 2019-09-29 2019-12-13 武汉青江化工黄冈有限公司 Dry-process slag-discharging cleaning device and method for pyrite-based sulfuric acid production
CN110562934B (en) * 2019-09-29 2023-06-30 武汉青江化工黄冈有限公司 Dry-method slag discharging and cleaning device and method for pyrite acid making

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